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Material 24 Hour Emergency Phone Numbers:
Medical: 1-800-327-3874
1-513-558-5111
Safety Transportation:
1-800-535-5053
1-352-323-3500
Data
Sheet
NOTE: National Response Center emergency numbers to be used
only in the event of chemical emergencies involving a spill, leak,
fire, exposure or accident involving chemicals.
IMPORTANT: Provide this information to employees, customers, and users of this product. Read this MSDS before handling or
disposing of this product. This product is covered by the OSHA Hazard Communication Standard and this document has been
prepared in accordance with requirements of this standard. All abbreviated terms used in this MSDS are further described in Section
16.
Section 1 - Chemical Product / Company Information
This Material Safety Data Sheet is available in Canadian French and Hispanic American Spanish upon request.
Esta hoja de datos de la seguridad de los materiales est谩 disponible en franc茅s canadiense y en espa帽ol a su solicitud.
Los Datos de Serguridad del Producto pueden obtenerse en Espanol si lo riquiere.
Product Name: BUTYL FLEX GUTTER & FLASHING Revision Date: 10/27/2004
SEALANT
Product UPC 7079818182 7079818184 7079818185 Supercedes: 04/26/2000
Number: 7079818188 7079873754 7079873751
7079873766 7079873763
Product Use/Class: Solvent Based Caulk MSDS Number: 00010006001
Manufacturer: DAP Inc.
2400 Boston Street Suite 200
Baltimore, MD 21224-4723
888-327-8477 (non-emergency matters)
Section 2 - Composition / Information On Ingredients
ACGIH
Chemical Name CASRN WT% ACGIH TWA ACGIH CEIL OSHA TWA OSHA STEL OSHA CEIL Skin
STEL
Calcium carbonate 1317 -65-3 40-70 10 MGM3 N.E. N.E. 5 MGM3 N.E. N.E. No
Stoddard solvent 8052 -41-3 10-30 100 PPM N.E. N.E. 500 PPM N.E. N.E. No
Quaternary ammonium bentonite 68153-30 -0 1-5 N.E. N.E. N.E. N.E. N.E. N.E. No
Titanium dioxide 13463-67 -7 0.5-1.5 10 MGM3 N.E. N.E. 15 MGM3 N.E. N.E. No
(10 梅 %
Silica, crystalline 14808-60 -7 0.1-1.0 0.05 MGM3 N.E. N.E. SiO2) / 2 N.E. N.E. No
MGM3
Exposure Notes:
Important: Listed Permissible Exposure Levels (PEL) are from the U.S. Dept. of Labor OSHA Final Rule Limits (CFR 29 1910.1000); these limits
may vary between states.
Note: An employee's skin exposure to substances having a "YES" in the "SKIN" column in the table above shall be prevented or reduced to the
extent necessary under the circumstances through the use of gloves, coveralls, goggles or other appropriate personal protective equipment,
engineering controls or work practices
Section 3 - Hazards Identification
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Emergency Overview: A white to off-white paste with a strong solvent odor. WARNING! Do not breathe vapors.
Avoid skin and eye contact. Combustible liquid and vapor. Vapors may ignite explosively. Keep away from heat,
sparks and flame. Harmful or fatal if swallowed. May cause eye, skin, nose, throat and respiratory tract irritation.
Refer to other MSDS sections for other detailed information.
Effects Of Overexposure - Eye Contact: May cause eye irritation. Signs and symptoms may include: pain,
tears, swelling, redness and blurred vision.
Effects Of Overexposure - Skin Contact: May cause skin irritation.
Effects Of Overexposure - Inhalation: Vapor harmful. May affect the brain or nervous system causing
dizziness, headache or nausea. Inhalation may cause irritation to the respiratory tract (nose, mouth, mucous
membranes). Inhalation of high vapor concentrations can cause central nervous system depression and narcosis.
Effects Of Overexposure - Ingestion: Harmful or fatal if swallowed. If ingested, may cause vomiting, diarrhea,
and depressed respiration.
Effects Of Overexposure - Chronic Hazards: NOTICE: Reports have associated repeated and prolonged
occupational overexposure to solvents with permanent brain and nervous system damage. Intentional misuse by
deliberately concentrating and inhaling the contents may be harmful or fatal. Prolonged or repeated contact with
skin can cause defatting of the skin, which may lead to dermatitis.
Primary Route(s) Of Entry: Skin Contact, Skin Absorption, Inhalation
Medical Conditions which May be Aggravated by Exposure: Pre-existing eye, skin and pulmonary disorders
may be aggrevated by exposure to this product.
Section 4 - First Aid Measures
First Aid - Eye Contact: If material gets into eyes, flush with water immediately for 15 minutes. Consult a
physician.
First Aid - Skin Contact: Wash off with soap and water.
First Aid - Inhalation: If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is
difficult, give oxygen. Get medical attention immediately.
