SFM + MSM Herbicide
MATERIAL SAFETY DATA SHEET
IF ON SKIN: Repeated dermal contact may cause skin irri-
1. PRODUCT AND COMPANY IDENTIFICATION
tation with itching, burning, redness, swelling and/or rash.
PRODUCT NAME: SFM + MSM E-Pro Herbicide IF INGESTED: High doses of Sulfometuron methyl may
Active Ingredients: Sulfometuron methyl + lead to red blood cell destruction.
Metsulfuron methyl
4. FIRST AID
Chemical Names: Sulfometuron methyl:
{Methyl 2-[[[[(4,6-dimethyl-
IF ON SKIN OR CLOTHING: Call a poison control center or
2pyrimidinyl)amino]-carbonyl]
doctor for treatment advice. Take off contaminated cloth-
amino]sulfonyl]benzoate}
ing. Rinse skin immediately with water for 15-20 minutes.
Metsulfuron methyl:
IF IN EYES: Hold eye open and rinse slowly and gently with
Methyl2-[[[[(4-methoxy-6-methyl-
water for 15-20 minutes. Remove contact lenses, if present,
1,3,5-triazin-2-yl)amino]-carbonyl]
after the first 5 minutes, then continue rinsing eye. Call a
amino]sulfonyl]benzoate
poison control center or doctor for treatment advice.
Chemical Formulas: Sulfometuron methyl:
C15H16N4O5S 5. FIRE-FIGHTING MEASURES
Metsulfuron methyl:
Flash Point: N/A
C14H15N5O6S
Flammable Limits (LFL-UFL): 0.092 g/L
COMPANY IDENTIFICATION:
Fire and Explosion Hazards: None. This product will not
Etigra, LLC
burn or burns with difficulty.
2214 Hwy 44 West
Means of Extinction: Use extinguishing agent suitable for
Inverness, FL 34453
surrounding fires.
UNITED STATES
Fire-Fighting Instructions: Keep unnecessary people
2. COMPOSITION/INFORMATION ON INGREDIENTS away and conduct fire-fighting and rescue operation from
upwind of the fire area. Evacuate people downwind who
Sulfometuron Methyl CAS No. 74222-97-2 56.25%
may come in contact with smoke, fumes or contaminated
Metsulfuron Methyl CAS No. 74223-64-6 15.00%
surfaces. If area is exposed to fire and conditions permit,
allow fire to burn itself out. Use as little water as possible
3. HAZARD IDENTIFICATION
and use spray or fog and avoid heavy hose streams to
Causes moderate eye irritation. Harmful if absorbed prevent runoff.
through skin. Avoid contact with skin, eyes, or clothing. Fire-fighting Equipment: Self-contained breathing appa-
Wash thoroughly with soap and water after handling and ratus with full face piece. Wear full fire-fighting turn-out
before eating, drinking, chewing gum, or using tobacco. gear (Bunker gear).
Hazardous Combustion Products: May produce carbon
POTENTIAL HEALTH EFFECTS 鈥?
monoxide, carbon dioxide, hydrogen chloride and alky-
IF IN EYES: May cause irritation with tearing, pain or
lamines.
blurred vision.
NFPA RATINGS: Health: 1 / Flammability: 1 / Reactivity: 0
Etigra, LLC
Manufactured for: Emergency Phone: Chemtrec 800-424-9300
Etigra, LLC Effective Date: May 9, 2006
2214 Hwy 44 West EPA Reg. No. 81959-15
Inverness, FL 34453
REV 0506
CARCINOGENICITY:
6. ACCIDENTAL RELEASE MEASURES
ACGIH: Not listed
For emergency response, wear chemical-resistant cover- IARC: Not listed
alls, waterproof gloves and boots and face/eye protec- NTP: Not listed
tion. If dusting occurs, wear NIOSH-approved respirator OSHA: Not listed
protection. MUTAGENIC DATA: No evidence of mutagenic effects
during in vivo and in vitro assays.
Dike spill and prevent material from entering sewers,
waterways or low areas. Shovel or sweep up and place in ADDITIONAL DATA: Not known to cause reproductive or
a closed container for disposal. Dispose in accordance birth defects.
with local, state and federal regulations.
