P120-20-060
Issue: B
Rev Date: 01-02-05
MATERIAL SAFETY DATA SHEET Page: 1 of 11
PRODUCT NAME: VisionCoat 2000
1. Product and Company Identification
Product Name: VisionCoat 2000
Synonyms: None
Item Numbers : E45022100
European Contact Details US Contact Details
BOC Edwards, Manor Royal, Crawley, BOC Edwards, 301 Ballardvale Street,
West Sussex, RH10 2LW, England Wilmington, MA 01887
General enquiries General enquiries
UK : +44 (0) 1293 528844 +(1) 978-658-5410
France : +(33) 1 47 98 24 01 Toll Free: 800-848-9800
Germany : +(49) 6420-82-410
Italy : +(39) 248-4471 24 Hr Emergency telephone number:
Chemtrec : 1-800-424-9300
2. Composition/Information on Ingredients
Ingredient % Weight Hazard Symbols Risk Phrases CAS No EINECS No
Perfluoro Compounds, 60 NAV NAV 86508-42-1 NAV
(primarily compounds with 8
Carbons) (perfluorooctane)
m-Xylenehexafluoride 38 NAV R10 402-31-3 206-939-4
Proprietary fluorine 2 NAV NAV Proprietary Proprietary
compound containing
organopolysiloxane
OSHA Regulatory Status: This product is classified as hazardous under OSHA regulations.
Additional Information :
m-Xylenehexafluoride is also known as 1,3-Bis(Trifluoromethyl)Benzene
3. Hazards Identification
EMERGENCY OVERVIEW
Clear to pale yellow flammable liquid with solvent odor. Dangerous fire and explosion hazard. May cause skin and
eye irritation. Repeated exposure to fluorides over time may have long-term health effects.
For short and long term exposure effects see Toxicological data section 11
Route of Entry
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Rev Date: 01-02-05
MATERIAL SAFETY DATA SHEET Page: 2 of 11
PRODUCT NAME: VisionCoat 2000
Skin Contact Skin Absorption Eye Contact Inhalation Ingestion
Yes Yes Yes Yes Yes
Health Effects
Exposure Limits Irritant Sensitisation
No Yes Yes
Teratogen Reproductive Hazard Mutagen
No No No
Synergistic : None known
May cause eye irritation.
Eye Effects:
May cause skin irritation .Can be skin absorbed. Prolonged contact may cause dermatitis.
Skin Effects:
No information available. Exposure to fluoride compounds can result in systemic toxic
Ingestion Effects:
effects on the heart, liver, and kidneys. It may also deplete calcium levels in the body
leading to hypocalcemia and death.
May cause slight irritation to mucous membranes and upper respiratory tract.
Inhalation Effects:
If thermal decomposition occurs: May be absorbed following inhalation and cause target
organ effects.
NFPA Hazard codes HMIS Hazard codes Rating System
2 2 0 = No Hazard
Health Health
3 3 1 = Slight hazard
Flammability Flammability
0 0 2 = Moderate Hazard
Reactivity Reactivity
3 = Serious Hazard
4 = Severe hazard
Note :
National Fire Protection Association Hazard Codes are designed for use by firefighters, sheriffs, or other emergency response teams who are
concerned with the hazards associated with emergency releases and fire conditions. These NFPA codes are designed to address the hazards
of this product during a fire or emergency release.
Hazardous Material Information Service codes are intended for use in everyday workplace settings to provide a rapid indication of the
occupational hazards associated with chemicals used in the workplace.
Additional Information :
Flammable Liquids (based on IMO)
Flammable Liquids (based on DOT)
m-Xylenehexafluoride
Chronic: Chronic inhalation and ingestion may cause fluorosis with skeletal abnormalities. Chronic exposure to
fluoride compounds may cause systemic toxicity.
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Rev Date: 01-02-05
MATERIAL SAFETY DATA SHEET Page: 3 of 11
PRODUCT NAME: VisionCoat 2000
4. First Aid Measures
Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and
Eyes:
lower eyelids. Get medical aid immediately.
