Double O Herbicide
MATERIAL SAFETY DATA SHEET
1. PRODUCT AND COMPANY IDENTIFICATION 4. FIRST AID
IF IN EYES: Hold eye open and rinse slowly and gently
PRODUCT NAME: Double O E-Pro Herbicide
with water for 15-20 minutes. Remove contact lenses, if
COMPANY IDENTIFICATION: present, after the first 5 minutes, then continue rinsing
Etigra鈩? eye. Call a poison control center or doctor for treatment
501 Cascade Pointe Lane advice. Have the product container or label with you
Suite 103 when calling a poison control center or doctor, or going
Cary, NC 27513 for treatment. You may also contact 1-800-424-9300 for
www.Etigra.com emergency medical treatment information.
2. COMPOSITION/INFORMATION ON INGREDIENTS 5. FIRE-FIGHTING MEASURES
Active Ingredients CAS No. % Composition
Flash Point: N/A
Oxyfluorfen 42874-03-3 2.0% Flammable Limits (LFL-UFL): N/A
Oryzalin 19044-88-3 1.0%
Fire and Explosion Hazards: May form an explosive dust /
Active Ingredients Chemical Name Formula air mixture.
Oxyfluorfen 2-Chloro-1-(3- C15H11CIF3NO4 Means of Extinction: Use carbon dioxide, or water spray
ethoxy-4-nitrophenoxy)- or dry chemical.
4-(trifluoromethyl)benzene Fire-Fighting Instructions: Evacuate area and flood with
Oryzalin 3,5-Dinitro-N',N'- C12H18N4O6S water.
dipropylsulfanilamide Fire-fighting Equipment: Self-contained breathing appara-
tus with full face piece. For large fires wear full bunker gear.
3. HAZARD IDENTIFICATION
Hazardous Combustion Products: May produce irritating
gases and vapors in a fire.
EMERGENCY OVERVIEW
Causes moderate eye irritation. Avoid contact with eyes
6. ACCIDENTAL RELEASE MEASURES
or clothing.
Avoid dusting or misting conditions during cleanup. Do
POTENTIAL HEALTH HAZARDS 鈥? not allow to contaminate water supplies. After spill
EYE 鈥? May cause eye irritation. cleanup, flush area with water.
SKIN 鈥? May cause skin irritation. SMALL SPILL: If material is uncontaminated, collect and
INGESTION 鈥? May be harmful if swallowed. reuse as recommended for product. If contaminated, put
in appropriate container and dispose of according to the
MEDICAL CONDITIONS AGGRAVATED: Skin contact may
instructions in Section 13 of this MSDS.
cause allergic reaction in sensitive individuals. Persons
with preexisting skin disorders or impaired respiratory LARGE SPILL: Extinguish all ignition sources and venti-
function may be more susceptible to the effects of this late area. Cleanup personnel must wear protective cloth-
product. ing and respiratory protection.
Etigra鈩?
Manufactured for: Emergency Phone: Chemtrec 800-424-9300
Etigra鈩? Effective Date: June 20, 2006
501 Cascade Pointe Lane EPA Reg. No. 79676-20
Suite 103
Cary, NC 27513
REV 0606
SENSITIZATION
7. HANDLING AND STORAGE
Guinea Pig 鈥? Not a Contact Sensitizer
Keep out of reach of children and animals. Do not use or
CARCINOGENICITY:
store near water, heat, open flame or hot surfaces. Do not
ACGIH: Not listed
contaminate other pesticides, fertilizers, water, food or
IARC: Not listed
feed by storage or disposal. Wash thoroughly after han-
NTP: Not listed
dling this product.
OSHA: Not listed
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
12. ECOLOGICAL INFORMATION
ENGINEERING CONTROLS: Local exhaust ventilation
ENVIRONMENTAL DATA: This pesticide is toxic to
may be necessary to control any air contaminants.
wildlife and fish. Use with care when applying in areas
PERSONAL PROTECTIVE EQUIPMENT: Some materials adjacent to any body of water. Apply this product only as
that are chemical-resistant to this product are listed specified on the label. Do not contaminate water by
below. If you want more options, follow the instructions cleaning of equipment or disposal of wastes.
for category A on an EPA chemical-resistance category
selection chart. 13. DISPOSAL CONSIDERATIONS
Applicators and other Handlers must wear:
PESTICIDE DISPOSAL: Wastes resulting from the use of
鈥? Coveralls over long-sleeved shirt and long pants
this product may be disposed of on site or at an approved
鈥? Chemical-resistant gloves, such as natural rubber 鈮? 14 mils
waste disposal facility.
