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| MATERIAL SAFETY DATA SHEET |
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| SECTION 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION |
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THIS MATERIAL SAFETY DATA SHEET IS AVAILABLE IN SPANISH UPON REQUEST.
LOS DATOS DE SEGURIDAD DEL PRODUCTO PUEDEN OBTENERSE EN ESPANOL SI LO
REQUIERE.
PRODUCT NAME : SIDEWINDER CLEAR ADHESIVE SEALANT
UPC # : 7079800816
PRODUCT USE/CLASS : CAULK SEALANT
MANUFACTURER: 24 HOUR EMERGENCY:
DAP INC. TRANSPORTATION: 1-800-535-5053 (352-323-3500)
2400 BOSTON STREET MEDICAL : 1-800-327-3874 (513-636-5118)
BALTIMORE, MD 21224
PREPARE DATE: 06/18/2003 GENERAL INFORMATION
REVISION NO. : 1 DAP INC. : 1-888-DAP-TIPS (1-888-327-8477)
REVISION DATE: 06/18/2003
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| SECTION 2 - COMPOSITION/INFORMATION ON INGREDIENTS |
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WT/WT %
ITEM ------------ CHEMICAL NAME ---------- CAS NUMBER EQUAL TO
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01 Ethyl benzene 100-41-4 20 - 30 %
02 Xylene 1330-20-7 5 - 10 %
---------------------- EXPOSURE LIMITS --------------------
ACGIH OSHA COMPANY
ITEM TLV-TWA TLV-STEL PEL-TWA PEL-CEILING TLV-TWA SKIN
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01 100 ppm 125 ppm 100 ppm N.E. N.E. NO
02 100 ppm 150 ppm N.E. 100 ppm N.E. NO
(See Section 16 for abbreviation legend)
Remaining ingredients are not considered hazardous per the OSHA Hazard
Communication Standard.
Listed Permissible Exposure Levels (PEL) are from the U.S. Dept. of Labor
OSHA Final Rule Limits (CFR 29 1910.1000); limits may vary between states.
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| SECTION 3 - HAZARDS IDENTIFICATION |
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EMERGENCY OVERVIEW: DANGER! Flammable liquid and vapor. Vapor
harmful. Harmful or fatal if swallowed. Vapors may cause flash fire or
explosion. Aspiration hazard if swallowed - can enter lungs and cause
damage. Harmful if inhaled. May irritate eyes, skin nose and upper
respiratory tract.
(Continued on Page 2)
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Product Name: SIDEWINDER CLEAR ADHESIVE SEALANT
Revision Date: 06/18/2003 Page 2
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| SECTION 3 - HAZARDS IDENTIFICATION |
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POTENTIAL HEALTH EFFECTS:
EFFECTS OF OVEREXPOSURE - EYE CONTACT: May cause eye irritation.
EFFECTS OF OVEREXPOSURE - SKIN CONTACT: May irritate skin. Prolonged
or repeated contact can result in defatting and drying of the skin which
may result in skin irritation and dermatitis (rash). Can be absorbed
through the skin.
EFFECTS OF OVEREXPOSURE - INHALATION: Vapor harmful if inhaled. Vapor
may irritate nose and upper respiratory tract. Vapor inhalation may affect
the brain or nervous system causing dizziness, headache or nausea.
Prolonged vapor inhalation may result in severe physical injury.
EFFECTS OF OVEREXPOSURE - INGESTION: This material may be harmful or
fatal if swallowed. Aspiration of material into the lungs due to vomiting
can cause chemical pneumonitis which can be fatal. If ingested, this
product may cause vomiting, diarrhea, and depressed respiration.
EFFECTS OF OVEREXPOSURE - CHRONIC HAZARDS: Reports have associated
permanent brain and nervous system damage with prolonged and repeated
occupational overexposure to solvents. May cause kidney and liver damage as
well as developmental and reproductive toxicity.
MEDICAL CONDITIONS WHICH MAY BE AGGRAVATED BY CONTACT: None known.
