MATERIAL SAFETY DATA SHEET
MANUFACTURER Varian Instruments 鈥? Middelburg
ADDRESS Herculesweg 8
4338 PL Middelburg, Netherlands
PHONE 31.118.67100 MSDS Number: 1002-346 Rev. 0
EMERGENCY PHONE 1.800.424.9300 鈥? CHEMTREC USA Date: December 13, 2002
FAX 31.118.633118 Prepared by: Corporate EH&S
SECTION 1: MATERIAL IDENTIFICATION
Product Name: GC32 (C12-C36) mix - Testmix CP346
Synonyms: Dodecane, Hexadecane, Eicosane, Tetracosane, Octacosane, Dotriacontane, and Hexatriacontane in
Heptane. Heptane is also known as Heptyl hydride and Dipropylmethane.
SECTION 2: COMPOSITION
An ampoule/vial containing the following:
Approximate NTP IARC
Component CAS Number Concentration Carcinogen Status Carcinogen Status
n-Dodecane 112-40-3 0.03% not listed not listed
n-Hexadecane 544-76-3 0.03% not listed not listed
n-Eicosane 112-95-8 0.03% not listed not listed
n-Tetracosane 646-31-1 0.03% not listed not listed
n-Octacosane 630-02-4 0.03% not listed not listed
n-Dotriacontane 544-85-4 0.03% not listed not listed
n-Hexatriacontane 630-06-8 0.03% not listed not listed
n-Heptane 142-82-5 balance not listed not listed
NOTE: Unless otherwise noted, the information below pertains only to the Heptane solvent in the ampoule/vial.
SECTION 3: HAZARD IDENTIFICATION
Emergency Overview: Colorless liquid. Flash Point: -4 deg C. Flammable liquid and vapor. Harmful or fatal if swallowed.
Aspiration hazard if swallowed. May cause respiratory tract irritation. Breathing vapors may cause drowsiness and dizziness.
Dangerous for the environment. Target Organs: Central nervous system, skin.
Potential Health Effects
Inhalation: Inhalation of high concentrations may cause central nervous system effects characterized by nausea, headache,
dizziness, unconsciousness and coma. Causes respiratory tract irritation. Aspiration may lead to pulmonary edema. Vapors may
cause dizziness or suffocation.
Ingestion: Aspiration hazard. Causes gastrointestinal irritation with nausea, vomiting and diarrhea. Aspiration of material into the
lungs may cause chemical pneumonitis, which may be fatal.
Skin Contact: May cause skin irritation with itching and redness. Prolonged or repeated skin contact may cause defatting and
dermatitis.
Eye Contact: May cause irritation, redness, and pain.
Carcinogen Status: NTP: Not listed IARC: Not listed
SECTION 4: FIRST AID INFORMATION
Inhalation: Get medical attention immediately. Remove to fresh air. If breathing is difficult, give oxygen. Do NOT use mouth-to-
mouth resuscitation. If breathing has ceased apply artificial respiration using oxygen and a suitable mechanical device such as a
bag and a mask.
Ingestion: Do NOT induce vomiting. If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by
mouth to an unconscious person. Possible aspiration hazard. Get medical aid immediately.
Skin Contact: In case of contact, immediately flush skin with plenty of soap and water for at least 15 minutes. Remove
contaminated clothing and shoes. Wash clothing before reuse. Get medical aid if irritation develops or persists.
Eye Contact: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical
aid. Do NOT allow victim to rub or keep eyes closed.
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SECTION 5: FIRE-FIGHTING INFORMATION
Fire: Flash point (closed cup): -4C (25F)
Autoignition temperature: 204C (399F)
Flammable limits in air % by volume: Lower = 1.0 Upper = 6.7
NFPA Rating: health-1; flammability-3; reactivity-0
Explosion: Above flash point, vapor-air mixtures are explosive within flammable limits noted above. Vapors can flow along
surfaces to distant ignition source and flash back. Sealed containers may rupture when heated. Contact with strong oxidizers may
cause fire. Sensitive to static discharge.
