Buffered Neutral Formalin 10%
Material Safety Data Sheet
Section 1. Product and Company Identification
Product Name Product Code R04586
Buffered Neutral Formalin 10%
Manufacturer EMD Chemicals Inc. Effective Date 10/14/2005
P.O. Box 70
480 Democrat Road
Gibbstown, NJ 08027
Prior to January 1, 2003 EMD Chemicals Inc. was EM Industries, Inc. or EM
Science, Division of EM Industries, Inc.
For More Information Call In Case of Emergency Call
856-423-6300 Technical Service 800-424-9300 CHEMTREC (USA)
Monday-Friday: 8:00 AM - 5:00 PM 613-996-6666 CANUTEC (Canada)
24 Hours/Day: 7 Days/Week
Synonym None.
Material Uses Laboratory Reagent
Chemical Family Mixture.
Section 2. Composition and Information on Ingredients
Component CAS # % by Weight
Formaldehyde. 50-00-0 3.7
Methanol 67-56-1 1.5
Sodium Phosphate, Dibasic 7558-79-4 <0.7
Sodium Dihydrogen Phosphate,Monohydrate 10049-21-5 <0.5
Water 7732-18-5 >94
+ Section 3. Hazards Identification
Physical State and Appearance Liquid.
Emergency Overview WARNING !
HARMFUL IF SWALLOWED.
CAUSES RESPIRATORY TRACT, EYE AND SKIN IRRITATION.
CANCER HAZARD
CONTAINS MATERIAL WHICH CAN CAUSE CANCER
CONTAINS MATERIAL WHICH CAUSES DAMAGE TO THE FOLLOWING ORGANS: MUCOUS MEMBRANES,
GASTROINTESTINAL TRACT, RESPIRATORY TRACT, SKIN, CENTRAL NERVOUS SYSTEM, EYE, LENS OR
CORNEA.
WARNING: This product contains a chemical(s) known to the State of California to cause cancer.
Routes of Entry Absorbed through skin. Dermal contact. Eye contact. Inhalation. Ingestion.
Potential Acute Health Effects
Eyes Hazardous in case of eye contact (irritant). Inflammation of the eye is characterized by redness, watering, and itching.
Skin Hazardous in case of skin contact (irritant). Skin inflammation is characterized by itching, scaling, reddening, or, occasionally,
blistering. Non-permeator by skin.
Inhalation Hazardous in case of inhalation (lung irritant). Non-hazardous in case of inhalation.
Ingestion Hazardous in case of ingestion. Do not take internally.
Potential Chronic Health Effects
Carcinogenic Effects Classified + (Proven.) by OSHA [Formaldehyde.]. Classified A2 (Suspected for human.) by ACGIH, 2A (Probable for human.)
by IARC [Formaldehyde.].
Additional information See Toxicological Information (section 11)
Medical Conditions Aggravated Repeated exposure to a highly toxic material may produce general deterioration of health by an accumulation in one or many
by Overexposure: human organs.
Section 4. First Aid Measures
Eye Contact Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for at least 15 minutes.
Cold water may be used. Get medical attention immediately.
Skin Contact In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and
shoes. Cover the irritated skin with an emollient. Cold water may be used. Wash clothing before reuse. Thoroughly clean shoes
before reuse. Get medical attention immediately.
Inhalation If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical
attention immediately.
Ingestion If swallowed, do not induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an
unconscious person. Loosen tight clothing such as a collar, tie, belt or waistband. Get medical attention immediately.
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Buffered Neutral Formalin 10%
+ Section 5. Fire Fighting Measures
Flammability of the Product Non-flammable.
Auto-ignition Temperature Not applicable.
Flash Points Not applicable.
Flammable Limits Not applicable.
Products of Combustion Not applicable.
Fire Hazards in Presence of Not applicable.
Various Substances
Explosion Hazards in Presence Risks of explosion of the product in presence of static discharge:
of Various Substances Slightly explosive in presence of open flames, sparks and static discharge.
Risks of explosion of the product in presence of mechanical impact:
Slightly explosive in presence of shocks.
Fire Fighting Media Not applicable.
and Instructions
Protective Clothing (Fire) Not applicable.
