Material Safety Data Sheet
nonyl Phenol
Version 2.1 Print Date 07/06/2007
Revision Date 06/03/2007
1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANY/UNDERTAKING
Product information
Trade name : nonyl Phenol
Product code : RA178
MSDS Number : 2074
Product Type : Curing agent.
Manufacturer, importer, : Hexion Specialty Chemicals, Inc.
supplier P. O. Box 4500
Houston TX 77210
Contact person : hsebox@hexion.com
Telephone : General Information:
(832) 486-6700
Emergency telephone:
CHEMTREC US Domestic (800) 424-9300
CHEMTREC International (703) 527-3887
SECTION 2. HAZARDS IDENTIFICATION
Emergency Overview
Human health hazards : Corrosive to the eyes. Corrosive to the skin. Vapors/mists may
be corrosive to upper respiratory tract. Harmful if swallowed.
May cause skin sensitization.
Safety hazards : Not classified as flammable but will burn.
SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS
Chemical Name CAS-No. Weight %
NONYLPHENOL 84852-15-3 > 90 %
SECTION 4. FIRST AID MEASURES
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Material Safety Data Sheet
nonyl Phenol
Version 2.1 Print Date 07/06/2007
Revision Date 06/03/2007
Inhalation : Remove to fresh air. If rapid recovery does not occur, obtain
medical attention.
Skin contact : Immediately remove contaminated clothing. Wash skin with
water using soap if available. If rapid recovery does not occur,
obtain medical attention.
Eye contact : DO NOT DELAY. Flush eye with copious quantities of water.
OBTAIN MEDICAL ATTENTION IMMEDIATELY.
Ingestion : DO NOT DELAY. Do not induce vomiting. Give water to drink,
providing patient is conscious. OBTAIN MEDICAL ATTENTION
IMMEDIATELY.
Notes to physician
Symptoms : Irritation of the skin, eyes and respiratory tract
Treatment : Treat symptomatically. In cases of ingestion, consider gastric
lavage. Gastric lavage must only be undertaken after cuffed
endotracheal intubation in view of the risk of aspiration.
SECTION 5. FIRE-FIGHTING MEASURES
Unsuitable extinguishing : Water in a jet.
media
Suitable extinguishing : Alcohol-resistant foam, water spray or fog. Dry chemical
media powder, carbon dioxide, sand or earth may be used for small
fires only.
Specific hazards during fire : Hazardous combustion products may include oxides of nitrogen,
fighting carbon monoxide, unidentified organic compounds
Keep adjacent containers cool by spraying with water.
Special protective : Do not enter confined fire space without full bunker gear (helmet
equipment for fire-fighters with face shield, bunker coats, gloves and rubber boots).
including a positive pressure NIOSH approved self-contained
breathing apparatus.
SECTION 6. ACCIDENTAL RELEASE MEASURES
Personal precautions : Prevent contact with:
skin
eyes
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Material Safety Data Sheet
nonyl Phenol
Version 2.1 Print Date 07/06/2007
Revision Date 06/03/2007
clothing
Do not breathe mists, aerosols, spray
Shut off leaks, if possible without personal risk.
Environmental precautions : Prevent contamination of soil and water.
Prevent from spreading or entering into drains, ditches or rivers
by using sand, earth, or other appropriate barriers.
Clean-up methods - small : Take up with an absorbent material and place in non-leaking
spillage containers.
Seal tightly for proper disposal.
Clean-up methods - large : Remove with vacuum trucks or pump to storage/salvage
spillage vessels.
Soak up residue with an absorbent such as clay, sand or other
suitable material; place in non-leaking containers for proper
disposal.
Flush area with water to remove trace residue.
Additional advice : Notify authorities if any exposures to the general public or
environment occurs or is likely to occur.
See Section 13 for information on disposal.
SECTION 7. HANDLING AND STORAGE
Handling
Advice on safe handling : Avoid contact with skin, eyes and clothing Do not breathe mists,
aerosols, spray Only use in well ventilated areas.
Storage
Requirements for storage : Keep only in original container. Keep container tightly closed
areas and containers and in a cool, well-ventilated place. Keep container dry.
SECTION 8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Protective measures : Wear appropriate respirator and full-body protective clothing.