Get medical aid. Flush skin with plenty of soap and water for at least 15 minutes while
Skin:
removing contaminated clothing and shoes.
Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If
Inhalation:
breathing is difficult, give oxygen. Get medical aid.
If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by
Ingestion:
mouth to an unconscious person. Get medical aid immediately.
Limited toxicological data is available for ingredients in this product. Treatment should be
Other Information:
symptomatic and supportive.
5. Fire Fighting Measures
Foam, dry chemical, carbon dioxide, water spray. Direct water stream may cause
Extinguishing Media:
frothing.
Flammable and explosive. Solvent vapours form explosive mixtures with air.
Fire and Explosion Hazard:
Vapors can travel to a source of ignition and flash back.
Firefighters should wear a full facepiece NIOSH-approved self-contained breathing
Special Protective
apparatus in pressure-demand and full protective gear with additional chemical
Equipment for Fire Fighters:
protective clothing adequate for toxic decomposition products. During fire irritating
and highly toxic fluorine compounds and other oxidation products may be
generated by thermal decomposition or combustion.
Carbon monoxide, Carbon dioxide, Silicon dioxide, Hydrogen Fluoride and
Hazardous Decomposition:
Perfluoroisobutylene (PFIB).
For Flammability Properties - see section 9
Additional Information : N/A
6. Accidental Release Measures
Remove all sources of ignition. Observe precautions from other sections. Ventilate the area with
Land Spill:
fresh air. Isolate hazard area and contain spill. Wear appropriate protective equipment (See
Section 8). Working from around the edges of the spill inward, cover with bentonite, vermiculite,
or commercially available inorganic absorbent material. Mix in sufficient absorbent until it
appears dry. Collect as much of the spilled material as possible. Dike well ahead of large spills for
later recycle or disposal. Absorbed materials may still be flammable. Use appropriate
precautions. Clean up residue with an appropriate organic solvent. Read and follow safety
precautions on the solvent label and MSDS. Place in a metal container approved for
transportation by appropriate authorities. Seal the container. Dispose of collected material as
soon as possible.
Additional Information : N/A
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The stripe symbol is a trade mark of the BOC Group.
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Issue: B
Rev Date: 01-02-05
MATERIAL SAFETY DATA SHEET Page: 4 of 11
PRODUCT NAME: VisionCoat 2000
7. Handling and Storage
Store in cool, well-ventilated area away from heat, sparks, flames and other sources of ignition.
Storage:
Keep container closed when not in use. Store in appropriate flammables-area.
Wash thoroughly after handling. Remove contaminated clothing promptly and wash before reuse.
Handling:
Do not eat, drink, smoke, apply cosmetics, or store personal items in work and storage areas.
Smoking cigarettes contaminated with this product may release hazardous fluorine compounds.
Use only in a well-ventilated area. Do not breath dust, vapour mist, or gas. Do not get in eyes, on
skin, or on clothing. Keep container tightly closed. Do not ingest or inhale. Use spark-proof tools
and explosion proof equipment. Ground and bond containers when transferring material. Do not
pressurize, cut, weld, solder, drill, grind, or expose empty or full containers to heat, sparks, and
flames.
Additional Information :
Empty containers remain a flammable and explosion hazard. Handle and store accordingly.
8. Exposure Controls/Personal Protection
Exposure Limits
Ingredient ACGIH - TLV OSHA - PEL Occupational Exposure
Limits EH40 (UK)
None listed None Established None Established None Established
Additional Information :
May give off hydrogen fluoride, perfluoroisobutylene, and other decomposition products at high temperatures.
ACGIH has established a Ceiling of 0.01 ppm for perfluoroisobutylene. Hydrogen fluoride has an ACGIH Ceiling
limit of 3 ppm and an OSHA PEL of 3 ppm (8-H TWA).
Personal Protection:
Provide appropriate local exhaust ventilation on open containers. For those
Engineering Measures:
situations where the fluid might be exposed to extreme overheating due to misuse
or equipment failure, use with appropriate local exhaust ventilation and enclosed
processes sufficient to maintain levels of thermal decomposition products below
their exposure guidelines. An emergency eyewash station and safety shower
should be located in close proximity to the work area.
