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MSDS Material Safety Data Sheet
CAS

700-12-9
287-92-3
109-66-0
109-67-1
110-82-7
107-83-5
488-23-3
592-41-6
693-89-0
108-87-2
591-76-4
142-82-5
592-76-7
1678-91-7
592-27-8
108-88-3
95-47-6
135-98-8
110-54-3
111-65-9
111-66-0
696-29-7
3221-61-2
111-84-2
124-11-8
3178-22-1
871-83-0
124-18-5
872-05-9
1120-21-4
112-40-3
493-01-6
71-43-2
100-41-4
98-82-8
526-73-8

File Name: varianinc_com---CP299103.asp
                                                                             MATERIAL SAFETY DATA SHEET
MANUFACTURER Varian Instruments 鈥? Middelburg
ADDRESS Herculesweg 8
4338 PL Middelburg, Netherlands

PHONE 31.118.67100 MSDS Number: 1002-299103 Rev. 0
EMERGENCY PHONE 1.800.424.9300 鈥? CHEMTREC USA Date: November 18, 2002
FAX 31.118.633118 Prepared by: Corporate EH&S

SECTION 1: MATERIAL IDENTIFICATION
Product Name: PIONA mix - Testmix CP299103
Synonyms: Hydrocarbon mixture.

SECTION 2: COMPOSITION
An ampoule/vial containing the following:
Concentration NTP IARC
Component CAS Number (Weight %) Carcinogen Status Carcinogen Status
1,2,3,4,5,-Pentamethylbenzene 700-12-9 2.0% not listed not listed
Cyclopentane 287-92-3 2.0% not listed not listed
n-Pentane 109-66-0 1.0% not listed not listed
Pentene-1 109-67-1 1.0% not listed not listed
Cyclohexane 110-82-7 3.9% not listed not listed
2-Methylpentane 107-83-5 3.9% not listed not listed
1,2,3,4,-Tetramethylbenzene 488-23-3 2.0% not listed not listed
Hexene-1 592-41-6 1.5% not listed not listed
1-Methyl-1-cyclopentene 693-89-0 1.5% not listed not listed
Methylcyclohexane 108-87-2 3.9% not listed not listed
2-Methylhexane 591-76-4 1.0% not listed not listed
n-Heptane 142-82-5 3.9% not listed not listed
Heptene-1 592-76-7 3.9% not listed not listed
Ethylcyclohexane 1678-91-7 4.9% not listed not listed
2-Methylheptane 592-27-8 1.0% not listed not listed
Toluene 108-88-3 2.0% not listed not listed
o-Xylene 95-47-6 2.0% not listed not listed
sec-Butylbenzene 135-98-8 2.0% not listed not listed
n-Hexane 110-54-3 3.9% not listed not listed
n-Octane 111-65-9 4.9% not listed not listed
Octene-1 111-66-0 3.9% not listed not listed
Isopropylcyclohexane 696-29-7 4.9% not listed not listed
2-Methyloctane 3221-61-2 1.0% not listed not listed
n-Nonane 111-84-2 4.9% not listed not listed
Nonene-1 124-11-8 3.9% not listed not listed
tert-Butylcyclohexane 3178-22-1 3.9% not listed not listed
2-Methylnonane 871-83-0 1.0% not listed not listed
n-Decane 124-18-5 3.9% not listed not listed
Decene-1 872-05-9 2.9% not listed not listed
n-Undecane 1120-21-4 3.9% not listed not listed
n-Dodecane 112-40-3 3.9% not listed not listed
cis-Decaline 493-01-6 2.0% not listed not listed
Benzene 71-43-2 2.0% listed* listed*
Ethylbenzene 100-41-4 2.0% not listed listed**
Isopropylbenzene 98-82-8 2.0% not listed not listed
1,2,3,-Trimethylbenzene 526-73-8 2.0% not listed not listed

*Listed as a known human carcinogen by NTP and IARC.
**IARC: Group 2B - Possibly carcinogenic to humans.

WARNING: This product contains Benzene [CAS# 71-43-2] and Toluene [CAS# 108-88-3], chemicals known to the State of
California to cause cancer and birth defects or other reproductive harm.




