MATERIAL SAFETY DATA SHEET
I D-11 - B - DEVELOPER
1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
I D-11 - B -DEVELOPER
TRADE NAME
I PID1ID
PART No.
I LFORD Imaging USA Inc., West 70 Century Road,
SUPPLIER
Paramus, NJ 07653 USA; Tel USA: 201-265-6000
I LFORD Imaging Canada Ltd., 361 Steelcase Road West,
Unit #4, Markham, Ontario, Canada, L3R 3V8, Tel Canada: 905-479-2555
Technical Service (USA), Terry Bevens (Canada)
CONTACT PERSON
FOR MEDICAL EMERGENCY IN THE UNITED STATES AND CANADA CALL 1-800842-9660
EMERGENCY TELEPHONE
(PRODUCT MISUSE). FOR TRANSPORTATION EMERGENCY CALL CHEMTREC 1-8004249300.
PRODUCT IDENTIFICATION NUMBER 0
2. COMPOSITION, INFORMATION ON INGREDIENTS
I NGREDIENT NAME CAS No. WEIGHT
SODIUM TRIPOLYPHOSPHATE 7758-29-4 1_5%
SODIUM TETRABORATE 1330-43-4 1-5%
SODIUM SULPHITE 7757-83-7 60-100
3. HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
White, odorless, non-flammable powder. Soluble In water.
Irritating to eyes, respiratory system and skin.
ACUTE EFFECTS
Dust may irritate respiratory system or lungs.
I NHALATION
May cause discomfort If swallowed.
INGESTION
Irritating to skin.
SKIN
EYES Irritating to eyes.
CHRONIC EFFECTS
SENSITIZATION No known information.
CARCINOGENICITY This substance has no evidence of carcinogenic properties.
TERATOGENICITY No known information.
1/5
No known information.
MUTAGENICITY
Severly Irritating by prolonged or repeated exposure. May cause irritation to the respiratory
HEALTH WARNINGS
system. Irritating. The powder can irritate the skin. May cause allergy. May cause
hypersensitivity.
Inhalation. Ingestion. Skin and/or eye contact.
ROUTE OF ENTRY
May aggravate existing: Chronic respiratory and obstructive airway diseases. Skin disorders
MEDICAL INFORMATION
and allergies. Pre-existing eye problems.
4. FIRST AID MEASURES
I NHALATION Move the exposed person to fresh air at once. Provide rest, warmth and fresh air. Rinse nose
and mouth with water. Get medical attention ff any discomfort continues.
EYES Make sure to remove any contact lenses from the eyes before rinsing. Promptly wash eyes with
l ots of water while lifting the eye lids. Continue to rinse for at least 15 minutes. Get medical
attention if any discomfort continues.
Remove affected person from source of contamination. Remove contaminated clothing. Wash the
SKIN
skin immediately with soap and water. Get medical attention If irritation persists after washing.
INGESTION DO NOT INDUCE VOMITINGI Remove victim immediately from source of exposure. Rinse mouth
thoroughly. Get medical attention immediately! Immediately give a couple of glasses of water,
provided the victim is fully conscious.
5. FIRE FIGHTING MEASURES
This material Is not flammable. Use extinguishing media appropriate for surrounding fire.
EXTINGUISHING MEDIA
No unusual fire or explosion hazards noted.
UNUSUAL FIRE & EXPLOSION HAZARDS
HAZARDOUS COMBUSTION PRODUCTS Fire creates: Irritating gases/vapors/fumes. Sulfur dioxide.
6. ACCOENTAL RELEASE MEASURES
SPILL CLEAN-UP PROCEDURES Use appropriate protective clothing. Do not contaminate drainage or waterways. Collect spillage
in containers, seal securely and deliver for disposal according to local regulations. Contain Spill.
Do not flush to septic tank. See Section 13 for disposal considerations. Flush with plenty of
water to clean spillage area. Do not let washing down water contaminate ponds or waterways.
Inform Authorities If large amounts are involved.
7. HANDLING AND STORAGE
Avoid spilling, skin and eye contact. Provide good ventilation. Avoid handling causing generation
HANDLING PRECAUTIONS
of dust Persons with impaired lung functions should not handle this preparation. Read and
follow manufacturer's recommendations.
Keep In cool, dry, ventilated storage and closed containers. Store below 75掳F. Keep In original
STORAGE PRECAUTIONS
container. Keep containers closed tightly.
STORAGE CRITERIA Chemical storage.
8. EXPOSURE CONTROLS, PERSONAL PROTECTION
COMPONENT STD TWA STEL TWA STEL
OSHA
SODIUM TETRABORATE None
ACGIH 1
5
2/5
PROTECTIVE EQUIPMENT
Provide eyewash station and it is recommended that a safety shower Is also available.
ENGINEERING CONTROLS
All handling to take place in well ventilated area. If enclosed handling cannot be guaranteed,
VENTILATION
ventilation and protective clothing must be used. Provide good ventilation If there is a risk of dust
being generated. General room ventilation should provide for 10 - 15 room air changes per hour.
No specific recommendation made, but respiratory protection may still be required under
RESPIRATORS
exceptional circumstances when excessive air contamination exists. Use dust filter mask if dust
is generated.
Use protective gloves made of. Neoprene, nitrite, polyethylene Butyl rubber. Use thin cotton
PROTECTIVE GLOVES
gloves Inside the rubber gloves if allergy risk.
Wear approved safety goggles.
EYE PROTECTION
Wear appropriate clothing to prevent any possibility of skin contact. Wear dust masks in dusty
PROTECTIVE CLOTHING
areas.
9. PHYSICAL AND CHEMICAL PROPERTES
Powder, dust.
APPEARANCEIPHYSICAL STATE
White.
COLOR
No characteristic odor.
