Wednesday, February 12, 2003 KODAK HC-110 Developer Page: 1
KODAK HC-110 Developer
MATERIAL SAFETY DATA SHEET
000003601/F/AUS
Approval Date: 2001-06-15
Print Date: 01.02.2003
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1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
Product Name: KODAK HC-110 Developer
Catalog Number(s): 140 8962 - To Make 13.2 litres
140 8988 - To Make 7.6 litres
Manufacturer: EASTMAN KODAK COMPANY, Rochester, New York 14650
Supplier: KODAK AUSTRALASIA Pty. Ltd., 173 Elizabeth Street, Coburg, Victoria
3058, AUSTRALIA
For Chemical Emergency Information, in Australia call 1800 033111 (24 hour
service Australia-wide); in New Zealand call 0800 734 607 (24 hour service)
For Other Information, call 61 3 9353 2222
Synonym(s): Concentrate: KAN 427909; PCD 4987
Working solution: KAN 471326
Product Use: Black and white film photographic processing solution
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2. COMPOSITION/INFORMATION ON INGREDIENTS
Weight % - Component - (CAS Registry No.)
Concentrate:
50-55 Diethanolamine-sulphur dioxide complex (063149-47-3)
15-20 Water (007732-18-5)
5-10 Hydroquinone (000123-31-9)
5-10 Diethylene glycol (000111-46-6)
5-10 Ethanolamine (000141-43-5)
1-5 Diethanolamine (000111-42-2)
1-5 Diethylenetriamine pentaacetic acid (000067-43-6)
1-5 Potassium bromide (007758-02-3)
鈥?1 Ethylene glycol (000107-21-1)
Working solution:
90-95 Water (007732-18-5)
1-5 Diethanolamine-sulphur dioxide complex (063149-47-3)
鈥?1 Hydroquinone (000123-31-9)
鈥?1 Diethylene glycol (000111-46-6)
鈥?1 Ethanolamine (000141-43-5)
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3. HAZARDS IDENTIFICATION
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Concentrate:
STATEMENT OF HAZARDOUS NATURE: Hazardous according to criteria of Worksafe
Australia
HARMFUL, Possible risk of irreversible effects. Harmful in contact with skin
and if swallowed. Risk of serious damage to eyes. Irritating to skin. May
cause sensitization by skin contact. Contact with acids liberates toxic gas.
Poisons Schedule: 5, 6
CONTAINS Ethanolamine, Diethanolamine-sulphur dioxide complex,
Diethanolamine
Working solution:
STATEMENT OF HAZARDOUS NATURE: Not classified as hazardous according to
criteria of Worksafe Australia
Contains no scheduled poisons
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4. FIRST-AID MEASURES
Inhalation: If symptomatic, move to fresh air. Get medical attention if
symptoms persist.
Eyes: Immediately flush with plenty of water for at least 15 minutes. Get
medical attention.
Skin: Immediately flush with plenty of water for at least 15 minutes and wash
using soap. Remove contaminated clothing and shoes. If skin irritation or an
allergic skin reaction develops, get medical attention.
Ingestion: Drink 1-2 glasses of water. Seek medical attention. Never give
anything by mouth to an unconscious person.
First Aid Facilities: Not specified
Note to Physicians: Due to rapid absorption of material, evacuation of the
stomach is effective only if performed immediately after ingestion. Whenever
possible, stomach evacuation should be accomplished by gastric lavage with
appropriate airway control to prevent aspiration.
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5. FIRE FIGHTING MEASURES
Hazchem Code: Not specified
Extinguishing Media: Use appropriate agent for adjacent fire.
Special Fire-Fighting Procedures: Wear self-contained breathing apparatus and
protective clothing. Use water spray to keep fire-exposed containers cool.
Special Exposure Hazards: None (see also Stability and Reactivity section).
Unusual Fire and Explosion Hazards:
Concentrate: Elevated temperature can cause decomposition.
Working solution: None
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6. ACCIDENTAL RELEASE MEASURES
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Absorb spill with vermiculite or other inert material, then place in a
container for chemical waste. Clean surface thoroughly to remove residual
contamination.
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7. HANDLING AND STORAGE
Personal Precautionary Measures: Avoid prolonged or repeated breathing of mist
or vapour. Avoid contact with eyes, skin, and clothing. Use with adequate
ventilation. Wash thoroughly after handling.
Prevention of Fire and Explosion: Keep from contact with oxidizing materials.
Keep away from heat.
Storage: Keep container closed. Store in a cool place. Keep away from
incompatible substances (see Incompatibility section).
