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24 Hour Emergency Phone Numbers:
Medical/Poison Control:
Material 1-800-327-3874
1-513-558-5111
Safety
Transportation/National Response
Center:
1-800-535-5053
Data
1-352-323-3500
Sheet NOTE: The National Response Center emergency numbers
to be used only in the event of chemical emergencies
involving a spill, leak, fire, exposure or accident involving
chemicals.
IMPORTANT: Provide this information to employees, customers, and users of this product. Read this MSDS before handling or disposing of
this product. This product is covered by the OSHA Hazard Communication Standard and this document has been prepared in accordance with
requirements of this standard. All abbreviated terms used in this MSDS are further described in Section 16.
Section 1 - Chemical Product / Company Information
This Material Safety Data Sheet is available in Canadian French and Hispanic American Spanish upon request.
On peut demader cette fiche signal茅tique (MSDS) a la langue francaise -canadienne.
Los Datos de Serguridad del Producto pueden obtenerse en Espanol si lo riquiere.
Product Name: Kwik Seal庐 Grout Repair Revision Date: 09/21/2007
Product UPC Number: 070798183728 Supercedes: New
Product Use/Class: Tile Grout Repair - Latex MSDS Number: 00010052001
Manufacturer: DAP Inc.
2400 Boston Street Suite 200
Baltimore, MD 21224-4723
888-327-8477 (non-emergency matters)
Section 2 - Hazards Identification
Emergency Overview: A colored paste product with a very slight ammonia odor. WARNING! May cause eye, skin, nose,
throat and respiratory tract irritation. Harmful in contact with skin and if swallowed. Harmful if swallowed or absorbed
through the skin. This product contains ethylene glycol.
Refer to other MSDS sections for other detailed information.
Effects Of Overexposure - Eye Contact: May cause eye irritation.
Effects Of Overexposure - Skin Contact: May cause sensitization by skin contact. May cause skin irritation. Prolonged
and repeated skin contact may cause irritation and possibly dermatitis. Harmful if absorbed through the skin.
Effects Of Overexposure - Inhalation: Vapor harmful. May affect the brain or nervous system causing dizziness,
headache or nausea. Inhalation of high vapor concentrations can cause central nervous system depression and narcosis.
Inhalation may cause irritation to the respiratory tract (nose, mouth, mucous membranes).
Effects Of Overexposure - Ingestion: Harmful or fatal if swallowed. If ingested, may cause vomiting, diarrhea, and
depressed respiration.
Effects Of Overexposure - Chronic Hazards: Repeated and prolonged exposure to solvents may cause brain and
nervous system damage.
Ethylene Glycol may cause kidney and liver damage upon prolonged and repeated overexposures. Studies have shown
that repeated inhalation of ethylene glycol has produced adverse cardiovascular changes in laboratory animals. Ethylene
00010052001 English Page 2 of 6
glycol has been shown to cause birth defects in laboratory animals.
Primary Route(s) Of Entry: Skin Contact, Skin Absorption, Inhalation, Eye Contact
Medical Conditions which May be Aggravated by Exposure: None known.
Carcinogenicity:
CAS No. Chemical Name ACGIH OSHA IARC NTP
13463-67-7 Titanium dioxide Not Listed. Not Listed. Possible carcinogen. Not Listed.
Section 3 - Composition / Information On Ingredients
Chemical Name CASRN Wt%
Limestone 1317-65-3 60-100
Ethylene glycol 107-21-1 1-5
Stoddard solvent 8052-41-3 0.5-1.5
Titanium dioxide 13463-67-7 0.5-1.5
Section 4 - First Aid Measures
First Aid - Eye Contact: In case of contact, immediately flush eyes with large quantities of water for at least 15 minutes
until irritation subsides. Get medical attention immediately.
First Aid - Skin Contact: Wash off immediately with soap and plenty of water for at least 15 minutes. Get medical aid if
symptoms persist. Remove and wash contaminated clothing.
First Aid - Inhalation: If inhaled, remove to fresh air. If breathing is difficult, leave the area to obtain fresh air. If
continued breathing difficulty is experienced, get medical attention immediately.
First Aid - Ingestion: If swallowed, DO NOT INDUCE VOMITING. Get medical attention immediately. Harmful or fatal if
liquid is aspirated into the lungs. If swallowed, drink 8 -10 oz. of water, get immediate medical attention.
Note to Physician: None.
COMMENTS: Call Medical Emergency at 1-800-327-3874 if any irritation or complication arises from any of the above
routes of entry.