PRIMARY ROUTE(S) OF ENTRY: SKIN CONTACT INHALATION
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| SECTION 4 - FIRST AID MEASURES |
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EYE CONTACT: Immediately flush with large quantities of water until
irritation subsides. Get medical attention immediately.
SKIN CONTACT: Wash with soap and water.
INHALATION: Remove to fresh air. If not breathing, give artificial
respiration. If breathing is difficult, give oxygen.
Note: Only trained personnel should give artificial respiration or
administer oxygen.
INGESTION: DO NOT INDUCE VOMITING. Get medical attention immediately.
COMMENTS: Call 1-800-327-3874 if irritation or complications arise from
any of the above exposures.
(Continued on Page 3)
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Product Name: SIDEWINDER CLEAR ADHESIVE SEALANT
Revision Date: 06/18/2003 Page 3
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| SECTION 4 - FIRST AID MEASURES |
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| SECTION 5 - FIRE FIGHTING MEASURES |
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FLASH POINT: 80 F LOWER EXPLOSIVE LIMIT: N.A.
UPPER EXPLOSIVE LIMIT: N.A.
AUTOIGNITION TEMPERATURE:
EXTINGUISHING MEDIA: Foam, CO2, dry chemical.
UNUSUAL FIRE AND EXPLOSION HAZARDS: Flammable! Material will readily
ignite at room temperature. Vapors may form an explosive mixture with air.
Vapors can travel long distances to a source of ignition and flashback.
Eliminate sources of ignition: heat, electrical equipment, sparks, pilot
lights, stoves and flames. Do not smoke Do not put in contact with
oxidizing or caustic materials.
SPECIAL FIREFIGHTING PROCEDURES: Full protective equipment, including
self-contained breathing apparatus, is recommended to protect from
combustion products. Cool exposed containers with water.
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| SECTION 6 - ACCIDENTAL RELEASE MEASURES |
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SPILL OR LEAK PROCEDURES: Dike spill area. Immediately eliminate sources
of ignition. Use absorbent material or scrape up dried material and place
into containers.
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| SECTION 7 - HANDLING AND STORAGE |
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HANDLING INFORMATION: KEEP OUT OF REACH OF CHILDREN. Avoid skin and eye
contact. Avoid breathing vapors. Use only in a well ventilated area. Ensure
fresh air entry.
STORAGE INFORMATION: Store away from caustics and oxidizers. Keep away
from heat, spark, and flame. Keep containers tightly closed when not in
use. Keep containers from excessive heat and freezing. Do not store at
temperatures above 120 degrees F.
OTHER PRECAUTIONS: Intentional misuse by deliberately concentrating and
inhaling vapors may be harmful or fatal. Do not take internally.
Construction and repair activities can adversely affect indoor air
quality. Consult with the occupants or a representative(i.e. maintenance,
building manager, industrial hygienist, or safety officer) to determine
ways to minimize any impact.
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| SECTION 8 - EXPOSURE CONTROLS/PERSONAL PROTECTION |
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(Continued on Page 4)
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Product Name: SIDEWINDER CLEAR ADHESIVE SEALANT
Revision Date: 06/18/2003 Page 4
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| SECTION 8 - EXPOSURE CONTROLS/PERSONAL PROTECTION |
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ENGINEERING CONTROLS: Provide sufficient mechanical ventilation (local or
general exhaust) to maintain exposure below PEL and TLV. Vapors are
heavier than air and will collect in low areas. Check all low areas
(basements, sumps, etc.) for vapors before entering.
RESPIRATORY PROTECTION: If you experience eye watering, headache or
dizziness or if used in the work place and air monitoring demonstrates
vapor levels are above exposure limits, use NIOSH approved respiratory
protection in accordance with applicable federal, state and local
requirements. Consult your safety equipment supplier and the OSHA
regulation, 29 CFR 1910.134 for respirator requirements. A respiratory
protection program that meets OSHA 1910.134 and ANSI Z88.2 requirements
must be followed whenever workplace conditions warrant a respirator's use.