ODOR
Soluble In water. 100%
SOLUBILITY DESCRIPTION
Temperature (掳C)
VAPOUR PRESSURE 0 Not relevant
EVAPORATION RATE 0 Reference Not relevant.
9.3
pH-VALUE, CONC. SOLUTION
TEST TEST UNIT REFERENCE
PARAMETER
METHOD RESULT
0%
VOC's: SWISS ORD. 814.018
VOCs: EU Vapour 0%
pressure
>0.01kPa
10. STABILITY AND REACTIVITY
Normally stable.
STABILITY
Avoid contact with acids. Avoid excessive heat for prolonged periods of time.
CONDITIONS TO AVOID
Will not polymerize.
HAZARDOUS POLYMERIZATION
Avoid contact with other photographic solutions and/or cleaning compounds.
MATERIALS TO AVOID
High temperatures generate: Irritating gases/vapors/fumes of: Sulfur dioxide.
HAZARDOUS DECOMPOSITION
PRODUCTS
11. TOXICOLOGICAL. INFORMATION
315
This chemical formulation has not been tested for health effects. Exposure effects listed are
TOXICOLOGICAL INFORMATION
based on existing health data for the Individual components which comprise the mixture.
sodium sulphite 2610; sodium tripolyphosphate 3900; sodium tetraborate 2660 mg/kg (oral rat)
TOXIC DOSE - LD 50
11 ECOLOGICAL INFORMATION
2600 sodium sulphite; 104 sodium tetraborate
LC 50, 96 HRS, FISH, mg/I
69 sodium sulphite; 141 sodium tetraborate
EC 50, 48 HRS, DAPHNIA, mg/I
I C 50,72 HRS, ALGAE, mg/I 158 sodium tetraborate
Not regarded as dangerous for the environment.
ECOLOGICAL INFORMATION
13. DISPOSAL CONSIDERATIONS
DISPOSAL METHODS Unused and spent solutions may be allowed to be discharged to sanitary sewer by permit IF
allowed by local regulations. Consult your local authority for advice. Waste may have to be
pretreated before discharge. Consult local authorities before discharging any waste to sewer.
Do not discharge to septic system. Waste that cannot be discharged to sewer may have to
handled by a licensed hazardous waste contractor.
14. TRANSPORT INFORMATION
To obtain additional Information on packaging for shipment refer to the Code of Federal
CLASSIFICATION COMMENT
Regulations - CFR 49 and your carrier. NOT SOLD SEPARATELY. PART OF A MULTI-PART KIT.
REFER TO SAFETY DATA SHEETS FOR ALL PARTS OF THIS PRODUCT.
No classification noted.
DOT HAZARD CLASS
I DENTIFICATION No. 0
No DOT label requirement noted
U.S. DOT HAZARD LABEL
Not classified for sea transport
SEA TRANSPORT NOTES
Not classified for air transport
AIR TRANSPORT NOTES
15. REGULATORY INFORMATION
US FEDERAL REGULATIONS
COMPONENT SARA 302 CERCLA SARA 313
SODIUM TRIPOLYPHOSPHATE 5 000 lbs
TETRABORATE No
SODIUM
CLEAN AIR ACT
US STATE REGULATIONS
REGULATORY STATUS TSCA. The Ingredients of this product are on the TSCA Inventory.
4/5
(UNEP). OSHA Chemical Hazard Communic. Std. -Air Contaminants (29CFR1910). ACGIH
Threshold Limit Values. EPA Reportable & Threshold Quantities. SARA Section 302, Extremely
Hazardous Substances. SARA Section 313, Toxic Chemicals. SARA Title III Consolidated
Chemical List (302, CERCLA, 313, RCRA).
WORKPLACE HAZARDOUS MATERIALS INFORMATION SYSTEM - WHIMIS
LABEL(S) FOR SUPPLY
This Material Safety Data Sheet has been prepared in compliance with the Controlled Product
Regulations. Canadian WHMIS Classification.
CONTROLLED PRODUCT
CLASSIFICATION
INVENTORIES
CAN tS EU AUS JAP KOR CHN PHLP
COMPONENT
P-METHYLAMINOPHENOL SULFATE NDSL Yes
1& OTHER INFORMATION
ILFORD IMAGING USA INC. AND ILFORD IMAGING CANADA LTD. BEIJEVE THE INFORMATION
AND RECOMMENDATIONS CONTAINED HEREIN ARE BASED ON CORRECT AND FACTUAL DATA
USER NOTES
HOWEVER NO EXPRESS OR IMPLIED GUARANTEE OR WARRANTY OF ANY KIND IS MADE
WITH RESPECT TO THIS INFORMATION. USE THIS INFORMATION ONLY TO SUPPLEMENT OTHER
INFORMATION YOU HAVE GATHERED AND THEN MAKE AN INDEPENDENT DETERMINATION
ABOUT THE COMPLETENESS AND SUITABILITY OF ALL INFORMATION TO INSURE THE PROPER
USE AND DISPOSAL OF THIS PRODUCT AND THE HEALTH AND SAFETY OF EMPLOYEES AND
CUSTOMERS.
European Photographic Chemical Industry Code of Practice For Classification And Labelling
Material Safety Data Sheet, Misc. manufacturers. Safeware Quasar Ltd USA Regulatory
I NFORMATION SOURCES
I nformation ANSI Z400.1-1998 Material Safety Data Sheets - Preparation
02 Jul 2002
REVISION DATE:
Dr D W Butcher, ILFORD Imaging Ltd, Mobberley, Knutsford, Cheshire, WA16 7JL, ENGLAND.
Tel. +44 (0)1565 683983; dave.butcher@ilford.com
PREPARED BY
23 Aug 2000
REVISION NoJRepl. MSDS of
515
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