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24 Hour Emergency Phone Numbers:
Medical/Poison Control:
Material In U.S.: Call 1-800-222-1222
Outside U.S.: Call your local poison
Safety
control center
Transportation/National Response
Center:
Data
1-800-535-5053
1-352-323-3500
Sheet NOTE: The National Response Center emergency numbers to
be used only in the event of chemical emergencies involving a
spill, leak, fire, exposure or accident involving chemicals.
IMPORTANT: Provide this information to employees, customers, and users of this product. Read this MSDS before handling or disposing of
this product. This product is covered by the OSHA Hazard Communication Standard and this document has been prepared in accordance with
requirements of this standard. All abbreviated terms used in this MSDS are further described in Section 16.
Section 1 - Chemical Product / Company Information
This Material Safety Data Sheet is available in Canadian French and Hispanic American Spanish upon request.
On peut demader cette fiche signal茅tique (MSDS) a la langue francaise-canadienne.
Los Datos de Serguridad del Producto pueden obtenerse en Espanol si lo riquiere.
Product Name: Gutter & Flashing 3.0 Sealant w/Kwik Dry Revision Date: 02/28/2008
Technology - Colors
Product UPC Number: 070798183667 Supersedes: 01/14/2008
Product Use/Class: MS Polymer Caulk MSDS Number: 00010049001
Manufacturer: DAP Inc.
2400 Boston Street Suite 200
Baltimore, MD 21224-4723
888-327 -8477 (non-emergency matters)
Section 2 - Hazards Identification
Emergency Overview: A colored paste product with a slight odor. WARNING! May cause eye, skin, nose, throat and
respiratory tract irritation. May cause eye or skin irritation. Harmful if swallowed or absorbed through the skin.
Refer to other MSDS sections for other detailed information.
Effects Of Overexposure - Eye Contact: Causes eye irritation. Signs and symptoms may include: pain, tears, swelling,
redness and blurred vision.
Effects Of Overexposure - Skin Contact: Causes Moderate skin irritation. May cause skin irritation. Harmful if absorbed
through the skin. Prolonged or repeated skin contact can result in sensitization and dermatitis.
Effects Of Overexposure - Inhalation: Vapor harmful. During application and cure, this product releases methanol,
which may affect the brain or nervous system causing dizziness, headache or nausea. Vapor harmful. Inhalation of high
concentrations may cause headache, nausea, and dizziness. Inhalation may cause irritation to the respiratory tract (nose,
mouth, mucous membranes). Inhalation may cause mild irritation to the respiratory tract (nose, mouth, mucous
membranes). May cause blurred vision. May cause drowsiness. Overexposure by inhalation may injure the liver.
Effects Of Overexposure - Ingestion: Harmful if swallowed. Ingestion may cause gastrointestinal irritation, nausea,
vomiting and diarrhea. Ingestion may result in obstruction when material hardens.
Effects Of Overexposure - Chronic Hazards: Repeated or prolonged exposure may cause respiratory system damage.
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Prolonged and repeated skin contact may cause irritation and possibly dermatitis. Overexposure may cause kidney,
cardiovascular, skin and liver damage.
A mixture of diisodecyl phthalate and diisononyl phthalate has been tested in a two-generation toxicity study in laboratory
animals. No effects on reproductive parameters were seen. However, a small but statistically significant increase in early
offspring mortality was seen at high oral doses. The significance of this to humans is uncertain.
Trimethoxyvinylsilane may cause heart muscle damage, anemia and lung, liver and kidney damage.
Primary Route(s) Of Entry: Skin Contact, Inhalation, Eye Contact
Medical Conditions which May be Aggravated by Exposure: None known.
Carcinogenicity:
CAS No. Chemical Name ACGIH OSHA IARC NTP
13463-67-7 Titanium dioxide Not Listed. Not Listed. Possible carcinogen. Not Listed.
Section 3 - Composition / Information On Ingredients
Chemical Name CASRN Wt%
Calcium Carbonate 471-34-1 30 -60
Diisodecyl phthalate 68515-49 -1 10 -30
Titanium dioxide 13463-67 -7 3-7
Diisononyl phthalate 68515-48 -0 0.5-1.5
Trimethoxyvinylsilane 2768-02-7 0.1-1.0
Section 4 - First Aid Measures
First Aid - Eye Contact: In case of contact, immediately flush eyes with large quantities of water for at least 15 minutes
until irritation subsides. Get medical attention immediately.
First Aid - Skin Contact: Wash off immediately with soap and plenty of water for at least 15 minutes. Get medical aid if
symptoms persist. Remove and wash contaminated clothing. In case of contact, immediately flush skin with plenty of
water while removing contaminated clothing and shoes.
First Aid - Inhalation: If inhaled, remove to fresh air. If breathing is difficult, leave the area to obtain fresh air. If
continued breathing difficulty is experienced, get medical attention immediately. First Aid: If you experience difficulty in
breathing, leave the area to obtain fresh air. If continued difficulty is experienced, get medical attention Immediately.
