Wednesday, February 12, 2003 KODAK PHOTO-FLO 600 Solution Page: 1
KODAK PHOTO-FLO 600 Solution
MATERIAL SAFETY DATA SHEET
000006542/F/AUS
Approval Date: 1998-03-09 - Revision
Print Date: 01.02.2003
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Supersedes MSDS No. 6542 Approval Date 1996-05-22
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1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
Product Name: KODAK PHOTO-FLO 600 Solution
Catalog Number(s): 405 5786 - 100 ml Concentrate
Manufacturer/Supplier: KODAK AUSTRALASIA Pty. Ltd., 173 Elizabeth Street,
Coburg, Victoria 3058, AUSTRALIA
For Chemical Emergency Information, in Australia call 1800 033111 (24 hour
service Australia-wide); in New Zealand call 0800 734 607 (24 hour service)
For Other Information, call 61 3 9353 2222
Synonym(s): KAN 354632; PCD 790; PCD F1145
Product Use: Professional black and white photographic processing solution
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2. COMPOSITION/INFORMATION ON INGREDIENTS
Weight % - Component - (CAS Registry No.)
Concentrate:
30-40 Water (007732-18-5)
35-40 Ethylene glycol (000107-21-1)
25-30 p-tert-octylphenoxy polyethoxyethyl alcohol (009002-93-1)
Working solution:
鈥? 99 Water (007732-18-5)
鈥? 0.5 Ethylene glycol (000107-21-1)
鈥? 0.5 p-tert-octylphenoxy polyethoxyethyl alcohol (009002-93-1)
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3. HAZARDS IDENTIFICATION
Concentrate:
STATEMENT OF HAZARDOUS NATURE: Hazardous according to criteria of Worksafe
Australia
HARMFUL, Harmful if swallowed.
Contains no scheduled poisons
Working solution:
STATEMENT OF HAZARDOUS NATURE: Not classified as hazardous according to
criteria of Worksafe Australia
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4. FIRST-AID MEASURES
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Inhalation: If symptomatic, move to fresh air. Get medical attention if
symptoms persist.
Eyes: Immediately flush with plenty of water for at least 15 minutes. Get
medical attention.
Skin: Immediately remove contaminated clothing and shoes and wash with soap
and plenty of water. Get medical attention if symptoms occur. Wash
contaminated clothing before reuse. Destroy or thoroughly clean contaminated
shoes.
Ingestion: Drink 1-2 glasses of water. Seek medical attention. Never give
anything by mouth to an unconscious person.
First Aid Facilities: Not specified
Note to Physicians: Not specified
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5. FIRE FIGHTING MEASURES
Hazchem Code: Not specified
Extinguishing Media: Use appropriate agent for adjacent fire.
Special Fire-Fighting Procedures: Wear self-contained breathing apparatus and
protective clothing.
Special Exposure Hazards: None
Unusual Fire and Explosion Hazards: None
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6. ACCIDENTAL RELEASE MEASURES
Absorb spill with vermiculite or other inert material, then place in a
container for chemical waste. Clean surface thoroughly to remove residual
contamination.
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7. HANDLING AND STORAGE
Personal Precautionary Measures: Avoid contact with eyes, skin, and clothing.
Use with adequate ventilation. Wash thoroughly after handling.
Prevention of Fire and Explosion: No special precautionary measures should be
needed under anticipated conditions of use.
Storage: Keep container closed. Keep away from incompatible substances (see
Incompatibility section).
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8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Exposure Standards:
ACGIH Threshold Limit Value (TLV):
Ethylene glycol: 100 mg/m3 Ceiling, aerosol
WORKSAFE AUSTRALIA National Exposure Standards:
Ethylene glycol: 60 mg/m3 TWA; 120 mg/m3 STEL, vapour
Ventilation: Good general ventilation (typically 10 air changes per hour)
should be used. Ventilation rates should be matched to conditions.
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Respiratory Protection: None should be needed.
Eye Protection: Wear safety glasses with side shields (or goggles).
Skin Protection: Wear impervious gloves.
