00010303001 English Page 1 of 6
24 Hour Emergency Phone Numbers:
Material
Medical/Poison Control:
1-800-327-3874
1-513-558-5111
Safety Transportation/National Response
Center:
1-800-535-5053
Data 1-352-323-3500
Sheet NOTE: The National Response Center emergency numbers to
be used only in the event of chemical emergencies involving a
spill, leak, fire, exposure or accident involving chemicals.
IMPORTANT: Provide this information to employees, customers, and users of this product. Read this MSDS before handling or disposing of
this product. This product is covered by the OSHA Hazard Communication Standard and this document has been prepared in accordance with
requirements of this standard. All abbreviated terms used in this MSDS are further described in Section 16.
Section 1 - Chemical Product / Company Information
This Material Safety Data Sheet is available in Canadian French and Hispanic American Spanish upon request.
On peut demader cette fiche signal茅tique (MSDS) a la alngue francaise-canadienne.
Los Datos de Serguridad del Producto pueden obtenerse en Espanol si lo riquiere.
Product Name: Revision Date: 08/30/2007
DAP 庐 4000庐 Subfloor & Deck Construction
Adhesive
Product UPC Number: 070798250208, 070798251175 Supercedes: 05/31/2000
Product Use/Class: Subfloor & Deck Construction Adhesive MSDS Number: 00010303001
Manufacturer: DAP Inc.
2400 Boston Street Suite 200
Baltimore, MD 21224-4723
888 -327-8477 (non-emergency matters)
Section 2 - Hazards Identification
Emergency Overview: A tan paste product with a strong solvent odor. DANGER! Extremely flammable liquid and vapor.
Vapors may cause flash fire or explosion. Vapors may ignite explosively. Keep away from heat, sparks and flame. Do not
breathe vapors. Do not breathe dust, vapors or spray mist. Use only with adequate ventilation. Prevent build-up of vapors
by opening all windows and doors to achieve cross-ventilation. Aspiration hazard if swallowed. Aspiration may cause
pulmonary edema and pneumonitis.
Refer to other MSDS sections for other detailed information.
Effects Of Overexposure - Eye Contact: Causes eye irritation.
Effects Of Overexposure - Skin Contact: Causes skin irritation. Prolonged and repeated skin contact may cause
dermatitis, drying and defatting due to the solvent properties.
Effects Of Overexposure - Inhalation: Vapor harmful. May affect the brain or nervous system causing dizziness,
headache or nausea. Inhalation causes irritation to the respiratory tract (nose, mouth, throat, mucous membranes).
Aspiration into lungs may cause pulmonary edema and chemical pneumonitis. Can cause nerve damage to arms and
legs. Effects may be permanent.
Effects Of Overexposure - Ingestion: Harmful or fatal if swallowed. If ingested, may cause vomiting, diarrhea, and
depressed respiration.
Effects Of Overexposure - Chronic Hazards: NOTICE: Reports have associated repeated and prolonged occupational
00010303001 English Page 2 of 6
overexposure to solvents with permanent brain and nervous system damage. Symptoms include: loss of memory, loss of
intellectual ability and loss of coordination. Intentional misuse by deliberately concentrating and inhaling the contents may
be harmful or fatal. Overexposure or misuse of toluene can cause liver, kidney, and brain damage as well as cardiac
abnormalities. There have been cases of aplastic anemia from toluene in industrial exposures (ACGIH, 1992). Increased
coagulation time and reduced clotting factors have also been found, which are indicators of damage to the bone marrow
(Clayton & Clayton, 1994).
n-Hexane exposure can cause nerve damage to arms and legs causing numbness of the fingers and toes, effect may be
permanent. Symptoms include: loss of memory, loss of intellectual ability and loss of coordination.
Primary Route(s) Of Entry: Skin Contact, Inhalation, Ingestion, Eye Contact
Medical Conditions which May be Aggravated by Exposure: None known.
Carcinogenicity:
CAS No. Chemical Name ACGIH OSHA IARC NTP
13463-67-7 Titanium dioxide Not Listed. Not Listed. Possible carcinogen. Not Listed.
