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MSDS Material Safety Data Sheet
CAS

138261-41-3

File Name: etigra_com---imida_e-pro_75_wsp_pre-post_construction_msds.asp
                          Imida Pre/Post Construction Insecticide
75 WSP
MATERIAL SAFETY DATA SHEET
1. PRODUCT AND COMPANY IDENTIFICATION 4. FIRST AID
PRODUCT NAME: Imida E-Pro 75 WSP 鈥? IF ON SKIN OR CLOTHING: Call a poison control center or
Pre/Post Construction Insecticide doctor for treatment advice. Take off contaminated cloth-
Active Ingredient: Imidacloprid ing. Rinse skin immediately with water for 15-20 minutes.
Chemical Name: 1-[(6-Chloro-3-pyridinyl)methyl]- IF IN EYES: Hold eye open and rinse slowly and gently with
N-nitro-2-imidazolidinimine water for 15-20 minutes. Remove contact lenses, if present,
Chemical Formula: C9H10CIN5O2 after the first 5 minutes, then continue rinsing eye. Call a
poison control center or doctor for treatment advice.
COMPANY IDENTIFICATION:
Etigra, LLC IF INHALED: Move person to fresh air. If person is not
2214 Highway 44 West breathing, call 911 or an ambulance, then give artificial res-
Inverness, FL 34453 piration, preferably by mouth-to-mouth if possible.
UNITED STATES IF SWALLOWED: Call a poison control center or doctor
immediately for treatment advice. Have person sip a glass
2. COMPOSITION/INFORMATION ON INGREDIENTS of water if able to swallow. Do not induce vomiting unless
told to do so by a poison control center or doctor. Do not
Imidacloprid CAS No. 138261-41-3 75.00%
give anything by mouth to an unconscious person.
3. HAZARD IDENTIFICATION NOTE TO PHYSICIAN: No specific antidote is available.
Treat patient symptomatically.
HAZARDS TO HUMANS AND DOMESTIC ANIMALS: May
be fatal if swallowed. Harmful if absorbed through skin. 5. FIRE-FIGHTING MEASURES
Causes moderate eye irritation. Avoid contact with skin,
Flash Point: N/A
eyes, or clothing.
Flammable Limits (LFL-UFL): Unknown
ENVIRONMENTAL HAZARDS: This product is highly toxic
Fire and Explosion Hazards: Can burn in fire releasing
to aquatic invertebrates. Do not apply directly to water, or
irritating and toxic gasses due to thermal decomposition
to areas where surface water is present or to intertidal
or combustion.
areas below the mean high water mark. Do not contami-
nate water when disposing of equipment washwaters. Means of Extinction: Use foam, dry chemical, carbon
This product is highly toxic to bees exposed to direct dioxide or water spray.
treatment or residues on the foliage of blooming crops or
Fire-Fighting Instructions: Evacuate area and fight fire
weeds. Do not apply this product or allow it to drift to
upwind a safe distance to avoid hazardous vapors and
blooming crops or weeds if bees are visiting the treat-
decomposition products. Use as little water as possible
ment area. This product is toxic to wildlife. This chemical
and use spray or fog and avoid heavy hose streams to
demonstrates the properties and characteristics associat-
prevent runoff. Dike and collect water used to fight fire to
ed with chemicals detected in groundwater. The use of
prevent environmental damage due to runoff. Foam or
this chemical in areas where soils are permeable, partic-
dry chemical extinguishing systems are preferred to pre-
ularly where the water table is shallow, may result in
vent environmental damage due to runoff.
groundwater contamination.


Etigra, LLC
Manufactured for: Emergency Phone: Chemtrec 800-424-9300
Etigra, LLC Effective Date: June 29, 2006
2214 Hwy 44 West EPA Reg. No. 81959-29
Inverness, FL 34453