Special Remarks on Fire Hazards Development of hazardous combustion gases or vapors possible in the event of fire.
Special Remarks on Explosion Not available.
Hazards
+ Section 6. Accidental Release Measures
Small Spill and Leak Dilute with water and mop up, or absorb with an inert dry material and place in an appropriate waste disposal container.
Large Spill and Leak Stop leak if without risk. Do not get water inside container. Do not touch spilled material. Use water spray to reduce vapors.
Prevent entry into sewers, basements or confined areas; dike if needed. Call for assistance on disposal. Be careful that the product
is not present at a concentration level above TLV. Check TLV on the MSDS and with local authorities.
Spill Kit Information The following EMD Chemicals Inc. SpillSolv (TM) absorbent is recommended for this product:
SX1340 Formaldehyde Treatment Kit
Section 7. Handling and Storage
Handling Avoid prolonged contact with eyes, skin, and clothing. Avoid contact with eyes. Do not ingest. Avoid breathing vapors or spray
mists. Avoid prolonged or repeated contact with skin. Use only with adequate ventilation. Wash thoroughly after handling.
Storage Keep container tightly closed. Keep container in a cool, well-ventilated area.
+ Section 8. Exposure Controls/Personal Protection
Engineering Controls Provide exhaust ventilation or other engineering controls to keep the airborne concentrations of vapors below their respective
occupational exposure limits.
Personal Protection
Eyes Splash goggles.
Body Lab coat.
Respiratory Vapor respirator. Be sure to use an approved/certified respirator or equivalent. Wear appropriate respirator when ventilation is
inadequate.
Hands Gloves.
Feet Not applicable.
Protective Clothing (Pictograms)
Personal Protection in Case of a Splash goggles. Full suit. Vapor respirator. Boots. Gloves. A self-contained breathing apparatus should be used to avoid inhalation
Large Spill of the product. Suggested protective clothing might not be sufficient; consult a specialist BEFORE handling this product.
Product Name Exposure Limits
Formaldehyde. EH40-MEL (United Kingdom (UK), 1997).
STEL: 2.5 mg/m3 15 minute(s).
STEL: 2 ppm 15 minute(s).
TWA: 2.5 mg/m3 8 hour(s).
TWA: 2 ppm 8 hour(s).
ACGIH (United States, 2000).
CEIL: 0.37 mg/m3
CEIL: 0.3 ppm
NIOSH REL (United States, 1994).
CEIL: 0.1 ppm 15 minute(s).
TWA: 0.01 ppm 10 hour(s).
OSHA Final Rule (United States, 1989).
STEL: 2 ppm 15 minute(s).
TWA: 0.75 ppm 8 hour(s).
OSHA Transitional Rule (United States, 1993).
STEL: 2 ppm 15 minute(s).
TWA: 0.75 ppm 8 hour(s).
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Buffered Neutral Formalin 10%
Methanol ACGIH (United States, 1994). Skin
TWA: 262 mg/m3
STEL: 328 mg/m3
OSHA (United States, 1989). Skin
TWA: 260 mg/m3
STEL: 325 mg/m3
ACGIH (United States, 1994). Skin
STEL: 328 mg/m3 15 minute(s).
STEL: 250 ppm 15 minute(s).
TWA: 262 mg/m3 8 hour(s).
TWA: 200 ppm 8 hour(s).
NIOSH REL (United States, 1994). Skin
STEL: 325 mg/m3 15 minute(s).
STEL: 250 ppm 15 minute(s).
TWA: 260 mg/m3 10 hour(s).
TWA: 200 ppm 10 hour(s).
OSHA Final Rule (United States, 1989). Skin
STEL: 325 mg/m3 15 minute(s).
STEL: 250 ppm 15 minute(s).
TWA: 260 mg/m3 8 hour(s).
TWA: 200 ppm 8 hour(s).
Sodium Phosphate, Dibasic Not available.
Sodium Dihydrogen Phosphate,Monohydrate Not available.
Water Not available.
Section 9. Physical and Chemical Properties
Odor Pungent.
Color Clear. Colorless.
Physical State and Appearance Liquid.
Molecular Weight Not applicable.
Molecular Formula Not applicable.
pH 7 [Neutral.]