Section 3 - Composition / Information On Ingredients
Chemical Name CASRN Wt%
Calcium Carbonate 471-34-1 10 -30
Kaolin 1332-58-7 10 -30
n-Hexane 110-54-3 7-13
Toluene 108-88-3 5-10
2-Methylpentane 107-83-5 5-10
3-Methylpentane 96-14 -0 3-7
Magnesite 546-93-0 1-5
Methylcyclopentane 96-37 -7 1-5
Isoheptane 591-76-4 0.5-1.5
Titanium dioxide 13463-67 -7 0.1-1.0
Section 4 - First Aid Measures
First Aid - Eye Contact: In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Get
medical attention immediately.
First Aid - Skin Contact: Wash off immediately with soap and plenty of water.
First Aid - Inhalation: If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical attention immediately.
First Aid - Ingestion: If swallowed, DO NOT INDUCE VOMITING. Get medical attention immediately.
Note to Physician: None.
COMMENTS: Call Medical Emergency at 1-800-327-3874 if any irritation or complication arises from any of the above
routes of entry.
Section 5 - Fire Fighting Measures
Extinguishing Media: Carbon Dioxide, Dry Chemical, Foam
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Unusual Fire And Explosion Hazards: Material will readily ignite at room temperature. Extremely Flammable! Do not
smoke. Extinguish all flames and pilot lights, and turn off stoves, heaters, electric motors and other sources of ignition
during use and until all vapors are gone. Closed containers may burst if exposed to extreme heat or fire. Vapors may form
explosive mixtures with air. Vapors can flow along surfaces to a distant ignition source and flash back.
Special Firefighting Procedures: Wear self-contained breathing apparatus pressure-demand (NIOSH approved or
equivalent) and full protective gear. Use water spray to cool exposed surfaces.
Section 6 - Accidental Release Measures
Steps To Be Taken If Material Is Released Or Spilled: Wear proper protective equipment as specified in Section 8.
Immediately eliminate sources of ignition. Dike to prevent entering any sewer or waterway. Absorb with suitable chemical
absorbent.
Section 7 - Handling And Storage
Handling: KEEP OUT OF REACH OF CHILDREN! Vapors are heavier than air and will collect in low areas. Check all low
areas (basements, sumps, etc.) for vapor before entering. Avoid breathing vapors. Intentional misuse by deliberately
concentrating and inhaling vapors may be harmful or fatal. Use in well ventilated area. Do not get in eyes, on skin or
clothing. Wash thoroughly after handling. Turn off stoves, heaters, electric motors or other sources of ignition during use
and until all vapors are gone. Vapors may travel long distances to a source of ignition and flash back.
Construction and repair activities can adversely affect indoor air quality. Consult with occupants or a representative (i.e.
maintenance, building manager, industrial hygienist, or safety officer) to determine ways to minimize impact.
Storage: Keep away from heat and sources of ignition. Do not store at temperatures above 120 degrees F. Store
containers away from excessive heat and freezing. Close container after each use. Keep tightly closed in a dry and cool
place. Store away from caustics and oxidizers.
Section 8 - Exposure Controls / Personal Protection
Chemical Name CASRN ACGIH TWA ACGIH STEL ACGIH CEIL OSHA TWA OSHA STEL OSHA CEIL Skin
5 MGM3
Calcium Carbonate 471-34-1 10 MGM3 N.E. N.E. (respirable N.E. N.E. No
fraction)
Kaolin 1332-58-7 2 MGM3 N.E. N.E. 15 MGM3 N.E. N.E. No
n-Hexane 110-54-3 50 PPM N.E. N.E. 500 PPM N.E. N.E. Yes
Toluene 108-88-3 50 PPM N.E. N.E. 200 PPM N.E. 300 PPM Yes
2-Methylpentane 107-83-5 500 PPM 1000 PPM N.E. N.E. N.E. N.E. No
3-Methylpentane 96-14-0 500 PPM 1000 PPM N.E. N.E. N.E. N.E. No
Magnesite 546-93-0 10 MGM3 N.E. N.E. 5 MGM3 N.E. N.E. No
Methylcyclopentane 96-37-7 N.E. N.E. N.E. N.E. N.E. N.E. No
Isoheptane 591-76-4 400 PPM 500 PPM N.E. 500 PPM N.E. N.E. No
Titanium dioxide 13463-67-7 10 MGM3 N.E. N.E. 15 MGM3 N.E. N.E. No
Exposure Notes: None.
