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YELLOW 0001747,
RUST-OLEUM - FLUORESCENT
GRAINGER
RUST-OLEUM
FLUORESCENT YELLOW 0001747, 2242 Revised: 511112000
MSDS Confirm
Item Number:
5W907
SECTION 1 - CHEMICAL PRODUCT AND COMPANY
IDENTIFICATION
Mfg. Model Number:
SECTION 2 -COMPOSITIOM/NFORMATION ON INGREDIENTS
2242
SECTION 3 - HAZARDS IDENTIFICATION
SECTION 4 - FIRST AID MEASURES
SCION 5 - FIRE FIGHTING MEASURES
SECTION 9 - ACCIDENTAL RELEASE MEASURES
CF
SECTION 7 - HANDLING AND STORAGE,A
SECTION 6-EXPOSURE CONTROLS/PERSONAL PROTECTION
SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIE S
SECTION 10 - STABILITY AND REACTIVITY
SECTION 1.1 - TOXICOLOGICAL PROPERTIES
SECTION 12 - ECOLOGICAL INFORMATION
SECTION 13 -DISPOSAL CONSIDERATIONS
SECTION 14 - TRANSPORTATION INFORMATION
SECTION 15 - REGULATORY SECTION 16 - OTHER I NFORMATION
MATERIAL SAFETY DATA SHEET
SECTION 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME: FLUORESCENT YELLOW 0001747
IDENTIFICATION NUMBER: 2242 838
DATE PRINTED: 05/12/00
PRODUCT USE/CLASS: HARD HAT INDUSTRIAL SPRAY
SUPPLIER:
RUST-OLEUM CORPORATION
11 HAWTHORN PARKWAY
VERNON HILLS, ILLINOIS
60061 USA
( 847)367-7700 RUST-OLEUM CORP.
8:00 AM-4:30 PM/24-HR EMER. ASSIST
MANUFACTURER:
RUST-OLEUM CORPORATION
11 HAWTHORN PARKWAY
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RUST
VERNON HILLS, ILLINOIS
60061 USA
( 847)367-7700 RUST-OLEUM CORP.
8:00 AM-4:30 PM/24-HR EMER.ASSIST
PREPARER: L.J.W.
PHONE: 847-816-2445
PREPARE DATE: 05/11/00
SECTION 2 - COMPOSITION/INFORMATION ON INGREDIENTS
WT/WT %
ITEM CHEMICAL NAME CAS NUMBER LESS THAN
01 30.0 %
LIQUIFIED PETROLEUM GAS 68476-85-7
02 110-54-3 25.0 %
03
HEXANE HI PURITY
8052-41-3 10.0 %
STODDARD SOLVENT
04 TOLUENE 108-88-3 10.0 %
05 ALIPHATIC PETROLEUM DISTILLATES 64742-89-8 10.0 %
06 CALCIUM CARBONATE (LIMESTONE) 1317-65-3 5.0 %
07 NOT AVAILABLE 5.0 %
C6-C8 PARAFFINS & CYCLOPARAFFINS
64742-95-6 5.0 %
08 SUPER HIGH FLASH NAPTHA
09 METHYLCYCLOHEXANE 108-87-2 5.0 %
10 AROMATIC PETROLEUM DISTILLATES 64742-94-5 5.0 %
EXPOSURE LIMITS
ACGIH OSHA MEXICAN
ITEM TLV-TWA TLV-STEL PEL-TWA PEL-CEILING TLV-TWA SKIN
01 1000 PPM N.E. 1000 PPM N. E. N. E. NO
02 50 PPM N.E. 500 PPM N. E. NO
N. E.
03 100 PPM N.E. 100 PPM N.E. 100 PPM NO
04 50 PPM N.E. 200 PPM 300 PPM N.E. YES
05 300 PPM N.E. 300 PPM N.E. NO
N.E.
