MSDS Number: A0326 Effective Date: 07/02/02
Supercedes: 05/17/01
====
MSDS MATERIAL SAFETY DATA SHEET CHEMTREC: 800-424-9300 (USA)
==== ---------------------------- 703-527-3887
From: Mallinckrodt Baker, Inc. (Outside USA & CANADA)
222 Red School Lane CANUTEC: 613-996-6666
Phillipsburg, NJ 08865
NOTE: Use CHEMTREC and CANUTEC
Emergency Telephone Number: 908-859-2151 phone numbers only in the event
of a chemical emergency.
All non-emergency questions should be directed to Customer Service
(1-800-582-2537) for assistance.
M A L L I N C K R O D T J. T. B A K E R
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ACETIC ACID GLACIAL
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1. Product Identification
Synonyms: Acetic acid, methane carboxylic acid; ethanoic acid
CAS No: 64-19-7
Molecular Weight: 60.05
Chemical Formula: CH3COOH
Product Codes: J.T. Baker:
5355, 5579, 5844, 6903, 9500, 9501, 9503, 9505, 9507,
9508, 9511, 9513, 9515, 9522, 9524, 9526
Mallinckrodt:
2501, 2504, 3121, 7711, 8817, H979, H983, V155, V193,
V194
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2. Composition/Information on Ingredients
Ingredient CAS No Percent Hazardous
--------------------------------------- ------------ ----------- ---------
Acetic Acid 64-19-7 99.5 - 100% Yes
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3. Hazards Identification
Emergency Overview
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POISON! DANGER! CORROSIVE. LIQUID AND MIST CAUSE SEVERE BURNS TO ALL BODY
TISSUE. MAY BE FATAL IF SWALLOWED. HARMFUL IF INHALED. INHALATION MAY CAUSE
LUNG AND TOOTH DAMAGE. FLAMMABLE LIQUID AND VAPOR.
SAF-T-DATA(tm) Ratings (Provided here for your convenience)
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Health Rating: 3 - Severe (Poison)
Flammability Rating: 2 - Moderate
Reactivity Rating: 2 - Moderate
Contact Rating: 4 - Extreme (Corrosive)
Lab Protective Equip: GOGGLES & SHIELD; LAB COAT & APRON; VENT HOOD; PROPER
GLOVES; CLASS B EXTINGUISHER
Storage Color Code: Red (Flammable)
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Potential Health Effects
------------------------
Inhalation:
Inhalation of concentrated vapors may cause serious damage to the lining of
the nose, throat, and lungs. Breathing difficulties may occur. Neither odor
nor degree of irritation are adequate to indicate vapor concentration.
Ingestion:
Swallowing can cause severe injury leading to death. Symptoms include sore
throat, vomiting, and diarrhea. Ingestion of as little as 1.0 ml has
resulted in perforation of the esophagus.
Skin Contact:
Contact with concentrated solution may cause serious damage to the skin.
Effects may include redness, pain, skin burns. High vapor concentrations
may cause skin sensitization.
Eye Contact:
Eye contact with concentrated solutions may cause severe eye damage
followed by loss of sight. Exposure to vapor may cause intense watering and
irritation to eyes.
Chronic Exposure:
Repeated or prolonged exposures may cause darkening of the skin, erosion of
exposed front teeth, and chronic inflammation of the nose, throat, and
bronchial tubes.
Aggravation of Pre-existing Conditions:
Persons with pre-existing skin disorders or eye problems, or impaired
respiratory function may be more susceptible to the effects of the
substance.
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4. First Aid Measures
Inhalation:
Remove to fresh air. If not breathing, give artificial respiration. If
breathing is difficult, give oxygen. Call a physician.
Ingestion:
DO NOT INDUCE VOMITING! Give large quantities of water or milk if
available. Never give anything by mouth to an unconscious person. Get
medical attention immediately.