Engineering measures : Use local exhaust ventilation.
Eye protection : Monogoggles
Hand protection : Neoprene or nitrile rubber gloves
gauntlet type
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Material Safety Data Sheet
nonyl Phenol
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Revision Date 06/03/2007
Skin and body protection : Do not get on skin, on clothing.
Wear chemical-resistant protective clothing such as gloves,
outer clothing or apron, overshoes and a face-shield suitable to
potential exposure.
Respiratory protection : If risk of inhalation, use approved respirator (e.g. CEN,
NIOSH/OSHA, AS) as required to prevent over exposure. Use
an air-supplied respirator where high concentrations are
expected, or an air-purifying respirator for organic vapours (with
combined particulate filter if mist is present). Note: an
air-supplied respirator should always be used in confined
spaces.
Exposure Guidelines
Components with Regulation Exposure time Value Remarks
workplace control
parameters
NONYLPHENOL ACGIH None established.
SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES
Form : Liquid
Colour : Colourless
Odour : Mild
Boiling point : 285 掳C (545 掳F)
Melting point : -10 掳C (14 掳F)
Flash point : 149 掳C (300 掳F) (Tag closed cup)
Vapour pressure : 1 - 10 hPa
Relative density : 0.95
Solubility in water : Insoluble.
Other physico-chemical : The above properties are typical values only and do not
properties constitute a specification (refer to supplier for supply
specification).
SECTION 10. STABILITY AND REACTIVITY
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Material Safety Data Sheet
nonyl Phenol
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Revision Date 06/03/2007
Conditions to avoid : Heat, flames and sparks.
Materials to avoid : Avoid contact with strong oxidizing agents.
Hazardous decomposition : Nitrogen oxides, carbon monoxide and unidentified organic
products compounds may be formed during combustion.
Hazardous reactions : Hazardous polymerization will not occur.
SECTION 11. TOXICOLOGICAL INFORMATION
Acute oral toxicity : Moderately toxic, 400 < LD50 <= 2000 mg/kg.
Acute dermal toxicity : Low toxicity, LD50 > 2000 mg/kg.
Acute inhalation toxicity : Inhalation of aerosols/mist/sprays/vapours may cause irritation.
Chronic Health Hazard
Components Concentration Regulation Value Remarks
NONYLPHENOL > 90 % US. IARC Monographs on This
Occupational Exposures to component
Chemical Agents has not been
classified by
the
International
Agency for
Research on
Cancer
(IARC).
Eye irritation : Severe irritant.
Skin irritation : Severe irritant.
Sensitisation : May cause skin sensitization.
Basis for assessment : Information given is based on product data, a knowledge of the
components and the toxicology of similar products.
Human effects : See Section 4 for information regarding acute effects to humans.
Potential Health Effects
Inhalation : Vapors/mists may be corrosive to upper respiratory tract.
Repeated or prolonged exposure can result in lung damage.
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Material Safety Data Sheet
nonyl Phenol
Version 2.1 Print Date 07/06/2007
Revision Date 06/03/2007
Skin : Corrosive to the skin.
May cause skin sensitization.
Eyes : Corrosive to the eyes and may cause severe damage including
blindness.
Vapors may be irritating.
SECTION 12. ECOLOGICAL INFORMATION
Elimination information (persistence and degradability)
Biodegradability : Expected to be not readily biodegradable.
Bioaccumulation : Not expected to bioaccumulate significantly.
Ecotoxicity effects
Toxicity to fish : Expected to be practically non toxic, LC/EC/IC 50 > 100 mg/l.
Toxicity to algae : Expected to be slightly toxic, 10 < LC/EC/IC 50 <= 100 mg/l .
Acute toxicity - invertebrates : Expected to be slightly toxic, 10 < LC/EC/IC 50 <= 100 mg/l .
Sewage treatment : Expected to be practically non toxic, LC/EC/IC 50 > 100 mg/l.
Basis for assessment : Ecotoxicological data have not been determined specifically for
this product. The information given below is based on a
knowledge of the components and the ecotoxicology of similar
products.
SECTION 13. DISPOSAL CONSIDERATIONS
Product disposal : If this material becomes a waste, it would not be a hazardous
waste by RCRA criteria (40 CFR 261). Place in an appropriate
disposal facility in compliance with local and federal regulations.