First Aid - Ingestion: Harmful or fatal if liquid is aspirated into the lungs. If swallowed, drink 8-10 oz. of water,
get immediate medical attention. Do not induce vomiting.
Note to Physician: No Information.
COMMENTS: Call Medical Emergency at 1-800-327-3874 if any irritation or complication arise from any of the
above routes of entry.
Section 5 - Fire Fighting Measures
Flash Point, F: 105 Lower Explosive Limit, %: Not Established
Method: ( Seta Closed Cup) Upper Explosive Limit, %: Not Established
Extinguishing Media: Carbon Dioxide, Dry Chemical, Foam
Unusual Fire And Explosion Hazards: Do not smoke. Extinguish all flames and pilot lights, and turn off stoves,
heaters, electric motors and other sources of ignition during use and until all vapors are gone. Store away from
caustics and oxidizers. Containers may explode if exposed to extreme heat.
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Special Firefighting Procedures: Wear self-contained breathing apparatus pressure-demand (NIOSH approved
or equivalent) and full protective gear. Use water spray to cool exposed surfaces.
Section 6 - Accidental Release Measures
Steps To Be Taken If Material Is Released Or Spilled: Wear proper protective equipment as specified in
Section 8. Immediately eliminate sources of ignition. Scrape up dried material and place into containers.
Section 7 - Handling And Storage
Handling: KEEP OUT OF REACH OF CHILDREN! DO NOT TAKE INTERNALLY. Do not breathe vapors.
Provide fresh air such that chemical odors cannot be detected during use and while drying. Avoid contact with
skin and eyes. Use in well ventilated area. Keep containers closed when not in use. Intentional misuse by
deliberately concentrating and inhaling vapors may be harmful or fatal. Keep away from heat. Vapors are heavier
than air and will collect in low areas. Check all low areas (basements, sumps, etc.) for vapor before entering.
Wash thoroughly after handling. Do not smoke.
Storage: Avoid excessive heat and freezing. Keep away from heat and sources of ignition. Store away from
caustics and oxidizers. Do not store at temperatures above 120 degrees F.
Section 8 - Exposure Controls / Personal Protection
Precautionary Measures: Please refer to other sections and subsections of this MSDS.
Engineering Controls: Provide sufficient general and/or local exhaust ventilation to maintain exposure below
recommended exposure limit. Ensure fresh air entry during application and drying. If you experience eye
watering, headache or dizziness or if air monitoring demonstrates vapor/mist levels are above applicable limits,
wear an appropriate, properly fitted respirator (NIOSH approved) during and after application. Follow respirator
manufacturer's directions for respirator use. Vapors are heavier than air and may spread along floors.
Respiratory Protection: A NIOSH -approved air purifying respirator with an organic vapor cartridge or canister
may be necessary under certain circumstances where airborne concentrations are expected to exceed exposure
limits. A respiratory protection program that meets the OSHA 1910.134 and ANSI Z88.2 requirements must be
followed whenever workplace conditions warrant a respirator's use. If you experience eye watering, headache or
dizziness or if air monitoring demonstrates vapor/mist levels are above applicable limits, wear and appropriate,
properly fitted respirator (NIOSH approved) during and after application.
Skin Protection: Impervious gloves.
Eye Protection: Goggles or safety glasses with side shields.
Other protective equipment: Provide eyewash and solvent impervious apron if body contact may occur.
Hygienic Practices: Remove and wash contaminated clothing before re-use. Do not smoke.
Section 9 - Physical And Chemical Properties
Boiling Range: 350 - 355 F Vapor Density: Not Established
Odor: Strong Solvent Odor Threshold: Not Established
Appearance: White to Off-White Evaporation Rate: Faster Than n-Butyl Acetate
Solubility in H2O: Not Established Specific Gravity: 1.441
Freeze Point: Not Established pH: Not Applicable
Vapor Pressure: 5 mmHg Viscosity: Not Established
Physical State: Paste
When reported, vapor pressure of this product has been calculated theoretically based on its constituent makeup and has not been determined
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experimentally.
(See section 16 for abbreviation legend)
Section 10 - Stability And Reactivity
Conditions To Avoid: Excessive heat and freezing.
Incompatibility: Strong acids and strong bases.
Hazardous Decomposition Products: Normal decomposition products, i.e., COx, NOx.
Hazardous Polymerization: Hazardous polymerization will not occur under normal conditions.
Stability: Stable under normal conditions.
Section 11 - Toxicological Information
Product LD50: Not Established Product LC50: Not Established
Carcinogenicity:
CAS No. Chemical Name ACGIH OSHA IARC NTP WT%
Classification not
13463-67 -7 Titanium dioxide ----- ----- possible from current ----- 0.5-1.5
data.
Suspected human
14808-60 -7 Silica, crystalline ----- ----- Known carcinogen. 0.1-1.0
carcinogen.