06 10 MG/M3 N.E. 15 MG/M3 N.E. N.E. NO
07 N.E. N.E. N.E. N.E. N.E. NO
08 N.E. N.E. N.E. N.E. N.E. NO
09 400 PPM N.E. 500 PPM N.E. N.E. NO
N.E.
10 N.E. 100 PPM N.E. N.E. NO
( SEE SECTION 16 FOR ABBREVIATION LEGEND)
SECTION 3 - HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW:
HARMFUL IF INHALED. HARMFUL IF SWALLOWED. EXTREMELY FLAMMABLE LIQUID AND
VAPOR. VAPORS MAY CAUSE FLASH FIRE OR EXPLOSION. HARMFUL IF INHALED. MAY
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HEADACHE OR NAUSEA.
EFFECT THE BRAIN OR NERVOUS SYSTEM CAUSTNG DIZZINESS ,
CONTENTS UNDER PRESSURE.
EFFECTS OF OVEREXPOSURE - EYE CONTACT: CAUSES EYE IRRITATION.
EFFECTS OF OVEREXPOSURE - SKIN CONTACT:
SUBSTANCE MAY CAUSE SLIGHT SKIN IRRITATION. PROLONGED OR REPEATED CONTACT
MAY CAUSE SKIN IRRITATION.
EFFECTS OF OVEREXPOSURE - INHALATION:
HARMFUL IF INHALED. HIGH GAS, VAPOR, MIST OR DUST CONCENTRATIONS MAY BE
HARMFUL IF INHALED. AVOID BREATHING VAPORS OR MISTS, HIGH VAPOR
CONCENTRATIONS ARE IRRITATING TO THE EYES, NOSE, THROAT AND LUNGS.
EFFECTS OF OVEREXPOSURE - INGESTION:
SUBSTANCE MAY BE HARMFUL IF SWALLOWED. ASPIRATION HAZARD IF SWALLOWED; CAN
ENTER LUNGS AND CAUSE DAMAGE.
EFFECTS OF OVEREXPOSURE - CHRONIC HAZARDS:
MAY CAUSE CENTRAL NERVOUS SYSTEM DISORDER (E.G., NARCOSIS INVOLVING A LOSS
OF COORDINATION, WEAKNESS, FATIGUE, MENTAL CONFUSION, AND BLURRED VISION)
AND/OR DAMAGE. REPORTS HAVE ASSOCIATED REPEATED AND PROLONGED OCCUPATIONAL
OVEREXPOSURE TO SOLVENTS WITH PERMANENT BRAIN AND NERVOUS SYSTEM DAMAGE.
OVEREXPOSURE TO TOLUENE IN LABORATORY ANIMALS HAS BEEN ASSOCIATED WITH
LIVER ABNORMALITIES, KIDNEY, LUNG AND SPLEEN DAMAGE. EFFECTS IN HUMANS
HAVE INCLUDED LIVER AND CARDIAC ABNORMALITIES. EXCESSIVE EXPOSURE TO
N-HEXANE CAN RESULT IN DAMAGE TO PERIPHERAL NERVES. THE INITIAL SYMPTOMS
ARE NUMBNESS OF THE FINGERS AND TOES. MOTOR WEAKNESS CAN ALSO OCCUR IN THE
DIGITS, BUT MAY INVOLVE MUSCLES OF THE ARMS, THIGHS AND FOREARMS. THE
ONSET OF THESE SYMPTOMS MAY BE DELAYED FOR SEVERAL MONTHS TO A YEAR AFTER
THE BEGINNING EXPOSURE. THE NEUROTOXIC PROPERTIES OF N-HEXANE ARE
POTENTIATED BY EXPOSURE TO METHYL ETHYL KETONE AND METHYL ISOBUTYL KETONE.
PRIMARY ROUTE(S) OF ENTRY: SKIN ABSORPTION, INHALATION, EYE CONTACT
SECTION 4 - FIRST AID MEASURES
FIRST AID - EYE CONTACT:
HOLD EYELIDS APART AND FLUSH WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES.
