SDS Number 127072 Approved/Revised 03-Oct-2003 Version 03
Material DEBROX DROPS
SAFETY DATA SHEET
1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE
COMPANY/UNDERTAKING
Material DEBROX DROPS
DEBROX DROPS (US) * DEBROX * DEBROX LIQUID * MFC 50004069 *
Synonyms
CARBAMIDE PEROXIDE, FORMULATED PRODUCT
GlaxoSmithKline, Corporate Environment, Health & Safety
Company Name
980 Great West Road
Brentford, Middlesex TW8 9GS UK
UK General Information: +44-20-8047-5000
Transport Emergency (EU) +44-1865-407333
Medical Emergency +1-612-221-3999, Ext 221
Information and Advice: US number, available 24 hours
Multi-language response
GlaxoSmithKline, Corporate Environment, Health & Safety
2200 Renaissance Blvd, Suite 105
King of Prussia, PA 19406 US
US General Information: +1-888-825-5249
Transport Emergency (non EU) +1-703-527-3887
US number, available 24 hours
Multi-language response
2. COMPOSITION / INFORMATION ON INGREDIENTS
Percentage
Ingredients CAS RN
UREA 4.5
57-13-6
HYDROGEN PEROXIDE 2.6
7722-84-1
NON-HAZARDOUS INGREDIENTS 92.9
Unassigned
3. HAZARDS IDENTIFICATION
This product is expected to be non-combustible.
Fire and Explosion
Health Handling this product in its final form presents minimal risk from
occupational exposure.
Health effects information is based on hazards of components.
Environment Dangerous for the environment. Harmful to aquatic organisms.
4. FIRST-AID MEASURES
Ingestion Never attempt to induce vomiting. Do not attempt to give any solid or liquid
by mouth if the exposed subject is unconscious or semi-conscious. Wash
out the mouth with water. If the exposed subject is fully conscious, give
plenty of water to drink. Obtain medical attention.
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SDS Number 127072 Approved/Revised 03-Oct-2003 Version 03
Material DEBROX DROPS
Inhalation Physical form suggests that risk of inhalation exposure is negligible.
Skin Contact Using appropriate personal protective equipment, remove contaminated
clothing and flush exposed area with large amounts of water. Obtain
medical attention if skin reaction occurs, which may be immediate or
delayed.
Eye Contact Wash immediately with clean and gently flowing water. Continue for at least
15 minutes. Obtain medical attention.
NOTES TO HEALTH PROFESSIONALS
Medical Treatment Treat according to locally accepted protocols. For additional guidance, refer
to the local poison control information centre.
Medical Conditions None for occupational exposure.
Caused or Aggravated
by Exposure
Health Surveillance Pre-placement and periodic health surveillance is not usually indicated. The
final determination of the need for health surveillance should be determined
Procedures
by local risk assessment.
Antidotes No specific antidotes are recommended.
5. FIRE-FIGHTING MEASURES
Fire and Explosion Not expected for the product, although the packaging is combustible.
Hazards
Extinguishing Media Water, dry powder or foam extinguishers are recommended. Carbon
dioxide extinguishers may be ineffective.
Special Firefighting For single units (packages): No special requirements needed.
For larger amounts (multiple packages/pallets) of product: Since toxic,
Procedures
corrosive or flammable vapours might be evolved from fires involving this
product and associated packaging, self contained breathing apparatus and
full protective equipment are recommended for firefighters.
If possible, contain and collect firefighting water for later disposal.
Hazardous Combustion Toxic, corrosive or flammable thermal decomposition products are
expected when the product is exposed to fire.
Products
6. ACCIDENTAL RELEASE MEASURES
Personal Precautions Wear protective clothing and equipment consistent with the degree of
hazard.
Environmental Precautions For large spills, take precautions to prevent entry into waterways, sewers, or
surface drainage systems.
Clean-up Methods Spread an inert absorbent on the spill and place in a suitable, properly
labelled container for recovery or disposal.
Decontamination No specific decontamination or detoxification procedures have been
identified for this product.
Procedures
7. HANDLING AND STORAGE
HANDLING
General Requirements No special control measures required for the normal handling of this
product. Normal room ventilation is expected to be adequate for routine
handling of this product.
STORAGE Keep containers tightly closed in a cool, well ventilated area. No storage
requirements necessary for occupational hazards. Follow product
information storage instructions to maintain efficacy.
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SDS Number 127072 Approved/Revised 03-Oct-2003 Version 03
Material DEBROX DROPS
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Other Equipment or None required for normal handling. Wash hands and arms thoroughly after
handling.
