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Material
24 Hour Emergency Phone Numbers:
Medical: 1-800-327-3874
1-513 -558-5111
Safety Transportation:
1-800 -535-5053
1-352 -323-3500
Data
Sheet
NOTE: National Response Center emergency numbers to be used only in
the event of chemical emergencies involving a spill, leak, fire, exposure or
accident involving chemicals.
IMPORTANT: Provide this information to employees, customers, and users of this product. Read this MSDS before handling or disposing of
this product. This product is covered by the OSHA Hazard Communication Standard and this document has been prepared in accordance with
requirements of this standard. All abbreviated terms used in this MSDS are further described in Section 16.
Section 1 - Chemical Product / Company Information
This Material Safety Data Sheet is available in Canadian French and Hispanic American Spanish upon request.
Esta hoja de datos de la seguridad de los materiales est谩 disponible en franc茅s canadiense y en espa帽ol a su solicitud.
Los Datos de Serguridad del Producto pueden obtenerse en Espanol si lo riquiere.
Product Name: 33 Glazing - All Colors Revision Date: 07/27/2006
Product UPC 7079812019 7079812117 7079812120 7079812121 Supercedes: 07/19/1999
Number: 7079812122 7079812124 7079871090 7079871112
7079871151
Product Use/Class: Glazing MSDS Number: 00010401001
Manufacturer: DAP Inc.
2400 Boston Street Suite 200
Baltimore, MD 21224-4723
888 -327-8477 (non-emergency matters)
Section 2 - Composition / Information On Ingredients
ACGIH
Chemical Name CASRN WT% ACGIH TWA ACGIH CEIL OSHA TWA OSHA STEL OSHA CEIL Skin
STEL
5 MGM3
Calcium carbonate 1317-65-3 60-100 10 MGM3 N.E. N.E. (respirable N.E. N.E. No
fraction)
Soya oil 8001-22-7 3-7 N.E. N.E. N.E. N.E. N.E. N.E. No
Parrafinic process oil 64742-65-0 1-5 N.E. N.E. N.E. 500 PPM N.E. N.E. No
Non-Asbestiform Tremolite 14567-73-8 1-5 10 MGM3 N.E. N.E. 5 MGM3 N.E. N.E. No
Talc, non-asbestiform 14807-96-6 1-5 2 MGM3 N.E. N.E. 5 MGM3 N.E. N.E. No
Antigorite, non-asbestiform 12135-86-3 0.5-1.5 N.E. N.E. N.E. N.E. N.E. N.E. No
10/(%SiO2 +
Silica, crystalline 14808-60-7 0.1-1.0 0.05 MGM. N.E. N.E. N.E. N.E. No
2) MGM3
0.1 0.1 1.0
Anthophyllite, non-asbestiform 17068-78-9 0.1-1.0 N.E. N.E. N.E. No
FIBE.S/CM3 FIBERS/CM3 FIBERS/CM3
Titanium dioxide 13463-67-7 0.1-1.0 10 MGM3 N.E. N.E. 15 MGM3 N.E. N.E. No
Exposure Notes:
CASRN Exposure Note
The talc (CAS number 14807-96-6) within this product naturally contains a non -fibrous tremolite (CAS number 14567-73-8), non-fibrous serpentine
14807-96-6 (CAS number 12135-86-3), and non-fibrous anthophyllite (CAS number 17068-78-9). Refer to 29 CFR 1910.1000 Table Z 3 for the permissible
exposure limits associated with non -fibrous talc and these naturally occurring incidental constituents.
Important: Listed Permissible Exposure Levels (PEL) are from the U.S. Dept. of Labor OSHA Final Rule Limits (CFR 29 1910.1000); these limits may vary
between states.
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Note: An employee's skin exposure to substances having a "YES" in the "SKIN" column in the table above shall be prevented or reduced to the extent
necessary under the circumstances through the use of gloves, coveralls, goggles or other appropriate personal protective equipment, engineering controls or work
practices
Section 3 - Hazards Identification
Emergency Overview: A colored paste product with a little or no odor. WARNING! May cause eye, skin, nose, throat
and respiratory tract irritation. Harmful if swallowed or absorbed through the skin.
Refer to other MSDS sections for other detailed information.
Effects Of Overexposure - Eye Contact: May cause eye irritation.
Effects Of Overexposure - Skin Contact: Harmful if absorbed through the skin. May cause skin irritation.
Effects Of Overexposure - Inhalation: Harmful if inhaled. Inhalation may cause irritation to the respiratory tract (nose,
mouth, mucous membranes). Dust from dry sanding may cause eye, skin, nose, throat and respiratory tract irritation.
Effects Of Overexposure - Ingestion: Harmful if swallowed.