EYE PROTECTION: Goggles or safety glasses with side shields.
SKIN PROTECTION: Solvent impervious gloves.
OTHER PROTECTIVE EQUIPMENT: Provide eyewash and solvent impervious apron
if body contact may occur.
HYGIENIC PRACTICES: Remove contaminated clothing and wash before reuse.
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| SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES |
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BOILING RANGE : N.A. VAPOR DENSITY : Heavier than air
ODOR : Solvent ODOR THRESHOLD : N. E.
APPEARANCE : Paste EVAPORATION RATE: Faster than butyl
SOLUBILITY IN H2O : Insoluble acetate
SPECIFIC GRAVITY: 0.93 pH: N. E.
FREEZE POINT : N.E. VISCOSITY : 250,00 没 300,000
VAPOR PRESSURE : N.A. cPs
PHYSICAL STATE : Paste
COEFFICIENT OF WATER/OIL DISTRIBUTION: N.E.
(See Section 16 for abbreviation legend)
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| SECTION 10 - STABILITY AND REACTIVITY |
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CONDITIONS TO AVOID: Excessive heat and freezing.
INCOMPATIBILITY: Strong oxidizers and caustics.
HAZARDOUS DECOMPOSITION PRODUCTS: Normal decomposition products, i.e. COx,
NOx
HAZARDOUS POLYMERIZATION: Will not occur under normal conditions.
STABILITY: This product is stable under normal storage conditions.
(Continued on Page 5)
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Product Name: SIDEWINDER CLEAR ADHESIVE SEALANT
Revision Date: 06/18/2003 Page 5
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| SECTION 11 - TOXICOLOGICAL PROPERTIES |
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No product toxicological information is available.
This product contains ethylbenzene. The International Agency for Research
of Cancer (IARC) has classified ethylbenzene as a Group 2B carcinogen -
possibly carcinogenic to humans. While there is inadequate evidence of
carcinogenicity in humans, this compound shows sufficient evidence of
carcinogenicity in animals (IARC, 2001). The US Environmental Protection
Agency (EPA) has classified ethylbenzene as a Class D carcinogen (not
classifiable as to human carcinogenicity). This is based on the lack of
animal bioassays and human studies. The American Conference of
Governmental Industrial Hygienists has classified ethylbenzene as a
Confirmed Animal Carcinogen with Unknown Relevance to Humans. There should
be minimal risk when used with ventilation adequate to keep the atmospheric
concentration of ethylbenzene below the recommended exposure limit.
Maintain adequate ventilation to prevent exposure above current OSHA /
ACGIH exposure limits. Workplace monitoring of the air to define
ethylbenzne exposure levels may be necessary.
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| SECTION 12 - ECOLOGICAL INFORMATION |
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No product information is available.
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| SECTION 13 - DISPOSAL CONSIDERATIONS |
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WASTE MANAGEMENT/DISPOSAL: Dispose of according to Federal, State, and
Local Standards. Discarded material should be incinerated at a permitted
facility. Liquids cannot be disposed of in a landfill. Do not reuse empty
container. State and Local regulations/restrictions are complex and may
differ from Federal regulations. Responsibility for proper waste disposal
is with the owner of the waste.
EPA WASTE CODE - If discarded (40 CFR 261): D001 Ignitable.
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| SECTION 14 - TRANSPORTATION INFORMATION |
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DOT PROPER SHIPPING NAME: Solids containing flammable liquids, N.O.S.
(Xylene) (Consummer Commodity*)
DOT HAZARD CLASS: 4.1 (Flammable Solid) (ORM-D*)
DOT UN/NA NUMBER: 3175 (NONE*) PACKING GROUP: II (None*)
* For containers of 1 gallon or less.
Note: The shipping information provided is applicable for domestic ground
transport only. Different categorization may apply is shipped via other
modes of transportation and/or to non-domestic destinations.