SECTION 14. TRANSPORT INFORMATION
: UN/NA-No 3145
DOT
Class 8
Packing group III
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Material Safety Data Sheet
nonyl Phenol
Version 2.1 Print Date 07/06/2007
Revision Date 06/03/2007
ERG No. 153
Proper shipping name ALKYLPHENOLS, LIQUID, N.O.S.
contains NONYLPHENOL
: UN-Number 3145
IMDG
Class 8
Packaging group III
EmS F-A S-B
Description of the goods ALKYLPHENOLS, LIQUID, N.O.S.
contains NONYLPHENOL
: UN-Number 3145
IATA
Cargo
Class 8
Packaging group III
ERG No. 153
Description of the goods ALKYLPHENOLS, LIQUID, N.O.S.
contains NONYLPHENOL
SECTION 15. REGULATORY INFORMATION
The regulatory information is not intended to be comprehensive. Other regulations may apply to this material.
Notification status
AICS : y
DSL : y
INV (CN) : y
ENCS (JP) : y
TSCA : y
EINECS : y
KECI (KR) : y
PICCS (PH) : y
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Material Safety Data Sheet
nonyl Phenol
Version 2.1 Print Date 07/06/2007
Revision Date 06/03/2007
y = Yes (Listed); AICS = Australian Inventory of Chemical
Notification status
Substances; DSL = Canadian Domestic Substances List;
Legend
INV(CN) = Inventory of Existing Chemicals Substances in
China; ENCS(JP) = Japanese Existing and New Chemical
Substances; TSCA = Toxic Substance Control Act; EINECS =
European Inventory of New and Existing Chemicals; KECI(KR)
= Korean Existing Chemicals Inventory; PICCS(PH) = Philippine
Inventory of Chemicals and Chemical Substances
US. EPA CERCLA Hazardous Substances (40 CFR 302)
NONYLPHENOL No RQ
SARA 311/312 Hazards
Acute Health Hazard
Chronic Health Hazard
US. EPA Emergency Planning and Community Right-To-Know Act (EPCRA) SARA Title III
Section 313 Toxic Chemicals(40 CFR 372. 65) - Supplier Notification Required
NONYLPHENOL No De minimis Concentration
US. EPA Emergency Planning and Community Right-To-Know Act (EPCRA) SARA Title III
Section 302 Extremely Hazardous Substance (40 CFR 355, Appendix A)
NONYLPHENOL Threshold Planning Quantity: No TPQ
NONYLPHENOL Reportable quantity: No RQ
New Jersey Right-To-Know Chemical List
NONYLPHENOL Not Listed
Pennsylvania Right-To-Know Chemical List
NONYLPHENOL Not Listed
Massachusetts Right-To-Know Chemical List
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Material Safety Data Sheet
nonyl Phenol
Version 2.1 Print Date 07/06/2007
Revision Date 06/03/2007
NONYLPHENOL Not Listed
HMIS Rating : Health: 3
Fire: 1
Reactivity: 0
SECTION 16. OTHER INFORMATION
Reference : Prepared in accordance with 29 CFR 1910.1200.
The information provided herein was believed by Hexion Specialty Chemicals ("Hexion") to be accurate at the
time of preparation or prepared from sources believed to be reliable, but it is the responsibility of the user to
investigate and understand other pertinent sources of information, to comply with all laws and procedures
applicable to the safe handling and use of the product and to determine the suitability of the product for its
intended use. All products supplied by Hexion are subject to Hexion's terms and conditions of sale. HEXION
MAKES NO WARRANTY, EXPRESS OR IMPLIED, CONCERNING THE PRODUCT OR THE
MERCHANTABILITY OR FITNESS THEREOF FOR ANY PURPOSE OR CONCERNING THE ACCURACY OF
ANY INFORMATION PROVIDED BY HEXION, except that the product shall conform to Hexion's specifications.
Nothing contained herein constitutes an offer for the sale of any product.
庐 鈩?
and Licensed trademarks of Hexion Specialty Chemicals, Inc.
A vertical bar ( | ) in the left margin indicates an amendment from the previous version.
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