1%
Mole Cricket Bait
MATERIAL SAFETY DATA SHEET
POTENTIAL HEALTH HAZARDS:
1. PRODUCT AND COMPANY IDENTIFICATION
EYE 鈥? Mildly irritating to the eyes.
PRODUCT NAME: Chlorpyrifos E-Pro 1% SKIN 鈥? Harmful if absorbed through skin.
Mole Cricket Bait INHALATION 鈥? Slightly irritating to respiratory tract.
Active Ingredient: Chlorpyrifos INGESTION 鈥? May be harmful if swallowed.
O,O-diethyl O-(3,5,6-trichloro-2-
Chemical Name:
POTENTIAL PHYSICAL HAZARDS: None
pyridinyl) phosphorothioate
Chemical Formula: C9H11Cl3NO3PS 4. FIRST AID
COMPANY IDENTIFICATION: IF SWALLOWED: Immediately call a poison control center
Etigra or doctor. Drink one or two glasses of water and induce
501 Cascade Pointe Lane, Suite 103 vomiting by touching the back of the throat with finger.
Cary, NC 27513 Do not give anything by mouth to an unconscious person.
UNITED STATES
IF IN EYES: Hold eye open and rinse slowly and gently
with water for 15-20 minutes. Remove contact lenses, if
2. COMPOSITION/INFORMATION ON INGREDIENTS
present, after the first 5 minutes, then continue rinsing
Chlorpyrifos CAS No. 2921-88-2 1% eye. Call a poison control center or doctor for treatment
advice. Flush eyes with plenty of water. See a doctor if
3. HAZARD IDENTIFICATION irritation develops.
IF ON SKIN OR CLOTHING: Take off contaminated cloth-
EMERGENCY OVERVIEW
ing. Rinse skin immediately with plenty of water for 15-20
May be fatal if swallowed. Harmful if absorbed through
minutes. Call a poison control center or doctor if irritation
skin or inhaled. Wash thoroughly with soap and water
persists.
after handling. Causes moderate eye irritation. Avoid
contact with eyes, skin or clothing. Avoid breathing IF INHALED: Move person to fresh air. If person is not
vapors. Chlorpyrifos is a cholinesterase inhibitor. If breathing, call 911 or an ambulance, then give artificial
exposed, plasma and red blood cell cholinesterase tests respiration, preferably by mouth-to-mouth, if possible.
may indicate degree of exposure (baseline data are use- Call a poison control center or doctor for further treat-
ful). Treat symptomatically. Atropine, only by injection, ment advice.
is an antidote. Oximes, such as 2-PAM/protopam, may NOTE TO PHYSICIAN: This product is an organophos-
be therapeutic if used early; however, use only in con- phorus ester that inhibits cholinesterase. In case of
junction with atropine. This product is an organophos- severe acute poisoning, the decision of whether to induce
phorus ester that inhibits cholinesterase. vomiting or not should be made by the attending physi-
POTENTIAL HEALTH EFFECTS: Symptoms of overexpo- cian. If lavage is performed, endotracheal and/or
sure include headaches, nausea, vomiting, cramps, weak- esophageal control is suggested. Danger from lung aspi-
ness, blurred vision, pin point pupils, tightness in chest, ration must be evaluated against toxicity when consider-
labored breathing, nervousness, sweating, watering of ing emptying the stomach. Treat symptomatically. In case
eyes, drooling, muscle spasms and coma. of severe acute poisoning, use antidotes immediately
after establishing an open airway and respiration.
(continued on next page)
Etigra
Manufactured for: Emergency Phone: Chemtrec 800-424-9300
Etigra Effective Date: December 3, 2004
501 Cascade Pointe Lane EPA Reg. No. 79676-6
Suite 103
Cary, NC 27513
www.etigra.com
REV 0107
4. FIRST AID (continued) 8. EXPOSURE CONTROLS/PERSONAL PROTECTION
ANTIDOTE: Treat symptomatically based on judgment of ENGINEERING CONTROLS: Local exhaust ventilation
the attending physician in response to reactions of the may be necessary to control any air contaminants to
patient. Atropine (by injection only) is an antidote. Oximes within their TLVs during the use of this product. Facilities
such as 2-PAM/protopam, may be therapeutic but should storing or utilizing this material should be equipped with
only be used in conjunction with atropine. Contact your an eyewash facility and a safety shower.
supplier or doctor to ensure this information is up to date.
