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                              WD-40 3-IN-ONE PENETRANT SPRAY
ChemWatch Material Safety Data Sheet CHEMWATCH 4944-63
Issue Date: Thu 17-Apr-2003 CD 2003/1 Page 1 of 10

IDENTIFICATION


STATEMENT OF HAZARDOUS NATURE

HAZARDOUS ACCORDING TO WORKSAFE AUSTRALIA CRITERIA.

SUPPLIER

Company: WD-40 Company (Australia P/L)
Address:
41 Rawson Street
Epping
NSW2121
Australia
Telephone: +61 2 9868 2200
Fax: +61 2 9869 7512




Product Name: WD-40 3-in-One Penetrant Spray

CAS RN No(s): None
UN Number: 1950
Packing Group: None
Dangerous Goods Class: 2.1
Subsidiary Risk: None
Hazchem Code: 2Y
Poisons Schedule Number: None

USE
Lubricant spray.
Application is by spray atomisation from a hand held aerosol pack

PHYSICAL DESCRIPTION/PROPERTIES

APPEARANCE
Light amber liquid with a petroleum odour; does not mix with water.
Supplied as an aerosol pack. Contents under PRESSURE. Contains highly flammable
hydrocarbon propellant.

Boiling Point (掳C): Not available
Melting Point (掳C): Not available
Vapour Pressure (kPa): Not available
Specific Gravity: 0.80
Flash Point (掳C): -28.89
Lower Explosive Limit (%): 1.8
Upper Explosive Limit (%): 9.5

continued...
WD-40 3-IN-ONE PENETRANT SPRAY
ChemWatch Material Safety Data Sheet CHEMWATCH 4944-63
Issue Date: Thu 17-Apr-2003 CD 2003/1 Page 2 of 10

IDENTIFICATION ...

Solubility in Water (g/L): Immiscible

INGREDIENTS

NAME CAS RN %
solvent naphtha petroleum, medium aliphatic 64742-88-7 30-40
isoparaffins petroleum hydrotreated HFP 64742-47-8. 30-40
paraffinic distillate, light, solvent-dewaxed (sev 64742-56-9. 3-6
fragrance <1
dye <1
hydrocarbon propellant 68476-85-7. 25-30
NOTE: Manufacturer has supplied full ingredient
information to allow CHEMWATCH assessment.


HEALTH HAZARD


ACUTE HEALTH EFFECTS

SWALLOWED
The liquid is discomforting to the gastro-intestinal tract and may be harmful
if swallowed
Ingestion may result in nausea, pain, vomiting. Vomit entering the lungs by
aspiration may cause potentially lethal chemical pneumonitis.
Considered an unlikely route of entry in commercial/industrial environments


EYE
The mist is highly discomforting to the eyes if exposure is prolonged and is
capable of causing pain and severe conjunctivitis. Corneal injury may develop,
with possible permanent impairment of vision, if not promptly and adequately
treated
The material may produce severe irritation to the eye causing pronounced
inflammation. Repeated or prolonged exposure to irritants may produce
conjunctivitis.


SKIN
The liquid is discomforting to the skin and is capable of causing skin
reactions which may lead to dermatitis
Toxic effects may result from skin absorption
The material may accentuate any pre-existing skin condition
The material may cause skin irritation after prolonged or repeated exposure and
may produce on contact skin redness, swelling, the production of vesicles,
scaling and thickening of the skin.


INHALED
The vapour/mist is discomforting to the upper respiratory tract
Inhalation hazard is increased at higher temperatures.
Inhalation of high concentrations of gas/vapour causes lung irritation with

continued...
WD-40 3-IN-ONE PENETRANT SPRAY
ChemWatch Material Safety Data Sheet CHEMWATCH 4944-63
Issue Date: Thu 17-Apr-2003 CD 2003/1 Page 3 of 10

HEALTH HAZARD ...

coughing and nausea, central nervous depression with headache and dizziness,
slowing of reflexes, fatigue and inco-ordination.
If exposure to highly concentrated solvent atmosphere is prolonged this may
lead to narcosis, unconsciousness, even coma and possible death.
WARNING:Intentional misuse by concentrating/inhaling contents may be lethal.

