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MSDS Material Safety Data Sheet
CAS

64742-47-8
64742-48-9
64742-88-7
64742-65-0
74-98-6
9002-84-0

File Name: wd40_com---msds-3in1pro_lub_ptfe.us.asp
                          Material Safety Data Sheet
1 - Chemical Product and Company Identification
Manufacturer: WD-40 Company
Trade Name: 3-IN-ONE Professional
Address: 1061 Cudahy Place (92110) Lubricant with PTFE
P.O. Box 80607
San Diego, California, USA Chemical Name: Organic Mixture
92138 鈥?0607
Telephone: Product Use: Cleaner, Lubricant
Emergency only: 1-888-324-7596
(PROSAR)
Information: 1-888-324-7596

2 鈥? Hazards Identification
Emergency Overview:
DANGER! Harmful of fatal if swallowed. Extremely Flammable aerosol. Contents under
pressure. Avoid eye contact. Use with adequate ventilation. Keep away from heat, sparks and all
other sources of ignition.

Symptoms of Overexposure:
Inhalation: High concentrations may cause nasal and respiratory irritation and central nervous
system effects such as headache, dizziness and nausea. Intentional abuse may be harmful or
fatal.
Skin Contact: Prolonged and/or repeated contact may produce mild irritation and defatting with
possible dermatitis.
Eye Contact: Contact may be mildly irritating to eyes. May cause redness and tearing.
Ingestion: This product has low oral toxicity. Swallowing may cause gastrointestinal irritation,
nausea, vomiting and diarrhea. The liquid contents are an aspiration hazard. If swallowed, can
enter the lungs and may cause chemical pneumonitis.
Chronic Effects: None expected.
Medical Conditions Aggravated by Exposure: Preexisting eye, skin and respiratory conditions
may be aggravated by exposure.

Suspected Cancer Agent:
Yes No X

3 - Composition/Information on Ingredients
Ingredient CAS # Weight Percent
LVP Aliphatic Hydrocarbon 64742-47-8 30-40
Aliphatic Hydrocarbon 64742-47-8 10-20
64742-48-9
64742-88-7
Non-Hazardous Ingredients Mixture <20
Petroleum Base Oil 64742-65-0 <15
Propane Propellant 74-98-6 12-18%
Polytetrafluoroethylene 9002-84-0 <1%

4 鈥? First Aid Measures
Ingestion (Swallowed): Aspiration Hazard. DO NOT induce vomiting. Call physician, poison
control center or the WD-40 Safety Hotline at 1-888-324-7596 immediately.
Eye Contact: Flush thoroughly with water. Get medical attention if irritation persists.




Page 1 of 4
Skin Contact: Wash with soap and water. If irritation develops and persists, get medical
attention.
Inhalation (Breathing): If irritation is experienced, move to fresh air. Get medical attention if
irritation or other symptoms develop and persist.

5 鈥? Fire Fighting Measures
Extinguishing Media: Use water fog, dry chemical, carbon dioxide or foam. Do not use water jet
or flooding amounts of water. Burning product will float on the surface and spread fire.
Special Fire Fighting Procedures: Firefighters should always wear positive pressure self-
contained breathing apparatus and full protective clothing. Cool fire-exposed containers with
water. Use shielding to protect against bursting containers.
Unusual Fire and Explosion Hazards: Contents under pressure. Aerosol containers may burst
under fire conditions. Vapors are heavier than air and may travel along surfaces to remote ignition
sources and flash back.

6 鈥? Accidental Release Measures
Wear appropriate protective clothing (see Section 8). Eliminate all sources of ignition and
ventilate area. Leaking cans should be placed in a plastic bag or open pail until the pressure has
dissipated. Contain and collect liquid with an inert absorbent and place in a container for disposal.
Clean spill area thoroughly. Report spills to authorities as required.

7 鈥? Handling and Storage
Handling: Avoid contact with eyes. Avoid prolonged contact with skin. Avoid breathing vapors or
aerosols. Use with adequate ventilation. Keep away from heat, sparks, hot surfaces and open
flames. Wash thoroughly with soap and water after handling. Do not puncture or incinerate
containers. Keep can away from electrical current or battery terminals. Electrical arcing can cause
burn-through (puncture) which may result in flash fire, causing serious injury. Keep out of the
reach of children.
Storage: Do not store above 120掳F or in direct sunlight. U.F.C (NFPA 30B) Level 3 Aerosol.