12. ECOLOGICAL INFORMATION
7. HANDLING AND STORAGE
This product is injurious to plants at extremely low con-
Do not contaminate other pesticides, fertilizers, water, centrations. Do not apply directly to water, or to areas
food or feed by storage or disposal. Wash thoroughly where surface water is present, or to intertidal areas
after handling this product. Store in original container in below the mean high water mark. Do not apply where
a secured cool, dry storage area. runoff water may flow, during periods of intense rainfall
or to water-saturated soils as off-target movement and
8. EXPOSURE CONTROLS/PERSONAL PROTECTION injury may occur. Do not contaminate water when dispos-
ing of equipment washwaters.
Engineering Controls: Use only with adequate ventilation.
Protective Clothing: All pesticide handlers must wear a 13. DISPOSAL CONSIDERATIONS
long-sleeved shirt and long pants and shoes plus socks.
Do not contaminate water, food or feed by storage or dis-
General: Wash thoroughly with soap and water after han-
posal.
dling.
PESTICIDE DISPOSAL: Wastes resulting from the use of
this product must be disposed of on site or at an approved
9. PHYSICAL AND CHEMICAL PROPERTIES
waste disposal facility.
Appearance: Light brown granules
CONTAINER DISPOSAL: Triple rinse (or equivalent). Then
Odor: Slight offer for recycling or reconditioning or puncture and dis-
pH: 7.537 pose of in a sanitary landfill, or incineration, or, if allowed
Flashpoint (PMA-4): N/A by state and local authorities, by burning. If burned, stay
Specific Gravity: 1.2562 g/ml at 20掳C out of smoke.
Solubility in Water: Dispersible
14. TRANSPORT INFORMATION
10. STABILITY AND REACTIVITY
DOT PROPER SHIPPING NAME: Not Regulated by DOT
CONDITIONS TO AVOID: None known. DOT HAZARD CLASS OR DIVISION: N/A
DOT UN/NA NUMBER: N/A
CHEMICAL STABILITY: Stable.
DOT PACKING GROUP: N/A
HAZARDOUS DECOMPOSITION PRODUCTS: Combustion
REPORTABLE QUANTITY: N/A
may produce by-products more toxic than the active
ingredient. MARINE POLLUTANT: Not Listed
DOT EMERGENCY RESPONSE GUIDE: N/A
INCOMPATIBILITY WITH OTHER MATERIALS: None known.
POLYMERIZATION: Will not occur. 15. REGULATORY INFORMATION
11. TOXICOLOGICAL INFORMATION FIFRA 鈥?
All pesticides are governed under the Federal Insecticide,
ACUTE ORAL TOXICITY
Fungicide, and Rodenticide Act. The regulatory informa-
Oral LD50 (rat): > 5,000 mg/kg
tion presented below is pertinent only when this product
is handled outside of the normal use and application as a
ACUTE DERMAL TOXICITY
pesticide.
Dermal LD50 (rat): > 5,000 mg/kg
SARA Title III 鈥? Section 302 Extremely Hazardous Substances
ACUTE INHALATION TOXICITY
Not Listed
Inhalation LC50 (rat): >2.09 mg/L
SARA Title III 鈥? Section 311/312 Hazard Categories
EYE IRRITANT
Immediate
Rabbit 鈥? Mildly Irritating
SARA Title III 鈥? Section 312 Threshold Planning Quantity
SKIN IRRITATION N/A
Rabbit 鈥? Slightly Irritating
SARA Title III 鈥? Section 313 Reportable Ingredients
SENSITIZATION None
Guinea Pig 鈥? Not a Contact Sensitizer
CERCLA 鈥?
MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE: None Listed
None known.
CALIFORNIA PROP 65 STATUS 鈥?
Not Listed
16. OTHER INFORMATION
This product has been classified in accordance with the
hazard criteria of the Controlled Products Regulations
(CPR) and the MSDS contains all of the information
required by CPR.
DISCLAIMER:
Etigra, LLC believes the information and recommenda-
tions provided above to be accurate. NO WARRANTY OF
FITNESS FOR ANY PARTICULAR PURPOSE, WARRANTY
OF MERCHANTABILITY, OR ANY OTHER WARRANTY,
EXPRESS OR IMPLIED, IS MADE CONCERNING THE
INFORMATION PROVIDED HEREIN. The information pro-
vided above relates only to the specific product designat-
ed and may not be applicable where such product is used
in combination with any other materials or in any
process. Use of this product is regulated by the U.S.
Environmental Protection Agency (EPA). It is a violation
of Federal law to use this product in a manner inconsis-
tent with its labeling. Additionally, as the conditions and
methods of use are beyond the control of Etigra, LLC,
Etigra expressly disclaims any and all liability as to any
results obtained or arising from any use of the product or
reliance on such information.
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