A respiratory protection program that meets OSHA鈥檚 29 CFR 1910.134 and ANSI
Respiratory Protection:
Z88.2 requirement or European Standard EN 149 must be followed whenever
workplace conditions warrant a respirator鈥檚 use.
Wear appropriate protective gloves and clothing to prevent skin exposure.
Hand/Skin Protection:
Wear appropriate protective eyeglasses or chemical safety goggles as described
Eye/Face Protection:
by OSHA鈥檚 eye and face protection regulations in 29 CFR 1910.133 or European
Standard EN166.
DO NOT eat or smoke whilst using the product. Wash hands before eating or
Hygiene Measures:
smoking.
Overalls should be laundered regularly
Other/General Protection:
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P120-20-060
Issue: B
Rev Date: 01-02-05
MATERIAL SAFETY DATA SHEET Page: 5 of 11
PRODUCT NAME: VisionCoat 2000
Additional Information :
VisionCoat 2000 Solvent / 3M PF-5080
Ingredient Authority Type Limit Additional Information
PERFLUORO COMPOUNDS, 3M TWA 1000 ppm 5 through 8 carbons
(PRIMARILY COMPOUNDS -specific form
WITH 8 CARBONS)
9. Physical and Chemical Properties
0 0
Water white to slight 62.5 C 144.5 F
Appearance and Odour Boiling Point
yellow clear liquid.
Solvent like.
0 0
N/A C F
pH (as supplied) Melting Point
0 0
Not Soluble C F
Solubility in Water Freezing Point
0 0
C F
Volatile Content by Auto Ignition
Volume
0 0
Not determined 26c* C F
Specific Gravity Flash Point
o
Not determined value range - @ F
Vapour Pressure Vapour Pressure (Torr)
Closed cup * for KP-801m
Flash Point Method
N/A = Not Applicable
Additional Information :
VisionCoat 2000 Solvent / 3M PF-5080
Specific Physical Form: Liquid
Odor, Color, Grade: Colorless with no odor.
General Physical Form: Liquid
Autoignition temperature Not Applicable
Flash Point Not Applicable
Flammable Limits - LEL Not Applicable
Flammable Limits - UEL Not Applicable
Boiling point 90 - 107 潞C [Details: CONDITIONS: (Typical)]
Density 1.7 g/ml
Vapor Density Approximately 15.1 [@ 20 潞C] [Ref Std: AIR=1]
Vapor Pressure Approximately 45.7 [@ 20 潞C]
Specific Gravity Approximately 1.7 [Ref Std: WATER=1]
pH Not Applicable
Melting point Not Applicable
Solubility in Water Nil
Evaporation rate >=1.0 [Ref Std: BUOAC=1]
Volatile Organic Compounds Not Applicable
Percent volatile Approximately 100 %
VOC Less H2O & Exempt Solvents Not Applicable
Viscosity 0.8 centistoke
705
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The stripe symbol is a trade mark of the BOC Group.
Ref 2D01 form issue 1.2
P120-20-060
Issue: B
Rev Date: 01-02-05
MATERIAL SAFETY DATA SHEET Page: 6 of 11
PRODUCT NAME: VisionCoat 2000
m-Xylenehexafluoride
Physical State: Liquid
Appearance: colorless to light yellow
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Vapor Density: Not available.
Evaporation Rate:Not available.
Viscosity: Not available.
Boiling Point: 116 - 116.3 deg C
Freezing/Melting Point:Not available.
Decomposition Temperature:Not available.
Autoignition Temperature: Not available.
Flash Point: 26 deg C ( 78.80 deg F)
NFPA Rating: Not published.
Explosion Limits, Lower:Not available.
Upper: Not available.
Solubility: Not available.
Specific Gravity/Density:1.3780g/cm3
Molecular Formula:(CF3)2C6H4
Molecular Weight:214.11
10. Stability and Reactivity
Stable at room temperature in closed containers under normal storage and
Stability:
handling conditions.