8 鈥? Exposure Controls/Personal Protection
Chemical Occupational Exposure Limits
LVP Aliphatic Hydrocarbon 1200 mg/m3 TWA (manufacturer recommended)
Aliphatic Hydrocarbon 100 ppm TWA (ACGIH)
1200 mg/m3 TWA (manufacturer recommended)
Non-Hazardous Ingredients None Established
Petroleum Base Oil 5 mg/m3 TWA (OSHA/ACGIH)
Propane Propellant 1000 ppm TWA OSHA PEL
1000 ppm TWA ACGIH TLV (aliphatic hydrocarbon gas)
Polytetrafluoroethylene None Established
The Following Controls are Recommended for Normal Consumer Use of this Product
Engineering Controls: Use in a well-ventilated area.
Personal Protection:
Eye Protection: Avoid eye contact. Safety glasses or goggles recommended.
Skin Protection: Avoid prolonged skin contact. Chemical resistant gloves recommended for
operations where skin contact is likely.
Respiratory Protection: None needed for normal use with adequate ventilation.

For Bulk Processing or Workplace Use the Following Controls are Recommended
Engineering Controls: Use adequate general and local exhaust ventilation to maintain exposure
levels below that occupational exposure limits.
Personal Protection:
Eye Protection: Safety goggles recommended where eye contact is possible.


Page 2 of 4
Skin Protection: Wear chemical resistant gloves.
Respiratory Protection: None required if ventilation is adequate. If the occupational exposure
limits are exceeded, wear a NIOSH approved respirator. Respirator selection and use should be
based on contaminant type, form and concentration. Follow OSHA 1910.134, ANSI Z88.2 and
good Industrial Hygiene practice.
Work/Hygiene Practices: Wash with soap and water after handling.

9 鈥? Physical and Chemical Properties
Boiling Point: Specific Gravity:
323掳F (minimum) 0.816 @ 72掳F
Solubility in Water: Insoluble pH: Not Applicable
Vapor Pressure: Vapor Density: Greater than 1
110 PSI @ 70掳F
Percent Volatile: 90% VOC: Not Determined
Coefficient of Not Determined Appearance/Odor Light amber liquid/mild
Water/Oil Distribution: odor
Flash Point: -20掳F Tag Closed Cup Flammable LEL: 1.8% UE:: 9.5%
Limits:
(Propellant)

10 鈥? Stability and Reactivity
Stability: Stable
Hazardous Polymerization: Will not occur.
Conditions to Avoid: Avoid heat, sparks, flames and other sources of ignition. Do not puncture
or incinerate containers.
Incompatibilities: Strong oxidizing agents.
Hazardous Decomposition Products: Carbon monoxide and carbon dioxide, smoke fumes,
unburned hydrocarbons and small amounts of hydrogen fluoride and carbonyl fluoride.

11 鈥? Toxicological Information
The oral toxicity of this product is estimated to be greater than 5,000 mg/kg based on an
assessment of the ingredients. This product is not classified as toxic by established criteria. It is
an aspiration hazard.
None of the components of this product is listed as a carcinogen or suspected carcinogen or is
considered a reproductive hazard.

12 鈥? Ecological Information
No data is currently available.

13 - Disposal Considerations
If this product becomes a waste, it would be expected to meet the criteria of a RCRA ignitable
hazardous waste (D001). However, it is the responsibility of the generator to determine at the
time of disposal the proper classification and method of disposal. Dispose in accordance with
federal, state, and local regulations.

14 鈥? Transportation Information_
DOT Surface Shipping Description: Consumer Commodity, ORM-D
IMDG Shipping Description: UN1950, Aerosols, 2.1

15 鈥? Regulatory Information
U.S. Federal Regulations:
CERCLA 103 Reportable Quantity: This product is not subject to CERCLA reporting
requirements, however, oil spills are reportable to the National Response Center under the Clean
Water Act and many states have more stringent release reporting requirements. Report spills
required under federal, state and local regulations.



Page 3 of 4
SARA TITLE III:
Hazard Category For Section 311/312: Acute Health, Fire Hazard, Sudden Release of
Pressure
Section 313 Toxic Chemicals: This product contains the following chemicals subject to SARA
Title III Section 313 Reporting requirements: None
Section 302 Extremely Hazardous Substances (TPQ): None
EPA Toxic Substances Control Act (TSCA) Status: All of the components of this product are
listed on the TSCA inventory
Canadian Environmental Protection Act: All of the ingredients are listed on the Canadian
Domestic Substances List or exempt from notification
Canadian WHMIS Classification: Class B-5 (Flammable Aerosol)
This MSDS has been prepared according to the criteria of the Controlled Products Regulation
(CPR) and the MSDS contains all of the information required by the CPR.

16 鈥? Other Information:
HMIS Hazard Rating:
Health 鈥? 1 (slight hazard), Fire Hazard 鈥? 4 (severe hazard), Reactivity 鈥? 0 (minimal hazard)




SIGNATURE: TITLE: Director Of Global Quality Assurance

REVISION DATE: January 2008 SUPERSEDES: December 2004




Page 4 of 4

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