Significant Data with Possible Relevance to Humans: None
Section 12 - Ecological Information
Ecological Information: None known.
Section 13 - Disposal Information
Disposal Information: State and Local regulations/restrictions are complex and may differ from Federal
regulations. Responsibility for proper waste disposal is with the owner of the waste.
EPA Waste Code if Discarded (40 CFR Section 261): None; yields no liquid component when evaluated by
EPA method 1311 (TCLP)
Section 14 - Transportation Information
DOT Proper Shipping Combustible liquid, n.o.s. (in Packing Group: None (III if not domestic by
Name: accordance with 49CFR173.150 ground)
(f)(2) when transported
domestically by ground)
DOT Technical Name: Combustible liquid Hazard Subclass: N.A.
DOT Hazard Class: None (3 for non-domestic / or DOT UN/NA Number: None (NA1993 when not
air) domestic ground)
Note: The shipping information provided is applicable for domestic ground transport only. Different categorization
may apply if shipped via other modes of transportation and/or to non-domestic destinations.
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Section 15 - Regulatory Information
CERCLA - SARA Hazard Category:
This product has been reviewed according to the EPA 'Hazard Categories' promulgated under Sections 311 and
312 of the Superfund Amendment and Reauthorization Act of 1986 (SARA Title III) and is considered, under
applicable definitions, to meet the following categories:
Immediate Health Hazard, Chronic Health Hazard
SARA Section 313:
This product contains the following substances subject to the reporting requirements of Section 313 of Title III of
the Superfund Amendment and Reauthorization Act of 1986 and 40 CFR part 372:
None
Toxic Substances Control Act:
All ingredients in this product are either on TSCA inventory list, or otherwise exempt.
This product contains the following chemical substances subject to the reporting requirements of TSCA 12(B) if
exported from the United States:
None
U.S. State Regulations:
New Jersey Right-to-Know:
The following materials are non-hazardous, but are among the top five components in this product:
Chemical Name CAS Number WT%
Butene, homopolymer Proprietary 7-13
Propene polymers Proprietary 5-10
Isobutylene/isoprene copolymer Proprietary 1-5
Pennsylvania Right-to-Know:
The following non-hazardous ingredients are present in the product at greater than 3%:
Chemical Name CAS Number WT%
Butene, homopolymer Proprietary 7-13
Propene polymers Proprietary 5-10
Isobutylene/isoprene copolymer Proprietary 1-5
California Proposition 65:
Warning: The following ingredients present in the product are known to the State of California to cause cancer:
Chemical Name CAS Number Definition Date Listed WT%
Silica, crystalline 14808-60-7 Carcinogenic. Listed: October 1, 1988 0.1-1.0
Warning: The following ingredients present in the product are known to the State of California to cause birth
defects or other reproductive harm:
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None.
Section 16 - Other Information
HMIS Ratings:
Health: 2 Flammability: 2 Reactivity: 0 Personal Protection: X
VOLATILE ORGANIC COMPOUNDS, GR/LTR: 221.1 LB/GAL: 1.8 WT%: 15.377
REASON FOR REVISION: Periodic Update
Legend: N.A. 鈥? Not Applicable ACGIH 鈥? American Conference of Governmental Industrial Hygienists
N.E. 鈥? Not Established SARA 鈥? Superfund Amendments and Reauthorization Act of 1986
N.D. 鈥? Not Determined NJRTK 鈥? New Jersey Right-to-Know Law
VOC 鈥? Volatile Organic Compound OSHA 鈥? Occupational Safety and Health Administration
PEL 鈥? Permissible Exposure Limit HMIS 鈥? Hazardous Materials Identification System
TLV 鈥? Threshold Limit Value NTP 鈥? National Toxicology Program
STEL 鈥? Short Term Exposure Limit CEIL 鈥? Ceiling Exposure Limit
LD50 鈥? Lethal Dose 50 LC50 鈥? Lethal Concentration 50
F 鈥? Degree Fahrenheit C 鈥? Degree Celcius
MSDS 鈥? Material Safety Data Sheet CASRN 鈥? The Chemical Abstracts Service Registry Number
DAP believes the data and statements contained herein are accurate as of the date hereof. They are offered in good faith as
typical values and not as a product specification. NO WARRANTY OF MERCHANTABILITY, WARRANTY OF
FITNESS FOR ANY PARTICULAR PURPOSE OR ANY OTHER WARRANTY, EXPRESS OR IMPLIED, IS
MADE WITH REGARD TO THE INFORMATION HEREIN PROVIDED OR THE PRODUCT TO WHICH THE
INFORMATION REFERS. Since this document is intended only as a guide to the appropriate use and precautionary
handling of the referenced product by a properly trained person, it is therefore the responsibility of the user to (i) review the
recommendations with due consideration for the specific context of the intended use and (ii) determine if they are
appropriate.
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