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MSDS Material Safety Data Sheet
CAS

118-52-5
89415-87-2

File Name: wd40_com---msds-2000-bowl_blue_bleach.us.asp
                          Material Safety Data Sheet
1 - Chemical Product and Company Identification
Manufacturer: WD-40 Company
Trade Name: 2000 Flushes Blue plus Bleach
Address: 1061 Cudahy Place (92110)
P.O. Box 80607 Chemical Name: Mixture
San Diego, California, USA
92138 鈥?0607 Product Use: Toilet Bowl Cleaner and
Telephone: Deodorizer
Emergency only: 1-888-324-7596 EPA Registration Number: 6836-288-71903
(PROZAR)
Information: 1-888-324-7596 MSDS Date Of Preparation: 05/29/08

2 - Composition/Information on Ingredients
Ingredient CAS # Weight Percent
Deodorant Tablet
Surfactants Mixture 45-60%
Fragrance Mixture 5-10%
Bleach Tablet
1,3-Dichloro-5,5-dimethylhydantoin 118-52-5 81.1%
1,3-Dichloro-5-ethyl-5-methylhydantoin 89415-87-2 16.1%
Chloro-5-ethyl-5-methylhydantoin Not assigned 1.8%
Non-Hazardous Ingredients Mixture 1.0%
See Section 8 for Exposure Limits

3 鈥? Hazards Identification
Emergency Overview: DANGER!
Bleach tablets are strong oxidizers. Possible fire hazard in contact with flammable or combustible
material. Bleach tablets are corrosive and may cause burns to the eyes, skin, mouth and
gastrointestinal tract. May be fatal if swallowed. Repeated exposure may cause allergic skin
reaction (sensitization). Blue deodorant is an eye irritant.

Symptoms of Overexposure:
Inhalation: Inhalation is not a normal route of exposure for this product. If dust from Bleach
Tablets is inhaled, severe irritation of the nose, mouth and upper respiratory tract would be
expected. May aggravate existing respiratory conditions such as asthma. No adverse effects
expected in an otherwise health individual exposed to the solid Deodorant.
Skin Contact: Bleach Tablets are corrosive. Direct contact with bleach tablet may cause severe
irritation and possible burns. Repeated skin contact may result in sensitization with swelling and
rash. Prolonged contact with Deodorant may cause mild irritation.
Eye Contact: Bleach Tablets are corrosive. Direct contact will cause severe irritation, pain, burns
and possible permanent eye damage. Blue deodorant is an eye irritant.
Ingestion: Bleach Tablets are corrosive and will cause immediate and severe burns of the
mucous membranes of the mouth and gastrointestinal tract. May be fatal if swallowed.
Swallowing deodorant may produce mild gastrointestinal upset if ingested involving nausea,
vomiting and diarrhea.

Chronic Effects: None currently known.
Medical Conditions Aggravated by Exposure: Pre-existing skin disorders.

Suspected Cancer Agent:
Yes No X



Page 1 of 4
4 鈥? First Aid Measures
FOR CONTACT WITH BLEACH TABLETS:
Ingestion (Swallowed): Rinse out mouth and give sips of water if the person is able to swallow
and is alert. DO NOT INDUCE VOMITING. Get immediate medical attention. Call physician,
poison control center or the WD-40 Safety Hotline at 1-888-324-7596.
Eye Contact: Flush with water. Remove contact lenses, if present, after the first 5 minutes and
flush again with water for at least 15 -20 minutes. Get immediate medical attention.
Skin Contact: Immediately flush skin with plenty of water for 15-20 minutes. Remove any
contaminated clothing and rinse immediately with water to dilute concentrated bleach. Launder
clothing before reuse. If irritation develops and persists, get medical attention. Note concentrated
bleach in contact with clothing may be a fire hazard.
Inhalation (Breathing): If dust from product is inhaled, move to fresh air. If the person is not
breathing call 911 or an ambulance, then give artificial respiration. Call a poison center for
treatment advice. Have the product container or label with you when calling a poison center or
going for treatment.
Note to Physician: Probable mucosal damage may contraindicate the use of gastric lavage.

FOR CONTACT WITH DEODORANT:
Ingestion: Rinse out mouth and dilute with fluids. Call physician, poison control center or the
WD-40 Safety Hotline at 1-888-324-7596.
Eye Contact: Flush thoroughly with water and if irritation persists, get medical attention.
Skin Contact: Flush thoroughly with water and if irritation develops and persists, get medical
attention.
Inhalation: Move to fresh air and get medical attention if irritation develops and persists.

5 鈥? Fire Fighting Measures
Extinguishing Media: Flood with water or foam. Do not use dry chemicals, carbon dioxide or
halogenated extinguishing agents.
Unusual Fire or Explosion Hazards: Heating Bleach Tablets will generate noxious gases. To
minimize the generation of these gases, flood with a large quantity of water. Bleach Tablets are
strong oxidizers and may react with flammable or combustible materials to cause a fire or
explosion.