Strong oxidizing agents, strong bases. Finely divided active metals; Alkali and
Material/Conditions to Avoid:
alkaline earth metals
During Combustion Carbon monoxide, Carbon dioxide, Hydrogen Fluoride and
Hazardous Decomposition:
Perfluoroisobutylene (PFIB).
Will not occur.
Hazardous Polymerisation:
Additional Information : N/A
11. Toxicological Information
For information available concerning the various toxicological (health) effects which may arise if the user comes
into contact with the substance or preparation refer to Section 3 Hazards Identification.
Animal Data:
No Data
LD50 value:
No Data
LC50 value:
No Data
Tumorigenic :
No Data
Reproductive :
No Data
Mutagenic :
No Data
Others :
No Data
Carcinogenicity :
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Ref 2D01 form issue 1.2
P120-20-060
Issue: B
Rev Date: 01-02-05
MATERIAL SAFETY DATA SHEET Page: 7 of 11
PRODUCT NAME: VisionCoat 2000
Additional Information :
Limited toxicological information was available for ingredients contained in this product.
VisionCoat 2000 Solvent / 3M PF-5080
No Data Available
m-Xylenehexafluoride
RTECS#:
CAS# 402-31-3 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
CAS# 402-31-3: Not listed by ACGIH, IARC, NIOSH, NTP, or OSHA.
Epidemiology: No data available.
Teratogenicity: No data available.
Reproductive Effects: No data available.
Neurotoxicity: No data available.
Mutagenicity: No data available.
Other Studies: No data available.
12. Ecological Information
Elimination
No data for mixture. See below for ingredient information.
Persistence
No data for mixture. See below for ingredient information.
Degradability
Behaviour in the Aquatic Compartment
No data for mixture. See below for ingredient information.
Mobility
No data for mixture. See below for ingredient information.
Bio accumulation
Ecotoxicity
No data for mixture. See below for ingredient information.
Aquatic
No data for mixture. See below for ingredient information.
Terrestrial
Additional Information :
VisionCoat 2000 Solvent / 3M PF-5080
ECOTOXICOLOGICAL INFORMATION
Test Organism Test Type Result
Fathead Minnow, Pimephales promelas 96 hours Lethal Concentration 50% >1000 mg/l
CHEMICAL FATE INFORMATION
Test Type Result Protocol
Chemical Oxygen Demand Nil
20 days Biological Oxygen Demand Nil
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BOC Edwards is part of BOC Limited.
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P120-20-060
Issue: B
Rev Date: 01-02-05
MATERIAL SAFETY DATA SHEET Page: 8 of 11
PRODUCT NAME: VisionCoat 2000
Additional Information:
This compound is completely fluorinated (perfluorinated), or it contains perfluorinated portions. Perfluoroalkyl
groups resist degradation in most natural environments. This low-solubility substance has insignificant toxicity to
aquatic organisms (Lowest LL50 or EL50 is >1000 mg/L). LL50 (Lethal Level) and EL50 are similar to LC50 and
EC50, but tests the water phase from incompletely-miscible mixtures. Take precautions to prevent direct release of
this substance to the environment. ATMOSPHERIC FATE: Perfluoro compounds (PFCs) are photochemically
stable and expected to persist in the atmosphere for more than 1000 yrs. PFCs have high global warming
potentials (GWP), exceeding 5000 (100-yr ITH). The Ozone Depletion Potential (ODP) is Zero.
m-Xylenehexafluoride
Ecotoxicity: Not available.
Environmental Fate: Not available.
Physical/Chemical: Not available.
Other: Not available.
13. Disposal Considerations
Chemical waste generators must determine whether a discarded chemical is classified as a hazardous waste and
act in accordance with local regulations..
Products which are considered hazardous for supply are classified as Special Waste and the disposal of such
chemicals is covered by regulations which may vary according to location. Contact a specialist disposal company or
the local waste regulator for advice. Empty containers must be decontaminated before returning for recycling.
