00010054001 English Page 1 of 6
24 Hour Emergency Phone Numbers:
Material
Medical/Poison Control:
1-800-327-3874
1-513-558-5111
Safety Transportation/National Response
Center:
1-800-535-5053
Data 1-352-323-3500
Sheet NOTE: The National Response Center emergency numbers to
be used only in the event of chemical emergencies involving a
spill, leak, fire, exposure or accident involving chemicals.
IMPORTANT: Provide this information to employees, customers, and users of this product. Read this MSDS before handling or disposing of
this product. This product is covered by the OSHA Hazard Communication Standard and this document has been prepared in accordance with
requirements of this standard. All abbreviated terms used in this MSDS are further described in Section 16.
Section 1 - Chemical Product / Company Information
This Material Safety Data Sheet is available in Canadian French and Hispanic American Spanish upon request.
On peut demader cette fiche signal茅tique (MSDS) a la langue francaise-canadienne.
Los Datos de Serguridad del Producto pueden obtenerse en Espanol si lo riquiere.
Product Name: Blacktop & Roof 3.0 Sealant w/Kwik Dry Revision Date: 01/07/2008
Technology-Black
Product UPC Number: 070798183681 Supersedes: New
Product Use/Class: MS Polymer Caulk MSDS Number: 00010054001
Manufacturer: DAP Inc.
2400 Boston Street Suite 200
Baltimore, MD 21224-4723
888-327-8477 (non-emergency matters)
Section 2 - Hazards Identification
Emergency Overview: A black paste product with a slight solvent odor. WARNING! May cause eye, skin, nose, throat
and respiratory tract irritation. Harmful if swallowed or absorbed through the skin. HEATING MAY RELEASE HYDROGEN
SULFIDE GAS (H2S).
Refer to other MSDS sections for other detailed information.
Effects Of Overexposure - Eye Contact: Causes eye irritation. Signs and symptoms may include: pain, tears, swelling,
redness and blurred vision.
Effects Of Overexposure - Skin Contact: Causes Moderate skin irritation. Signs and symptoms may include: pain,
discoloration and swelling. Harmful if absorbed through the skin. Prolonged or repeated contact with skin may cause
irritation. Prolonged or repeated skin contact can result in sensitization and dermatitis. DO NOT try to peel the solidified
material from the skin or use solvents or thinners to dissolve it. The use of vegetable oil or mineral oil is recommended for
removal of this material from the skin. Flush exposed area with water while removing contaminated clothing. Get medical
attention if irritation persists.
Effects Of Overexposure - Inhalation: Vapor harmful. During application and cure, this product releases methanol,
which may affect the brain or nervous system causing dizziness, headache or nausea. This substance contains sulfur
compounds that may form hydrogen sulfide. The rotten eggs odor of hydrogen sulfide is unreliable as an indicator of
concentration. Signs and symptoms of over exposure to hydrogen sulfide include respiratory tract irritation, headaches,
dizziness, nausea, gastrointestinal disturbances, coughing, a sensation of dryness and pain in the nose, throat and chest,
confusion and unconsciousness. Hydrogen sulfide concentrations of 1000-2000 ppm can be extremely hazardous. This
hazard evaluation is based on data from similar materials.
00010054001 English Page 2 of 6
Vapor harmful. Inhalation may cause irritation to the respiratory tract (nose, mouth, mucous membranes).
N-beta-(aminoethyl)-gamma-aminopropyltrimethoxysilane may cause asthma with possible long term lung damage. May
cause blurred vision. May cause drowsiness. Overexposure by inhalation may injure the liver.
Effects Of Overexposure - Ingestion: Harmful if swallowed.
Effects Of Overexposure - Chronic Hazards: Repeated or prolonged exposure may cause respiratory system damage.