Boiling/Condensation Point The lowest known value is 64.55掳C (148.2掳F) (Methanol). Weighted average: 99.27掳C (210.7掳F)
Melting/Freezing Point May start to solidify at -0.1掳C (31.8掳F) based on data for: Water. Weighted average: -4.96掳C (23.1掳F)
Specific Gravity Weighted average: 0.98 (Water = 1)
Vapor Pressure The highest known value is 12.9 kPa (97 mmHg) (@ 20掳C) (METHANOL).
Vapor Density The highest known value is 1.11 (Air = 1) (METHANOL). Weighted average: 1.06 (Air = 1)
Volatility 99.9% (v/v). (METHANOL.)
Odor Threshold The lowest known value is 0.05 ppm (Formaldehyde.) Weighted average: 28.88 ppm
Evaporation Rate 0.36 (Water) compared to(n-Butyl Acetate =1)
VOC 5 (%)
LogKow Not available.
Solubility Soluble in water.
+ Section 10. Stability and Reactivity
Stability and Reactivity The product is stable.
Conditions of Instability Not available.
Incompatibility with Various Highly reactive with oxidizing agents, acids, alkalis.
Substances Slightly reactive to reactive with metals.
Rem/Incompatibility Not available.
Hazardous Decomposition COx , Na2O
Products
Hazardous Polymerization Will not occur.
Section 11. Toxicological Information
RTECS Number:
Formaldehyde LP8925000
Methanol PC1400000
Sodium Phosphate, Dibasic, Anhydrous WC4500000
Sodium dihydrogen phosphate monohydrate Not available.
Water ZC0110000
Toxicity Acute oral toxicity (LD50): 100 mg/kg [Rat]. (Formaldehyde.).
Acute dermal toxicity (LD50): 15800 mg/kg [Rabbit]. (Methanol).
Acute toxicity of the vapor (LC50): 64000 ppm 4 hour(s) [Rat]. (Methanol).
Chronic Effects on Humans CARCINOGENIC EFFECTS: Classified + (Proven.) by OSHA [Formaldehyde.]. Classified A2 (Suspected for human.) by
ACGIH, 2A (Probable for human.) by IARC [Formaldehyde.].
Acute Effects on Humans Hazardous in case of eye contact (irritant). Inflammation of the eye is characterized by redness, watering, and itching. Hazardous
in case of skin contact (irritant). Skin inflammation is characterized by itching, scaling, reddening, or, occasionally, blistering.
Non-permeator by skin. Hazardous in case of inhalation (lung irritant). Non-hazardous in case of inhalation. Hazardous in case of
ingestion.
Synergetic Products Not available.
(Toxicologically)
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Buffered Neutral Formalin 10%
Irritancy Draize Test: Not available.
Sensitization Not available.
Carcinogenic Effects Classified + (Proven.) by OSHA [Formaldehyde.]. Classified A2 (Suspected for human.) by ACGIH, 2A (Probable for human.)
by IARC [Formaldehyde.].
Toxicity to Reproductive System Not available.
Teratogenic Effects Not available.
Mutagenic Effects Not available.
Section 12. Ecological Information
Ecotoxicity Not available.
BOD5 and COD Not available.
Toxicity of the Products of The products of degradation are less toxic than the product itself.
Biodegradation
Section 13. Disposal Considerations
EPA Waste Number U122 U154
Treatment Incineration, fuels blending or recycle. Contact your local permitted waste disposal site (TSD) for permissible treatment sites.
ALWAYS CONTACT PERMITTED WASTE DISPOSER (TSD) TO ASSURE COMPLIANCE WITH ALL CURRENT
LOCAL, STATE AND FEDERAL REGULATIONS.
Section 14. Transport Information
DOT Classification Not available.
TDG Classification Not available.
IMO/IMDG Classification Not available.
ICAO/IATA Classification Not available.
+ Section 15. Regulatory Information
U.S. Federal Regulations TSCA 8(b) inventory: Formaldehyde.; Methanol; Sodium Phosphate, Dibasic ; Sodium Dihydrogen Phosphate,Monohydrate; Water
SARA 302/304/311/312 extremely hazardous substances: Formaldehyde.