Additional Information : N/A
14. Transport Information
PARAMETER EUROPEAN CANADIAN TDG UNITED STATES DOT
Resin solution, flammable Resin solution, flammable Resin solution, flammable
Proper Shipping Name
3 3 3
Hazard Class
UN 1866 UN 1866 UN 1866
Identification Number
FLAMMABLE LIQUID FLAMMABLE LIQUID FLAMMABLE LIQUID
Shipping Label
Additional Information : Packing Group III
VisionCoat 2000 Solvent / 3M PF-5080
ID Number(s):
98-0211-6506-7, 98-0211-6508-3, 98-0211-6510-9, 98-0211-6511-7, 98-0211-7177-6, 98-0211-7374-9,
98-0211-7937-3, 98-0212-1161-4, ZF-0002-0680-3, ZF-0002-0883-3, ZF-0002-0924-5, ZF-0002-1137-3,
ZF-0002-1138-1, ZF-0002-1171-2, ZF-0002-1362-7, ZF-0002-1394-0
m-Xylenehexafluoride
Shipping Name: FLAMMABLE LIQUID,N.O.S. (1,3-BIS(TRIFLUOROMETHYL))
Hazard Class: 3
UN Number: UN1993
Packing Group: III
705
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Ref 2D01 form issue 1.2
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Issue: B
Rev Date: 01-02-05
MATERIAL SAFETY DATA SHEET Page: 9 of 11
PRODUCT NAME: VisionCoat 2000
15. Regulatory Information
European Regulatory Information
Dangerous to supply : flammable material
Risk Phrases : R10
Safety Phrases :S15,S21,S24,S25,S41
Hazard Symbols : FLAMMABLE
United States Regulatory Information
U.S. TSCA: All CAS numbers listed in Section 2 are on the U.S. Toxic Substances Control Act Inventory (TSCA).
SARA TITLE III - SECTION 313 SUPPLIER NOTIFICATION:
This product does not contain toxic chemicals subject to reporting requirements of section 313 of the Emergency
Planning and Community Right-To-Know Act (EPCRA) of 1986 and of 40 CFR 372.
California Proposition 65: This product does not contain ingredient(s) known to the State of California to cause
cancer, birth defects, or other reproductive harm.
Canadian Regulatory Information
Canadian DSL: All CAS numbers listed in Section 2 are on the Canadian Domestic Substances List (DSL) or Non-
Domestic Substances List (NDSL).
Additional Information :
VisionCoat 2000 Solvent / 3M PF-5080
United States Regulatory Information
311/312 Hazard Categories:
Fire Hazard - No Pressure Hazard - No Reactivity Hazard - No Immediate Hazard - No Delayed Hazard 鈥? No
The components of this product are in compliance with the chemical notification requirements of TSCA.
All applicable chemical ingredients in this material are listed on the European Inventory of Existing Chemical
Substances (EINECS), or are exempt polymers whose monomers are listed on EINECS.
The components of this product are in compliance with the chemical registration requirements of: CDSL,
AICS, MITI.
m-Xylenehexafluoride
TSCA
CAS# 402-31-3 is listed on the TSCA inventory.
Health & Safety Reporting List
None of the chemicals are on the Health & Safety Reporting List.
Chemical Test Rules
None of the chemicals in this product are under a Chemical Test Rule.
Section 12b
None of the chemicals are listed under TSCA Section 12b.
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BOC Edwards is part of BOC Limited.
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Rev Date: 01-02-05
MATERIAL SAFETY DATA SHEET Page: 10 of 11
PRODUCT NAME: VisionCoat 2000
TSCA Significant New Use Rule
None of the chemicals in this material have a SNUR under TSCA.
SARA
Section 302 (RQ)
None of the chemicals in this material have an RQ.
Section 302 (TPQ)
None of the chemicals in this product have a TPQ.
Section 313
No chemicals are reportable under Section 313.
Clean Air Act:
This material does not contain any hazardous air pollutants. This material does not contain any
Class 1 Ozone depletors. This material does not contain any Class 2 Ozone depletors.