MSDS# 1002-299103 Revision 0 Effective Date 11/18/02 Page 1 of 5
SECTION 3: HAZARD IDENTIFICATION
Emergency Overview: Colorless, extremely flammable liquid. May cause blood abnormalities. May cause reproductive and fetal
effects. Cancer hazard. May cause central nervous system effects. Harmful or fatal if swallowed. Aspiration hazard if swallowed.
Can enter lungs and cause damage. Causes eye and skin irritation. Causes digestive and respiratory tract irritation. Blood, central
nervous system, eyes, bone marrow, immune system.
Potential Health Effects
Inhalation: Causes respiratory tract irritation. May cause adverse central nervous system effects including headache, convulsions,
and possible death. May cause drowsiness, unconsciousness, and central nervous system depression. Central nervous system
effects may include confusion, ataxia, vertigo, tinnitus, weakness, disorientation, lethargy, drowsiness, and finally coma. Exposure
may lead to irreversible bone marrow injury. Exposure may lead to aplastic anemia. May be absorbed through the lungs.

Ingestion: Aspiration hazard. May cause central nervous system depression, characterized by excitement, followed by headache,
dizziness, drowsiness, and nausea. Advanced stages may cause collapse, unconsciousness, coma and possible death due to
respiratory failure. May cause effects similar to those for inhalation exposure. Aspiration of material into the lungs may cause
chemical pneumonitis, which may be fatal.

Skin Contact: Causes moderate skin irritation. May be absorbed through the skin in harmful amounts. Direct contact with the liquid
may cause erythema (redness) and vesiculation (blistering). Prolonged or repeated contact has been associated with the
development of a dry scaly dermatitis or with secondary infections.

Eye Contact: Causes severe eye irritation. May cause slight transient injury.

Carcinogen Status: Benzene is listed as a known human carcinogen by the NTP and IARC.
Ethylbenzene is listed as possibly carcinogenic to humans by the IARC.
Note : The toxicological properties of this mixture have not been thoroughly investigated.
SECTION 4: FIRST AID INFORMATION
Inhalation: Get medical attention immediately. Remove to fresh air. If breathing is difficult, give oxygen. Do NOT use mouth-to-
mouth resuscitation. If breathing has ceased apply artificial respiration using oxygen and a suitable mechanical device such as a
bag and a mask.
Ingestion: If swallowed, vomiting may occur spontaneously, but DO NOT INDUCE. If vomiting occurs, keep head below hips to
help prevent aspiration. If person is unconscious, turn head to side. Get medical attention immediately. Never give anything by
mouth to an unconscious person.
Skin Contact: In case of contact, immediately flush skin with plenty of soap and water for at least 15 minutes. Remove
contaminated clothing and shoes. Wash clothing before reuse. Get medical aid if irritation develops or persists.
Eye Contact: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical
aid. Do NOT allow victim to rub or keep eyes closed.

SECTION 5: FIRE-FIGHTING INFORMATION
Fire: Flash point (closed cup): No data for liquid mixture
Autoignition temperature: No data for liquid mixture
Flammable limits in air % by volume: No data for liquid mixture
NFPA Rating: health-2; flammability-3; reactivity-0
Explosion: Above flash point, vapor-air mixtures are explosive. Vapors can flow along surfaces to distant ignition source and
flash back. Sealed containers may rupture when heated. Contact with strong oxidizers may cause fire. Sensitive to static
discharge.
Fire Extinguishing Media: Dry chemical, foam or carbon dioxide. Water may be ineffective. Water spray may be used to keep fire
exposed containers cool, dilute spills to nonflammable mixtures, protect personnel attempting to stop leak and disperse vapors.

SECTION 6: ACCIDENTAL RELEASE MEASURES
Use proper personal protective equipment as indicated in Section 8. Ventilate area of leak or spill. Remove all sources of ignition.
Absorb spill with inert material (e.g. vermiculite, sand or earth), scoop up with a nonsparking tool, then place into a suitable
container for disposal. Do not flush to sewer!

SECTION 7: HANDLING AND STORAGE
Handling: Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use only in a well-ventilated
area. Keep container tightly closed. Avoid contact with heat, sparks and flame. Do not get on skin or in eyes. Avoid ingestion and
inhalation.
Storage: Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances.



