Material Safety Data Sheet
1.0 Product and Company Identification
Identification of the preparation HP LaserJet Print Cartridge
92291A/X
Hewlett-Packard Company
Company Identification
11311 Chinden Boulevard
Boise, Idaho 83714
United States
1-800-457-4209 (USA and Canada)
Emergency telephone number
Hewlett-Packard Health Effects Line Intl: +1-503-494-7199 (all other areas)
Singapore: +001-800-332-13321
1-208-323-2551 (USA and Canada)
General information telephone number
Intl: +1-208-323-2551 (all other areas)
Local Contact Information Ireland
Liffey Park Technology Park
Barnhall Road Leixlip, Co.
Kildare, Ireland
Phone: 01 6150000
United Kingdom
Hewlett-Packard, Ltd.
Cain Road, Amen Corner
Bracknell, Berkshire, RG12 1HN
Phone: 1344 36-0000
Hazard Rating US NFPA/HMIS
Health 1
Flammability 1
Instability/Reactivity 0
Special N/A
2.0 Composition/Information on Ingredients
This product is a toner preparation that is used in Hewlett-Packard 3Si, 4Si, or 4Si MX
LaserJet printers.
Component/Substance CAS Number EU Number % by Weight Risk Phrases
Styrene Acrylate
- - 45 - 55 -
Copolymer
Iron Oxide 1317-61-9 215-277-5 45 - 55 -
3.0 Hazard Identification
The preparation is not classified according to EU Directive 1999/45/EC
Inhalation, ingestion, skin and eyes.
Routes of Exposure
Acute Health Hazards
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Material Safety Data Sheet
Inhalation: Minimal respiratory tract irritation may occur with
exposure to large amount of toner dust
Ingestion: Ingestion is not applicable route of entry for intended
use.
Skin: Unlikely to cause skin irritation
Eyes: May cause eye irritation
Prolonged inhalation of excessive amounts of any dust
Chronic Health Hazards
may cause lung damage. Use of this product as
intended does not result in inhalation of excessive
amounts of dust.
Refer to section 11.
Carcinogenicity
4.0 First Aid Measures
Inhalation: Move person to fresh air immediately. If symptoms
occur, consult a physician.
Ingestion: Rinse mouth with water. Drink one to two glasses of
water. If symptoms occur, consult a physician.
Skin: Wash affected areas thoroughly with soap and
water. If symptoms occur, consult a physician.
Eyes: Immediately flush with large amounts of clean,
lukewarm water (low pressure) for at least 15
minutes. If symptoms occur, consult a physician.
5.0 Fire Fighting Measures
Extinguishing media CO2, water, dry chemical
Unsuitable Extinguishing None known
Media
Special Firefighting None
Procedures
Unusual fire and explosion Toner material, like most organic material in powder
hazards form, is capable of creating a dust explosion
Auto-ignition temperature No data available
Flashpoint (method) Not applicable
Hazardous Combustion Combustion will produce carbon dioxide and,
Products possibly toxic chemicals such as carbon monoxide.
6.0 Accidental release measures
Spill or leak procedures Wear personal protective equipment as described in
Section 8. Minimize the release of particulates.
Vacuum or sweep the material into a bag or other
sealed container and dispose in accordance with
local requirements.
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Material Safety Data Sheet
Environmental precautions Do not discharge into drains (See also section 13
Disposal Considerations).
7.0 Handling and Storage
Advice on safe handling and Keep material out of reach of children. Avoid
protection against fire inhalation of dust and contact with eyes. Keep away
from excessive heat, sparks, and open flames.