CHRONIC HEALTH EFFECTS

Principal routes of exposure are usually by skin contact and inhalation of
vapour/spray mist
Chronic solvent inhalation exposures may result in nervous system impairment
and liver and blood changes. [PATTYS]
Prolonged or continuous skin contact with the liquid may cause defatting with
drying, cracking, irritation and dermatitis following.
WARNING: Aerosol containers may present pressure related hazards.

FIRST AID

SWALLOWED
If swallowed do NOT induce vomiting.
If vomiting occurs, lean patient forward or place on left side (head-down
position, if possible) to maintain open airway and prevent aspiration.
Observe the patient carefully.
Never give liquid to a person showing signs of being sleepy or with reduced
awareness; i.e. becoming unconscious.
Give water to rinse out mouth, then provide liquid slowly and as much as
casualty can comfortably drink.
Seek medical advice.


EYE
If this product comes in contact with the eyes:
Immediately hold eyelids apart and flush the eye continuously with running
water.
Ensure complete irrigation of the eye by keeping eyelids apart and away from
eye and moving the eyelids by occasionally lifting the upper and lower lids.
Continue flushing until advised to stop by the Poisons Information Centre or a
doctor, or for at least 15 minutes.
Transport to hospital or doctor without delay.
Removal of contact lenses after an eye injury should only be undertaken by
skilled personnel.


SKIN
If solids or aerosol mists are deposited upon the skin:
Flush skin and hair with running water (and soap if available).
Remove any adhering solids with industrial skin cleansing cream.
DO NOT use solvents.
Seek medical attention in the event of irritation.




continued...
WD-40 3-IN-ONE PENETRANT SPRAY
ChemWatch Material Safety Data Sheet CHEMWATCH 4944-63
Issue Date: Thu 17-Apr-2003 CD 2003/1 Page 4 of 10

HEALTH HAZARD ...

INHALED
If fumes or combustion products are inhaled remove from contaminated area.
Lay patient down. Keep warm and rested.
Prostheses such as false teeth, which may block airway, should be removed,
where possible, prior to initiating first aid procedures.
Apply artificial respiration if not breathing, preferably with a demand valve
resuscitator, bag-valve mask device, or pocket mask as trained. Perform CPR if
necessary.
Transport to hospital, or doctor.

ADVICE TO DOCTOR

For acute or short term repeated exposures to petroleum distillates or related
hydrocarbons:
Primary threat to life, from pure petroleum distillate ingestion and/or
inhalation, is respiratory failure.
Patients should be quicklyevaluated for signs of respiratory distress (e.g.
cyanosis, tachypnoea, intercostal retraction, obtundation) and given oxygen.
Patients with inadequate tidal volumes or poor arterial blood gases (pO2 50 mm
Hg) should be intubated.
Arrhythmias complicate some hydrocarbon ingestion and/or inhalation and
electrocardiographic evidence of myocardial injury has been reported;
intravenous lines and cardiac monitors should be established in obviously
symptomatic patients. The lungs excrete inhaled solvents, so that
hyperventilation improves clearance
Achest x-rayshould be taken immediatelyafter stabilisation of breathing and
circulation to document aspiration and detect the presence of pneumothorax.
Epinephrine (adrenalin) is not recommended for treatment of bronchospasm
because of potential myocardial sensitisation to catecholamines. Inhaled
cardioselective bronchodilators (e.g. Alupent, Salbutamol) are the preferred
agents, with aminophylline a second choice.
Lavage is indicated in patients who require decontamination; ensure use of
cuffed endotracheal tube in adult patients. [Ellenhorn and Barceloux: Medical
Toxicology]


PRECAUTIONS FOR USE


EXPOSURE STANDARDS

None assigned. Refer to individual constituents.