Fire Extinguishing Media: Dry chemical, foam or carbon dioxide. Water may be ineffective. Water spray may be used to keep fire
exposed containers cool, dilute spills to nonflammable mixtures, protect personnel attempting to stop leak and disperse vapors.
SECTION 6: ACCIDENTAL RELEASE MEASURES
Use proper personal protective equipment as indicated in Section 8. Ventilate area of leak or spill. Remove all sources of ignition.
Absorb spill with inert material (e.g. vermiculite, sand or earth), scoop up with a nonsparking tool, then place into a suitable
container for disposal. Do not flush to sewer!
SECTION 7: HANDLING AND STORAGE
Handling: Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use only in a well-ventilated
area. Keep container tightly closed. Avoid contact with heat, sparks and flame. Do not get on skin or in eyes. Avoid ingestion and
inhalation.
Storage: Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances.
SECTION 8: EXPOSURE CONTROL/PERSONAL PROTECTIVE EQUIPMENT
Airborne Exposure Limits: United States - OSHA Permissible Exposure Limit (PEL): 500 ppm (TWA)
United States - ACGIH Threshold Limit Value (TLV): 400 ppm (TWA); 500 ppm (STEL)
Australia: Time-weighted average 400 ppm (1600 mg/m3), 1993
The Netherlands: MAC-TGG 400 ppm (1600 mg/m3), JAN1999
Personal Protective Equipment
Eye Protection: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European Standard EN166. Maintain eye wash fountain and quick-drench facilities in
work area.
Skin Protection: Wear impervious gloves, apron, and/or clothing.
Clothing: Wear appropriate protective clothing to prevent skin exposure.
Respirators: Follow the OSHA respirator regulations found in 29CFR 1910.134 or European Standard EN 149. Use a NIOSH or
European Standard EN 149 approved respirator when necessary.
Ventilation System: A system of local and/or general exhaust is recommended to keep employee exposures below the Airborne
Exposure Limits. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its
source, preventing dispersion of it into the general work area. Please refer to the ACGIH document, "Industrial Ventilation, A
Manual of Recommended Practices", most recent edition, for details.
SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES
Appearance: Clear, colorless liquid Boiling Point: 98C (208F)
Odor: Gasoline-like odor Melting Point: - 91C (-132F)
Solubility: Insoluble Vapor Density: 3.5 (Air=1)
Specific Gravity: 0.68 (Water = 1) Vapor Pressure (mm Hg): 40 @ 20C (68F)
pH: Not available. Evaporation Rate: 3.2 (Butyl Acetate = 1)
Molecular Formula: C7H16 % Volatiles by Volume: 100
Molecular Weight: 100.2
SECTION 10: STABILITY AND REACTIVITY DATA
Stability: Stable at room temperature in sealed containers.
Hazardous Decomposition Products: Carbon dioxide and carbon monoxide may form when heated to decomposition.
Hazardous Polymerization: Will not occur.
Incompatibilities: Strong oxidizers, heat, and sources of ignition.
Conditions to Avoid: Incompatibles.
MSDS# 1002-346 Revision 0 Effective Date 12/13/02 Page 2 of 4
SECTION 11: TOXICOLOGICAL INFORMATION
RTECS#: MI7700000 for CAS# 142-82-5
LD50/LC50:
Inhalation, rat: LD50 = 103 gm/m3 /4 hour
Carcinogenicity: Not listed by ACGIH, IARC, NIOSH, NTP, or OSHA.
Reproductive effects: Not available.
Mutagenicity: Not available.
SECTION 12: ECOLOGICAL INFORMATION
Environmental Fate: When released into the soil, this material may biodegrade to a moderate extent. When released into the
soil, this material is not expected to leach into groundwater. When released into the soil, this material is expected to quickly
evaporate. When released into water, this material may biodegrade to a moderate extent. When released to water, this
material is expected to quickly evaporate. This material may bioaccumulate to some extent. When released into the air, this
material is expected to be readily degraded by reaction with photochemically produced hydroxyl radicals. When released into
the air, this material is expected to have a half-life between 1 and 10 days.