Requirements for storage Keep container closed and store at room
rooms and advice on storage temperature. Keep away from strong oxidizers.
compatibility
8.0 Exposure control/ personal protection
Exposure Limit Values
USA OSHA (TWA)/PEL): 15 mg/m3 (Total Dust)
5 mg/m3 (Respirable Fraction)
ACGIH (TWA/TLV): 10 mg/m3 (Inhalable Particulate)
3 mg/m3 (Respirable Particulate)
TRGS 900 (Luftgrenzwert): 10 mg/m3 (Einatembare Partikel)
3 mg/m3 (Alveoleng盲ngige Fraktion)
Exposure Controls
Respiratory protection Not required under intended use
Ventilation Good general ventilation should be sufficient under
intended use
Protective gloves Not required under intended use
Eye protection Not required under intended use
Other protective equipment Not required under intended use
9.0 Physical and chemical properties
Not applicable
pH
Not applicable
Boiling point
Not applicable
Flash point
100 - 150oC (Softening Point)
Melting point
Non-flammable solid (according to test methods of
Flammability
USA 16 CFR 1500.44 and 84/449/EEC (Annex V)
A.10)
Toner material, like most organic material in powder
Explosive properties
form, is capable of creating a dust explosion
No data available
Oxidizing properties
Not applicable
Vapor Pressure
1.4 - 1.6
Specific gravity (H2O=1)
Negligible
Solubility in Water
Partially soluble in toluene and xylene
Solubility in organic solvents
Not applicable
Partition coefficient
Not applicable
Viscosity
Not applicable
Vapor density
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Material Safety Data Sheet
Not applicable
Evaporation rate
Fine powder
Physical state
Black
Color
Slight plastic odor
Odor
None known
Other
10.0 Stability and reactivity
Stable under normal storage conditions
Stability
Strong oxidizers
Incompatibilities
Combustion will produce carbon dioxide and,
Hazardous decomposition
possibly toxic chemicals such as carbon monoxide.
products
Will not occur.
Hazardous polymerization
11.0 Toxicological information
Refer to Section 3 for potential heath effects and Section 4 for first aid measures
Acute Toxicity:
Ingestion: LD50: oral-rat>5000 mg/kg, not harmful.
Eye Contact: Not classified as irritant, according to OSHA Hazard
Communication Standard (HCS) and EU Directive
67/548/EEC.
Skin Contact: Not classified as irritant, according to OSHA Hazard
Communication Standard (HCS) and EU Directive
67/548/EEC.
Chronic Toxicity: No data available
Other Toxicity Data:
Mutagenicity: Negative, does not indicate mutagenic potential,
(Ames Test: Salmonella typhimurium).
Carcinogenicity: Not a known or suspected carcinogen according to
any IARC Monograph, NTP, OSHA Regulations
(USA), EU Directive, or Proposition 65 (California).
12.0 Ecological Information
No data available for ecological and wastewater treatment (sewage) systems.
13.0 Disposal considerations
Product / unused product / contaminated packaging (for Germany only)
Recommendation: consultation with the disposal agency and the relevant authorities;
cleansing agent is water.
14.0 Transportation information
Not a regulated article under DOT, IATA, ADR, or RID
UN Number None
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Material Safety Data Sheet
Class None
Proper Shipping Name None
Packing Group None
Special Precautions None
15.0 Regulatory information
US EPA TSCA Inventory All ingredients are listed on TSCA inventory
US EPA TSCA 12(b) None
US California Proposition 65 None
EU Notification All components in this product are compliant with
EU Chemical Inventory regulations.
EU R&S Phrase Information No European Risk Phrases (labeling data)
Dangerous Components (CAS None
No.) wt%
USA Labeling
Not required
Symbol
Not required
Hazard Warning
Not required
Safety Advice
None
Hazardous Component(s)
16.0 Other information
August 1, 2002
Date Prepared:
09000de7821f4f1
HP-DMS Document Control
Number:
This document replaces all prior versions of the MSDS
Revision Information:
This MSDS was prepared in compliance with EU
EU Information
Directive 91/155/EEC as amended by 2001/58/EC and
USA OSHA Hazard Communications regulations
(29CFR1910:1200).
DISCLAIMER: This Material Safety Data Sheet (MSDS) is provided without charge to
customers of Hewlett-Packard. Data is the most current known to Hewlett-Packard at
the time of preparation of this MSDS and is believed to be accurate. It should not be
construed as guaranteeing specific properties of the products as described or their
suitability for a particular application.
August 1, 2002 Page 5 of 5 HP Laser Jet 92291A/X
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