Prolonged and repeated skin contact may cause irritation and possibly dermatitis. This product contains clay, which
contains crystalline silica. Crystalline silica has been listed as a carcinogen by IARC; however, the particles are coated
with asphalt and are not available for inhalation. As such, there is little or no chance of inhalation of crystalline silica and
resultant diseases. Overexposure may cause kidney, cardiovascular, skin and liver damage.
N-beta-(aminoethyl)-gamma-aminopropyltrimethoxysilane may cause allergic skin reaction, heart muscle damage,
anemia, and lung, liver and kidney damage. It may also cause cross-sensitization to other amines. Studies in which mice
were exposed to a variety of whole asphalts did not result in any increased cancer rate; mice exposed to asphalts diluted
with hydrocarbon solvents had increased incidence of certain types of cancer. Brief or intermittent skin contact with this
asphalt product is not expected to produce any delayed effects. While normal handling of this product is not likely to cause
cancer in humans, skin contact and breathing of mists or vapors should be reduced to a minimum.
Primary Route(s) Of Entry: Skin Contact, Inhalation, Eye Contact
Medical Conditions which May be Aggravated by Exposure: None known.
Carcinogenicity:
CAS No. Chemical Name ACGIH OSHA IARC NTP
Classification not possible
8052-42-4 Asphalt Not Listed. Not Listed. Not Listed.
from current data.
Section 3 - Composition / Information On Ingredients
Chemical Name CASRN Wt%
Asphalt 8052-42-4 15-40
N-beta-(aminoethyl)-gamma-aminopropyltrimethoxysilane 1760-24-3 3-7
Section 4 - First Aid Measures
First Aid - Eye Contact: In case of contact, immediately flush eyes with large quantities of water for at least 15 minutes
until irritation subsides. Get medical attention immediately.
First Aid - Skin Contact: Immediately remove from skin by wiping with waterless hand cleaner followed by soap and
water. Get medical aid if symptoms persist. Wash off immediately with soap and plenty of water for at least 15 minutes.
Get medical aid if symptoms persist. Remove and wash contaminated clothing.
First Aid - Inhalation: If inhaled, remove to fresh air. If breathing is difficult, leave the area to obtain fresh air. If
continued breathing difficulty is experienced, get medical attention immediately. If there are signs or symptoms of
hydrogen sulfide exposure (respiratory tract irritation, headache, dizziness, nausea, gastrointestinal disturbances,
coughing, a sensation of dryness and pain in the nose, throat and chest, confusion and unconsciousness), move the
person to fresh air. If breathing has stopped, apply artificial respiration. Call a doctor.
First Aid - Ingestion: If swallowed, DO NOT INDUCE VOMITING. Get medical attention immediately.
Note to Physician: None.
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COMMENTS: Call Medical Emergency at 1-800-327-3874 if any irritation or complication arises from any of the above
routes of entry.
Section 5 - Fire Fighting Measures
Extinguishing Media: Carbon Dioxide, Dry Chemical, Foam, Water Fog
Unusual Fire And Explosion Hazards: No special protective measures against fire required.
Special Firefighting Procedures: Wear self-contained breathing apparatus pressure-demand (NIOSH approved or
equivalent) and full protective gear. Use water spray to cool exposed surfaces.
Do not use a solid stream of water since the stream will scatter and spread the fire.
Section 6 - Accidental Release Measures
Steps To Be Taken If Material Is Released Or Spilled: Wear proper protective equipment as specified in Section 8. Use
absorbent material or scrape up dried material and place in container.
Section 7 - Handling And Storage
Handling: KEEP OUT OF REACH OF CHILDREN! DO NOT TAKE INTERNALLY. Avoid breathing vapor and contact
with eyes, skin and clothing. Use only with adequate ventilation. Open all windows and doors or use other means to
ensure cross-ventilation and fresh air entry during application and drying. Odor is not an adequate warning for hazardous
conditions. Wash thoroughly after handling. Remove contact lenses before using. Do not handle contact lenses until all
sealant has been cleaned from fingertips, nails and cuticles. Residual sealant may transfer to contact lenses and cause
severe eye irritation.