Effects Of Overexposure - Chronic Hazards: Prolonged and repeated skin contact may cause irritation and possibly
dermatitis. Repeated or prolonged exposure may cause respiratory system damage.
Primary Route(s) Of Entry: Skin Contact, Eye Contact
Medical Conditions which May be Aggravated by Exposure: None known.
Section 4 - First Aid Measures
First Aid - Eye Contact: In case of contact, immediately flush eyes with large quantities of water for at least 15 minutes
until irritation subsides. Get medical attention immediately.
First Aid - Skin Contact: Wash off immediately with soap and plenty of water for at least 15 minutes. Get medical aid if
symptoms persist. Remove and wash contaminated clothing.
First Aid - Inhalation: If inhaled, remove to fresh air. If breathing is difficult, leave the area to obtain fresh air. If
continued breathing difficulty is experienced, get medical attention immediately.
First Aid - Ingestion: If swallowed, DO NOT INDUCE VOMITING. Get medical attention immediately.
Note to Physician: None.
COMMENTS: Call Medical Emergency at 1-800-327-3874 if any irritation or complication arises from any of the above
routes of entry.
Section 5 - Fire Fighting Measures
Flash Point, F: Greater than 200 Lower Explosive Limit, %: Not Established
Method: ( Seta Closed Cup) Upper Explosive Limit, %: Not Established
Extinguishing Media: Carbon Dioxide, Dry Chemical, Foam
Unusual Fire And Explosion Hazards: No special protective measures against fire required.
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Special Firefighting Procedures: Wear self-contained breathing apparatus pressure-demand (NIOSH approved or
equivalent) and full protective gear. Use water spray to cool exposed surfaces.
Section 6 - Accidental Release Measures
Steps To Be Taken If Material Is Released Or Spilled: Wear proper protective equipment as specified in Section 8. Use
absorbent material or scrape up dried material and place in container.
Section 7 - Handling And Storage
Handling: KEEP OUT OF REACH OF CHILDREN! DO NOT TAKE INTERNALLY. Use only with adequate ventilation.
Avoid breathing vapor and contact with eyes, skin and clothing. Wash thoroughly after handling. Open all windows and
doors or use other means to ensure cross-ventilation and fresh air entry during application and drying. Odor is not an
adequate warning for hazardous conditions.
Storage: Close container after each use. Store away from caustics and oxidizers. Store containers away from excessive
heat and freezing. Do not store at temperatures above 120 degrees F.
Section 8 - Exposure Controls / Personal Protection
Precautionary Measures: Please refer to other sections and subsections of this MSDS.
Engineering Controls: Good general ventilation should be sufficient to control airborne levels. Ensure adequate
ventilation, especially in confined areas. Local ventilation of emission sources may be necessary to maintain ambient
concentrations below recommended exposure limits.
Respiratory Protection: In case of insufficient ventilation, wear suitable respiratory equipment. A NIOSH-approved air
purifying respirator with an organic vapor cartridge or canister may be necessary under certain circumstances where
airborne concentrations are expected to exceed exposure limits. A respiratory protection program that meets the OSHA
1910.134 and ANSI Z88.2 requirements must be followed whenever workplace conditions warrant a respirator's use.
Skin Protection: Rubber gloves.
Eye Protection: Goggles or safety glasses with side shields.
Other protective equipment: Not required under normal use.
Hygienic Practices: Remove and wash contaminated clothing before re-use. Wash hands before breaks and at the end
of workday.
Section 9 - Physical And Chemical Properties
Boiling Range: Not Established Vapor Density: Heavier Than Air
Odor: Little or None Odor Threshold: Not Established
Appearance: Colored Evaporation Rate: Slower Than n-Butyl Acetate
Solubility in H2O: Not Established Specific Gravity: 2.214
Freeze Point: Not Established pH: Between 7.0 and 12.0
Vapor Pressure: Not Established Viscosity: Not Established
Physical State: Paste
When reported, vapor pressure of this product has been calculated theoretically based on its constituent makeup and has not been determined experimentally.
(See section 16 for abbreviation legend)
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Section 10 - Stability And Reactivity
Conditions To Avoid: Excessive heat and freezing.
Incompatibility: Incompatible with strong bases and oxidizing agents.
Hazardous Decomposition Products: Normal decomposition products, i.e., COx, NOx.
Hazardous Polymerization: Hazardous polymerization will not occur under normal conditions.
Stability: Stable under recommended storage conditions.
Section 11 - Toxicological Information
Product LD50: Not Established Product LC50: Not Established
Carcinogenicity:
CAS No. Chemical Name ACGIH OSHA IARC NTP WT%
14808-60-7 Silica, crystalline Suspected human carcinogen. Not Listed. Human carcinogen. Known carcinogen. 0.1-1.0
Anthophyllite, non- Confirmed human
17068-78-9 Cancer hazard. Human carcinogen. Known carcinogen. 0.1-1.0
asbestiform carcinogen.
