00010337001 English Page 1 of 7
24 Hour Emergency Phone
Numbers:
Medical/Poison Control:
Material 1-800-327-3874
1-513-558-5111
Safety
Transportation/National
Response
Center:
Data
1-800-535-5053
1-352-323-3500
Sheet NOTE: The National Response Center
emergency numbers to be used only in the event
of chemical emergencies involving a spill, leak,
fire, exposure or accident involving chemicals.
IMPORTANT: Provide this information to employees, customers, and users of this product. Read this MSDS before handling or
disposing of this product. This product is covered by the OSHA Hazard Communication Standard and this document has been
prepared in accordance with requirements of this standard. All abbreviated terms used in this MSDS are further described in Section
16.
Section 1 - Chemical Product / Company Information
This Material Safety Data Sheet is available in Canadian French and Hispanic American Spanish upon request.
On peut demader cette fiche signal茅tique (MSDS) a la langue francaise -canadienne.
Los Datos de Serguridad del Producto pueden obtenerse en Espanol si lo riquiere.
Product Name: DAP 7000 LOW VOC SUBFLR ADH Revision Date: 09/04/2007
Product UPC 070798270428, 070798270442 Supercedes: 11/02/2004
Number:
Product Use/Class: Subfloor Construction Adhesive MSDS Number: 00010337001
Manufacturer: DAP Inc.
2400 Boston Street Suite 200
Baltimore, MD 21224-4723
888-327-8477 (non-emergency matters)
Section 2 - Hazards Identification
Emergency Overview: A tan paste product with a strong solvent odor. DANGER! Extremely flammable liquid
and vapor. Vapors may cause flash fire or explosion. Vapors may ignite explosively. Keep away from heat, sparks
and flame. Do not breathe vapors. Use only with adequate ventilation. Prevent build -up of vapors by opening all
windows and doors to achieve cross-ventilation. May cause eye, skin, nose, throat and respiratory tract irritation.
Refer to other MSDS sections for other detailed information.
Effects Of Overexposure - Eye Contact: Causes eye irritation.
Effects Of Overexposure - Skin Contact: Causes skin irritation. Prolonged and repeated skin contact may
cause dermatitis, drying and defatting due to the solvent properties.
Effects Of Overexposure - Inhalation: Vapor harmful. May affect the brain or nervous system causing
dizziness, headache or nausea. Inhalation causes irritation to the respiratory tract (nose, mouth, throat, mucous
membranes). May be fatal if inhaled.
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Effects Of Overexposure - Ingestion: Harmful or fatal if swallowed. If ingested, may cause vomiting, diarrhea,
and depressed respiration. Aspiration of material into the lungs due to vomiting can cause chemical pneumonitis,
which can be fatal.
Effects Of Overexposure - Chronic Hazards: NOTICE: Reports have associated repeated and prolonged
occupational overexposure to solvents with permanent brain and nervous system damage. Symptoms include:
loss of memory, loss of intellectual ability and loss of coordination. Intentional misuse by deliberately
concentrating and inhaling the contents may be harmful or fatal. Prolonged or repeated contact with skin can
cause defatting of the skin, which may lead to dermatitis. Overexposure or misuse of toluene can cause liver,
kidney, and brain damage as well as cardiac abnormalities. There have been cases of aplastic anemia from
toluene in industrial exposures (ACGIH, 1992). Increased coagulation time and reduced clotting factors have also
been found, which are indicators of damage to the bone marrow (Clayton & Clayton, 1994).
Symptoms include: loss of memory, loss of intellectual ability and loss of coordination.
Primary Route(s) Of Entry: Skin Contact, Inhalation, Ingestion, Eye Contact
Medical Conditions which May be Aggravated by Exposure: None known.
Carcinogenicity:
CAS No. Chemical Name ACGIH OSHA IARC NTP
13463-67-7 Titanium dioxide Not Listed. Not Listed. Possible carcinogen. Not Listed.
Suspected human
14808-60-7 Silica, crystalline Not Listed. Human carcinogen. Known carcinogen.
carcinogen.