Storage: Do not store at temperatures above 120 degrees F. Store containers away from excessive heat and freezing.
Close container after each use. Store away from caustics and oxidizers.
Section 8 - Exposure Controls / Personal Protection
Chemical Name CASRN ACGIH TWA ACGIH STEL ACGIH CEIL OSHA TWA OSHA STEL OSHA CEIL Skin
Asphalt 8052-42-4 0.5 MGM3 N.E. N.E. N.E. N.E. N.E. No
N-beta-(aminoethyl)-gamma-
1760-24-3 N.E. N.E. N.E. N.E. N.E. N.E. No
aminopropyltrimethoxysilane
Precautionary Measures: Contact lenses pose a special hazard; soft lenses may absorb and all lenses concentrate
irritants.
Engineering Controls: Good general ventilation should be sufficient to control airborne levels. Ensure adequate
ventilation, especially in confined areas. Local ventilation of emission sources may be necessary to maintain ambient
concentrations below recommended exposure limits.
Respiratory Protection: In case of insufficient ventilation, wear suitable respiratory equipment. A NIOSH-approved air
purifying respirator with an organic vapor cartridge or canister may be necessary under certain circumstances where
airborne concentrations are expected to exceed exposure limits. A respiratory protection program that meets the OSHA
1910.134 and ANSI Z88.2 requirements must be followed whenever workplace conditions warrant a respirator's use.
Skin Protection: Rubber gloves.
Eye Protection: Goggles or safety glasses with side shields.
Other protective equipment: If repeated or prolonged contact with liquid is likely, wear protective clothing including
boots, apron, and face shield or splash goggles. Not required under normal use.
Hygienic Practices: Wash hands before breaks and at the end of workday. Remove and wash contaminated clothing
00010054001 English Page 4 of 6
before re-use.
Important: Listed Permissible Exposure Levels (PEL) are from the U.S. Dept. of Labor OSHA Final Rule Limits (CFR 29 1910.1000); these limits may vary
between states.
Note: An employee's skin exposure to substances having a "YES" in the "SKIN" column in the table above shall be prevented or reduced to the extent
necessary under the circumstances through the use of gloves, coveralls, goggles or other appropriate personal protective equipment, engineering controls or work
practices.
Section 9 - Physical And Chemical Properties
Boiling Range: Not Established Vapor Density: Heavier Than Air
Odor: Slight Solvent Odor Threshold: Not Established
Color: Black Evaporation Rate: Slower Than n-Butyl Acetate
Solubility in H2O: Not Established Specific Gravity: Greater Than 1
Freeze Point: Not Established pH: Between 7.0 and 12.9
Vapor Pressure: Not Established Viscosity: ~ 500,000 cP
Physical State: Paste Flammability: Non-Flammable
Flash Point, F: Greater Than 200 Method: (Seta Closed Cup)
Lower Explosive Limit, %: Not Established Upper Explosive Limit, %:Not Established
When reported, vapor pressure of this product has been calculated theoretically based on its constituent makeup and has not been determined experimentally.
(See section 16 for abbreviation legend)
Section 10 - Stability And Reactivity
Conditions To Avoid: Excessive heat and freezing.
Incompatibility: Incompatible with strong bases and oxidizing agents.
Hazardous Decomposition Products: Normal decomposition products, i.e., COx, NOx.
Hazardous Polymerization: Hazardous polymerization will not occur under normal conditions.
Stability: Stable under recommended storage conditions.
Section 11 - Toxicological Information
Product LD50: Not Established Product LC50: Not Established
None
Significant Data with Possible Relevance to Humans: None.
Section 12 - Ecological Information
Ecological Information: Ecological injuries are not known or expected under normal use.
Section 13 - Disposal Information
Disposal Information: Dispose of material in accordance with all federal, state and local regulations. State and Local
regulations/restrictions are complex and may differ from Federal regulations. Responsibility for proper waste disposal is
with the owner of the waste.