Classification not possible
13463-67-7 Titanium dioxide Not Listed. Not Listed. Not Listed. 0.1-1.0
from current data.
Significant Data with Possible Relevance to Humans: None.
Section 12 - Ecological Information
Ecological Information: Ecological injuries are not known or expected under normal use.
Section 13 - Disposal Information
Disposal Information: Dispose of material in accordance with all federal, state and local regulations. State and Local
regulations/restrictions are complex and may differ from Federal regulations. Responsibility for proper waste disposal is
with the owner of the waste.
EPA Waste Code if Discarded (40 CFR Section 261): none
Section 14 - Transportation Information
DOT Proper Shipping Not Regulated. Packing Group: N.A.
Name:
DOT Technical Name: N.A. Hazard Subclass: N.A.
DOT Hazard Class: N.A. DOT UN/NA Number: N.A.
Note: The shipping information provided is applicable for domestic ground transport only. Different
categorization may apply if shipped via other modes of transportation and/or to non-domestic destinations.
Section 15 - Regulatory Information
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CERCLA - SARA Hazard Category:
This product has been reviewed according to the EPA 'Hazard Categories' promulgated under Sections 311 and 312 of
the Superfund Amendment and Reauthorization Act of 1986 (SARA Title III) and is considered, under applicable
definitions, to meet the following categories:
Immediate Health Hazard, Chronic Health Hazard
SARA Section 313:
This product contains the following substances subject to the reporting requirements of Section 313 of Title III of the
Superfund Amendment and Reauthorization Act of 1986 and 40 CFR part 372:
Chemical Name CAS Number WT%
Anthophyllite, non-asbestiform 17068-78-9 0.1-1.0
Toxic Substances Control Act:
All ingredients in this product are either on TSCA inventory list, or otherwise exempt.
This product contains the following chemical substances subject to the reporting requirements of TSCA 12(B) if exported
from the United States:
None
U.S. State Regulations
New Jersey Right-to-Know:
The following materials are non-hazardous, but are among the top five components in this product:
None
Pennsylvania Right-to-Know:
The following non-hazardous ingredients are present in the product at greater than 3%:
None
California Proposition 65:
Warning: The following ingredients present in the product are known to the State of California to cause cancer:
Chemical Name CAS Number Definition Date Listed WT%
Silica, crystalline 14808-60-7 Carcinogenic. Listed: October 1, 1988 0.1-1.0
Anthophyllite, non-asbestiform 17068-78-9 Carcinogenic. Listed: February 27, 1987 0.1-1.0
Warning: The following ingredients present in the product are known to the State of California to cause birth defects or
other reproductive harm:
None
Section 16 - Other Information
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HMIS Ratings:
Health: 1 Flammability: 1 Reactivity: 0 Personal Protection: X
VOLATILE ORGANIC COMPOUNDS, GR/LTR: 10.7 LB/GAL: 0.1 WT%: 0.486
REASON FOR REVISION: Periodic Update
Legend: N.A. 鈥? Not Applicable ACGIH 鈥? American Conference of Governmental Industrial Hygienists
N.E. 鈥? Not Established SARA 鈥? Superfund Amendments and Reauthorization Act of 1986
N.D. 鈥? Not Determined NJRTK 鈥? New Jersey Right-to-Know Law
VOC 鈥? Volatile Organic Compound OSHA 鈥? Occupational Safety and Health Administration
PEL 鈥? Permissible Exposure Limit HMIS 鈥? Hazardous Materials Identification System
TLV 鈥? Threshold Limit Value NTP 鈥? National Toxicology Program
STEL 鈥? Short Term Exposure Limit CEIL 鈥? Ceiling Exposure Limit
LD50 鈥? Lethal Dose 50 LC50 鈥? Lethal Concentration 50
F 鈥? Degree Fahrenheit C 鈥? Degree Celsius
MSDS 鈥? Material Safety Data Sheet CASRN 鈥? The Chemical Abstracts Service Registry Number
DAP believes the data and statements contained herein are accurate as of the date hereof. They are offered in good faith as typical
values and not as a product specification. NO WARRANTY OF MERCHANTABILITY, WARRANTY OF FITNESS FOR ANY
PARTICULAR PURPOSE OR ANY OTHER WARRANTY, EXPRESS OR IMPLIED, IS MADE WITH REGARD TO THE
INFORMATION HEREIN PROVIDED OR THE PRODUCT TO WHICH THE INFORMATION REFERS. Since this
document is intended only as a guide to the appropriate use and precautionary handling of the referenced product by a properly trained
person, it is therefore the responsibility of the user to (i) review the recommendations with due consideration for the specific context
of the intended use and (ii) determine if they are appropriate.
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