SECTION V HEALTH HAZARD DATA
MATERIAL SAFETY DATA SHEET SS 932
Threshold Limited Value Airborne Exposure Limits: OSHA Permissible Exposure Limits (PEL): 2 mg (Sn)m3 (TWA).
ALDON 1533 W.Henrietta Rd.
ACGIH Threshold Limit Value (TLV): 2 mg (Sn)/m3 (TWA); 4 mg (Sn)/m3 (STEL).
SS 932
Avon, New York 14414 MSDS No.
庐
CORPORATION Effective Date January 8, 1997
(716) 226-6177 INHALATION: May cause irritation to the mucous membranes. Symptoms
Effects of Overexposure
may include coughing, sore throat, and shortness of breath. INGESTION:
May cause burning pain in mouth, nausea, vomiting, and diarrhea. May
SECTION I NAME 24 HOUR EMERGENCY ASSISTANCE cause irritation and blistering to mucous membranes. SKIN: May cause
redness, pain, blistering or burns. EYE CONTACT: May cause irritation,
Product STANNIC CHLORIDE, HYDRATED LUMPS CHEMTREC redness, pain, blurred vision, burns, and corneal damage.
Health 2
800-424-9300
Chemical
Emergency and
Tin Tetrachloride, Pentahydrate
Synonyms INHALATION: Remove to fresh air. If not breathing, give artificial
0
Fire
Day 716-226-6177
First Aid Procedures respiration. If breathing is difficult, give oxygen. Get medical attention.
Formula SnCl 鈥?5H O 0
Reactivity INGESTION: If swallowed, do NOT induce vomiting. If conscious, give
4 2
NFPA
large quantities of water to drink. Call a physician immediately. Never give
HAZARD RATING HMIS *
Unit Size up to 500 grams
anything by mouth to an unconscious person. SKIN: Wash with mild soap
LEAST SLIGHT MODERATE HIGH EXTREME
and water. EYES: Flush eyes with plenty of water for at least 15 minutes,
0 1 2 3 4
C.A.S. No. 10026-06-9
lifting lower and upper eyelids occasionally. Get medical attention
SECTION II INGREDIENTS OF MIXTURES immediately.
SECTION VI REACTIVITY DATA
Principal Component(s) % TLV Units
Conditions to Avoid
Stability Unstable Stable under ordinary conditions of use and
Stannic Chloride, Hydrated Lumps 100% See Section V.
storage. Excessive heat and temperature.
Stable X
Incompatibility
Potassium, Sodium, Turpentine and acids.
(Materials to Avoid)
DANGER! CORROSIVE! HARMFUL IF SWALLOWED.
Hazardous
CAUSES BURNS TO SKIN AND EYES. Emits toxic fumes of chlorine when heated to decomposition. Tin oxides.
Decomposition Products
SECTION III PHYSICAL DATA
Conditions to Avoid
Hazardous Polymerization
Specific Gravity (H2O = 1)
Melting Point (掳F) 53掳-56掳C (127掳-132掳F) 2.04
May Occur Will Not Occur Not applicable.
Percent Volatile
Boiling Point (掳F) 114掳C (237掳F) Non-volatile.
by Volume (%) X
Evaporation Rate
SECTION VII SPILL OR LEAK PROCEDURES
Vapor Pressure (mm Hg) Negligible as solid. N/A
=1)
(
Steps to be taken in case
Vapor Density (Air=1) Data not listed. Recover for use if not contaminated. Wear protective safety equipment
material is released or spilled and use adequate ventilation. Avoid making dust. Sweep up and place
Solubility in Water Soluble in water with evolution of heat. in a suitable container for disposal. Small quantities may be dissolved
in water and flushed to sewer with copious amounts of water.
Appearance & Odor White or slightly yellow crystals or fused lumps; slightly Hydrochloric acid odor.
Discharge, treatment, or disposal may be subject to Federal, State or Local laws.
Waste Disposal Method
SECTION IV FIRE AND EXPLOSION HAZARD DATA These disposal guidelines are intended for the disposal of catalog-size quantities only.
Lower
Flammable Limits in Air Upper
Flash Point
Whatever cannot be saved for reclamation may be disposed in a RCRA approved
Non-flammable. N/A
% by Volume
(Method Used)
hazardous waste facility.
Extinguisher
Use any means suitable for extinguishing surrounding fire. SECTION VIII SPECIAL PROTECTION INFORMATION
Media
None needed in normal laboratory handling. If dusty conditions prevail, work in ventilation
Respiration Protection
hood or wear a NIOSH/MSHA-approved dust mask or respirator.
(Specify Type)
SPECIAL FIREFIGHTING
Recommended. No.
Local Exhaust Special
PROCEDURES Ventilation
In the event of a fire, wear full protective clothing and NIOSH/MSHA- Recommended. Adequate to maintain below exposure limit.
Mechanical (General) Other
approved self-contained breathing apparatus with full facepiece
Protective Gloves Eye Protection
Rubber. Chemical safety glasses.
operated in the pressure demand or other positive pressure mode.
Other Protective
Goggles and shield, lab coat and apron, ventilation hood, proper gloves, eye wash station.
Equipment
SECTION IX SPECIAL PRECAUTIONS
(1993 EMERGENCY RESPONSE GUIDEBOOK, DOT P 5800.6, GUIDE PAGE NO. 60)
Precautions to be Taken
UNUSUAL FIRE AND Keep container tightly closed when not in use. Store in a cool, dry place.
in Handling & Storing
EXPLOSION HAZARDS Wash thoroughly after handling.
Keep container tightly closed when not in use.
Read label on container before using. Do not wear contact lenses when working with chemicals.
Other Precautions
FIRE: Not considered to be a fire hazard.
EXPLOSION: Not considered to be an explosion hazard.
Do not get in eyes, on skin, or on clothing. Avoid breathing dust. Use with
Emits toxic fumes of chlorine when heated to decomposition.
adequate ventilation. Remove and wash contaminated clothing.
For laboratory use only. Not for drug, food or household use. Keep out of reach of children.
Chemical Safety
Approved
Revision Date
No. 4 Michael Raszeja MR
1/08/97 Coordinator
D.O.T. STANNIC CHLORIDE, PENTAHYDRATE, 8, UN 2440, PG III The information contained herein is furnished without warranty of any kind. Employers should use this information only as a supplement to other information
gathered by them and must make independent determinations of suitability and completeness of information from all sources to assure proper use of these
Approved by U.S. Department of Labor "essentially similar" to form OSHA-20 materials and the safety and health of employees. * Hazardous Materials Industrial Standards. Printed on recycled paper.
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