Skin Contact:
In case of contact, immediately flush skin with plenty of water for at
least 15 minutes while removing contaminated clothing and shoes. Wash
clothing before reuse. Call a physician.
Eye Contact:
Immediately flush eyes with plenty of water for at least 15 minutes,
lifting lower and upper eyelids occasionally. Get medical attention
immediately.
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5. Fire Fighting Measures
Fire:
Flash point: 40C (104F) CC
Autoignition temperature: 427C (801F)
Flammable limits in air % by volume:
lel: 4.0; uel: 16.0
Flammable Liquid and Vapor!
Explosion:
Above flash point, vapor-air mixtures are explosive within flammable limits
noted above. Vapors can flow along surfaces to distant ignition source and
flash back. Contact with strong oxidizers may cause fire. Reacts with most
metals to produce hydrogen gas, which can form an explosive mixture with
air.
Fire Extinguishing Media:
Water, dry chemical, foam or carbon dioxide. Water spray may be used to
keep fire exposed containers cool.
Special Information:
In the event of a fire, wear full protective clothing and NIOSH-approved
self-contained breathing apparatus with full facepiece operated in the
pressure demand or other positive pressure mode. Water may be used to flush
spills away from exposures and to dilute spills to non-flammable mixtures.
Water diluted acid can react with metals to form hydrogen gas.
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6. Accidental Release Measures
Ventilate area of leak or spill. Remove all sources of ignition. Wear
appropriate personal protective equipment as specified in Section 8.
Isolate hazard area. Keep unnecessary and unprotected personnel from
entering. Use water spray to dilute spill to a nonflammable mixture.
Contain and recover liquid when possible. Collect liquid in an appropriate
container or absorb with an inert material (e. g., vermiculite, dry sand,
earth), and place in a chemical waste container. Use non-sparking tools and
equipment. Do not use combustible materials, such as saw dust. Do not flush
to sewer! US Regulations (CERCLA) require reporting spills and releases to
soil, water and air in excess of reportable quantities. The toll free
number for the US Coast Guard National Response Center is (800) 424-8802.
J. T. Baker NEUTRASORB(R) or TEAM(R) 'Low Na+' acid neutralizers are
recommended for spills of this product.
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7. Handling and Storage
Protect against physical damage. Store in a cool, dry well-ventilated
location, away from any area where the fire hazard may be acute. Outside or
detached storage is preferred. Separate from incompatibles. Containers
should be bonded and grounded for transfers to avoid static sparks. Storage
and use areas should be No Smoking areas. Use non-sparking type tools and
equipment, including explosion proof ventilation. Protect from freezing.
Store above 17C (63F). Containers of this material may be hazardous when
empty since they retain product residues (vapors, liquid); observe all
warnings and precautions listed for the product.
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8. Exposure Controls/Personal Protection
Airborne Exposure Limits:
-OSHA Permissible Exposure Limit (PEL):
10 ppm (TWA).
-ACGIH Threshold Limit Value (TLV):
10 ppm (TWA); 15 ppm (STEL).
Ventilation System:
A system of local and/or general exhaust is recommended to keep employee
exposures below the Airborne Exposure Limits. Local exhaust ventilation is
generally preferred because it can control the emissions of the contaminant
at its source, preventing dispersion of it into the general work area.
Please refer to the ACGIH document, "Industrial Ventilation, A Manual of
Recommended Practices", most recent edition, for details.
Personal Respirators (NIOSH Approved):
If the exposure limit is exceeded, a full facepiece respirator with organic
vapor cartridge may be worn up to 50 times the exposure limit or the
maximum use concentration specified by the appropriate regulatory agency or
respirator supplier, whichever is lowest. For emergencies or instances
where the exposure levels are not known, use a full-facepiece
positive-pressure, air-supplied respirator. WARNING: Air purifying
respirators do not protect workers in oxygen-deficient atmospheres.
Skin Protection:
Wear impervious protective clothing, including boots, gloves, lab coat,
apron or coveralls, as appropriate, to prevent skin contact.