Section 5 - Fire Fighting Measures
Extinguishing Media: Carbon Dioxide, Dry Chemical, Foam, Water Fog
Unusual Fire And Explosion Hazards: Store away from caustics and oxidizers. Containers may explode if exposed to
extreme heat. Eliminate sources of ignition: heat, electrical equipment, sparks and flames.
Special Firefighting Procedures: Wear self-contained breathing apparatus pressure-demand (NIOSH approved or
equivalent) and full protective gear. Use water spray to cool exposed surfaces.
Section 6 - Accidental Release Measures
Steps To Be Taken If Material Is Released Or Spilled: Wear proper protective equipment as specified in Section 8.
Dike to prevent entering any sewer or waterway. Use absorbent material or scrape up dried material and place in
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container.
Section 7 - Handling And Storage
Handling: KEEP OUT OF REACH OF CHILDREN! DO NOT TAKE INTERNALLY. Avoid breathing vapor and contact
with eyes, skin and clothing. Use only with adequate ventilation. Open all windows and doors or use other means to
ensure cross-ventilation and fresh air entry during application and drying. Odor is not an adequate warning for hazardous
conditions. Wash thoroughly after handling.
Storage: Keep away from heat and sources of ignition. Do not store at temperatures above 120 degrees F. Store
containers away from excessive heat and freezing. Keep containers tightly closed. Store away from caustics and
oxidizers.
Section 8 - Exposure Controls / Personal Protection
Chemical Name CASRN ACGIH TWA ACGIH STEL ACGIH CEIL OSHA TWA OSHA STEL OSHA CEIL Skin
5 MGM3
Limestone 1317-65-3 10 MGM3 N.E. N.E. (respirable N.E. N.E. No
fraction)
Ethylene glycol 107-21-1 N.E. N.E. 100 MGM3 N.E. N.E. N.E. No
Stoddard solvent 8052-41-3 100 PPM N.E. N.E. 500 PPM N.E. N.E. No
Titanium dioxide 13463-67-7 10 MGM3 N.E. N.E. 15 MGM3 N.E. N.E. No
Exposure Notes: Please refer to other sections and subsections of this MSDS.
Precautionary Measures: Please refer to other sections and subsections of this MSDS.
Engineering Controls: Provide sufficient general and/or local exhaust ventilation to maintain exposure below
recommended exposure limit. Check all low areas for presence of vapor. Vapors are heavier than air and may spread
along floors.
Respiratory Protection: A NIOSH-approved air purifying respirator with an organic vapor cartridge or canister may be
necessary under certain circumstances where airborne concentrations are expected to exceed exposure limits. A
respiratory protection program that meets the OSHA 1910.134 and ANSI Z88.2 requirements must be followed whenever
workplace conditions warrant a respirator's use.
Skin Protection: Latex gloves.
Eye Protection: Goggles or safety glasses with side shields.
Other protective equipment: Not required under normal use.
Hygienic Practices: Wash hands before breaks and at the end of workday. Remove and wash contaminated clothing
before re-use.
Important: Listed Permissible Exposure Levels (PEL) are from the U.S. Dept. of Labor OSHA Final Rule Limits (CFR 29 1910.1000); these limits may vary
between states.
Note: An employee's skin exposure to substances having a "YES" in the "SKIN" column in the table above shall be prevented or reduced to the extent
necessary under the circumstances through the use of gloves, coveralls, goggles or other appropriate personal protective equipment, engineering controls or work
practices.
Section 9 - Physical And Chemical Properties
Boiling Range: 210 - 220 F Vapor Density: Heavier Than Air
Odor: Very Slight Ammonia Odor Threshold: Not Established
Color: Colored Evaporation Rate: Slower Than n-Butyl Acetate
Solubility in H2O: Not Established Specific Gravity: 1.9
Freeze Point: Not Established pH: Between 7.0 and 12.9
Vapor Pressure: Not Established Viscosity: Not Established
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Physical State: Paste Flammability: Non-Flammable
Flash Point, F: >200 F Method: (Seta Closed Cup)
Lower Explosive Limit, %: Not Established Upper Explosive Limit, %:Not Established
When reported, vapor pressure of this product has been calculated theoretically based on its constituent makeup and has not been determined experimentally.
(See section 16 for abbreviation legend)
Section 10 - Stability And Reactivity
Conditions To Avoid: Excessive heat and freezing.
Incompatibility: Incompatible with strong bases and oxidizing agents.
Hazardous Decomposition Products: Normal decomposition products, i.e., COx, NOx.
Hazardous Polymerization: Hazardous polymerization will not occur under normal conditions.
Stability: Stable under recommended storage conditions.
Section 11 - Toxicological Information
Product LD50: Not Established Product LC50: Not Established
CASRN Chemical Name LD50 LC50
107-21-1 Ethylene glycol Rat:4700 mg/kg Rat:10876 mg/kg
Significant Data with Possible Relevance to Humans: None.