Section 3 - Composition / Information On Ingredients
Chemical Name CASRN Wt%
Limestone 1317-65-3 10-30
Kaolin 1332-58-7 10-30
Acetone 67-64-1 10-30
Methyl acetate 79-20-9 10-30
Toluene 108-88-3 7-13
Mica 12001-26-2 0.1-1.0
Titanium dioxide 13463-67-7 0.1-1.0
Silica, crystalline 14808-60-7 <0.07
Section 4 - First Aid Measures
First Aid - Eye Contact: In case of contact, immediately flush eyes with plenty of water for at least 15 minutes.
Get medical attention immediately.
First Aid - Skin Contact: Wash off immediately with soap and plenty of water. Remove and wash contaminated
clothing.
First Aid - Inhalation: If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is
difficult, give oxygen. Get medical attention immediately.
First Aid - Ingestion: If swallowed, DO NOT INDUCE VOMITING. Get medical attention immediately. Never
give anything by mouth to an unconscious person.
Note to Physician: None.
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COMMENTS: Call Medical Emergency at 1-800-327-3874 if any irritation or complication arises from any of the
above routes of entry.
Section 5 - Fire Fighting Measures
Extinguishing Media: Alcohol, Carbon Dioxide, Dry Chemical
Unusual Fire And Explosion Hazards: Material will readily ignite at room temperature. Extremely Flammable!
Do not smoke. Extinguish all flames and pilot lights, and turn off stoves, heaters, electric motors and other
sources of ignition during use and until all vapors are gone. Closed containers may burst if exposed to extreme
heat or fire. Eliminate sources of ignition: heat, electrical equipment, sparks and flames. Vapors may form
explosive mixtures with air. Vapors can flow along surfaces to a distant ignition source and flash back.
Special Firefighting Procedures: Wear self-contained breathing apparatus pressure-demand (NIOSH approved
or equivalent) and full protective gear. Use water spray to cool exposed surfaces.
Section 6 - Accidental Release Measures
Steps To Be Taken If Material Is Released Or Spilled: Wear proper protective equipment as specified in
Section 8. Immediately eliminate sources of ignition. Dike to prevent entering any sewer or waterway. If spilled,
contain spilled material and remove with inert absorbent. Dispose of contaminated absorbent, container and
unused contents in accordance with local, state and federal regulations.
Section 7 - Handling And Storage
Handling: KEEP OUT OF REACH OF CHILDREN! DO NOT TAKE INTERNALLY. Do not breathe vapors.
Vapors are heavier than air and will collect in low areas. Check all low areas (basements, sumps, etc.) for vapor
before entering. Intentional misuse by deliberately concentrating and inhaling vapors may be harmful or fatal. Use
in well ventilated area. Do not get in eyes, on skin or clothing. Wash thoroughly after handling. Turn off stoves,
heaters, electric motors or other sources of ignition during use and until all vapors are gone. Vapors may travel
long distances to a source of ignition and flash back.
Construction and repair activities can adversely affect indoor air quality. Consult with occupants or a
representative (i.e. maintenance, building manager, industrial hygienist, or safety officer) to determine ways to
minimize impact.
Storage: Keep away from heat and sources of ignition. Do not store at temperatures above 120 degrees F. Store
containers away from excessive heat and freezing. Keep containers closed when not in use. Close container after
each use. Keep tightly closed in a dry and cool place. Store away from caustics and oxidizers.
Section 8 - Exposure Controls / Personal Protection
Chemical Name CASRN ACGIH TWA ACGIH STEL ACGIH CEIL OSHA TWA OSHA STEL OSHA CEIL Skin
5 MGM3
Limestone 1317-65-3 10 MGM3 N.E. N.E. (respirable N.E. N.E. No
fraction)
Kaolin 1332-58-7 2 MGM3 N.E. N.E. 15 MGM3 N.E. N.E. No
Acetone 67-64-1 500 PPM 750 PPM N.E. 1000 PPM N.E. N.E. No
Methyl acetate 79-20-9 200 PPM 250 PPM N.E. 200 PPM N.E. N.E. No
Toluene 108-88-3 50 PPM N.E. N.E. 200 PPM N.E. 300 PPM Yes
Mica 12001-26-2 3 MGM3 N.E. N.E. 5 MGM3 N.E. N.E. No
Titanium dioxide 13463-67-7 10 MGM3 N.E. N.E. 15 MGM3 N.E. N.E. No
10/(%SiO2 + 2)
Silica, crystalline 14808-60-7 0.05 MGM3 N.E. N.E. N.E. N.E. No
MGM3
Exposure Notes:
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Precautionary Measures: Please refer to other sections and subsections of this MSDS.