Personal Protective Equipment:
Eyes and Face: Safety glasses
5. FIRE-FIGHTING MEASURES
Respiratory Protection: When handling in enclosed areas
Flash point: Not applicable to this product. where exposure limits may be exceeded, use a dust/mist
Flammable Limits (LFL-UFL): Not applicable to this product. filtering respirator (NIOSH/MSHA approval number prefix
TC-21C).
Fire and Explosion Hazards: Can burn in fire with irritat-
ing and toxic gases generated by thermal decomposition Protective Clothing: All pesticide handlers must wear a
or combustion. long-sleeved shirt and long pants and shoes plus socks.
Means of Extinction: Use foam, dry chemical, carbon Gloves: Waterproof gloves. Inspect gloves regularly for
dioxide, or water spray when fighting fires involving this leaks. Thoroughly wash the outside of gloves with soap
material. and water prior to removing.
Fire Fighting Instructions: Evacuate area and fight fire
9. PHYSICAL AND CHEMICAL PROPERTIES
from a safe distance. Approach from upwind to avoid
hazardous vapors and decomposition products. Foam Appearance: Tan Granule
fire extinguishing system is preferred to prevent environ- Odor: Slight mercaptan
mental damage from excessive water run off. If water is
pH: N/A
used, avoid heavy hose streams. If possible, dike and col-
Boiling Point: N/A
lect water used to fight fire to prevent/minimize run off.
Melting Point: N/A
Firefighting Equipment: Self-contained breathing appara-
Vapor Pressure: Nil
tus with full facepiece. Wear full firefighting turn-out gear
(Bunker gear). % Volatile: < 3.0%
Hazardous Combustion Products: Heat and fire may Solubility in Water: Not dispersible
result in thermal decomposition and the release of hydro-
10. STABILITY AND REACTIVITY
gen chloride, hydrogen, carbon, sulfur, phosphorus and
nitrogen oxides. CONDITIONS TO AVOID: Avoid temperatures above 125掳F
(52掳C)
6. ACCIDENTAL RELEASE MEASURES
CHEMICAL STABILITY: Product is normally stable.
Clean up spills immediately. Isolate and post spill area. However, product may decompose if heated.
Wear protective clothing and personal protective equip-
HAZARDOUS DECOMPOSITION PRODUCTS: Heat and
ment as prescribed in Section 8 鈥淓xposure Controls/
fire may result in thermal decomposition and the release
Personal Protection鈥?. Keep unprotected persons and ani-
of hydrogen chloride, ethyl sulfide, diethyl sulfide, and
mals out of area.
nitrogen oxides.
SMALL SPILL: Vacuum or sweep up material and place in
INCOMPATIBILITY WITH OTHER MATERIALS: Alkaline
a container for reuse or disposal.
conditions and materials.
LARGE SPILL: Same as for small spills; may neutralize
POLYMERIZATION: Will not occur.
with dilute alkaline solutions of soda and ash and place
into chemical waste container. Do not allow run off into
soil, drainage systems, or bodies of water. Notify and
consult with proper regulatory authorities.
7. HANDLING AND STORAGE
Keep out of reach of children and animals. Use only in a
well-ventilated area.
Store in original container in a secured dry storage area.
11. TOXICOLOGICAL INFORMATION 14. TRANSPORT INFORMATION
ACUTE ORAL TOXICITY DOT PROPER SHIPPING NAME: Environmentally
Oral LD50 (rat): > 2,000 mg/kg Hazardous Substances, Solid, n.o.s. (Chlorpyrifos)
DOT HAZARD CLASS OR DIVISION: 9
ACUTE DERMAL TOXICITY
Dermal LD50 (rat): > 2,000 mg/kg DOT UN/NA NUMBER: UN3077
DOT PACKING GROUP: III
ACUTE INHALATION TOXICITY
Inhalation LC50 (rat): N/A REPORTABLE QUANTITY: 1 lb.