INGREDIENT DATA

SOLVENTNAPHTHAPETROLEUM, MEDIUMALIPHATIC:
TLVTWA: 300 ppm A3 [ACGIH]
CEL TWA: 100 ppm, 525 mg/m鲁 [Manufacturer]
as VM& P Naphtha (petroleum ether) (CAS RN: 8032-32-4)
TLVTWA: 300 ppm, A3

continued...
WD-40 3-IN-ONE PENETRANT SPRAY
ChemWatch Material Safety Data Sheet CHEMWATCH 4944-63
Issue Date: Thu 17-Apr-2003 CD 2003/1 Page 5 of 10

PRECAUTIONS FOR USE ...

Naphthas of this type produce central nervous system depression and are mild
irritants of the eyes and upper respiratory tract. The carcinogenic potential
of middle petroleum distillates is recognised and is related to the content of
polynuclear aromatic hydrocarbons
(PAHs). The TLVis thought to be protective against the acute effects of upper
respiratory tract and eye irritation and chronic systemic effects.
CAUTION: This substance has been classified by the ACGIH as A3
Animal carcinogen (at relativelyhigh doses)
for petroleum distillates:
CEL TWA: 500 ppm, 2000 mg/m鲁 (compare OSHATWA)

ISOPARAFFINS PETROLEUMHYDROTREATED HFP:
REL TWA: 300 ppm [EXXON]
for petroleum distillates:
CEL TWA: 500 ppm, 2000 mg/m鲁 (compare OSHATWA)

PARAFFINIC DISTILLATE, LIGHT, SOLVENT-DEWAXED (SEV:
PEL TWA: 5 mg/m鲁 [OSHAZ1]
oil mist, mineral
TLVTWA: 5 mg/m鲁; STEL: 10 mg/m鲁.
NOTICE OF INTENDED CHANGE.
TLVTWA 0.2 mg/m鲁 inhalable fraction highlyrefined A4
NOTE: This substance has been classified by the ACGIH as A4
NOT classifiable as causing cancer in humans.
ES TWA: 5 mg/m鲁 (oil mist, refined mineral)
Human exposure to oil mist alone has not been demonstrated to cause health
effects except at levels above 5 mg/m鲁 (this applies to particulates sampled by
a method that does not collect vapour). It is not advisable to applythis
standard to oils containing unknown concentrations and types of additive.

HYDROCARBON PROPELLANT:
hydrocarbon propellant, as liquified petroleum gas
TLVTWA: 1000 ppm, 1800 mg/m鲁
ES TWA: 1000 ppm, 1800 mg/m鲁
OES TWA: 1000 ppm, 1750 mg/m鲁; STEL: 1250 ppm, 2180 mg/m鲁

ENGINEERING CONTROLS

General exhaust is adequate under normal operating conditions. If risk of
overexposure exists, wear SAA approved respirator. Correct fit is essential to
obtain adequate protection. Provide adequate ventilation in warehouse or closed
storage areas. Air contaminants generated in the workplace possess varying
"escape" velocities which, in turn, determine the "capture velocities" of fresh
circulating air required to effectivelyremove the contaminant.

Type of Contaminant: Air Speed:
solvent, vapours, degreasing etc., 0.25-0.5 m/s (50-100 f/min)
evaporating from tank (in still air)
aerosols, fumes from pouring 0.5-1 m/s (100-200 f/min.)
operations, intermittent container
filling, low speed conveyer transfers,
welding, spray drift, plating acid

continued...
WD-40 3-IN-ONE PENETRANT SPRAY
ChemWatch Material Safety Data Sheet CHEMWATCH 4944-63
Issue Date: Thu 17-Apr-2003 CD 2003/1 Page 6 of 10

PRECAUTIONS FOR USE ...

fumes, pickling (released at low
velocity into zone of active
generation)
direct spray, spray painting in 1-2.5 m/s (200-500 f/min)
shallow booths, drum filling, conveyer
loading, crusher dusts, gas discharge
(active generation into zone of rapid
air motion)
grinding, abrasive blasting, tumbling, 2.5-10 m/s (500-2000 f/min.)
high speed wheel generated dusts
(released at high initial velocity
into zone of veryhigh rapid air
motion).