Procedures
9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance
Clear.
Clarity
Viscous liquid.
Physical Form
10. STABILITY AND REACTIVITY
Stability This product is expected to be stable.
Conditions to Avoid None for normal handling of this product.
11. TOXICOLOGICAL INFORMATION
Oral Toxicity Not expected to be toxic following ingestion.
Inhalation Toxicity Overexposure may result in irritation of the respiratory tract.
Skin Effects Minor irritation might occur following direct contact.
Eye Effects Minor irritation might occur following direct contact with eyes.
Target Organ Effects No specific target organ effects have been identified.
Sensitisation Sensitisation (allergic skin reaction) is not expected.
Genetic Toxicity No studies have been conducted.
Carcinogenicity No components are listed as carcinogens by GSK, IARC, NTP or US
OSHA.
Reproductive Effects Insufficient information available to classify for reproductive toxicity.
12. ECOLOGICAL INFORMATION
Summary This product contains an active ingredient that has been tested and which
may be harmful if released directly to the environment. Appropriate
precautions should be taken to limit release of this mixture to the
environment. Local regulations and procedures should be consulted prior to
environmental release.
ECOTOXICITY
Aquatic
Microtox Microtox is a general toxicity test which utilizes a sensitive marine photo
bacteria as the test species. This mixture contains a major component(s)
that is harmful to these organisms.
EC50: 41.5 mg/l, 15 Minutes
Algal This mixture contains a major component(s) that is toxic to algae.
IC50: 6.9 mg/l, 72 Hours, Chlorella vulgaris, green algae
Daphnid This mixture contains a major component(s) that is toxic to daphnids.
EC50: 6.6 mg/l, 48 Hours, Daphnia pulex
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SDS Number 127072 Approved/Revised 03-Oct-2003 Version 03
Material DEBROX DROPS
Fish This mixture contains a major component(s) that is harmful to some fish
species tested.
Adult Pimephales promelas, fathead minnow
EC50: 45.4 mg/l, 96 Hours
Adult Oncorhyncus mykiss, rainbow trout
EC50: 88.5 mg/l, 96 Hours, Static test
Adult Lepomis macrochirus, bluegill sunfish
EC50: 155 mg/l, 96 Hours, Static test
MOBILITY
Solubility This mixture contains a major component(s) that for environmental fate
predictions has solubility in water.
PERSISTENCE/DEGRADATION
Biodegradation The major component(s) of this mixture is not expected to persist in the
environment.
BIOACCUMULATION This mixture contains a major component(s) with mobility and persistence
data that suggests that the major component(s) is not likely to
bioaccumulate in the food chain.
13. DISPOSAL CONSIDERATIONS
Disposal Collect for recycling or recovery if possible. The disposal method for
rejected products/returned goods must ensure that they cannot be re-sold or
Recommendations
re-used.
Regulatory Requirements Observe all local and national regulations when disposing of this product.
14. TRANSPORT INFORMATION
The SDS should accompany all shipments for reference in the event of spillage or accidental release. Only
authorised persons trained and competent in accordance with appropriate national and international
regulatory requirements may prepare dangerous goods for transport.
UN Classification and Labelling
Transportation and shipping of this product is not restricted. It has no known,
Transport Information
significant hazards requiring special packaging or labelling for air, maritime, US
or European ground transport purposes.
15. REGULATORY INFORMATION
The information included below is an overview of the major regulatory requirements. It should not be
considered to be an exhaustive summary. Local regulations should be consulted for additional requirements.
EU Classification and Labelling
None.
US OSHA Standard (29 CFR Part 1910.1200)
Classification This product is exempt from the requirements of the OSHA Hazard
Communication Standard.
Other US Regulations
TSCA Status Exempt
16. OTHER INFORMATION
References GSK Hazard Determination
Date Approved/Revised 03-Oct-2003 SDS Version Number 3
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SDS Number 127072 Approved/Revised 03-Oct-2003 Version 03
Material DEBROX DROPS
SDS Sections Updated
Sections Subsections
COMPOSITION / INFORMATION ON INGREDIENTS
IDENTIFICATION OF SUBSTANCE / PREPARATION AND
OF COMPANY
The information and recommendations in this safety data sheet are, to the best of our knowledge, accurate
as of the date of issue. Nothing herein shall be deemed to create any warranty, express or implied. It is the
responsibility of the user to determine the applicability of this information and the suitability of the material
or product for any particular purpose.
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