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| SECTION 15 - REGULATORY INFORMATION |
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U.S. FEDERAL REGULATIONS: AS FOLLOWS -
OSHA: Hazardous by definition of Hazard Communication Standard (29 CFR
1910.1200)
(Continued on Page 6)
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Product Name: SIDEWINDER CLEAR ADHESIVE SEALANT
Revision Date: 06/18/2003 Page 6
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| SECTION 15 - REGULATORY INFORMATION |
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CERCLA - SARA HAZARD CATEGORY:
This product has been reviewed according to the EPA 'Hazard Categories'
promulgated under Sections 311 and 312 of the Superfund Amendment and
Reauthorization Act of 1986 (SARA Title III) and is considered, under
applicable definitions, to meet the following categories:
IMMEDIATE HEALTH HAZARD CHRONIC HEALTH HAZARD FIRE HAZARD
SARA SECTION 313:
This product contains the following substances subject to the reporting
requirements of Section 313 of Title III of the Superfund Amendments and
Reauthorization Act of 1986 and 40 CFR Part 372:
----------- CHEMICAL NAME ----------- CAS NUMBER
Xylene 1330-20-7
Ethyl Benzene 100-41-4
TOXIC SUBSTANCES CONTROL ACT:
This product contains the following chemical substances subject to the
reporting requirements of TSCA 12(b) if exported from the United States:
----------- CHEMICAL NAME ----------- CAS NUMBER
Xylene 1330-20-7
U.S. STATE REGULATIONS: AS FOLLOWS -
NEW JERSEY RIGHT-TO-KNOW:
The following materials are non-hazardous, but are among the top five
components in this product:
----------- CHEMICAL NAME ----------- CAS NUMBER
Contents partially unknown
----------- CHEMICAL NAME ----------- CAS NUMBER
PENNSYLVANIA RIGHT-TO-KNOW:
The following non-hazardous ingredients are present in the product at
greater than 3%:
----------- CHEMICAL NAME ----------- CAS NUMBER
Contents partially unknown
CALIFORNIA PROPOSITION 65:
WARNING: The chemical(s) noted below and contained in this product, are
known to the state of California to cause cancer, birth defects or other
reproductive harm:
----------- CHEMICAL NAME ----------- CAS NUMBER
Formaldehyde 50-00-0
Toluene 108-88-3
Benzene 71-43-2
(Continued on Page 7)
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Product Name: SIDEWINDER CLEAR ADHESIVE SEALANT
Revision Date: 06/18/2003 Page 7
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| SECTION 15 - REGULATORY INFORMATION |
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INTERNATIONAL REGULATIONS: AS FOLLOWS -
CANADIAN WHMIS: This MSDS has been prepared in compliance with
Controlled Product Regulations except for use of the 16 headings.
CANADIAN WHMIS CLASS: No information available.
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| SECTION 16 - OTHER INFORMATION |
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HMIS RATINGS - HEALTH: 1 FLAMMABILITY: 2 REACTIVITY: 1
PREVIOUS MSDS REVISION DATE: 09/12/2001
VOC less water, less exempt 300 g/l (32 没 33%)
LEGEND: ACGIH - AMERICAN CONFERENCE OF GOVERNMENTAL INDUSTRIAL HYGIENISTS
N.A. - NOT APPLICABLE
N.E. - NOT ESTABLISHED
PEL - PERMISSIBLE EXPOSURE LIMIT
NTP - NATIONAL TOXICOLOGY PROGRAM
SARA - SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT OF 1986
STEL - SHORT TERM EXPOSURE LIMIT
TLV - THRESHOLD LIMIT VALUE(8 HR. TIME WEIGHTED AVERAGE OR TWA)
VOC - VOLATILE ORGANIC COMPOUND
NJRTK - NEW JERSEY RIGHT TO KNOW LAW
N.D. - NOT DETERMINED
MSDS# 10036
This data is offered in good faith as typical values and not as a product
specification. No warranty either expressed or implied, is hereby made.
The recommended industrial hygiene and safe handling procedures are
believed to be generally applicable. However, each user should review the
recommendations in specific context of the intended use and determine if
they are appropriate.
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< End OF MSDS >
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