GET MEDICAL ATTENTION.
FIRST AID - SKIN CONTACT:
WASH WITH SOAP AND WATER. GET MEDICAL ATTENTION IF IRRITATION DEVELOPS OR
PERSISTS.
FIRST AID - INHALATION:
IF YOU EXPERIENCE DIFFICULTY IN BREATHING, LEAVE THE AREA TO OBTAIN FRESH
AIR. IF CONTINUED DIFFICULTY IS EXPERIENCED, GET MEDICAL ASSISTANCE
IMMEDIATELY.
FIRST AID - INGESTION:
ASPIRATION HAZARD:
DO NOT INDUCE VOMITING OR GIVE ANYTHING BY MOUTH BECAUSE THIS MATERIAL CAN
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ENTER THE LUNGS AND CAUSE SEVERE LUNG DAMAGE. GET IMMEDIATE MEDICAL
ATTENTION.
SECTION 6 - FIRE FIGHTING MEASURES
FLASH POINT: -99 F
LOWER EXPLOSIVE LIMIT: 1.0 %
UPPER EXPLOSIVE LIMIT: 10.0 %
AUTOIGNITION TEMPERATURE: ND
EXTINGUISHING MEDIA: DRY CHEMICAL, FOAL, WATER FOG
UNUSUAL FIRE AND EXPLOSION HAZARDS:
FLASH POINT IS LESS THAN 20 DEG. F.
EXTREMELY FLAMMABLE LIQUID AND VAPOR!
WATER SPRAY MAY BE INEFFECTIVE. CLOSED CONTAINERS MAY EXPLODE WHEN
EXPOSED TO EXTREME HEAT DUE TO BUILDUP OF STEAM. CLOSED CONTAINERS MAY
EXPLODE WHEN EXPOSED TO EXTREME HEAT. VAPORS MAY FORM EXPLOSIVE MIXTURES
WITH AIR. VAPORS CAN TRAVEL TO A SOURCE OF IGNITION AND FLASH BACK. KEEP
CONTAINERS TIGHTLY CLOSED. ISOLATE FROM HEAT, ELECTRICAL EQUIPMENT, SPARKS
AND OPEN FLAME. PERFORATION OF THE PRESSURIZED CONTAINER MAY CAUSE
BURSTING OF THE CAN. CLOSED CONTAINERS MAY EXPLODE WHEN EXPOSED TO EXTREME
HEAT.
SPECIAL FIREFIGHTING PROCEDURES:
EVACUATE AREA AND FIGHT FIRE FROM A SAFE DISTANCE.
SECTION 6 - ACCIDENTAL RELEASE MEASURES
STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED:
EVACUATE THE AREA, REMOVE ALL SOURCES OF IGNITION AND VENTILATE WELL.
CONTAIN SPILLED LIQUID WITH SAND OR EARTH. DO NOT USE COMBUSTIBLE
MATERIALS SUCH AS SAWDUST. REMOVE ALL, SOURCES OF IGNITION, VENTILATE
AREA AND REMOVE WITH INERT ABSORBENT AND NON-SPARKING TOOLS. DISPOSE OF
ACCORDING TO LOCAL, STATE (PROVINCIAL) AND FEDERAL REGULATIONS. DO NOT
INCINERATE CLOSED CONTAINERS.
SECTION 7 - HANDLING AND STORAGE
HANDLING:
WASH THOROUGHLY AFTER HANDLING. WASH HANDS BEFORE EATING. USE ONLY IN A
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WELL-VENTILATED AREA. FOLLOW ALL MSDS/LABEL PRECAUTIONS EVEN AFTER
CONTAINER IS EMPTIED BECAUSE IT MAY RETAIN PRODUCT RESIDUES. AVOID
BREATHING VAPOR OR MIST.
