Part Number(s):
MATERIAL SAFETY DATA SHEET 11-20X-XX
Form WI04-11A Rev. 1
Product Name: KRATON TM D2104 Thermoplastic Rubber Release Date: May 14, 2007
1. Product and Company Identification
Trade Name & Synonyms MSDS Code Number
KRATON TM D2104 Thermoplastic Rubber 2017-13
Chemical Name Manufacture / Distributor
NA GAC International Inc.
C.A.S. Number Address
9003-55-8 355 Knickerbocker Ave.
Bohemia, NY USA 11716
Grades or Minor Variant Identities Information Telephone Number
NA 1-631-419-1700
Product Use (for Canada) Emergency Telephone Number
NA 1-631-419-1700
2. Composition of Ingredients
Hazardous Components C.A.S. Number Exposure Limits %
Styrene- Butadiene-Styrene Block Copolymer 9003-55-8 NA <65
Mineral oil 8042-47-5 NA <40
Zinc Stearate 557-05-1 NA <1
Magnesium Carbonate 546-93-0 NA <1
Hydrated Amorphous Silica 63231-67-4 NA <1
Antioxidant/Stabilizers NA NA <1
3. Hazard Identification
Emergency Overview
Appearance & Odor: Solid. Essentially odorless. Health hazards: Polymer product with no unusually emergency concerns.
Physical hazards: The material will burn and should not present an unusual hazard during fires. Avoid smoke from fires.
Routes of Signs and Symptoms Single, Repeated, or Severity (Mild, Acute and Chronic Target
Exposure Lifetime Exposure Moderate, Severe) Health Effect(s) Organ(s)
If polymer dusts are NA NA NA NA
Eye
generated they could
scratch the eyes.
NA NA NA NA NA
Skin
If polymer dusts are NA NA NA NA
Inhalation
generated they could
cause minor irritation to
the respiratory tract.
NA NA NA NA NA
Ingestion
These materials are NA NA NA NA
Other
rubber compounds which
are essentially non-toxic.
Material is not irritating.
Medical Conditions Aggravated by Exposure
NA
Carcinogenicity (IARC, NTP)
NA
Potential Environmental Effects
NA
Page 1 of 5
Part Number(s):
MATERIAL SAFETY DATA SHEET 11-20X-XX
Form WI04-11A Rev. 1
Product Name: KRATON TM D2104 Thermoplastic Rubber Release Date: May 14, 2007
4. First Aid Measures
Routes of Exposure First Aid Instructions Immediate Medical Attention Delayed Effects
Flush eyes with water while NA NA
Eye
holding eyelids open.
If contact with hot material, cool NA NA
Skin
the burn area by flushing with
large amounts of water. Do not
attempt to remove anything from
the burn area or apply burn creams
or ointments. Cover the burn area
loosely with a sterile dressing, if
available.
NA NA NA
Inhalation
NA NA NA
Ingestion
NA NA NA
Other
Note to Physicians (Treatment, Testing, and Monitoring)
NA
5. Fire and Explosion Data
Flashpoint & Method: Flammable (Explosive) Limits in Air Autoignition Temperature Other
掳C / 掳F N LEL: NA UEL: NA NA
NA
Properties Contributing to Flammability Classification
Flame Propagation or Burning
Fire Intensity Health- , Flammability- , Reactivity-
NA
NA NA
Extinguishing Media Extinguishing Media to Avoid
Use water fog, foam, dry chemical or carbon dioxide (CO2) to NA
extinguish flames.
Protection and Procedures for Firefighters
Material will not burn unless preheated. Do not enter confined fire space without full bu7nker gear (helmet with face shield, bunker coats, gloves
and rubber boots), including a positive pressure, NIOSH approved, self-contained breathing apparatus.
Unusual Fire and Explosion Hazards
NA
6. Accidental Release Measures
Containment Techniques
NA
Spill/Leak Clean-Up Procedures and Equipment
Shovel and sweep up or use industrial vacuum cleaner. Avoid generating dust clouds. Place inc container for proper disposal.
Evacuation Procedures
NA
Special Instructions
NA
Reporting Requirements
U.S. regulations may require reporting releases of this material to the environment which exceed the reportable quantity to the national response
center at (800) 424-8802.
Page 2 of 5
Part Number(s):
MATERIAL SAFETY DATA SHEET 11-20X-XX
Form WI04-11A Rev. 1
Product Name: KRATON TM D2104 Thermoplastic Rubber Release Date: May 14, 2007
7. Handling and Storage
Handling Practices and Warnings
Practice good housekeeping. Do not allow product to accumulate in processing area.
Handling: Potentially toxic/irritating fumes may be evolved from heated material. KRATON thermoplastic rubber has a tendency to accumulate
static charge during transport, handling and processing. Reducing the velocity of transport will reduce charging. Static charge buildup can be a
potential fire hazard when used in the presence of volatile or flammable mixtures. For more information, consult the KRATON rubber static
electricity safety bulletin available from your sales representative.
Storage Practices and Warnings
(掳C / 掳F). Avoid vapors from heated material. Adequate ventilation and / or engineering controls must be employed in high temperature processing
to prevent exposure to potentially toxic/ irritating fumes.
8. Exposure Control/Personal Protection
Ventilation Other Engineering Controls
NA The level of protection and types of controls necessary will vary
depending upon potential exposure guidelines. Appropriate measures
include: adequate ventilation and /or engineering controls when material
is heated in processing.