Section 12 - Ecological Information
Ecological Information: Ecological injuries are not known or expected under normal use.
Section 13 - Disposal Information
Disposal Information: Dispose of material in accordance with all federal, state and local regulations. State and Local
regulations/restrictions are complex and may differ from Federal regulations. Responsibility for proper waste disposal is
with the owner of the waste.
EPA Waste Code if Discarded (40 CFR Section 261): This product does not meet the definition of a hazardous waste
according to U.S. EPA Hazardous Waste Management Regulation, 40 CFR Section 261.
Section 14 - Transportation Information
DOT Proper Shipping Not Regulated Packing Group: N.A.
Name:
DOT Technical Name: N.A. Hazard Subclass: N.A.
DOT Hazard Class: N.A. DOT UN/NA Number: None
Note: The shipping information provided is applicable for domestic ground transport only. Different categorization may
apply if shipped via other modes of transportation and/or to non-domestic destinations.
Section 15 - Regulatory Information
00010052001 English Page 5 of 6
CERCLA - SARA Hazard Category:
This product has been reviewed according to the EPA 'Hazard Categories' promulgated under Sections 311 and 312 of
the Superfund Amendment and Reauthorization Act of 1986 (SARA Title III) and is considered, under applicable
definitions, to meet the following categories:
Immediate Health Hazard, Chronic Health Hazard
SARA Section 313:
This product contains the following substances subject to the reporting requirements of Section 313 of Title III of the
Superfund Amendment and Reauthorization Act of 1986 and 40 CFR part 372:
Chemical Name CAS Number
Ethylene glycol 107-21-1
Toxic Substances Control Act:
All ingredients in this product are either on TSCA inventory list, or otherwise exempt.
This product contains the following chemical substances subject to the reporting requirements of TSCA 12(B) if exported
from the United States:
None
New Jersey Right-to-Know:
The following materials are non-hazardous, but are among the top five components in this product:
Chemical Name CAS Number
Water 7732-18-5
Styrene-acrylic latex polymer Proprietary
Pennsylvania Right-to-Know:
The following non-hazardous ingredients are present in the product at greater than 3%:
Chemical Name CAS Number
Water 7732-18-5
Styrene-acrylic latex polymer Proprietary
California Proposition 65:
WARNING: This product contains chemicals known to the State of California to cause cancer, birth defects or other
reproductive harm.
Section 16 - Other Information
HMIS Ratings:
Health: 1 Flammability: 1 Reactivity: 0 Personal Protection: X
Volatile Organic Compounds (VOC), less water less exempts: g/L: 77.1 lb/gal: 0.6 wt:wt%: 3.1
Volatile Organic Compounds (VOC), less water less exempts, less LVP-VOCs: wt:wt%: 1.2
REASON FOR REVISION: Periodic Update
00010052001 English Page 6 of 6
Legend: N.A. 鈥? Not Applicable ACGIH 鈥? American Conference of Governmental Industrial Hygienists
N.E. 鈥? Not Established SARA 鈥? Superfund Amendments and Reauthorization Act of 1986
N.D. 鈥? Not Determined NJRTK 鈥? New Jersey Right-to-Know Law
VOC 鈥? Volatile Organic Compound OSHA 鈥? Occupational Safety and Health Administration
PEL 鈥? Permissible Exposure Limit HMIS 鈥? Hazardous Materials Identification System
TLV 鈥? Threshold Limit Value NTP 鈥? National Toxicology Program
CEIL 鈥? Ceiling Exposure Limit STEL 鈥? Short Term Exposure Limit
LD50 鈥? Lethal Dose 50 LC50 鈥? Lethal Concentration 50
F 鈥? Degree Fahrenheit MSDS 鈥? Material Safety Data Sheet
C 鈥? Degree Celsius CASRN 鈥? The Chemical Abstracts Service Registry Number
DAP believes the data and statements contained herein are accurate as of the date hereof. They are offered in good faith as typical
values and not as a product specification. NO WARRANTY OF MERCHANTABILITY, WARRANTY OF FITNESS FOR ANY
PARTICULAR PURPOSE OR ANY OTHER WARRANTY, EXPRESS OR IMPLIED, IS MADE WITH REGARD TO THE
INFORMATION HEREIN PROVIDED OR THE PRODUCT TO WHICH THE INFORMATION REFERS. Since this
document is intended only as a guide to the appropriate use and precautionary handling of the referenced product by a properly trained
person, it is therefore the responsibility of the user to (i) review the recommendations with due consideration for the specific context
of the intended use and (ii) determine if they are appropriate.
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