REV 1106
Fire-fighting Equipment: Self-contained breathing appa- Tap Density: 0.424 g/ml
ratus with full face piece. Solubility in Water: Dispersible
Hazardous Combustion Products: Hydrogen cyanide,
10. STABILITY AND REACTIVITY
hydrogen chloride, carbon monoxide and nitrogen oxide.
CONDITIONS TO AVOID: Avoid temperatures over 100掳F
6. ACCIDENTAL RELEASE MEASURES
(38掳C) for extended periods of time. Strong exothermal
reaction can occur at temperatures above 390掳F (200掳C).
Clean up spills immediately observing the precautions in
Section 8 of this MSDS. Isolate the hazard area and keep CHEMICAL STABILITY: Stable but may decompose if
unnecessary and unprotected personnel from entering. heated.
Prevent material from contaminating soil or from entering
HAZARDOUS DECOMPOSITION PRODUCTS: Hydrogen
sewage and drainage systems and bodies of water.
chloride, hydrogen cyanide and oxides of nitrogen and
carbon.
SMALL SPILLS: Vacuum or sweep up material and place
in a container for reuse or disposal. Clean contaminated INCOMPATIBILITY WITH OTHER MATERIALS: None known.
floors and objects thoroughly, observing all environmental
POLYMERIZATION: Will not occur.
regulations.
LARGE SPILLS: Avoid creating a dust cloud. Vacuum or 11. TOXICOLOGICAL INFORMATION
sweep up material and place in a container for reuse or
ACUTE ORAL TOXICITY
disposal. If necessary, reduce airborne dust and prevent
Oral LD50 (rat): 440 mg/kg
scattering by moistening with water. Pick up wash liquid
with additional absorbent and place in a disposable con- ACUTE DERMAL TOXICITY
tainer. After removal, flush contaminated area thoroughly Dermal LD50 (rat): > 2,000 mg/kg
with water.
ACUTE INHALATION TOXICITY
7. HANDLING AND STORAGE Inhalation LC50 (rat): > 2.055 mg/L
EYE IRRITANT
Avoid breathing dust or vapor. Avoid contact with skin,
Rabbit 鈥? Causes moderate eye irritation
eyes and clothing. Remove and wash contaminated
clothing before reuse. Wash thoroughly with soap and SKIN IRRITATION
water after handling and before eating, drinking, chewing Rabbit 鈥? Non-Irritating
gum, or using tobacco.
SENSITIZATION
Store in a cool, dry place and in such a manner as to pre- Guinea Pig 鈥? Not a Contact Sensitizer
vent cross contamination with other pesticides, fertilizers,
MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE:
food, and feed. Store in original container and out of the
None known.
reach of children, preferably in a locked storage area.
CARCINOGENICITY:
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
ACGIH: Not listed
IARC: Not listed
Engineering Controls: To avoid exceeding exposure limits,
NTP: Not listed
handle only with adequate ventilation. Facilities storing or
OSHA: Not listed
utilizing this material should be equipped with an eyewash
station and a safety shower. MUTAGENIC DATA: No evidence of mutagenic effects
during in vivo and in vitro assays.
Protective Clothing: Tight fitting safety goggles. Chemical-
resistant gloves made of waterproof material such as poly-
ADDITIONAL DATA: Not known to cause reproductive or
ethylene or polyvinyl chloride (PVC). Long-sleeved shirt,
birth defects at normal exposure levels.
long pants and shoes plus socks. A respirator is not
required when handled under normal conditions. When 12. ECOLOGICAL INFORMATION
handling in enclosed areas with inadequate ventilation,
use a dust/mist filtering respirator (MSHA/NIOSH approval This product is highly toxic to aquatic invertebrates. Do
number prefix TC-21C). not apply directly to water, or to areas where surface
water is present or to intertidal areas below the mean high
General: Wash thoroughly with soap and water after han-
water mark. Do not contaminate water when disposing of
dling. Discard clothing and other absorbent materials that
equipment washwaters.
have been heavily contaminated with this product; do not
reuse them. Follow the manufacturer鈥檚 instructions for This product is highly toxic to bees exposed to direct
cleaning and maintaining PPE. If no such instructions for treatment or residues on the foliage of blooming crops or
washables exist, use detergent and hot water. Keep and weeds. Do not apply this product or allow it to drift to
wash PPE separately from other laundry. blooming crops or weeds if bees are visiting the treat-
ment area.
9. PHYSICAL AND CHEMICAL PROPERTIES
This product is toxic to wildlife.
Appearance: Off-white powder
This chemical demonstrates the properties and charac-
Odor: Weak characteristic
teristics associated with chemicals detected in ground-
pH: 6.93
water. The use of this chemical in areas where soils are
Flashpoint (PMA-4): N/A permeable, particularly where the water table is shallow,
Melting Point: 290.5掳F (143.6掳C) may result in groundwater contamination.
SARA Title III 鈥? Section 311/312 Hazard Categories
13. DISPOSAL CONSIDERATIONS
Immediate
Do not contaminate water, food or feed by disposal.
SARA Title III 鈥? Section 312 Threshold Planning Quantity
PESTICIDE DISPOSAL: Pesticide wastes are toxic. N/A
Improper disposal of excess pesticide, or rinsate is a vio-
SARA Title III 鈥? Section 313 Reportable Ingredients
lation of Federal Law. If these wastes cannot be disposed
None
of by use according to label instructions, contact your
State Pesticide or Environmental Control Agency, or the CERCLA 鈥?
Hazardous Waste Representative at the nearest EPA None Listed
Regional Office for guidance.
CALIFORNIA PROP 65 STATUS 鈥?
CONTAINER DISPOSAL: Completely empty bag into man- Not Listed
ufacturing equipment. Then dispose of empty bag in a
16. OTHER INFORMATION
sanitary landfill or by incineration, or, if allowed by state
and local authorities, by burning. If burned, stay out of
This product has been classified in accordance with the
smoke.
hazard criteria of the Controlled Products Regulations
(CPR) and the MSDS contains all of the information
14. TRANSPORT INFORMATION
required by CPR.
DOT PROPER SHIPPING NAME: Not regulated by DOT DISCLAIMER:
DOT HAZARD CLASS OR DIVISION: N/A Etigra, LLC believes the information and recommenda-
DOT UN/NA NUMBER: N/A tions provided above to be accurate. NO WARRANTY OF
FITNESS FOR ANY PARTICULAR PURPOSE, WARRANTY
DOT PACKING GROUP: N/A
OF MERCHANTABILITY, OR ANY OTHER WARRANTY,
REPORTABLE QUANTITY: N/A
EXPRESS OR IMPLIED, IS MADE CONCERNING THE
MARINE POLLUTANT: Not Listed
INFORMATION PROVIDED HEREIN. The information pro-
DOT EMERGENCY RESPONSE GUIDE: N/A vided above relates only to the specific product designat-
ed and may not be applicable where such product is used
15. REGULATORY INFORMATION in combination with any other materials or in any
process. Use of this product is regulated by the U.S.
FIFRA 鈥?
Environmental Protection Agency (EPA). It is a violation
All pesticides are governed under the Federal Insecticide,
of Federal law to use this product in a manner inconsis-
Fungicide, and Rodenticide Act. The regulatory informa-
tent with its labeling. Additionally, as the conditions and
tion presented below is pertinent only when this product
methods of use are beyond the control of Etigra, LLC,
is handled outside of the normal use and application as a
Etigra expressly disclaims any and all liability as to any
pesticide.
results obtained or arising from any use of the product or
SARA Title III 鈥? Section 302 Extremely Hazardous Substances reliance on such information.
Not Listed

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