MARINE POLLUTANT: Severe Marine Pollutant
EYE IRRITANT
Rabbit 鈥? Slight irritation DOT EMERGENCY RESPONSE GUIDE: 171
SKIN IRRITATION 15. REGULATORY INFORMATION
Rabbit 鈥? Very slight irritation
U.S. FEDERAL REGULATIONS
SENSITIZATION FIFRA 鈥?
Guinea pig 鈥? Non-sensitizing All pesticides are governed under the Federal Insecticide,
Fungicide, and Rodenticide Act. The regulatory informa-
MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE: tion presented below is pertinent only when this product
Pre-existing cholinesterase depression. is handled outside of the normal use and application as a
pesticide.
CARCINOGENICITY:
ACGIH: Not listed OSHA HAZARD COMMUNICATION STANDARD STATUS:
IARC: Not listed Regulated
NTP: Not listed
OSHA: Not listed SARA Title III 鈥? Section 302 Extremely Hazardous
Substances
MUTAGENIC DATA: No evidence of mutagenic effects Not listed
during in vivo and in vitro assays.
SARA Title III 鈥? Section 311/312 Hazardous Categories
ADDITIONAL DATA: Chlorpyrifos is not known to exhibit None
reproductive or birth defects. Repeated or prolonged
exposures may cause sensitization to subsequent expo- SARA Title III 鈥? Section 312 Threshold Planning Quantity
sures that mimic acute exposures. The threshold planning quantity (TPQ) for this product
treated as a mixture is 10,000 lbs. This product contains
12. ECOLOGICAL INFORMATION no ingredients with a TPQ of less than 10,000 lbs.
ENVIRONMENTAL DATA: This pesticide is toxic to birds SARA Title III 鈥? Section 313 Reportable Ingredients
and wildlife, and extremely toxic to fish and aquatic None
organisms. Do not discharge effluent containing this prod-
CERCLA
uct into lakes, streams, ponds, estuaries, oceans or other
Chemical Name Wt.% RQ
waters, or to areas where surface water is present or to
Chlorpyrifos 1.0% 1 lb.
intertidal areas below the mean high water mark. Drift and
runoff from treated areas may be hazardous to aquatic CALIFORNIA PROP 65 STATUS 鈥?
organisms in adjacent aquatic sites. Cover or incorporate Not listed
spills. Do not contaminate water by cleaning of equipment
or disposal of equipment wash water. 16. OTHER INFORMATION
FISH TOXICITY This product has been classified in accordance with the
96 hour LC50, Bluegill 鈥? 2.4 ppm hazard criteria of the Controlled Products Regulations
96 hour LC50, Rainbow trout 鈥? 3.0 ppm (CPR) and the MSDS contains all of the information
required by CPR.
AVIAN TOXICITY
Oral LD50, Mallard duck 鈥? 76.6 mg/kg DISCLAIMER:
Etigra believes the information and recommendations
BEE TOXICITY: Highly toxic.
provided above to be accurate. NO WARRANTY OF FIT-
NESS FOR ANY PARTICULAR PURPOSE, WARRANTY OF
13. DISPOSAL CONSIDERATIONS
MERCHANTABILITY, OR ANY OTHER WARRANTY,
PESTICIDE DISPOSAL: Pesticide wastes are toxic. EXPRESS OR IMPLIED, IS MADE CONCERNING THE
Improper disposal of excess pesticide, spray mixture, or INFORMATION PROVIDED HEREIN. The information pro-
rinsate is a violation of Federal Law. If these wastes can- vided above relates only to the specific product designat-
not be disposed of according to label instructions, contact ed and may not be applicable where such product is used
your State Pesticide or Environmental Control Agency, or in combination with any other materials or in any
the Hazardous Waste representative at the nearest EPA process. Use of this product is regulated by the U.S.
Regional Office for guidance. Environmental Protection Agency (EPA). It is a violation
of Federal law to use this product in a manner inconsis-
CONTAINER DISPOSAL: Completely empty bag into appli-
tent with its labeling. Additionally, as the conditions and
cation equipment. Then dispose of empty bag in a sani-
methods of use are beyond the control of Etigra, Etigra
tary landfill or by incineration, or, if allowed by state and
expressly disclaims any and all liability as to any results
local authorities, by burning. If burned, stay out of smoke.
obtained or arising from any use of the product or
reliance on such information.
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