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EPA Waste Code if Discarded (40 CFR Section 261): None.
Section 14 - Transportation Information
DOT Proper Shipping Not Regulated. Packing Group: N.A.
Name:
DOT Technical Name: None Hazard Subclass: N.A.
DOT Hazard Class: N.A. DOT UN/NA Number: None
Note: The shipping information provided is applicable for domestic ground transport only. Different categorization may
apply if shipped via other modes of transportation and/or to non-domestic destinations.
Section 15 - Regulatory Information
CERCLA - SARA Hazard Category:
This product has been reviewed according to the EPA 'Hazard Categories' promulgated under Sections 311 and 312 of
the Superfund Amendment and Reauthorization Act of 1986 (SARA Title III) and is considered, under applicable
definitions, to meet the following categories:
Immediate Health Hazard
SARA Section 313:
This product contains the following substances subject to the reporting requirements of Section 313 of Title III of the
Superfund Amendment and Reauthorization Act of 1986 and 40 CFR part 372:
None
Toxic Substances Control Act:
All ingredients in this product are either on TSCA inventory list, or otherwise exempt.
This product contains the following chemical substances subject to the reporting requirements of TSCA 12(B) if exported
from the United States:
None
New Jersey Right-to-Know:
The following materials are non-hazardous, but are among the top five components in this product:
Chemical Name CAS Number
Proprietary polyether Proprietary
Pennsylvania Right-to-Know:
The following non-hazardous ingredients are present in the product at greater than 3%:
Chemical Name CAS Number
Proprietary polyether Proprietary
00010054001 English Page 6 of 6
California Proposition 65:
None.
Section 16 - Other Information
HMIS Ratings:
Health: 1 Flammability: 0 Reactivity: 0 Personal Protection: X
Volatile Organic Compounds (VOC), less water less exempts: g/L: 0.0 lb/gal: 0.0 wt:wt%: 0.0
Volatile Organic Compounds (VOC), less water less exempts, less LVP-VOCs: wt:wt%: 0.0
REASON FOR REVISION: Periodic Update
Legend: N.A. 鈥? Not Applicable ACGIH 鈥? American Conference of Governmental Industrial Hygienists
N.E. 鈥? Not Established SARA 鈥? Superfund Amendments and Reauthorization Act of 1986
N.D. 鈥? Not Determined NJRTK 鈥? New Jersey Right-to-Know Law
VOC 鈥? Volatile Organic Compound OSHA 鈥? Occupational Safety and Health Administration
PEL 鈥? Permissible Exposure Limit HMIS 鈥? Hazardous Materials Identification System
TLV 鈥? Threshold Limit Value NTP 鈥? National Toxicology Program
CEIL 鈥? Ceiling Exposure Limit STEL 鈥? Short Term Exposure Limit
LD50 鈥? Lethal Dose 50 LC50 鈥? Lethal Concentration 50
F 鈥? Degree Fahrenheit MSDS 鈥? Material Safety Data Sheet
C 鈥? Degree Celsius CASRN 鈥? The Chemical Abstracts Service Registry Number
DAP believes the data and statements contained herein are accurate as of the date hereof. They are offered in good faith as typical
values and not as a product specification. NO WARRANTY OF MERCHANTABILITY, WARRANTY OF FITNESS FOR ANY
PARTICULAR PURPOSE OR ANY OTHER WARRANTY, EXPRESS OR IMPLIED, IS MADE WITH REGARD TO THE
INFORMATION HEREIN PROVIDED OR THE PRODUCT TO WHICH THE INFORMATION REFERS. Since this
document is intended only as a guide to the appropriate use and precautionary handling of the referenced product by a properly trained
person, it is therefore the responsibility of the user to (i) review the recommendations with due consideration for the specific context
of the intended use and (ii) determine if they are appropriate.
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