Engineering Controls: Local ventilation of emission sources may be necessary to maintain ambient
concentrations below recommended exposure limits. Use adequate general or local exhaust ventilation to keep
airborne concentrations below exposure limits. Ensure fresh air entry during application and drying. If you
experience eye watering, headache or dizziness or if air monitoring demonstrates vapor/mist levels are above
applicable limits, wear an appropriate, properly fitted respirator (NIOSH approved) during and after application.
Follow respirator manufacturer's directions for respirator use. When concentrations exceed the exposure limits
specified, use of a NIOSH approved full face piece organic vapor cartridge respirator is recommended. Where the
protection factor may be exceeded, use of a full face piece supplied air respirator or Self Contained Breathing
Apparatus (SCBA) may be necessary.
Respiratory Protection: If concentrations exceed the exposure limits specified, use of a NIOSH-approved
supplied air respirator is recommended. Where the protection factor is exceeded, use of a Self Contained
Breathing Apparatus (SCBA) may be necessary. A respiratory protection program that meets the OSHA 1910.134
and ANSI Z88.2 requirements must be followed whenever workplace conditions warrant a respirator's use.
Skin Protection: Impervious gloves.
Eye Protection: Goggles or safety glasses with side shields.
Other protective equipment: Safety shower and eyewash station should be located in immediate work area.
Provide eyewash and solvent impervious apron if body contact may occur.
Hygienic Practices: Remove and wash contaminated clothing before re-use.
Important: Listed Permissible Exposure Levels (PEL) are from the U.S. Dept. of Labor OSHA Final Rule Limits (CFR 29 1910.1000); these limits
may vary between states.
Note: An employee's skin exposure to substances having a "YES" in the "SKIN" column in the table above shall be prevented or reduced to the
extent necessary under the circumstances through the use of gloves, coveralls, goggles or other appropriate personal protective equipment,
engineering controls or work practices.
Section 9 - Physical And Chemical Properties
Boiling Range: Not Established Vapor Density: Heavier Than Air
Odor: Strong Solvent Odor Threshold: Not Established
Color: Tan Evaporation Rate: Faster Than n-Butyl Acetate
Solubility in H2O: Not Established Specific Gravity: 1.2
Freeze Point: Not Established pH: Not Applicable
Vapor Pressure: Not Established Viscosity: 170,000 - 250,000 cPs
Physical State: Paste Flammability: Flammable
Flash Point, F: 80 degree Fahrenheit Method: (Pensky-Martens Closed
Cup)
Lower Explosive Limit, Not Established Upper Explosive Limit, %:Not Established
%:
When reported, vapor pressure of this product has been calculated theoretically based on its constituent makeup and has not been determined
experimentally.
(See section 16 for abbreviation legend)
Section 10 - Stability And Reactivity
Conditions To Avoid: Excessive heat and freezing.
Incompatibility: Strong oxidizers, alkali metals and alkaline earth metals may cause fires or explosions.
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Hazardous Decomposition Products: Normal decomposition products, i.e., COx, NOx.
Hazardous Polymerization: Hazardous polymerization will not occur under normal conditions.
Stability: Stable under recommended storage conditions.
Section 11 - Toxicological Information
Product LD50: Not Established Product LC50: Not Established
CASRN Chemical Name LD50 LC50
67-64-1 Acetone ------------- Rat:50100 mg/m3/8H
79-20-9 Methyl acetate Oral Rabbit: 3,705 mg/kg -------------
108-88-3 Toluene ------------- Rat:49 gm/m3/4H
Significant Data with Possible Relevance to Humans: None.
Section 12 - Ecological Information
Ecological Information: Ecological injuries are not known or expected under normal use.
Section 13 - Disposal Information
Disposal Information: Do not re -use empty containers. Liquids cannot be disposed of in a landfill. Dispose of
material in accordance with all federal, state and local regulations. After recovery of solvent dispose of by special
waste incineration in compliance with the Environment Protection Act 1990 (Process Guidance Note IPR5/1).
State and Local regulations/restrictions are complex and may differ from Federal regulations. Responsibility for
proper waste disposal is with the owner of the waste.
EPA Waste Code if Discarded (40 CFR Section 261): D001
Section 14 - Transportation Information
DOT Proper Shipping Consumer Commodity Packing Group: N.A.