鈥? Chemical-resistant footwear
鈥? Protective eyewear CONTAINER DISPOSAL: Completely empty bag into
鈥? Chemical-resistant headgear for overhead exposures application equipment. Then dispose of empty bag in a
鈥? Chemical-resistant apron (mixers and loaders) sanitary landfill or by incineration, or, if allowed by state
鈥? Under prolonged use, a dust filter and disposable pro- and local authorities, by burning. If burned, stay out of
tective garment are additionally recommended. smoke.
Follow manufacturer鈥檚 instructions for cleaning/maintain-
14. TRANSPORT INFORMATION
ing PPE. If no such instructions for washables, use deter-
gent and hot water. Keep and wash PPE separately from DOT PROPER SHIPPING NAME: Not regulated by DOT
other laundry. Discard clothing and other absorbent
DOT HAZARD CLASS OR DIVISION: N/A
materials that have been drenched or heavily contami-
DOT UN/NA NUMBER: N/A
nated with this product鈥檚 concentrate. Do not reuse them.
DOT PACKING GROUP: N/A
9. PHYSICAL AND CHEMICAL PROPERTIES REPORTABLE QUANTITY: N/A
MARINE POLLUTANT: Not Listed
Appearance: Yellow granules
Odor: Musty 15. REGULATORY INFORMATION
pH: 8.98
FIFRA 鈥?
Flashpoint (PMA-4): N/A
All pesticides are governed under the Federal Insecticide,
Specific Gravity: 0.700 g/ml at 20掳C
Fungicide, and Rodenticide Act. The regulatory informa-
Solubility in Water: Soluble
tion presented below is pertinent only when this product
is handled outside of the normal use and application as a
10. STABILITY AND REACTIVITY
pesticide.
CONDITIONS TO AVOID: Protect from moisture and heat. OSHA HAZARD COMMUNICATION STANDARD STATUS:
CHEMICAL STABILITY: Product is normally stable. Not Regulated
HAZARDOUS DECOMPOSITION PRODUCTS: Heat and SARA Title III 鈥? Section 302 Extremely Hazardous
fire may result in thermal decomposition and the release Substances
of irritating gases and vapors. Not Listed
POLYMERIZATION: Will not occur. SARA Title III 鈥? Section 311/312 Hazard Categories
Immediate
11. TOXICOLOGICAL INFORMATION
SARA Title III 鈥? Section 312 Threshold Planning Quantity
ACUTE ORAL TOXICITY The threshold planning quantity (TPQ) for this product
Oral LD50 (rat, female): > 5,000 mg/kg treated as a mixture is 10,000 lbs. This product contains
no ingredients with a TPQ of less than 10,000 lbs.
ACUTE DERMAL TOXICITY
Dermal LD50 (rat): > 5,000 mg/kg SARA Title III 鈥? Section 313 Reportable Ingredients
Oxyfluorfen, Oryzalin
ACUTE INHALATION TOXICITY
Inhalation LC50 (rat): > 2.03 mg/L CERCLA 鈥?
Not Listed
EYE IRRITANT
Rabbit 鈥? Moderately Irritating CALIFORNIA PROP 65 STATUS 鈥?
Not Listed
SKIN IRRITATION
Rabbit 鈥? Non-Irritating
16. OTHER INFORMATION
This product has been classified in accordance with the
hazard criteria of the Controlled Products Regulations
(CPR) and the MSDS contains all of the information
required by CPR.
DISCLAIMER:
Etigra believes the information and recommendations
provided above to be accurate. NO WARRANTY OF FIT-
NESS FOR ANY PARTICULAR PURPOSE, WARRANTY OF
MERCHANTABILITY, OR ANY OTHER WARRANTY,
EXPRESS OR IMPLIED, IS MADE CONCERNING THE
INFORMATION PROVIDED HEREIN. The information pro-
vided above relates only to the specific product designat-
ed and may not be applicable where such product is used
in combination with any other materials or in any
process. Use of this product is regulated by the U.S.
Environmental Protection Agency (EPA). It is a violation
of Federal law to use this product in a manner inconsis-
tent with its labeling. Additionally, as the conditions and
methods of use are beyond the control of Etigra, Etigra
expressly disclaims any and all liability as to any results
obtained or arising from any use of the product or
reliance on such information.
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