Precautionary Measures: Please refer to other sections and subsections of this MSDS.
Engineering Controls: Local ventilation of emission sources may be necessary to maintain ambient concentrations
below recommended exposure limits. Ensure fresh air entry during application and drying. If you experience eye watering,
headache or dizziness or if air monitoring demonstrates vapor/mist levels are above applicable limits, wear an
appropriate, properly fitted respirator (NIOSH approved) during and after application. Follow respirator manufacturer's
directions for respirator use.
Respiratory Protection: If concentrations exceed the exposure limits specified, use of a NIOSH-approved supplied air
respirator is recommended. Where the protection factor is exceeded, use of a Self Contained Breathing Apparatus
(SCBA) may be necessary.
Skin Protection: Solvent-resistant gloves.
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Eye Protection: Goggles or safety glasses with side shields.
Other protective equipment: Safety shower and eyewash station should be located in immediate work area. Provide
eyewash and solvent impervious apron if body contact may occur.
Hygienic Practices: Remove and wash contaminated clothing before re-use.
Important: Listed Permissible Exposure Levels (PEL) are from the U.S. Dept. of Labor OSHA Final Rule Limits (CFR 29 1910.1000); these limits may vary
between states.
Note: An employee's skin exposure to substances having a "YES" in the "SKIN" column in the table above shall be prevented or reduced to the extent
necessary under the circumstances through the use of gloves, coveralls, goggles or other appropriate personal protective equipment, engineering controls or work
practices.
Section 9 - Physical And Chemical Properties
Boiling Range: 130 F 鈥? 180 F Vapor Density: Heavier Than Air
Odor: Strong Solvent Odor Threshold: Not Established
Color: Tan Evaporation Rate: Faster Than n-Butyl Acetate
Solubility in H2O: Negligible Specific Gravity: 1.1
Freeze Point: Not Established pH: Between 7.0 and 12.9
Vapor Pressure: 100 mm Hg @ 68 F Viscosity: 170,000 - 250,000 cPs
Physical State: Paste Flammability: Flammable
(Seta Closed Cup)
Flash Point, F: 75 Degrees F Method:
Lower Explosive Limit, %: Not Established Upper Explosive Limit, %:Not Established
When reported, vapor pressure of this product has been calculated theoretically based on its constituent makeup and has not been determined experimentally.
(See section 16 for abbreviation legend)
Section 10 - Stability And Reactivity
Conditions To Avoid: Excessive heat and freezing.
Incompatibility: Strong oxidizers, alkali metals and alkaline earth metals may cause fires or explosions.
Hazardous Decomposition Products: Normal decomposition products, i.e., COx, NOx.
Hazardous Polymerization: Hazardous polymerization will not occur under normal conditions.
Stability: Stable under recommended storage conditions.
Section 11 - Toxicological Information
Product LD50: Not Established Product LC50: Not Established
CASRN Chemical Name LD50 LC50
471-34-1 Calcium Carbonate Rat:6450 mg/kg -------------
110-54-3 n-Hexane Rat:28710 mg/kg Rat:48000 ppm/4H
108-88-3 Toluene ------------- Rat:49 gm/m3/4H
Significant Data with Possible Relevance to Humans: None.
Section 12 - Ecological Information
Ecological Information: Ecological injuries are not known or expected under normal use.
00010303001 English Page 5 of 6
Section 13 - Disposal Information
Disposal Information: Do not re-use empty containers. Liquids cannot be disposed of in a landfill. Dispose of material in
accordance with all federal, state and local regulations. After recovery of solvent dispose of by special waste incineration
in compliance with the Environment Protection Act 1990 (Process Guidance Note IPR5/1). State and Local
regulations/restrictions are complex and may differ from Federal regulations. Responsibility for proper waste disposal is
with the owner of the waste.
EPA Waste Code if Discarded (40 CFR Section 261): D001
Section 14 - Transportation Information
DOT Proper Shipping Consumer Commodity Packing Group: None (III if not domestic by
Name: ground)
DOT Technical Name: N.A. Hazard Subclass: N.A.