Eye Protection:
Use chemical safety goggles and/or a full face shield where splashing is
possible. Maintain eye wash fountain and quick-drench facilities in work
area.
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9. Physical and Chemical Properties
Appearance: Boiling Point:
Clear, colorless liquid. 118C (244F)
Odor: Melting Point:
Strong, vinegar-like. 16.6C (63F)
Solubility: Vapor Density (Air=1):
Infinitely soluble. 2.1
Density: Vapor Pressure (mm Hg):
1.05 11 @ 20C (68F)
pH: Evaporation Rate (BuAc=1):
2.4 (1.0M solution) 0.97
% Volatiles by volume @ 21C (70F):
100
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10. Stability and Reactivity
Stability:
Stable under ordinary conditions of use and storage. Heat and sunlight can
contribute to instability. Releases heat and toxic, irritating vapors when
mixed with water. Acetic acid contracts slightly upon freezing which may
cause the container to burst.
Hazardous Decomposition Products:
Carbon dioxide and carbon monoxide may form when heated to decomposition.
May also release toxic and irritating vapors.
Hazardous Polymerization:
Will not occur.
Incompatibilities:
Acetic Acid is incompatible with chromic acid, nitric acid, ethylene
glycol, perchloric acid, phosphorous trichloride, oxidizers, sodium
peroxide, strong caustics, most metals (except aluminum), carbonates,
hydroxides, oxides, and phosphates.
Conditions to Avoid:
Heat, flame, ignition sources, freezing, incompatibles
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11. Toxicological Information
Oral rat LD50: 3310 mg/kg; skin rabbit LD50: 1.06 g/kg; inhalation mouse
LC50: 5620ppm/1-hr; investigated as a mutagen, reproductive effector.
\Cancer Lists\
---NTP Carcinogen---
Ingredient Known Anticipated IARC Category
------------------------------------ ----- ----------- -------------
Acetic Acid (64-19-7) No No None
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12. Ecological Information
Environmental Fate:
When released into the air, this material may be moderately degraded by
reaction with photochemically produced hydroxyl radicals. When released
into air, this material is expected to have a half-life between 10 and 30
days. When released into water, this material is expected to readily
biodegrade. When released into the water, this material is expected to have
a half-life between 1 and 10 days. Standard dilution BOD5/TOD = 58% When
released into the soil, this material is expected to readily biodegrade.
This material is not expected to significantly bioaccumulate. This material
has an estimated bioconcentration factor (BCF) of less than 100.
Environmental Toxicity:
This material is expected to be slightly toxic to aquatic life. The
LC50/96-hour values for fish are between 10 and 100 mg/l.
For glacial acetic acid:
EC50 (wheat fumigation) = 23.3 mg/m3/2-hr, effect: leaf injury
LC50 (shrimp) = 100 - 300 mg/l/48-hr
LC50 (fathead minnow) = 88 mg/l/96-hr
This material may be toxic to aquatic life.
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13. Disposal Considerations
Whatever cannot be saved for recovery or recycling should be handled as
hazardous waste and sent to a RCRA approved waste facility. Processing, use
or contamination of this product may change the waste management options.
State and local disposal regulations may differ from federal disposal
regulations.
Dispose of container and unused contents in accordance with federal, state
and local requirements.
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14. Transport Information
Domestic (Land, D.O.T.)
-----------------------
Proper Shipping Name: ACETIC ACID, GLACIAL (WITH MORE THAN 80% ACID, BY
MASS)
Hazard Class: 8, 3
UN/NA: UN2789 Packing Group: II
Information reported for product/size: 450LB
International (Water, I.M.O.)
