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MATERIAL SAFETY DATA SHEET Date : 18/10/2005
Supersedes :
FLAKE WHITE 鈥? Oil colour
BL 2.X.081
1. Identification of the product
Identification of the product : Couleurs extra-fines 脿 l鈥檋uile 鈥? FLAKE WHITE
Producer: J. BLOCKX Fils S.A.
Le Tombeu, 10
B 鈥? 4550 Nandrin
Tel : +32.85.41.11.62
Fax : +32.85.41.25.35
Type of product : Artists鈥檆olour
Use : Restricted to professional users
Other : Packaging <= 125ml
Emergency phone nr : Belgique 0032 70 245 245
UK 0044 870 600 6266
2. Informations on ingredients
Composition Value n掳 CAS/n掳 EINECS/Index CE Symbole(s) Phrase(s)R
Trilead-bis (carbonate) 70-90% 1319-46-6 / 215-290-6 / 082-001-00-6 TN 61-20/22- 33
-dihydroxide 62-50/53
3. Hazards identification
Risk Phrases : Harmful by inhalation and if swallowed.
Danger of cumulative effects.
May cause harm to the unborn child.
Possible risk of impaired fertility.
Symptoms relating to use
- Inhalation : Danger of serious damage to health by exposure through
inhalation.
- Skin contact : Repeated exposure to this material can result in absorption
through skin causing significant health hazard.
- Eye contact : Direct contact with the eyes is likely irritating.
- Ingestion : Severe ingestion hazard.
Dangerous effects for the environment : Very toxic to aquatic organisms, may cause long-term
adverse effects in the aquatic environment.
Note : : This product is considered to be hazardous and contains hazardous components (Directive
1999/45/EC).
4. First aid measures
First aid
- Inhalation : Assure fresh air breathing.
- Skin contact : Wash skin thoroughly with mild soap and water.
- Eye contact : Rinse immediately with plenty of water.
- Ingestion : Rinse mouth with water. If swallowed seek medical advice
immediately and show this container or label.
J. BLOCKX Fils S.A. Poison Inform. Center -Tel. : 070/245.245
Le Tombeu, 10 鈥? 4550 Nandrin Belgique T茅l. : +32.85.41.11.62
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MATERIAL SAFETY DATA SHEET Date : 18/10/2005
Supersedes:
FLAKE WHITE 鈥? Oil colour
BL 2.X.081
5. Fire 鈥? fighting measures
Prevention : Avoid contact with : Fluorine (F).
Extinguishing media : All extinguishing media can be used.
Surrounding fires : Use water spray or fog for cooling exposed containers.
Special exposure hazards : When heated to decomposition, emits dangerous fumes.
(PbO)
Protection against fire : Do not enter fire area without proper protective equipment,
including respiratory protection.
Special procedures : Exercise caution when fighting any chemical fire. Avoid
(reject) fire-fighting water to enter environment.
6. Accidental release measures
Personal precautions : Equip cleanup crew with proper protection.
Environmental precautions : Prevent entry to sewers and public waters. Notify authorities
if product enters sewers or public waters.
After spillage and/or leakage : Clean up any spills as soon as possible, using an absorbent
material to collect it. Use suitable disposal containers.
7. Handling and storage
Precautions in handling and storage : Handle in accordance with good industrial hygiene and
safety procedures.
Storage : Keep only in the original container in a cool, well ventilated
place.
Handling This material or its emissions may affect pregnancy and/or
foetus development. Do not breathe gas, fumes, vapour or
spray. Wash hands and other exposed areas with mild soap
and water before eat, drink or smoke and when leaving
work.
8. Exposure controls / personal protection
Personal protection : This material or its emissions may affect pregnancy and/or
foetus development.
- Respiratory protection If skin contact or contamination of clothing is likely,
protective clothing should be worn. Wear a mask if sanding
of blasting.
- Eye protection : Eye protection should only be necessary where liquid could
be splashed or sprayed.
- Ingestion : When using, do not eat, drink or smoke.
Industrial hygiene : Either local exhaust or general room ventilation is usually
required.
Exposure controls
- Belgium (AR 11.03.02 - M.B. 14.03.2002) : trilead-bis(carbonate)-dihydroxide : TLV = 0,15 mg/m3
(Pb)
J. BLOCKX Fils S.A. Poison Inform. Center -Tel. : 070/245.245
Le Tombeu, 10 鈥? 4550 Nandrin Belgique T茅l. : +32.85.41.11.62
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MATERIAL SAFETY DATA SHEET Date : 18/10/2005
Supersedes:
FLAKE WHITE 鈥? Oil colour
BL 2.X.081
9. Physical and chemical properties
Physical state : Viscous liquid.
Colour : White.
Odour : Oil.
Melting point [掳C] : : 400 掳C
Density : 3,7
Solubility in water [g/100 ml] : Negligible.
10. Stability and reactivity
Hazardous reactions : Stable.
Materials to avoid : Fluorine (F). May cause fire.
11. Toxicological information
On product : This product is considered to be hazardous and contains hazardous components
(Directive 1999/45/EC).
Rat oral LD50 [mg/kg] : 2000
12. Ecological information
On product : Toxic to aquatic life.
13. Disposal considerations
Disposal : Avoid release to the environment. Dispose in a safe manner in accordance with
local/national regulations. Dispose of this material and its container at hazardous or special waste
collection point (container park). EURAL : 08 01 11.
14. Transport information
ADR/RID : LQ (UN 3082)
15. Regulatory information
Symbol(s) : Toxic. Dangerous for the environment.
R Phrase(s) : R20/22 - Harmful by inhalation and if swallowed. R33 - Danger of cumulative
effects. R50/53 - Very toxic to aquatic organisms, may cause long-term adverse
effects in the aquatic environment. R61 - May cause harm to the unborn child. R62
- Possible risk of impaired fertility.
S Phrase(s) S01/02 - Keep locked up and out of reach of children. S36/37 - Wear suitable
protective clothing and gloves. S45 - In case of accident or if you feel unwell, seek
medical advice immediately (show the label when possible). S53 - Avoid exposure
- obtain special instructions before use. S61 - Avoid release to the environment.
Refer to special instructions/Safety data sheets.
Contains : : Warning ! Contains lead.
Restricted to professional users.
J. BLOCKX Fils S.A. Poison Inform. Center -Tel. : 070/245.245
Le Tombeu, 10 鈥? 4550 Nandrin Belgique T茅l. : +32.85.41.11.62
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MATERIAL SAFETY DATA SHEET Date : 18/10/2005
Supersedes:
FLAKE WHITE 鈥? Oil colour
BL 2.X.081
16. Other information
Further information : Specifications and technical information on the product may be obtained from
your supplier.
The contents and format of this MSDS are in accordance with EEC Commission Directive
2001/58/EC.
DISCLAIMER OF LIABILITY The information in this MSDS was obtained from sources
which we believe are reliable. However, the information is provided without any warranty,
express or implied, regarding its correctness. The conditions or methods of handling, storage,
use or disposal of the product are beyond our control and may be beyond our knowledge. For
this and other reasons, we do not assume responsibility and expressly disclaim liability for loss,
damage or expense arising out of or in any way connected with the handling, storage, use or
disposal of the product. This MSDS was prepared and is to be used only for this product. If the
product is used as a component in another product, this MSDS information may not be
applicable.
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