First Aid - Ingestion: If swallowed, DO NOT INDUCE VOMITING. Get medical attention immediately. If ingested, drink 2
glasses of water. Immediately see a physician. Never give anything by mouth to an unconscious person.
Note to Physician: None.
COMMENTS: If over-exposure occurs, call your poison control center at 1 -800 -222-1222.
Section 5 - Fire Fighting Measures
Extinguishing Media: Carbon Dioxide, Dry Chemical, Foam, Water Fog
Unusual Fire And Explosion Hazards: No special protective measures against fire required.
Special Firefighting Procedures: Wear self-contained breathing apparatus pressure-demand (NIOSH approved or
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equivalent) and full protective gear. Use water spray to cool exposed surfaces.
Section 6 - Accidental Release Measures
Steps To Be Taken If Material Is Released Or Spilled: Wear proper protective equipment as specified in Section 8. Use
absorbent material or scrape up dried material and place in container.
Section 7 - Handling And Storage
Handling: KEEP OUT OF REACH OF CHILDREN! DO NOT TAKE INTERNALLY. Avoid breathing vapor and contact
with eyes, skin and clothing. Use only with adequate ventilation. Open all windows and doors or use other means to
ensure cross-ventilation and fresh air entry during application and drying. Odor is not an adequate warning for hazardous
conditions. Wash thoroughly after handling. Remove contact lenses before using. Do not handle contact lenses until all
sealant has been cleaned from fingertips, nails and cuticles. Residual sealant may transfer to contact lenses and cause
severe eye irritation.
Storage: Do not store at temperatures above 120 degrees F. Store containers away from excessive heat and freezing.
Close container after each use. Store away from caustics and oxidizers.
Section 8 - Exposure Controls / Personal Protection
Chemical Name CASRN ACGIH TWA ACGIH STEL ACGIH CEIL OSHA TWA OSHA STEL OSHA CEIL Skin
5 MGM3
Calcium Carbonate 471-34-1 10 MGM3 N.E. N.E. (respirable N.E. N.E. No
fraction)
Diisodecyl phthalate 68515-49-1 N.E. N.E. N.E. N.E. N.E. N.E. No
Titanium dioxide 13463-67-7 10 MGM3 N.E. N.E. 15 MGM3 N.E. N.E. No
Diisononyl phthalate 68515-48-0 N.E. N.E. N.E. N.E. N.E. N.E. No
Trimethoxyvinylsilane 2768-02-7 N.E. N.E. N.E. N.E. N.E. N.E. No
Exposure Notes: None.
Precautionary Measures: Contact lenses pose a special hazard; soft lenses may absorb and all lenses concentrate
irritants.
Engineering Controls: Good general ventilation should be sufficient to control airborne levels. Ensure adequate
ventilation, especially in confined areas. Local ventilation of emission sources may be necessary to maintain ambient
concentrations below recommended exposure limits.
Respiratory Protection: In case of insufficient ventilation, wear suitable respiratory equipment. A NIOSH-approved air
purifying respirator with an organic vapor cartridge or canister may be necessary under certain circumstances where
airborne concentrations are expected to exceed exposure limits. A respiratory protection program that meets the OSHA
1910.134 and ANSI Z88.2 requirements must be followed whenever workplace conditions warrant a respirator's use.
Skin Protection: Rubber gloves. Natural rubber, butyl rubber and polyvinyl chloride gloves are not suitable protection
against phthalates such as diisodecyl phthalate and diisononyl phthalate; neoprene is recommended.
Eye Protection: Goggles or safety glasses with side shields.
Other protective equipment: Not required under normal use.
Hygienic Practices: Wash hands before breaks and at the end of workday. Remove and wash contaminated clothing
before re-use.
Important: Listed Permissible Exposure Levels (PEL) are from the U.S. Dept. of Labor OSHA Final Rule Limits (CFR 29 1910.1000); these limits may vary
between states.
Note: An employee's skin exposure to substances having a "YES" in the "SKIN" column in the table above shall be prevented or reduced to the extent
necessary under the circumstances through the use of gloves, coveralls, goggles or other appropriate personal protective equipment, engineering controls or work
practices.
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Section 9 - Physical And Chemical Properties
Boiling Range: Not Established Vapor Density: Heavier Than Air
Odor: Slight Odor Threshold: Not Established
Color: Colored Evaporation Rate: Slower Than n-Butyl Acetate
Solubility in H2O: Not Established Specific Gravity: 1.4
Freeze Point: Not Established pH: Between 7.0 and 12.9
Vapor Pressure: Not Established Viscosity: Not Established
Physical State: Paste Flammability: Non-Flammable
(Seta Closed Cup)
Flash Point, F: Greater Than 200 Method:
Lower Explosive Limit, %: Not Established Upper Explosive Limit, %:Not Established
When reported, vapor pressure of this product has been calculated theoretically based on its constituent makeup and has not been determined experimentally.