STORAGE:
KEEP CONTAINERS TIGHTLY CLOSED. ISOLATE FROM HEAT, ELECTRICAL EQUIPMENT,
SPARKS AND OPEN FLAME. DO NOT STORE ABOVE 120 DEGREES F. STORE LARGE
QUANTITIES IN BUILDINGS DESIGNED AND PROTECTED FOR STORAGE OF NFPA CLASS I
FLAMMABLE LIQUIDS. CONTENTS UNDER PRESSURE. DO NOT EXPOSE TO HEAT OR STORE
ABOVE 120 DEGREES F.
SECTION 8 - EXPOSURE CONTROLS/PERSONAL PROTECTION
ENGINEERING CONTROLS:
USE PROCESS ENCLOSURES, LOCAL EXHAUST VENTILATION, OR OTHER ENGINEERING
CONTROLS TO CONTROL AIRBORNE LEVELS BELOW RECOMMENDED EXPOSURE LIMITS. USE
EXPLOSION-PROOF VENTILATION EQUIPMENT. PREVENT BUILD-UP OF VAPORS BY
OPENING ALL DOORS AND WINDOWS TO ACHIEVE CROSS-VENTILATION.
RESPIRATORY PROTECTION:
A RESPIRATORY PROTECTION PROGRAM THAT MEETS OSHA 1910.134 AND ANSI Z88.2
REQUIREMENTS MUST BE FOLLOWED WHENEVER WORKPLACE CONDITIONS WARRANT A
RESPIRATOR'S USE. A NIOSH/MSHA APPROVED AIR PURIFYING RESPIRATOR WITH AN
ORGANIC VAPOR CARTRIDGE OR CANISTER MAY BE PERMISSIBLE UNDER CERTAIN
CIRCUMSTANCES WHERE AIRBORNE CONCENTRATIONS ARE EXPECTED TO EXCEED
EXPOSURE LIMITS. PROTECTION PROVIDED BY AIR PURIFYING RESPIRATORS IS
LIMITED. USE A POSITIVE PRESSURE AIR SUPPLIED RESPIRATOR IF THERE IS ANY
POTENTIAL FOR AN UNCONTROLLED RELEASE, EXPOSURE LEVELS ARE NOT KNOWN, OR
ANY OTHER CIRCUMSTANCES WHERE AIR PURIFYING RESPIRATORS MAY NOT PROVIDE
ADEQUATE PROTECTION.
SKIN PROTECTION:
USE IMPERVIOUS GLOVES TO PREVENT SKIN CONTACT AND ABSORPTION OF THIS
MATERIAL THROUGH THE SKIN. NITRILE OR NEOPRENE GLOVES MAY AFFORD ADEQUATE
SKIN PROTECTION.
EYE PROTECTION:
USE SAFETY EYEWEAR DESIGNED TO PROTECT AGAINST SPLASH OF LIQUIDS.
OTHER PROTECTIVE EQUIPMENT:
REFER TO SAFETY SUPERVISOR OR INDUSTRIAL HYGIENIST FOR FURTHER INFORMATION
REGARDING PERSONAL PROTECTIVE EQUIPMENT AND ITS APPLICATION.
HYGIENIC PRACTICES:
WASH THOROUGHLY WITH SOAP AND WATER BEFORE EATING, DRINKING OR SMOKING.
SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES
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BOILING RANGE: -34 - 383 F
ODOR: SOLVENT-LIKE
APPEARANCE: LIQUID
SOLUBILITY IN H20: SLIGHT
FREEZE POINT: ND
VAPOR PRESSURE: ND
PHYSICAL STATE: LIQUID
VAPOR DENSITY: IS HEAVIER THAN AIR
ODOR THRESHOLD: ND
EVAPORATION RATE: IS FASTER THAN ETHER
SPECIFIC GRAVITY: 0.8976
pH @ 0.0 %: ND
VISCOSITY: ND
COEFFICIENT OF WATER/OIL DISTRIBUTION: ND
( SEE SECTION 16 FOR ABBREVIATION LEGEND)
SECTION 10 - STABILITY AND REACTIVITY
CONDITIONS TO AVOID:
AVOID TEMPERATURES ABOVE 120 DEGREES F. AVOID ALL POSSIBLE SOURCES OF
IGNITION.