MSDS# 1002-299103 Revision 0 Effective Date 11/18/02 Page 2 of 5
SECTION 8: EXPOSURE CONTROL/PERSONAL PROTECTIVE EQUIPMENT
Airborne Exposure Limits:
Benzene (CAS# 71-43-2) United States - OSHA Permissible Exposure Limit (PEL): 10 ppm TWA (apply only to exempt
industry segments)
United States - ACGIH Threshold Limit Value (TLV): 0.5 ppm (TWA) (skin)
Australia: Time-weighted average 5 ppm (16 mg/m3), Carcinogen, JAN1993
The Netherlands: MAC-TGG 10 ppm (30 mg/m3), Skin, Carcinogen, JAN1999
Toluene (CAS# 108-88-3) United States - OSHA Permissible Exposure Limit (PEL): 200 ppm (TWA)
United States - ACGIH Threshold Limit Value (TLV): 50 ppm (TWA) (skin)
Australia: Time-weighted average 100 ppm (375 mg/m3), 1993
The Netherlands: MAC-TGG 40 ppm (150 mg/m3), JAN1999
Ethylbenzene (CAS# 100-41-4) United States - OSHA Permissible Exposure Limit (PEL): 100 ppm (TWA)
United States - ACGIH Threshold Limit Value (TLV): 100 ppm (TWA)
Australia: Time-weighted average 100 ppm (435 mg/m3), short term exposure limit 125 ppm,
JAN1993
The Netherlands: MAC-TGG 50 ppm (215 mg/m3), (skin) 1999
Personal Protective Equipment
Eye Protection: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European Standard EN166. Maintain eye wash fountain and quick-drench facilities in
work area.
Skin Protection: Wear impervious gloves, apron, and/or clothing.
Clothing: Wear appropriate protective clothing to prevent skin exposure.
Respirators: Follow the OSHA respirator regulations found in 29CFR 1910.134 or European Standard EN 149. Use a NIOSH or
European Standard EN 149 approved respirator when necessary.
Ventilation System: A system of local and/or general exhaust is recommended to keep employee exposures below the Airborne
Exposure Limits. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its
source, preventing dispersion of it into the general work area. Please refer to the ACGIH document, "Industrial Ventilation, A
Manual of Recommended Practices", most recent edition, for details.

SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES
Appearance: Clear, colorless liquid Boiling Point: Not available
Odor: Gasoline-like odor Melting Point: Not available
Solubility: Insoluble Vapor Density: Not available
Specific Gravity: 0.8 (Water = 1) [calculated] Vapor Pressure (mm Hg): Not available
pH: Not available. Evaporation Rate: Not available
Molecular Formula: Mixture 鈥? Not applicable % Volatiles by Volume: 100
Molecular Weight: Mixture 鈥? Not applicable

SECTION 10: STABILITY AND REACTIVITY DATA
Stability: Stable at room temperature in sealed containers.
Hazardous Decomposition Products: Carbon dioxide and carbon monoxide may form when heated to decomposition.
Hazardous Polymerization: Will not occur.
Incompatibilities: Strong oxidizers, heat, and sources of ignition.
Conditions to Avoid: Incompatibles.

SECTION 11: TOXICOLOGICAL INFORMATION
Toxicity: Note : the toxicological properties of this mixture have not been thoroughly investigated.
RTECS#: CY1400000 for Benzene - CAS# 71-43-2
LD50/LC50:
Acute oral toxicity (LD50): 930 mg/kg [Rat].
Acute dermal toxicity (LD50): 48 mg/kg [Mouse].
Acute toxicity of the vapor (LC50): 10000 ppm 7 hour(s) [Rat].
Carcinogenicity: Classified A1 (Confirmed for human.) by ACGIH, 1 (Proven for human.) by IARC, + (Proven.) by OSHA, +
(Proven.) by NIOSH, 1 (Proven for human.) by European Union.
Reproductive effects: Tests on laboratory animals for reproductive effects are cited in Registry of Toxic Effects on Chemical
Substances (RTECS).
Mutagenicity: Tests on laboratory animals for mutagenic effects are cited in Registry of Toxic Effects of Chemical Substances
(RTECS).

RTECS#: XS5250000 for Toluene - CAS# 108-88-3
LD50/LC50:
Acute oral toxicity (LD50): 636 mg/kg [Rat].
MSDS# 1002-299103 Revision 0 Effective Date 11/18/02 Page 3 of 5
Acute toxicity of the vapor (LC50): 49 mg/m3/4 hour(s) [Rat].
Carcinogenicity: Not listed by ACGIH, IARC, NIOSH, NTP, or OSHA.
Reproductive effects: Tests on laboratory animals for reproductive effects are cited in Registry of Toxic Effects on Chemical
Substances (RTECS).
Mutagenicity: Tests on laboratory animals for mutagenic effects are cited in Registry of Toxic Effects of Chemical Substances
(RTECS).