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8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Exposure Standards:
ACGIH Threshold Limit Value (TLV):
2-aminoethanol: 3 ppm TWA; 6 ppm STEL
Hydroquinone: 2 mg/m3 TWA
Diethanolamine: 0.46 ppm TWA, skin
Ethylene glycol: 39.4 ppm Ceiling, aerosol
WORKSAFE AUSTRALIA National Exposure Standards:
2-aminoethanol: 3 ppm TWA; 6 ppm STEL
Ethylene glycol: 60 mg/m3 TWA; 120 mg/m3 STEL
Diethanolamine: 3 ppm TWA
Hydroquinone: 2 mg/m3 TWA
Ventilation: Good general ventilation (typically 10 air changes per hour)
should be used. Ventilation rates should be matched to conditions.
Supplementary local exhaust ventilation, closed systems, or respiratory
protection may be needed in special circumstances such as poorly ventilated
spaces, evaporation from large surfaces, spraying, heating, etc.
Respiratory Protection: None should be needed. If engineering controls do not
maintain airborne concentrations below recommended exposure limits, an
approved respirator must be worn. Respirator type: Organic vapour. If
respirators are used, a program should be instituted to assure compliance with
WORKSAFE AUSTRALIA standard AS/NZS 1716 : 1994.
Eye Protection: Wear safety glasses with side shields (or goggles).
Skin Protection: Wear impervious gloves and protective clothing appropriate
for the . risk of exposure. ,
Recommended Decontamination Facilities: Eye bath, washing facilities, safety
shower
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9. PHYSICAL AND CHEMICAL PROPERTIES
Concentrate working solution
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liquid
Physical Form: liquid
colorless
Color: brown
slight amine
Odor: amine
Specific Gravity (water = 1.24 1.02
1):
Vapour Pressure at 20掳C 14.7 mbar 24 mbar
(18 mm Hg)
(68掳F): (11 mm Hg)
Vapour Density (Air = 1): 2.1 0.6
90-95%
Volatile Fraction by 65-70%
Weight:
Boiling Point: >100掳C (>212掳F) >100掳C (>212掳F)
complete
Solubility in Water: complete
pH: 9.0 8.8-9.0
Flash Point: none none
Flammability Limits: not specified not specified
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10. STABILITY AND REACTIVITY
Stability: Safe handling temperatures are dependent on specific conditions of
use and are typically substantially below the onset temperature. Consult your
technical safety experts. Materials containing similar structural groups can
decompose if heated above 145掳C (293掳F).
Incompatibility: Strong oxidizing agents. Contact with strong acids may
liberate sulphur dioxide. Contact with acids liberates toxic gas.
Hazardous Decomposition Products: Oxides of nitrogen, oxides of sulphur
Hazardous Polymerization: Will not occur.
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11. TOXICOLOGICAL INFORMATION
Effects of Exposure:
General:
Contains hydroquinone. Hydroquinone has been classified as a Category 3
mutagen and carcinogen by the European union based on testing of rats and
mice given hydroquinone by stomach tube or at high dietary levels. The
International Agency for Research on Cancer (IARC) under ranking for
cancer potential has classified hydroquinone in Group 3, i.e. "not
classifiable" as a carcinogen. In the European Union a Catergory 3 mutagen
or carcinogen attracts the risk phrase R40 "Possible risk of irreversible
effects" at concentrations above 1%. Exposure to products containing such
substances should be controlled to below established control limits and
special care should be taken with pregnant or breast-feeding women to
ensure appropriate controls are in place to control the risk.
Contains diethylene glycol. Can cause kidney damage. Can cause CNS
effects.
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Contains diethanolamine. Based on animal data, may cause adverse effects
on the following organs/systems: kidney, liver, blood, nervous system,
testes.
Contains diethanolamine-sulphur dioxide complex, Ethanolamine. May cause
kidney damage based on animal data. May cause liver damage based on animal
data.
Inhalation:
Concentrate: May cause irritation to the mucous membranes and upper
respiratory tract.
Working solution: Expected to be a low hazard for recommended handling.
Eyes:
Concentrate: Risk of serious damage to eyes.
Working solution: May be irritating.
Skin:
Concentrate: Harmful in contact with skin. Irritating to skin. May cause
sensitization by skin contact. May cause allergic skin reaction. May cause
skin depigmentation.
Working solution: May cause allergic skin reaction based on human
experience.
Ingestion:
Concentrate: Harmful if swallowed. May cause irritation of the
gastrointestinal tract.
Working solution: May cause irritation of the gastrointestinal tract.