INCOMPATIBILITY:
INCOMPATIBLE WITH STRONG OXIDIZING AGENTS, STRONG ACIDS AND STRONG
ALKALIES.
HAZARDOUS DECOMPOSITION PRODUCTS:
BY OPEN FLAME, CARBON MONOXIDE AND CARBON DIOXIDE. WHEN HEATED TO
DECOMPOSITION IT EMITS ACRID SMOKE AND IRRITATING FUMES.
HAZARDOUS POLYMERIZATION: WILL NOT OCCUR UNDER NORMAL CONDITIONS.
STABILITY: THIS PRODUCT IS STABLE UNDER NORMAL STORAGE CONDITIONS.
SECTION 11 - TOXICOLOGICAL PROPERTIES
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COMPONENT TOXICOLOGICAL INFORMATION:
LD50
CHEMICAL NAME
LIOUIFIED PETROLEUM GAS N. E.
28710 MG/KG RAT-ORL
HEXANE HI PURITY
STODDARD SOLVENT 4900 MG/KG(RAT)
TOLUENE RAT 5000 MG/KG
NO INFORMATION
ALIPHATIC PETROLEUM DISTILLATES
NO INFORMATION
CALCIUM CARBONATE (LIMESTONE)
C6-C8 PARAFFINS & CYCLOPARAFFINS NO INFORMATION
3670 MG/KG RAT INH
SUPER HIGH FLASH NAPTHA
2250 MG/KG ORL-MUS
METHYLCYCLOHEXANE
4900 MG/KG(RAT)
AROMATIC PETROLEUM DISTILLATES
LC50
CHEMICAL NAME
LIQUIFIED PETROLEUM GAS N.E.
TCL0:5000 PPM/20 H
HEXANE HI PURITY
STODDARD SOLVENT N.E.
TOLUENE MOUSE 5320 PPM 8 HR
ALIPHATIC PETROLEUM DISTILLATES NO INFORMATION
CALCIUM CARBONATE (LIMESTONE) NO INFORMATION
C6-C8 PARAFFINS & CYCLOPARAFFINS NO INFORMATION
SUPER HIGH FLASH NAPTHA 4700 MG/KG RAT-ORL
METHYLCYCLOHEXANE 41500 MG/M3/2HIH-MS
AROMATIC PETROLEUM DISTILLATES N.E.
SECTION 12 - ECOLOGICAL INFORMATION
ECOLOGICAL INFORMATION:
PRODUCT IS A MIXTURE OF LISTED COMPONENTS. ACCORDING TO OUR RAW MATERIAL
SUPPLIERS, ALL COMPONENTS ARE LISTED ON THE TSCA INVENTORY AS REQUIRED OR
MEET THE POLYMER EXEMPTION AS DEFINED IN SECTION 5.5.2 OF THE TOXIC
SUBSTANCES CONTROL ACT.
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SECTION 13 - DISPOSAL CONSIDERATIONS
DISPOSAL METHOD:
DISPOSE OF MATERIAL IN ACCORDANCE TO LOCAL, STATE AND FEDERAL REGULATIONS
AND ORDINANCES. DO NOT ALLOW TO ENTER STORM DRAINS OR SEWER SYSTEMS.