Within each range the appropriate value depends on:

Lower end of the range Upper end of the range
1: Room air currents minimal or 1: Disturbing room air currents
favourable to capture
2: Contaminants of low toxicity or of 2: Contaminants of high toxicity
nuisance value only
3: Intermittent, low production. 3: High production, heavy use
4: Large hood or large air mass in 4: Small hood - local control only
motion

Simple theory shows that air velocity falls rapidlywith distance away from the
opening of a simple extraction pipe. Velocity generallydecreases with the
square of distance from the extraction point (in simple cases). Therefore the
air speed at the extraction point should be adjusted, accordingly, after
reference to distance from the contaminating source. The air velocity at the
extraction fan, for example, should be a minimum of 1-2 m/s (200-400 f/min.)
for extraction of solvents generated in a tank 2 meters distant from the
extraction point. Other mechanical considerations, producing performance
deficits within the extraction apparatus, make it essential that theoretical
air velocities are multiplied by factors of 10 or more when extraction systems
are installed or used.

PERSONAL PROTECTION

EYE
Safetyglasses with side shields; or as required, Chemical goggles. Contact
lenses pose a special hazard; soft lenses may absorb irritants and all lenses
concentrate them.


HANDS/FEET
No special equipment needed when handling small quantities.
OTHERWISE: Wear general protective gloves, eg. light weight rubber gloves. Or
as required: Wear chemical protective gloves, eg. PVC. Wear safety footwear.




continued...
WD-40 3-IN-ONE PENETRANT SPRAY
ChemWatch Material Safety Data Sheet CHEMWATCH 4944-63
Issue Date: Thu 17-Apr-2003 CD 2003/1 Page 7 of 10

PRECAUTIONS FOR USE ...

OTHER
No special equipment needed when handling small quantities.
OTHERWISE:
Overalls.
Skin cleansing cream.
Eyewash unit.
Do not spray on hot surfaces.


RESPIRATOR
Respiratory protection may be required when ANY"Worst Case" vapour-phase
concentration is exceeded (see Computer Prediction in "Exposure Standards")

Protection Factor (Min) Half-Face Respirator Full-Face Respirator
10 xES Air-line* A-2
- A-PAPR-2
20 xES - A-3
20+ xES - Air-line**

* - Continuous-flow; ** - Continuous-flow or positive pressure demand
^ - Full-face

The local concentration of material, quantity and conditions of use determine
the type of personal protective equipment required. For further information
consult site specific CHEMWATCH data (if available), or your Occupational
Health and SafetyAdvisor.


SAFE HANDLING


STORAGE AND TRANSPORT

SUITABLE CONTAINER
Aerosol dispenser. Check that containers are clearly labelled.


STORAGE INCOMPATIBILITY
Avoid storage with oxidisers


STORAGE REQUIREMENTS
Store in original containers in approved flame-proof area.
DO NOT store in pits, depressions, basements or areas where vapours may be
trapped.
No smoking, naked lights, heat or ignition sources.
Keep containers securely sealed. Contents under pressure.
Store away from incompatible materials.
Store in a cool, dry, well ventilated area in an upright position.
Avoid storage at temperatures higher than 40 deg C.
Protect containers against physical damage and check regularly for leaks.
Observe manufacturer's storing and handling recommendations.

continued...
WD-40 3-IN-ONE PENETRANT SPRAY
ChemWatch Material Safety Data Sheet CHEMWATCH 4944-63
Issue Date: Thu 17-Apr-2003 CD 2003/1 Page 8 of 10

SAFE HANDLING ...


TRANSPORTATION
Class 2.1 - Flammable gases shall not be loaded in the same vehicle or packed
in the same freight container with:
Class 1 - Explosives;
Class 3 - Flammable liquids (where both flammable liquids and flammable gases
are in bulk);
Class 4.1 - Flammable solids;
Class 4.2 - Spontaneously combustible substances;
Class 4.3 - Dangerous when wet substances;
Class 5.1 - Oxidising agents;
Class 5.2 - Organic peroxides;
Class 7 - Radioactive substances.

SPILLS AND DISPOSAL

MINOR SPILLS
Clean up all spills immediately.
Avoid breathing vapours and contact with skin and eyes.
Wear protective clothing, impervious gloves and safety glasses.
Shut off all possible sources of ignition and increase ventilation.
Wipe up.
If safe, damaged cans should be placed in a container outdoors, away from all
ignition sources, until pressure has dissipated.
Undamaged cans should be gathered and stowed safely.