Name:
DOT Technical Name: N.A. Hazard Subclass: N.A.
DOT Hazard Class: ORM-D DOT UN/NA Number: N.A.
Note: The shipping information provided is applicable for domestic ground transport only. Different categorization
may apply if shipped via other modes of transportation and/or to non-domestic destinations.
Section 15 - Regulatory Information
CERCLA - SARA Hazard Category:
This product has been reviewed according to the EPA 'Hazard Categories' promulgated under Sections 311 and
312 of the Superfund Amendment and Reauthorization Act of 1986 (SARA Title III) and is considered, under
applicable definitions, to meet the following categories:
Immediate Health Hazard, Chronic Health Hazard, Fire Hazard
SARA Section 313:
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This product contains the following substances subject to the reporting requirements of Section 313 of Title III of
the Superfund Amendment and Reauthorization Act of 1986 and 40 CFR part 372:
Chemical Name CAS Number
Toluene 108-88-3
Toxic Substances Control Act:
All ingredients in this product are either on TSCA inventory list, or otherwise exempt.
This product contains the following chemical substances subject to the reporting requirements of TSCA 12(B) if
exported from the United States:
Chemical Name CAS Number
Methyl acetate 79-20-9
New Jersey Right-to-Know:
The following materials are non-hazardous, but are among the top five components in this product:
Chemical Name CAS Number
Hydrocarbons, C9 unsaturated, polymerize TSRN-1223370035031P
Butadiene-styrene copolymer TSRN-618608-5037P
block copolymer of 1,3-butadiene-styrene TSRN-618608-5085P
Pennsylvania Right-to-Know:
The following non-hazardous ingredients are present in the product at greater than 3%:
Chemical Name CAS Number
Hydrocarbons, C9 unsaturated, polymerize Proprietary
Butadiene-styrene copolymer Proprietary
block copolymer of 1,3-butadiene-styrene Proprietary
California Proposition 65:
WARNING: This product contains chemicals known to the State of California to cause cancer, birth defects or
other reproductive harm.
Section 16 - Other Information
HMIS Ratings:
Health: 2 Flammability: 3 Reactivity: 0 Personal Protection: X
Volatile Organic Compounds (VOC), less water less exempts: g/L: 194.1 lb/gal: 1.6 wt:wt%: 10.5
Volatile Organic Compounds (VOC), less water less exempts, less LVP-VOCs: wt:wt%: 10.5
REASON FOR REVISION: Periodic Update
Legend: N.A. 鈥? Not Applicable ACGIH 鈥? American Conference of Governmental Industrial Hygienists
N.E. 鈥? Not Established SARA 鈥? Superfund Amendments and Reauthorization Act of 1986
00010337001 English Page 7 of 7
N.D. 鈥? Not Determined NJRTK 鈥? New Jersey Right-to-Know Law
VOC 鈥? Volatile Organic Compound OSHA 鈥? Occupational Safety and Health Administration
PEL 鈥? Permissible Exposure Limit HMIS 鈥? Hazardous Materials Identification System
TLV 鈥? Threshold Limit Value NTP 鈥? National Toxicology Program
CEIL 鈥? Ceiling Exposure Limit STEL 鈥? Short Term Exposure Limit
LD50 鈥? Lethal Dose 50 LC50 鈥? Lethal Concentration 50
F 鈥? Degree Fahrenheit MSDS 鈥? Material Safety Data Sheet
C 鈥? Degree Celsius CASRN 鈥? The Chemical Abstracts Service Registry Number
DAP believes the data and statements contained herein are accurate as of the date hereof. They are offered in good faith as
typical values and not as a product specification. NO WARRANTY OF MERCHANTABILITY, WARRANTY OF
FITNESS FOR ANY PARTICULAR PURPOSE OR ANY OTHER WARRANTY, EXPRESS OR IMPLIED, IS
MADE WITH REGARD TO THE INFORMATION HEREIN PROVIDED OR THE PRODUCT TO WHICH THE
INFORMATION REFERS. Since this document is intended only as a guide to the appropriate use and precautionary
handling of the referenced product by a properly trained person, it is therefore the responsibility of the user to (i) review the
recommendations with due consideration for the specific context of the intended use and (ii) determine if they are
appropriate.
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