Acute Toxicity Data:
Data for Concentrate:
Oral LD-50 (rat): > 3200 mg/kg
Dermal LD-50: > 20 ml/kg
Skin irritation: strong irritation
Eye irritation: moderate
Data for hydroquinone:
Oral LD-50 (rat): 400 mg/kg
Chronic Effects: Not specified
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12. ECOLOGICAL INFORMATION
The following properties are ESTIMATED from the components of the
preparations.
Concentrate Working Solution
Potential Toxicity
Fish LC50 mg/1: 1-10 10-100
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Daphnid EC50 mg/1: <1 1-10
Algal IC50 mg/1: 10-100 >100
Organics Readily Yes (7 days) Yes (7 days)
Degradable (>70%):
Log Pow <1
Potential Log Pow <1
Bioaccumulation:
COD (approximate g/1): 1310 81
BOD5 (approximate g/1): 901 56
Potential Toxicity
Waste treatment >100 >100
microorganisms EC50
( mg/1):
13. DISPOSAL CONSIDERATIONS
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Discharge, treatment, or disposal may be subject to Commonwealth, States or
local laws. Contract with a licensed chemical disposal agency.
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14. TRANSPORT INFORMATION
United Nations
UN Number: None, not regulated
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15. REGULATORY INFORMATION
Poisons Schedule:
Concentrate: 5, 6
Working solution: Not specified
carcinogenicity Classification (components present at 0.1% or more):
- International Agency for Research on Cancer (IARC): hydroquinone, Group 3,
not classifiable
- American Conference of Governmental Industrial Hygienists (ACGIH):
Ethylene glycol (A4); Hydroquinone (A3)
- National Toxicology Program (NTP): none
- Occupational Safety and Health Administration (OSHA): None
- Worksafe Australia: None
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16. OTHER INFORMATION
The data below reflects current legislative requirements whereas the product
in your possession may carry a different version of the label depending on the
date of manufacture.
Worksafe Australia Labeling:
Concentrate:
Contains hydroquinone and diethanolamine-sulphur dioxide complex
pH 9-12
Hazard Category: Xn - Harmful
Risk Phrases: R40 Possible risk of irreversible effects.
R21/22 Harmful in contact with skin and if
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swallowed.
R38 Irritating to skin.
R41 Risk of serious damage to eyes.
R43 May cause sensitisation by skin contact.
R31 Contact with acids liberates toxic gas.
S1/2 Keep locked up and out of reach of
Safety Phrases:
children.
S24 Avoid contact with skin.
S26 In case of contact with eyes, rinse
immediately with plenty of water and seek
medical advice.
S36/37/39 Wear suitable protective clothing,
gloves and eye/face protection.
S45 In case of accident or if you feel
unwell, contact a doctor or Poisons
Information Centre immediately (show the
label where possible).
S46 If swallowed, contact a doctor or
Poisons Information Centre immediately and
show this container or label.
Working solution:
Not classified as hazardous according to criteria of Worksafe Australia
National Health and Medical Research Council Standard for the Uniform
Scheduling of Drugs and Poisons Labeling:
Concentrate:
POISON
NOT TO BE TAKEN
KEEP OUT OF REACH OF CHILDREN
FOR PHOTOGRAPHIC PURPOSES ONLY
CONTAINS 83 g/l ethanolamine; 627 g/l diethanolamine-sulphur dioxide
complex; 32 g/l diethanolamine
WARNING: CORROSIVE. Product will irritate the eyes, nose, throat, and
skin. Vapour may be harmful.
SAFETY DIRECTIONS: Avoid contact with skin or eyes. Avoid breathing dust
( or) vapour (or) spray mist.
FIRST AID: If poisoning occurs, contact a doctor or Poisons Information
Centre (Australia 131126; New Zealand 03 4747000). If swallowed, DO NOT
induce vomiting. Give a glass of water. If skin contact occurs, remove
contaminated clothing and wash skin thoroughly. If in eyes, hold eyes
open, flood with water for at least 15 minutes and see a doctor.
working solution:
CONTAINS NO SCHEDULED POISONS
CAUTION: IRRITANT
SAFETY DIRECTIONS: Avoid contact with skin or eyes. Avoid prolonged or
repeated contact with solution.
FIRST AID: No first aid instructions are recommended for labelling
purposes.
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The information contained herein is furnished without warranty of any kind.
users should consider these data only as a supplement to other information
gathered by them and must make independent determinations of suitability and
completeness of information from all sources to assure proper use and disposal
of these materials and the safety and health of employees and customers and
the protection of the environment. The information relating to the working
solution is for guidance purposes only, and is based on' correct mixing and use
of the product according to instructions.
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Concentrate:R-1, S-2, F-1, C-iHT
WS:R-1, S-2, F-0, C-0
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