Routes of Entry: Personal Protective Equipment (PPE) for Normal Use: PPE for Emergencies:
PPE selections vary based on potential exposure conditions such as NA
handling practices, concentration and ventilation. Information on the
selection of eye, skin and respiratory protection for use with this material
is provided below.
Eye/Face Chemical goggles, or safety glasses. NA
Skin Use protective clothing which is chemical resistant to this material. NA
Selection of protective clothing depends on potential exposure conditions
and may include gloves, boots, suits and other items. The selection (s)
should take into account such factors as job task, type of exposure ad
durability requirements.
Inhalation If engineering controls do not maintain airborne concentrations to a level NA
which is adequate to protect worker health, an approved respirator must
be worn. Respirator selection, use and maintenance should be in
accordance with the requirements of the OSHA respiratory protection
standard, 29 CFR 1910.134. Types of respirator(s) to be considered in
the selection process include: Air purifying respirator for dusts and mists,
supplied-air respirator.
General Hygiene Considerations and Work Practices
NA
Protective Measures During Repair and Maintenance of Contaminated Equipment
NA
Other Protective Measures and Equipment
NA
9. Physical and Chemical Characteristics
Appearance Odor
Solid. Substance chemical family: Block copolymer. Essentially odorless.
Boiling Point 掳C / 掳F NA
Normal Physical State:
Liquid Gas
Melting Point 掳C / 掳F NA
Solid (Other) Freezing Point 掳C / 掳F NA
Specific Gravity or Density (H20=1) Solubility in Water pH
<1 Negligible. NA
Vapor Pressure (mm Hg @ 20掳C) Vapor Density (AIR= 1) Evaporation Rate (Butyl Acetate = 1)
NA NA NA
Other NA
Page 3 of 5
Part Number(s):
MATERIAL SAFETY DATA SHEET 11-20X-XX
Form WI04-11A Rev. 1
Product Name: KRATON TM D2104 Thermoplastic Rubber Release Date: May 14, 2007
10. Stability and Reactivity Data
Incompatibility (Materials to Avoid)
Avoid contact with strong oxidizing agents. Material contains residual unsaturation which can undergo exothermic oxidative degradation.
Accumulation of product in areas exposed to elevated temperatures for extended periods in air may result in self-heating and auto ignition.
Hazardous Products Produced During Decomposition
At processing temperatures, some degree of thermal degradation will occur. Although highly dependent on temperature and environmental
conditions, a variety of decomposition products may be present ranging from simple hydrocarbons (such as methane and propane) to toxic/irritating
vapors (such as carbon monoxide and dioxide, acrolein, aldehydes and ketones). See handling section.
Hazardous Polymerization? Conditions to Avoid
掳C / 掳F Shell鈥檚 internal guideline is five (5) days at 200 deg F.
May Occur May Not Occur NA
Avoid elevated temperatures for prolonged periods of time
(example: 5 days at 200 deg F).
Stability? Conditions to Avoid
Stable Unstable 掳C / 掳F NA Shell鈥檚 internal guideline is five (5) days at 200 deg F.
Avoid elevated temperatures for prolonged periods of time
(example: 5 days at 200 deg F).
11. Toxicological Information
Toxicity Data, Epidemiology Studies, Carcinogenicity, Neurological Effects, Genetic or Reproductive Effects, or Structure Activity Data
Carcinogenicity: The results of a national toxicology program 2-year inhalation study with talc indicated some evidence of carcinogenic activity in
the adrenal gland of male rats and clear evidence of carcinogenicity in mice. The female rat lung tumor is likely a secondary effect due to high
pulmonary overload and its associated chronic toxicity. The male adrenal effect is not likely a direct effect of talc particulates.
Other information: Elastomers are high molecular weight polymers which all evidence indicates are biologically inactive.
12. Ecological Information
Toxicity, Environmental Fate, Physical/Chemical Data, or Other Data Supporting Environmental Hazard Statements
This section will be updated as ecological reviews are completed.
13. Disposal Considerations
Regulations
General recommendations: If this material becomes a waste, it would not be a hazardous waste by RCRA criteria (40CFR 261). Place in an
appropriate disposal facility in compliance with local regulations.
Properties (Physical/Chemical) Affecting Disposal
NA
14. Transport Information
Regulated for shipping? Proper Shipping Name Packing Group
KRATON TM D2104 Thermoplastic Rubber NA
Yes No NA
Hazard Class Identification Number
Do changes in quantity, packaging, or shipment method change product classification?
NA NA
Yes No NA
Other
This material is not subject to DOT regulations under 49 CFR parts 171-180.
Page 4 of 5
Part Number(s):
MATERIAL SAFETY DATA SHEET 11-20X-XX
Form WI04-11A Rev. 1
Product Name: KRATON TM D2104 Thermoplastic Rubber Release Date: May 14, 2007
15. Regulatory Information
Federal Regulations
Federal Regulatory Status: Comprehensive Environmental Release, Compensation & Liability Act (CERCLA): Zinc RQ 1000 lbs reportable spill =
418667 lbs or 49978 gal.
SARA Toxic Release (TRI) (313): Zinc (Fume of dust)
Toxic Substances Control Act (TSCA) Inventory status: Component (s) of this material is (are) listed on the EPA / TSCA inventory of chemical
substances.
State Regulatory Status: This material is not regulated by California Prop 65, New Jersey right-to0know chemical list of Pennsylvania right-to-know
chemical list.
International Regulations
NA
Other
NA
16. Other Information
Supplier Number: 25/ 11 Supplier Release: June 1 , 2000
N/A = not applicable. NA = not available, N/E = not established. N/D = not determined.
Page 5 of 5
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