SECTION 14 - TRANSPORTATION INFORMATION
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AEROSOLS
DOT PROPER SHIPPING NAME
:
DOT TECHNICAL NAME:
DOT HAZARD CLASS: 2
HAZARD SUBCLASS: 1
DOT UN/NA NUMBER: UN1950
PACKING GROUP:
RESP. GUIDE PAGE: 126
SECTION 15 - REGULATORY INFORMATION
U.S. FEDERAL REGULATIONS AS FOLLOWS:
OSHA:
(29 CFR 1910.1200)
HAZARDOUS BY DEFINITION OF HAZARD COMMUNICATION STANDARD
CERCLA - SARA HAZARD CATEGORY:
THIS PRODUCT HAS BEEN REVIEWED ACCORDING TO THE EPA 'HAZARD CATEGORIES'
PROMULGATED UNDER SECTIONS 311 AND 312 OF THE SUPERFUND AMENDMENT AND
REAUTHORIZATION ACT OF 1986 (SARA TITLE III) AND IS CONSIDERED, UNDER
APPLICABLE DEFINITIONS, TO MEET THE FOLLOWING CATEGORIES:
IMMEDIATE HEALTH HAZARD, CHRONIC HEALTH HAZARD, FIRE HAZARD
SARA SECTION 313:
THIS PRODUCT CONTAINS THE FOLLOWING SUBSTANCES SUBJECT TO THE REPORTING
REQUIREMENTS OF SECTION 313 OF TITLE III OF THE SUPERFUND AMENDMENTS AND
REAUTHORIZATION ACT OF 1986 AND 40 CFR PART 372:
CHEMICAL NAME CAS NUMBER WT/WT % IS LESS THAN
110-54-3 25.0 %
HEXANE HI PURITY
TOLUENE 108-88-3 10.0 %
U.S. STATE REGULATIONS AS FOLLOWS:
NEW JERSEY RIGHT-TO-KNOW:
THE FOLLOWING MATERIALS ARE NON-HAZARDOUS, BUT ARE AMONG THE TOP FIVE
COMPONENTS IN THIS PRODUCT:
CHEMICAL NAME CAS NUMBER
LIGHTNING YEL AEROSOL CONC./POLYMER RES 39277-28-6
PENNSYLVANIA RIGHT-TO-KNOW:
THE FOLLOWING NON-HAZARDOUS INGREDIENTS ARE PRESENT IN THE PRODUCT AT
GREATER THAN 3%:
CHEMICAL NAME CAS NUMBER
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39277-28-6
LIGHTNING YEL AEROSOL CONC./POLYMER RES
CALIFORNIA PROPOSITION 65:
WARNING:
THE CHEMICAL(S) NOTED BELOW AND CONTAINED IN THIS PRODUCT, ARE KNOWN TO
THE STATE OF CALIFORNIA TO CAUSE CANCER, BIRTH DEFECTS OR OTHER
REPRODUCTIVE HARM:
CHEMICAL NAME CAS NUMBER
TOLUENE 108-88-3
INTERNATIONAL REGULATIONS AS FOLLOWS:
CANADIAN WHMIS:
THIS MSDS HAS BEEN PREPARED IN COMPLIANCE WITH CONTROLLED PRODUCT
REGULATIONS EXCEPT FOR USE OF THE 16 HEADINGS.
CANADIAN WHMIS CLASS: A, B5, D2A, D2B
SECTION 16 - OTHER INFORMATION
HMIS RATINGS:
HEALTH : 2*
FLAMMABILITY: 4
REACTIVITY : 0
PREVIOUS MSDS REVISION DATE: 04/27/00
REASON FOR REVISION: WHMIS CLASS ADDITION
LEGEND:
N.A.: NOT APPLICABLE
N.E.: NOT ESTABLISHED
N.D.: NOT DETERMINED
NO INFORMATION.
THE INFORMATION CONTAINED ON THIS MSDS HAS BEEN CHECKED AND SHOULD BE
ACCURATE. HOWEVER, IT IS THE RESPONSIBILITY OF THE USER TO COMPLY WITH ALL
FEDERAL, STATE, AND LOCAL LAWS AND REGULATIONS.
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