Clean Water Act:
None of the chemicals in this product are listed as Hazardous Substances under the CWA. None
of the chemicals in this product are listed as Priority Pollutants under the CWA. None of the
chemicals in this product are listed as Toxic Pollutants under the CWA.
OSHA:
None of the chemicals in this product are considered highly hazardous by OSHA.
STATE
CAS# 402-31-3 is not present on state lists from CA, PA, MN, MA, FL, or NJ.
California No Significant Risk Level: None of the chemicals in this product are listed.
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols:
Not available.
Risk Phrases:
R 10 Flammable.
Safety Phrases:
S 24/25 Avoid contact with skin and eyes.
WGK (Water Danger/Protection)
CAS# 402-31-3: 1
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
WHMIS: Not available.
CAS# 402-31-3 is not listed on Canada's Ingredient Disclosure List.
Exposure Limits
Shin-Etsu KP-801M
Labelling according to EC regulations required:
Symbol : Not Required
R-Phase : (R10) Flammable
S-Phrase : Not Required
Contains : m-Xylenehexafluoride
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Rev Date: 01-02-05
MATERIAL SAFETY DATA SHEET Page: 11 of 11
PRODUCT NAME: VisionCoat 2000
IMO Information
ID No : UN1866
Classification Analysis : Flammable Liquids / Class 3.3
Packaging Group : III
Proper Shipping Name : Resin Solution
Technical Shipping Name : Contains m-Xylenehexafluoride
Marine Pollutant : None
DOT Information
ID No: (49CFR 172.101) : UN 1866
Hazard Class (49CFR 172.101) : 3, Flammable Liquid
Packaging Group (49CFR 172.101) : III
Proper Shipping Name (49CFR 172.101) : Resin Solution
Technical Shipping Name : Contains m-Xylenehexafluoride
DOT Reportable Quantity (49CFR 172.101) : N/A
16. Other Information
Original Supplier Information:
PRODUCT NAME: PF-5080 3M Brand Performance Fluid
MANUFACTURER: 3M
DIVISION: 3M Specialty Materials
ADDRESS: 3M Center
St. Paul, MN 55144-1000
PRODUCT NAME: KP-801M
MANUFACTURER: Shin-Etsu Silicones Europe B.V.
MSDS No: EU-06-05301261
Glossary : CAS, Chemical Abstracts Service. TWA, Time-Weighted Average. STEL, Short Term Exposure Limit.
NFPA, National Fire Protection Association. HMIS, Hazardous Material Information Service. LD, Lethal Dose. LC,
Lethal Concentration. OSHA, Occupational Safety and Health Administration, US department of Labour. ACGIH,
American Conference of Governmental Industrial Hygienists. EINECS, European Inventory of Existing Commercial
Substances. MSHA, Mine Safety and Health Administration. N/A, Not Applicable. NAV, Not Available. NIOSH,
National Institute for Occupational Safety and Health. SCBA, Self-Contained Breathing Apparatus. CFR, Code of
Federal Regulations. RTECS, Registry of Toxic Effects of Chemical Substances. IARC, International Agency for
Research in Cancer. NTP, National Toxicology Program, OEL, Occupational Exposure Limit. TLV, Threshold Limit
Value. TSCA, Toxic Substances Control Act, CMRG: Chemical Manufacturer Recommended Guideline, AIHA:
American Industrial Hygiene Association Workplace Environmental Exposure Level (WEEL).
Revisions
This document has been reformatted. Individual changes are not highlighted.
___________________________________________________________________________________________
_
Although the information and recommendations in this data sheet are to the best of our knowledge correct, it is recommended
that you make your own determination of the material鈥檚 suitability for your purpose before you use it. The information contained in
this data sheet has been reproduced from the manufacturers data, the accuracy of this information is the responsibility of the
manufacturer. BOC Edwards accept no responsibility for damage of any nature resulting from the use of, or the reliance upon this
data sheet.
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Ref 2D01 form issue 1.2
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