RTECS#: DA0700000 for Ethylbenzene - CAS# 100-41-4
LD50/LC50:
Acute oral toxicity (LD50): 3500 mg/kg [Rat].
Carcinogenicity: Classified 2B (Possible for human.) by IARC.
Reproductive effects: Tests on laboratory animals for reproductive effects are cited in Registry of Toxic Effects on Chemical
Substances (RTECS).
Mutagenicity: Tests on laboratory animals for mutagenic effects are cited in Registry of Toxic Effects of Chemical Substances
(RTECS).



SECTION 12: ECOLOGICAL INFORMATION
Environmental Fate: Not available
Environmental Toxicity: Not available

SECTION 13: DISPOSAL GUIDELINES
Dispose in compliance with federal, state, and local regulations. Chemical waste generators must determine whether a discarded
chemical is classified as a hazardous waste. US EPA guidelines for the classification determination are listed in 40 CFR Parts
261.3. Additionally, waste generators must consult state and local hazardous waste regulations to ensure complete and accurate
classification.
USEPA RCRA waste number D001.
The information offered here is for the product as shipped. Use and/or alterations to the product such as mixing with other
materials may significantly change the characteristics of the material and alter the RCRA classification and the proper disposal
method.
SECTION 14: TRANSPORT INFORMATION
Ship in accordance with all applicable local, State, Federal, and International transportation regulations.
The following is a summary only. Check regulations for complete information:
United States (Land, D.O.T.) International (Air, I.C.A.O.)
Proper Shipping Name: Flammable liquid (Xylene, Proper Shipping Name: Flammable liquid (Xylene,
Ethylbenzene) Ethylbenzene)
Hazard Class: 3 Hazard Class: 3
UN/NA: UN1993 UN/NA: UN1993
Packing Group: II Packing Group: II



SECTION 15: REGULATORY INFORMATION
US Federal
TSCA: All components are listed on the TSCA inventory.
OSHA: None of the chemicals in this product are considered highly hazardous by OSHA.
SARA 311/312: Acute: Yes Chronic: Yes Fire: Yes Pressure: No Reactivity: No
US State
Components can be found on the following state right to know lists: New Jersey, Florida, Pennsylvania, Minnesota, Massachusetts.


California Proposition 65: WARNING: This product contains Benzene [CAS# 71-43-2] and Toluene [CAS# 108-88-3], chemicals
known to the State of California to cause cancer and birth defects or other reproductive harm.
Other Regulations
EC Classification: F 鈥? Highly Flammable, Xn - Harmful
EC Risk and Safety Phrases:
Risk Phrases:
R 45 May cause cancer.
R 11 Highly flammable.
R 23/24/25 Toxic by inhalation, in contact with skin and if swallowed.
R 48 Danger of serious damage to health by prolonged exposure.
Safety Phrases:
S 16 Keep away from sources of ignition - No smoking.
MSDS# 1002-299103 Revision 0 Effective Date 11/18/02 Page 4 of 5
S 24/25 Avoid contact with skin and eyes.
S 29 Do not empty into drains.
S 33 Take precautionary measures against static discharges.
S 36/37 Wear suitable protective clothing and gloves.
Inventory Status: Components listed on EINECS and Canadian DSL

SECTION 16: OTHER INFORMATION
This MSDS was prepared in accordance with ANSI Z400.1-1993 and 91/155/EEC recommended formats.

The information contained herein is believed to be accurate, but does not purport to be all-inclusive and shall be used only as a
guide. Varian, Inc., does not guarantee said information is accurate or complete, nor shall any of this information constitute a
warranty, whether expressed or implied, as to the safety of the goods, the merchantability of the goods, or the fitness of the goods
for a particular purpose. It is the user鈥檚 responsibility to determine the suitability of this information and to assure the adoption of
necessary precautions. Varian, Inc. shall not be held liable for any damage resulting from handling or from contact with the above
product, nor for the results obtained, or for incidental or consequential damage arising from the use of these data. No freedom from
infringement of any patent, copyright or trademark is to be inferred.




MSDS# 1002-299103 Revision 0 Effective Date 11/18/02 Page 5 of 5

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