6 鈥? Accidental Release Measures
Bleach Tablets spilled from a single retail package should be carefully collected and flushed down
the drain with plenty of water. Do not generate airborne dust. If a damp cloth or paper towel is
used to collect material, rinse it thoroughly with a large amount of water before reuse or disposal.
Concentrated bleach may cause a fire in contact with paper, rags or other combustible material.
Large amounts should be carefully collected into a plastic container for disposal.

For small spills of Deodorant (one retail container or less) flush down drain with plenty of water.
For larger spills, collect and place in a sealable container for later disposal

7 鈥? Handling and Storage
Handling: Do not touch tablet. Do not get in eyes, on skin or clothing. Wear rubber gloves when
handling. Avoid breathing dust from product. Wash thoroughly after use. Keep out of the reach of
children. Keep Bleach Tablets away from flammable and combustible materials. DO NOT mix
with anything other than water.
Storage: Store in original container in a cool, dry, well-ventilated area. Do not store at elevated
temperatures. Avoid heat and direct sunlight.

8 鈥? Exposure Controls/Personal Protection
Chemical Occupational Exposure Limits



Page 2 of 4
Surfactants None Established
Fragrance None Established
1,3-Dichloro-5,5-dimethylhydantoin 0.2 mg/m3 TWA OSHA PEL/ACGIH TLV
1,3-Dichloro-5-ethyl-5-methylhydantoin 0.2 mg/m3 TWA (Manufacturer Recommended)
Chloro-5-ethyl-5-methylhydantoin 0.2 mg/m3 TWA (Manufacturer Recommended)

The Following Controls are Recommended for Normal Consumer Use of this Product
Engineering Controls: No special controls required for normal use.
Personal Protection:
Eye Protection: None normally required. Prevent eye contact. When opening, hold plastic pouch
away from face.
Skin Protection: Avoid skin contact. Wear rubber gloves when handling product.
Respiratory Protection: None required for normal use.

For Bulk Processing or Workplace Use the Following Controls are Recommended
Engineering Controls: Use with adequate general ventilation or local exhaust to minimize
exposure levels.
Personal Protection:
Eye Protection: Chemical safety goggles recommended.
Skin Protection: Wear rubber gloves and protective clothing as required to prevent skin contact.
Respiratory Protection: None required for handling finished product. If exposure levels are
excessive, wear an approved respirator. Selection of respiratory protection depends on the
contaminant type, form and concentration. Select in accordance with OSHA 1910.134 and good
Industrial Hygiene practice.
Work/Hygiene Practices: Prevent contact with the eyes, skin and clothing. Wash thoroughly
after handling.

9 鈥? Physical and Chemical Properties
Boiling Point: Not available Evaporation Rate: <1 (butyl acetate=1)
Vapor Density (air = 1): Not available Vapor Pressure: Not available
Solubility in Water: Bleach - 0.56 g/100 pH: Bleach - 3.6 (1%
g @ 25掳C Blue - solution)
soluble
Specific Gravity (H2O=1): Not available Percent Volatile <0.5
(volume):
Flash Point: None Flammable Limits: Not applicable
Appearance and Odor: White tablet with a very slight, pungent odor. Blue solid with a
pleasant odor.

10 鈥? Stability and Reactivity
Stability: Stable
Hazardous Polymerization: Will not occur.
Conditions to Avoid: Avoid high temperatures and direct sunlight.
Incompatibilities: Acids, bases, moisture, reducing agents, readily utilizable materials including
flammable and combustible materials.
Hazardous Decomposition Products: Thermal decomposition of Bleach Tablets may generate
noxious gases including chlorine, nitrogen oxides, carbon oxides, organic materials.
11 鈥? Toxicological Information
1,3-Dichloro-5,5-dimethylhydantoin: Oral LD50 rat 766-800 mg/kg, eye irritation (rabbit) severe,
skin irritation (rabbit) corrosive.




Page 3 of 4
12 鈥? Ecological Information
1,3-Dichloro-5,5-dimethylhydantoin: LC50 fish 0.91 mg/L/96 hr. Concentrated material is toxic to
aquatic organisms. Diluted product in use is not expected to present a hazard to the environment.

13 - Disposal Considerations
Dispose in accordance with local, state and federal regulations.

14 鈥? Transportation Information_
US DOT Shipping Description: Consumer Commodity, ORM-D
Canadian TDG Shipping Description: Consumer Commodity (Limited Quantity)

15 鈥? Regulatory Information
US REGULATIONS
EPA TSCA: All ingredients for this product are listed on the TSCA inventory or exempt from
notification. This product is an EPA registered pesticide, EPA Registration No 6836-288-71903.
SARA Title III chemicals: None
CERCLA reportable quantity: This product is not subject to CERCLA release reporting
requirements. Many states have more stringent reporting requirements. Report spills and other
releases as required under federal, state and local regulations.
RCRA hazardous waste no: D001, D002

16 鈥? Other Information:
HMIS Rating: Health: 3 Fire: 0 Physical Hazard: 2



SIGNATURE: TITLE: Director of Global Quality Assurance

REVISION DATE: 05/29/2008 SUPERSEDES: 01/30/2007




Page 4 of 4

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