Environmental Toxicity: Fish: Goldfish: LC50 = 4.0 mg/L; 24 Hr.; Unspecified Mosquito Fish: LC50 = 4900 mg/L; 24 Hr.
SECTION 13: DISPOSAL GUIDELINES
Dispose in compliance with federal, state, and local regulations. Chemical waste generators must determine whether a discarded
chemical is classified as a hazardous waste. US EPA guidelines for the classification determination are listed in 40 CFR Parts
261.3. Additionally, waste generators must consult state and local hazardous waste regulations to ensure complete and accurate
classification.
USEPA RCRA waste number D001.
The information offered here is for the product as shipped. Use and/or alterations to the product such as mixing with other
materials may significantly change the characteristics of the material and alter the RCRA classification and the proper disposal
method.
SECTION 14: TRANSPORT INFORMATION
Ship in accordance with all applicable local, State, Federal, and International transportation regulations.
The following is a summary only. Check regulations for complete information:
United States (Land, D.O.T.) International (Air, I.C.A.O.)
Proper Shipping Name: Heptanes Proper Shipping Name: : Heptanes
Hazard Class: 3 Hazard Class: 3
UN/NA: : UN1206 UN/NA: UN1206
Packing Group: II Packing Group: II
MSDS# 1002-346 Revision 0 Effective Date 12/13/02 Page 3 of 4
SECTION 15: REGULATORY INFORMATION
US Federal
TSCA: CAS# 142-82-5 is listed on the TSCA inventory.
OSHA: None of the chemicals in this product are considered highly hazardous by OSHA.
SARA 311/312: Acute: Yes Chronic: Yes Fire: Yes Pressure: No Reactivity: No
US State
CAS# 110-54-3 can be found on the following state right to know lists: New Jersey, Florida, Pennsylvania, Minnesota,
Massachusetts.
California Proposition 65: Not regulated.
Other Regulations
EC Classification: F 鈥? Highly Flammable, Xi - Irritant
EC Risk and Safety Phrases:
Risk Phrases:
R 11 Highly flammable.
R 38 Irritating to skin.
R 50/53 Very toxic to aquatic organisms; may cause long-term adverse effects in the aquatic environment.
R 65 Harmful: may cause lung damage if swallowed.
R 67 Vapors may cause drowsiness and dizziness.
Safety Phrases:
S 16 Keep away from sources of ignition - No smoking.
S 29 Do not empty into drains.
S 33 Take precautionary measures against static discharges.
S 36/37 Wear suitable protective clothing and gloves.
S 9 Keep container in a well-ventilated place.
S 60 This material and/or its container must be
S 61 Avoid release to the environment. Refer to special instructions/Safety data sheets.
Australian Hazchem Code: 3[Y]E
SECTION 16: OTHER INFORMATION
NOTE: Unless otherwise noted, the information above pertains only to the Heptane solvent in the ampoule/vial.
This MSDS was prepared in accordance with ANSI Z400.1-1993 and 91/155/EEC recommended formats.
The information contained herein is believed to be accurate, but does not purport to be all-inclusive and shall be used only as a
guide. Varian, Inc., does not guarantee said information is accurate or complete, nor shall any of this information constitute a
warranty, whether expressed or implied, as to the safety of the goods, the merchantability of the goods, or the fitness of the goods
for a particular purpose. It is the user鈥檚 responsibility to determine the suitability of this information and to assure the adoption of
necessary precautions. Varian, Inc. shall not be held liable for any damage resulting from handling or from contact with the above
product, nor for the results obtained, or for incidental or consequential damage arising from the use of these data. No freedom from
infringement of any patent, copyright or trademark is to be inferred.
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