Recommended Decontamination Facilities: Eye bath, safety shower, washing
facilities
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9. PHYSICAL AND CHEMICAL PROPERTIES
Physical Form: Liquid
Color: Colorless
Odor: Odorless
Specific Gravity (water = 1):
Concentrate: 1.07
Working solution: 1.00
Vapour Pressure at 20掳C (68掳F): 24 mbar ( 18 mm Hg)
Vapour Density (Air = 1): 0.6
Volatile Fraction by Weight: 75
Boiling Point: >100掳C (>212掳F)
Solubility in Water: Complete
pH:
Concentrate: 8.0
Working solution: 7.0
Flash Point: None
Flammability Limits: Not specified
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10. STABILITY AND REACTIVITY
Stability: Stable
Incompatibility: Strong oxidizing agents
Hazardous Decomposition Products: None
Hazardous Polymerization: Will not occur.
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11. TOXICOLOGICAL INFORMATION
Effects of Exposure:
Inhalation: Expected to be a low hazard for recommended handling.
Eyes: May be irritating.
Skin: Prolonged or repeated contact may cause drying, cracking, or
irritation.
Ingestion: Harmful if swallowed. Can cause kidney damage. May depress
central nervous system activity and cause drowsiness.
Acute Toxicity Data:
Oral LD-50 (rat): 3200 mg/kg
Skin irritation: slight
Eye irritation: moderate
Chronic Effects: Not specified
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12. ECOLOGICAL INFORMATION
Introduction: This environmental effects summary is written to assist in
addressing emergencies created by an accidental spill which might occur during
the shipment of this material, and, in general, it is not meant to address
discharges to sanitary sewers or publically owned treatment works.
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Summary: Data for the major components of this material have been used to
estimate the environmental impact of this material. However, this material,
itself, has not been tested for environmental effects.
It is expected to have the following properties: a moderate biochemical oxygen
demand and may cause oxygen depletion in aqueous systems, a moderate potential
to affect some aquatic organisms, a low potential to affect secondary waste
treatment microbial metabolism, a low potential to bioconcentrate. After
dilution with a large amount of water, followed by secondary waste treatment,
this material is not expected to cause adverse environmental effects.
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13. DISPOSAL CONSIDERATIONS
Discharge, treatment, or disposal may be subject to Commonwealth, States or
local laws. Contract with a licensed chemical disposal agency.
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14. TRANSPORT INFORMATION
United Nations
UN Number: None, not regulated
Australian Code for the Transport of Dangerous Goods by Road and Rail (ADG
Code)
Dangerous good class: Not specified
Subsidiary Risk: Not specified
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15. REGULATORY INFORMATION
Poisons Schedule: Not specified
Carcinogenicity Classification (components present at 0.1% or more):
- American Conference of Governmental Industrial Hygienists (ACGIH) (ethylene
glycol): not classifiable as a human carcinogen (A4)
- International Agency for Research on Cancer (IARC): None
- National Toxicology Program (NTP): None
- Occupational Safety and Health Administration (OSHA): None
- Worksafe Australia: None
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16. OTHER INFORMATION
The data below reflects current legislative requirements whereas the product
in your possession may carry a different version of the label depending on the
date of manufacture.
Worksafe Australia Labeling:
Contains ethylene glycol
pH 6-9
Hazard Category: Xn - Harmful
Risk Phrases: R22 Harmful if swallowed.
Safety Phrases: S2 Keep out of reach of children.
S13 Keep away from food, drink and animal
feeding stuffs.
S46 If swallowed, contact a doctor or Poisons
Information Centre immediately and show this
container or label.
National Health and Medical Research Council Standard for the Uniform
Scheduling of Drugs and Poisons Labeling:
CONTAINS NO SCHEDULED POISONS
CAUTION: IRRITANT
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SAFETY DIRECTIONS: Avoid contact with skin or eyes. Avoid prolonged or
repeated contact with solution.
FIRST AID: No first aid instructions are recommended for labelling purposes.
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The information contained herein is furnished without warranty of any kind.
Users should consider these data only as a supplement to other information
gathered by them and must make independent determinations of suitability and
completeness of information from all sources to assure proper use and disposal
of these materials and the safety and health of employees and customers and
the protection of the environment.
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