SECTION V HEALTH HAZARD DATA
MATERIAL SAFETY DATA SHEET TT 240
Threshold Limited Value None established by (ACGIH 1992-93). The acute oral
ALDON 1533 W.Henrietta Rd. LD50 is 283 mg/kg in female rats and 317 mg/kg in male rats.
TT 240
Avon, New York 14414 MSDS No.
庐
CORPORATION November 22, 1996
Effective Date
(716) 226-6177 INGESTION: Chlorobutanol is a central nervous system depressant that has been used
Effects of Overexposure
as a sedative and hypnotic. Repeated ingestion of the material may be addictive.
Ingestion of the material in large quantities is capable of producing narcosis,
SECTION I NAME 24 HOUR EMERGENCY ASSISTANCE unconsciousness and death. SKIN: May produce local anesthesia. EYE CONTACT:
Non-irritant to rabbit eye. INHALATION: Specific data is not available. Exercise
Product CHLORETONE (CHLOROBUTANOL)
CHEMTREC appropriate procedures to minimize potential hazards.
2
Health
800-424-9300
Chemical
Emergency and
1,1,1-Trichloro-2-Methyl-2-Propanol INGESTION: If swallowed, if conscious, give one or two glasses of water to drink.
Synonyms 1
Fire
Day 716-226-6177
First Aid Procedures Induce vomiting. Repeat until vomit fluid is clear. Call physician. If victim is
Formula Cl3 CC(CH3)OH鈥?1/2H 2O unconscious or convulsing, do not induce vomiting or give anything by mouth.
0
Reactivity
NFPA SKIN: Flush all effected areas with plenty of water for several minutes. Seek
HAZARD RATING HMIS * medical attention if skin irritation occurs. EYE CONTACT: Flush the eyes
Unit Size up to 2.5 Kg.
thoroughly with plenty of running water for 15 minutes, occasionally lifting upper
LEAST SLIGHT MODERATE HIGH EXTREME
and lower eyelids. Seek medical attention if eye irritation occurs. INHALATION:
0 1 2 3 4
C.A.S. No. 6001-64-5
Remove to fresh air. If not breathing, give artificial respiration. If breathing is
SECTION II INGREDIENTS OF MIXTURES difficult, give oxygen. Get medical attention.
SECTION VI REACTIVITY DATA
Principal Component(s) % TLV Units
Conditions to Avoid
Stability Unstable
Avoid prolonged exposure to air, excessive
Chloretone (Chlorobutanol) 100% None established.
temperature and heat.
Stable X
Incompatibility
Strong oxidizers.
(Materials to Avoid)
WARNING! HARMFUL IF SWALLOWED.
Hazardous When heated to decomposition, emits toxic fumes of phosgene, hydrogen
chloride, carbon dioxide and/or carbon monoxide.
Decomposition Products
SECTION III PHYSICAL DATA
Conditions to Avoid
Hazardous Polymerization
Specific Gravity (H2O = 1)
76掳C (169掳F) N/A
Melting Point (掳F)
May Occur Will Not Occur Not applicable.
Percent Volatile
Boiling Point (掳F) 167掳C (332.6掳F) 100%
X
by Volume (%)
Evaporation Rate
SECTION VII SPILL OR LEAK PROCEDURES
N/A Sublimes easily.
Vapor Pressure (mm Hg) =1)
(
Steps to be taken in case
N/A
Vapor Density (Air=1) No emergency results from spillage. However, spills should be cleaned up
material is released or spilled promptly using the following procedures: Sweep up spilled material being
Solubility in Water 0.8 grams per 100 mL. cold water; very soluble in hot water. careful not to create dust. Sweep up and place in a suitable container for
disposal by incineration. Wash spill area with soap and water.
Appearance & Odor White crystals; camphor-like odor.
Discharge, treatment, or disposal may be subject to Federal, State or Local laws.
Waste Disposal Method
SECTION IV FIRE AND EXPLOSION HAZARD DATA These disposal guidelines are intended for the disposal of catalog-size quantities only.
Lower
Flammable Limits in Air Upper
Flash Point
Non-flammable. N/A
% by Volume
(Method Used) Dispose of in accordance with federal, state and local regulations.
Extinguisher
SECTION VIII SPECIAL PROTECTION INFORMATION
Foam; carbon dioxide; dry chemical.
Media
None should be needed in normal laboratory handling at room temperature. If dusty conditions
Respiration Protection
(Specify Type) prevail, work in ventilation hood or wear a NIOSH/MSHA-approved dust mask or respirator.
SPECIAL FIREFIGHTING
Local Exhaust Special
None needed. No.
PROCEDURES Ventilation Recommended. No.
Mechanical (General) Other
In fire conditions, wear a NIOSH/MSHA-approved self-contained
breathing apparatus and full protective clothing to prevent contact
Protective Gloves Eye Protection Chemical safety glasses.
Rubber, for repeated contact.
with skin and eyes.
Other Protective
Lab coat, eye wash station, proper gloves, ventilation hood.
Equipment
SECTION IX SPECIAL PRECAUTIONS
Precautions to be Taken Containers should be stored in a cool, dry, well-ventilated are away from
UNUSUAL FIRE AND in Handling & Storing flammable materials and sources of heat or flame. Avoid prolonged
EXPLOSION HAZARDS exposure to air. Wash thoroughly after handling.
Keep container tightly closed when not in use.
Fire hazard slight when exposed to heat or flame. Dangerous when Read label on container before using. Do not wear contact lenses when working with chemicals.
Other Precautions
heated to decomposition, it emits highly toxic fumes of phosgene and Exercise due caution to prevent damage to or leakage from the
hydrogen chloride; can react with oxidizing materials. container. Avoid prolonged exposure to air. Remove and wash
contaminated clothing.
For laboratory use only. Not for drug, food or household use. Keep out of reach of children.
Chemical Safety
Approved
Revision Date
No. 3 Michael Raszeja
11/22/96 MR
Coordinator
D.O.T. NON-REGULATED. The information contained herein is furnished without warranty of any kind. Employers should use this information only as a supplement to other information
gathered by them and must make independent determinations of suitability and completeness of information from all sources to assure proper use of these
Approved by U.S. Department of Labor "essentially similar" to form OSHA-20 materials and the safety and health of employees. * Hazardous Materials Industrial Standards. Printed on recycled paper.
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