SARA 302/304 emergency planning and notification: Formaldehyde.
SARA 302/304/311/312 hazardous chemicals: Formaldehyde.; Methanol; Sodium Phosphate, Dibasic
SARA 311/312 MSDS distribution - chemical inventory - hazard identification: Formaldehyde.: Fire Hazard, Immediate (Acute)
Health Hazard, Delayed (Chronic) Health Hazard; Methanol: Fire Hazard, Immediate (Acute) Health Hazard, Delayed (Chronic)
Health Hazard; Sodium Phosphate, Dibasic : Immediate (Acute) Health Hazard
SARA 313 toxic chemical notification and release reporting: Formaldehyde. 3.7%; Methanol 1.5%
Clean Water Act (CWA) 307: No products were found.
Clean Water Act (CWA) 311: Formaldehyde.; Sodium Phosphate, Dibasic
Clean air act (CAA) 112 accidental release prevention: Formaldehyde.
Clean air act (CAA) 112 regulated flammable substances: No products were found.
Clean air act (CAA) 112 regulated toxic substances: Formaldehyde.
WHMIS (Canada) Class D-2A: Material causing other toxic effects (VERY TOXIC).
CEPA DSL: Formaldehyde.; Methanol; Sodium Phosphate, Dibasic ; Water
This product has been classifed in accordance with the hazard criteria of the Controlled Product Regulations and the MSDS
contains all required information.
International Regulations
EINECS Formaldehyde. 200-001-8
Methanol 200-659-6
Sodium Phosphate, Dibasic 231-448-7
Sodium Dihydrogen Phosphate,Monohydrate 231-449-2
Water 231-791-2
DSCL (EEC) R22- Harmful if swallowed.
R36/38- Irritating to eyes and skin.
International Lists Australia (NICNAS): Formaldehyde.; Methanol; Sodium Phosphate, Dibasic ; Sodium Dihydrogen Phosphate,Monohydrate; Water
Japan (MITI): Formaldehyde.; Methanol; Sodium Phosphate, Dibasic ; Water
Japan (MOL): Formaldehyde.
Korea (TCCL): Formaldehyde.; Methanol; Sodium Phosphate, Dibasic ; Water
Philippines (RA6969): Formaldehyde.; Methanol; Sodium Phosphate, Dibasic ; Water
China: No products were found.
State Regulations Pennsylvania RTK: Formaldehyde.: (special hazard, environmental hazard, generic environmental hazard); Methanol:
(environmental hazard, generic environmental hazard); Sodium Phosphate, Dibasic : (environmental hazard, generic environmental
hazard)
Massachusetts RTK: Formaldehyde.; Methanol; Sodium Phosphate, Dibasic
New Jersey: Buffered Neutral Formalin 10%
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Buffered Neutral Formalin 10%
California prop. 65: This product contains the following ingredients for which the State of California has found to cause cancer,
birth defects or other reproductive harm, which would require a warning under the statute: Formaldehyde.
California prop. 65 (no significant risk level): Formaldehyde.
California prop. 65: This product contains the following ingredients for which the State of California has found to cause cancer
which would require a warning under the statute: Formaldehyde.
Section 16. Other Information
2 1 0 Fire Hazard
National Fire Health
Protection Reactivity
Association (U.S. Specific Hazard
A.)
Changed Since Last Revision +
Notice to Reader
The statements contained herein are based upon technical data that EMD Chemicals Inc. believes to be reliable, are offered for information purposes only
and as a guide to the appropriate precautionary and emergency handling of the material by a properly trained person having the necessary technical skills.
Users should consider these data only as a supplement to other information gathered by them and must make independent determinations of suitability and
completeness of information from all sources to assure proper use, storage and disposal of these materials and the safety and health of employees and
customers and the protection of the environment. EMD CHEMICALS INC. MAKES NO REPRESENTATION OR WARRANTY OF ANY KIND,
EXPRESS OR IMPLIED, INCLUDING MERCHANTABILITY OR FITNESS FOR A PARTICULAR USE, WITH RESPECT TO THE INFORMATION
HEREIN OR THE PRODUCT TO WHICH THE INFORMATION REFERS.
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