MAJOR SPILLS
Clear area of personnel and move upwind.
Alert Fire Brigade and tell them location and nature of hazard.
May be violently or explosively reactive.
Wear breathing apparatus plus protective gloves.
Prevent, by any means available, spillage from entering drains or water courses
No smoking, naked lights or ignition sources.
Increase ventilation.
Stop leak if safe to do so.
Water spray or fog may be used to disperse / absorb vapour.
Absorb or cover spill with sand, earth, inert materials or vermiculite.
If safe, damaged cans should be placed in a container outdoors, away from
ignition sources, until pressure has dissipated.
Undamaged cans should be gathered and stowed safely.
Collect residues and seal in labelled drums for disposal.

DISPOSAL
Consult State Land Waste Management Authority for disposal.
Discharge contents of damaged aerosol cans at an approved site.
Allow small quantities to evaporate.
DO NOT incinerate or puncture aerosol cans.
Bury residues and emptied aerosol cans at an approved site.




continued...
WD-40 3-IN-ONE PENETRANT SPRAY
ChemWatch Material Safety Data Sheet CHEMWATCH 4944-63
Issue Date: Thu 17-Apr-2003 CD 2003/1 Page 9 of 10

SAFE HANDLING ...

FIRE FIGHTERS' REPORT



EXTINGUISHING MEDIA
Water spray or fog.
Foam.
Dry chemical powder.
BCF (where regulations permit).
Carbon dioxide.


FIRE FIGHTING
Alert Fire Brigade and tell them location and nature of hazard.
May be violently or explosively reactive.
Wear breathing apparatus plus protective gloves.
Prevent, by any means available, spillage from entering drains or water course.
If safe, switch off electrical equipment until vapour fire hazard removed.
Use water delivered as a fine spray to control fire and cool adjacent area.
DO NOT approach containers suspected to be hot.
Cool fire exposed containers with water spray from a protected location.
If safe to do so, remove containers from path of fire.
Equipment should be thoroughly decontaminated after use.
When any large container (including road and rail tankers) is involved in a fire,
consider evacuation by 100 metres in all directions.


FIRE/EXPLOSION HAZARD
Liquid and vapour are highly flammable.
Severe fire hazard when exposed to heat or flame.
Vapour forms an explosive mixture with air.
Severe explosion hazard, in the form of vapour, when exposed to flame or spark.
Vapour may travel a considerable distance to source of ignition.
Heating may cause expansion or decomposition with violent container rupture.
Aerosol cans may explode on exposure to naked flames.
Rupturing containers may rocket and scatter burning materials.
Hazards may not be restricted to pressure effects.
May emit acrid, poisonous or corrosive fumes.
On combustion, may emit toxic fumes of carbon monoxide (CO).
Other combustion products include carbon dioxide (CO2)


FIRE INCOMPATIBILITY
Avoid contamination with strong oxidising agents as ignition may result

HAZCHEM
2Y




continued...
WD-40 3-IN-ONE PENETRANT SPRAY
ChemWatch Material Safety Data Sheet CHEMWATCH 4944-63
Issue Date: Thu 17-Apr-2003 CD 2003/1 Page 10 of 10

CONTACT POINT


COMPANYCONTACT
+61 2 9868 2200

AUSTRALIAN POISONS INFORMATION CENTRE
24 HOUR SERVICE: 13 11 26
POLICE, FIRE BRIGADE OR AMBULANCE: 000

NEWZEALAND POISONS INFORMATION CENTRE
24 HOUR SERVICE: (03) 4747 000
NZ EMERGENCYSERVICES: 111

End of Report

Issue Date: Thu 17-Apr-2003
Print Date: Wed 23-Apr-2003

This document is copyright. Apart from any fair dealing for the purposes of
private study, research, review or criticism, as permitted under the Copyright
Act, no part may be reproduced by any process without written permission from
CHEMWATCH. TEL (+61 3) 9572 4700.

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