DOT Hazard Class: None (3 for non-domestic / or air) DOT UN/NA Number: None (UN1133 when not
domestic ground)
Note: The shipping information provided is applicable for domestic ground transport only. Different categorization may
apply if shipped via other modes of transportation and/or to non-domestic destinations.
Section 15 - Regulatory Information
CERCLA - SARA Hazard Category:
This product has been reviewed according to the EPA 'Hazard Categories' promulgated under Sections 311 and 312 of
the Superfund Amendment and Reauthorization Act of 1986 (SARA Title III) and is considered, under applicable
definitions, to meet the following categories:
Immediate Health Hazard, Chronic Health Hazard, Fire
SARA Section 313:
This product contains the following substances subject to the reporting requirements of Section 313 of Title III of the
Superfund Amendment and Reauthorization Act of 1986 and 40 CFR part 372:
Chemical Name CAS Number
n-Hexane 110-54-3
Toluene 108-88-3
Toxic Substances Control Act:
All ingredients in this product are either on TSCA inventory list, or otherwise exempt.
This product contains the following chemical substances subject to the reporting requirements of TSCA 12(B) if exported
from the United States:
Chemical Name CAS Number
Isoheptane 591-76-4
New Jersey Right-to-Know:
The following materials are non-hazardous, but are among the top five components in this product:
Chemical Name CAS Number
00010303001 English Page 6 of 6
Butadiene-styrene copolymer TSRN 618608-5037P
Hydrocarbons, C9 unsaturated, polymerize TSRN 618608-5036P
Pennsylvania Right-to-Know:
The following non-hazardous ingredients are present in the product at greater than 3%:
Chemical Name CAS Number
Butadiene-styrene copolymer Proprietary
Hydrocarbons, C9 unsaturated, polymerize Proprietary
California Proposition 65:
WARNING: This product contains chemicals known to the State of California to cause cancer, birth defects or other
reproductive harm.
Section 16 - Other Information
HMIS Ratings:
Health: 2 Flammability: 3 Reactivity: 0 Personal Protection: X
Volatile Organic Compounds (VOC), less water less exempts: g/L: 427.4 lb/gal: 3.6 wt:wt%: 38.7
Volatile Organic Compounds (VOC), less water less exempts, less LVP -VOCs: wt:wt%: 38.7
REASON FOR REVISION: Periodic Update
Legend: N.A. 鈥? Not Applicable ACGIH 鈥? American Conference of Governmental Industrial Hygienists
N.E. 鈥? Not Established SARA 鈥? Superfund Amendments and Reauthorization Act of 1986
N.D. 鈥? Not Determined NJRTK 鈥? New Jersey Right-to-Know Law
VOC 鈥? Volatile Organic Compound OSHA 鈥? Occupational Safety and Health Administration
PEL 鈥? Permissible Exposure Limit HMIS 鈥? Hazardous Materials Identification System
TLV 鈥? Threshold Limit Value NTP 鈥? National Toxicology Program
CEIL 鈥? Ceiling Exposure Limit STEL 鈥? Short Term Exposure Limit
LD50 鈥? Lethal Dose 50 LC50 鈥? Lethal Concentration 50
F 鈥? Degree Fahrenheit MSDS 鈥? Material Safety Data Sheet
C 鈥? Degree Celsius CASRN 鈥? The Chemical Abstracts Service Registry Number
DAP believes the data and statements contained herein are accurate as of the date hereof. They are offered in good faith as typical
values and not as a product specification. NO WARRANTY OF MERCHANTABILITY, WARRANTY OF FITNESS FOR ANY
PARTICULAR PURPOSE OR ANY OTHER WARRANTY, EXPRESS OR IMPLIED, IS MADE WITH REGARD TO THE
INFORMATION HEREIN PROVIDED OR THE PRODUCT TO WHICH THE INFORMATION REFERS. Since this
document is intended only as a guide to the appropriate use and precautionary handling of the referenced product by a properly trained
person, it is therefore the responsibility of the user to (i) review the recommendations with due consideration for the specific context
of the intended use and (ii) determine if they are appropriate.
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