(See section 16 for abbreviation legend)
Section 10 - Stability And Reactivity
Conditions To Avoid: Excessive heat and freezing.
Incompatibility: Incompatible with strong bases and oxidizing agents.
Hazardous Decomposition Products: Normal decomposition products, i.e., COx, NOx.
Hazardous Polymerization: Hazardous polymerization will not occur under normal conditions.
Stability: Stable under recommended storage conditions.
Section 11 - Toxicological Information
Product LD50: Not Established Product LC50: Not Established
CASRN Chemical Name LD50 LC50
471-34-1 Calcium Carbonate Rat:6450 mg/kg -------------
Significant Data with Possible Relevance to Humans: None.
Section 12 - Ecological Information
Ecological Information: Ecological injuries are not known or expected under normal use.
Section 13 - Disposal Information
Disposal Information: Dispose of material in accordance with all federal, state and local regulations. State and Local
regulations/restrictions are complex and may differ from Federal regulations. Responsibility for proper waste disposal is
with the owner of the waste.
EPA Waste Code if Discarded (40 CFR Section 261): None
Section 14 - Transportation Information
DOT Proper Shipping Not Regulated Packing Group: N.A.
Name:
DOT Technical Name: None Hazard Subclass: N.A.
DOT Hazard Class: N.A. DOT UN/NA Number: None
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Note: The shipping information provided is applicable for domestic ground transport only. Different categorization may
apply if shipped via other modes of transportation and/or to non-domestic destinations.
Section 15 - Regulatory Information
CERCLA - SARA Hazard Category:
This product has been reviewed according to the EPA 'Hazard Categories' promulgated under Sections 311 and 312 of
the Superfund Amendment and Reauthorization Act of 1986 (SARA Title III) and is considered, under applicable
definitions, to meet the following categories:
Immediate Health Hazard, Chronic Health Hazard
SARA Section 313:
This product contains the following substances subject to the reporting requirements of Section 313 of Title III of the
Superfund Amendment and Reauthorization Act of 1986 and 40 CFR part 372:
None
Toxic Substances Control Act:
All ingredients in this product are either on TSCA inventory list, or otherwise exempt.
This product contains the following chemical substances subject to the reporting requirements of TSCA 12(B) if exported
from the United States:
None
New Jersey Right-to-Know:
The following materials are non-hazardous, but are among the top five components in this product:
Chemical Name CAS Number
Proprietary polyether Proprietary
Pennsylvania Right-to-Know:
The following non-hazardous ingredients are present in the product at greater than 3%:
Chemical Name CAS Number
Proprietary polyether Proprietary
California Proposition 65:
None.
Section 16 - Other Information
HMIS Ratings:
Health: 1 Flammability: 0 Reactivity: 0 Personal Protection: X
Volatile Organic Compounds (VOC), less water less exempts: g/L: 0.9 lb/gal: 0.0 wt:wt%: 0.1
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Volatile Organic Compounds (VOC), less water less exempts, less LVP -VOCs: wt:wt%: 0.1
REASON FOR REVISION: Periodic Update
Legend: N.A. 鈥? Not Applicable ACGIH 鈥? American Conference of Governmental Industrial Hygienists
N.E. 鈥? Not Established SARA 鈥? Superfund Amendments and Reauthorization Act of 1986
N.D. 鈥? Not Determined NJRTK 鈥? New Jersey Right-to-Know Law
VOC 鈥? Volatile Organic Compound OSHA 鈥? Occupational Safety and Health Administration
PEL 鈥? Permissible Exposure Limit HMIS 鈥? Hazardous Materials Identification System
TLV 鈥? Threshold Limit Value NTP 鈥? National Toxicology Program
CEIL 鈥? Ceiling Exposure Limit STEL 鈥? Short Term Exposure Limit
LD50 鈥? Lethal Dose 50 LC50 鈥? Lethal Concentration 50
F 鈥? Degree Fahrenheit MSDS 鈥? Material Safety Data Sheet
C 鈥? Degree Celsius CASRN 鈥? The Chemical Abstracts Service Registry Number
DAP believes the data and statements contained herein are accurate as of the date hereof. They are offered in good faith as typical
values and not as a product specification. NO WARRANTY OF MERCHANTABILITY, WARRANTY OF FITNESS FOR ANY
PARTICULAR PURPOSE OR ANY OTHER WARRANTY, EXPRESS OR IMPLIED, IS MADE WITH REGARD TO THE
INFORMATION HEREIN PROVIDED OR THE PRODUCT TO WHICH THE INFORMATION REFERS. Since this
document is intended only as a guide to the appropriate use and precautionary handling of the referenced product by a properly trained
person, it is therefore the responsibility of the user to (i) review the recommendations with due consideration for the specific context
of the intended use and (ii) determine if they are appropriate.
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