-----------------------------
Proper Shipping Name: ACETIC ACID, GLACIAL (WITH MORE THAN 80% ACID, BY
MASS)
Hazard Class: 8, 3
UN/NA: UN2789 Packing Group: II
Information reported for product/size: 450LB
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15. Regulatory Information
\Chemical Inventory Status - Part 1\
Ingredient TSCA EC Japan Australia
----------------------------------------------- ---- --- ----- ---------
Acetic Acid (64-19-7) Yes Yes Yes Yes
\Chemical Inventory Status - Part 2\
--Canada--
Ingredient Korea DSL NDSL Phil.
----------------------------------------------- ----- --- ---- -----
Acetic Acid (64-19-7) Yes Yes No Yes
\Federal, State & International Regulations - Part 1\
-SARA 302- ------SARA 313------
Ingredient RQ TPQ List Chemical Catg.
---------------------------------------- --- ----- ---- --------------
Acetic Acid (64-19-7) No No No No
\Federal, State & International Regulations - Part 2\
-RCRA- -TSCA-
Ingredient CERCLA 261.33 8(d)
----------------------------------------- ------ ------ ---
Acetic Acid (64-19-7) 5000 No No
Chemical Weapons Convention: No TSCA 12(b): No CDTA: No
SARA 311/312: Acute: Yes Chronic: Yes Fire: Yes Pressure: No
Reactivity: Yes (Pure / Liquid)
Australian Hazchem Code: 2P
Poison Schedule: S6
WHMIS: This MSDS has been prepared according to the hazard criteria of
the Controlled Products Regulations (CPR) and the MSDS contains
all of the information required by the CPR.
================================================================================
16. Other Information
NFPA Ratings:
Health: 3 Flammability: 2 Reactivity: 0
Label Hazard Warning:
POISON! DANGER! CORROSIVE. LIQUID AND MIST CAUSE SEVERE BURNS TO ALL BODY
TISSUE. MAY BE FATAL IF SWALLOWED. HARMFUL IF INHALED. INHALATION MAY CAUSE
LUNG AND TOOTH DAMAGE. FLAMMABLE LIQUID AND VAPOR.
Label Precautions:
Do not get in eyes, on skin, or on clothing.
Do not breathe vapor or mist.
Keep container closed.
Use only with adequate ventilation.
Wash thoroughly after handling.
Keep away from heat, sparks and flame.
Label First Aid:
In case of contact, immediately flush eyes or skin with plenty of water for
at least 15 minutes while removing contaminated clothing and shoes. Wash
clothing before reuse. If swallowed, DO NOT INDUCE VOMITING. Give large
quantities of water. Never give anything by mouth to an unconscious person.
If inhaled, remove to fresh air. If not breathing, give artificial
respiration. If breathing is difficult, give oxygen. In all cases get
medical attention immediately.
Product Use:
Laboratory Reagent.
Revision Information:
MSDS Section(s) changed since last revision of document include: 3.
Disclaimer:
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Mallinckrodt Baker, Inc. provides the information contained herein in good
faith but makes no representation as to its comprehensiveness or accuracy. This
document is intended only as a guide to the appropriate precautionary handling
of the material by a properly trained person using this product. Individuals
receiving the information must exercise their independent judgment in
determining its appropriateness for a particular purpose. MALLINCKRODT BAKER,
INC. MAKES NO REPRESENTATIONS OR WARRANTIES, EITHER EXPRESS OR IMPLIED,
INCLUDING WITHOUT LIMITATION ANY WARRANTIES OF MERCHANTABILITY, FITNESS FOR A
PARTICULAR PURPOSE WITH RESPECT TO THE INFORMATION SET FORTH HEREIN OR THE
PRODUCT TO WHICH THE INFORMATION REFERS. ACCORDINGLY, MALLINCKRODT BAKER, INC.
WILL NOT BE RESPONSIBLE FOR DAMAGES RESULTING FROM USE OF OR RELIANCE UPON THIS
INFORMATION.
********************************************************************************
Prepared by: Environmental Health & Safety
Phone Number: (314) 654-1600 (U.S.A.)
A0326
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