Part Number(s):
MATERIAL SAFETY DATA SHEET 17-222-11
Form WI04-11A Rev. 1
Product Name: TRACING PAPER TABLET Release Date: February 13, 2006
1. Product and Company Identification
Trade Name & Synonyms MSDS Code Number
Grafix acetate Refer to part number
Chemical Name Manufacture / Distributor
Cellulose Diacetate GAC International Inc.
C.A.S. Number Address
NA 355 Knickerbocker Ave.
Bohemia, NY USA 11716
Grades or Minor Variant Identities Information Telephone Number
NA 1-631-419-1700
Product Use (for Canada) Emergency Telephone Number
NA 1-631-419-1700
2. Composition of Ingredients
Hazardous Components C.A.S. Number Exposure Limits %
A flexible packaging material derived largely from natural resources. NA NA NA
Materials of this type have been widely used for many years, with no
adverse reactions reported. The principle components, cellulose
diacetate(CA) and diethylphthalate(DEP), have not changed over this period.
3. Hazard Identification
Emergency Overview
Similar safety hazards to paper.
Routes of Signs and Symptoms Single, Repeated, or Severity (Mild, Acute and Chronic Target
Exposure Lifetime Exposure Moderate, Severe) Health Effect(s) Organ(s)
NA NA NA NA NA
Eye
NA NA NA NA NA
Skin
NA NA NA NA NA
Inhalation
NA NA NA NA NA
Ingestion
NA NA NA NA NA
Other
Medical Conditions Aggravated by Exposure
NA
Carcinogenicity (IARC, NTP)
NA
Potential Environmental Effects
NA
4. First Aid Measures
Routes of Exposure First Aid Instructions Immediate Medical Attention Delayed Effects
No adverse effects anticipated. NA NA
Eye
No adverse effects anticipated. NA NA
Skin
N/A N/A N/A
Inhalation
No adverse effects anticipated NA No adverse effects anticipated on
Ingestion
prolonged exposure.
NA NA NA
Other
Note to Physicians (Treatment, Testing, and Monitoring)
NA
Page 1 of 4
Part Number(s):
MATERIAL SAFETY DATA SHEET 17-222-11
Form WI04-11A Rev. 1
Product Name: TRACING PAPER TABLET Release Date: February 13, 2006
5. Fire and Explosion Data
Flashpoint & Method: Flammable (Explosive) Limits in Air Autoignition Temperature Other
掳C / 掳F NA LEL: NA UEL: NA NA
Potential hazards: Clear,
Properties Contributing to Flammability Classification smooth flat sheets;(similar
Flame Propagation or Burning
Fire Intensity safety hazards to paper)
Health-, Flammability- , Reactivity-NA
NA
NA
Extinguishing Media Extinguishing Media to Avoid
Water, carbon dioxide, foam, dry powder, sand.
Protection and Procedures for Firefighters
As with any fire, use breathing apparatus in presence of smoke/ fumes.
Unusual Fire and Explosion Hazards
Supports combustion. Flame retardant formulations are available.
6. Accidental Release Measures
Containment Techniques
NA
Spill/Leak Clean-Up Procedures and Equipment
Loose waste and scrap material should be swept up for safe disposal.
Evacuation Procedures
NA
Special Instructions
NA
Reporting Requirements
NA
7. Handling and Storage
Handling Practices and Warnings
When moving pallets of material, always ensure the 鈥渇orks鈥? of the forklift truck are long enough to cover the complete base of the pallet. This will
ensure the even distribution of the forces throughout the packaging. Avoid damage to the edge of the roll. Never stand rolls on end, avoid placing or
rolling rolls on the floor. Handle rolls using mandrels inserted into the core. Store by suspending on racks using mandrels. Do not hammer mandrels
into the core.
Storage Practices and Warnings
Decades of reliable performance have demonstrated that Grafix cellulose diacetate film can be used in its many applications with the confidence
that the product provides a consistently high level of quality. However, cellulose diacetate, like all polymers, must be stored appropriately to
preserve its performance. Avoid wide variations in temperature and humidity in the storeroom. Temperatures between 15掳C - 23掳C (59掳C -73掳F)
and a relative humidity between 40 % - 65 % are the best conditions. Avoid exposure to ketone and ester solvent vapors such as acetone or ethyl
acetate. Do not store in bright sunlight.
Shelf life: As a general rule, Grafix acetate should be processed promptly. We would recommend that customers process Grafix acetate within 12
months of its receipt. Particularly for hot and / or humid climates. It may be advisable to convert Grafix acetate within 6 or even 3 months of receipt.
Some films will need to be processed in shorter periods to avoid problems. In particular, thicker films over 100 碌 may suffer unidirectional curl
(鈥渞oll set鈥?) after even a few months storage as rolls. For applications where this might be critical, thicker films should be sheeted as soon as possible
after receipt. In case of problems after such periods, Grafix reserves the right not to offer compensation in respect of problems arising with film
quality.
Page 2 of 4
Part Number(s):
MATERIAL SAFETY DATA SHEET 17-222-11
Form WI04-11A Rev. 1
Product Name: TRACING PAPER TABLET Release Date: February 13, 2006
8. Exposure Control/Personal Protection
Ventilation Other Engineering Controls
Fume extraction and fresh air circulation is recommended where Special requirements: None
solvents are being used during lamination or other finishing processes.
Routes of Entry: Personal Protective Equipment (PPE) for Normal Use: PPE for Emergencies:
Eye/Face NA NA
Skin NA NA
Inhalation NA NA
General Hygiene Considerations and Work Practices
NA
Protective Measures During Repair and Maintenance of Contaminated Equipment NA
NA
Other Protective Measures and Equipment
NA
9. Physical and Chemical Characteristics
Appearance Odor
Clear smooth flat sheets or rolled film. Practically odorless.
Boiling Point 掳C / 掳F NA
Normal Physical State:
Liquid Gas
Melting Point 掳C / 掳F NA
Solid (Other) Freezing Point 掳C / 掳F NA
Specific Gravity or Density (H20=1) Solubility in Water pH
1.31 卤 0.01. Insoluble NA
Vapor Pressure (mm Hg @ 20掳C) Vapor Density (AIR= 1) Evaporation Rate (Butyl Acetate = 1)
NA NA NA
Other
Flow temperature: N/A Viscosity: N/ A Equilibrium water content Circa 2 % (in air @ temp. 23掳C, RH 50 %)
10. Stability and Reactivity Data
Incompatibility (Materials to Avoid)
Solvent resistance: Low resistance to ketones and esters. Attacked by moderate to concentrated strong acids and bases. Resistant to non-polar
solvents.
Hazardous Products Produced During Decomposition
Carbon monoxide, carbon dioxide, acetic acid, water.
Hazardous Polymerization? Conditions to Avoid
掳C / 掳F NA
May Occur May Not Occur
Stability? Conditions to Avoid
Stable Unstable Thermal stability: Decomposes circa 250掳C / 掳F
11. Toxicological Information
Toxicity Data, Epidemiology Studies, Carcinogenicity, Neurological Effects, Genetic or Reproductive Effects, or Structure Activity Data
Material of this type has been in use for many years. There have been no chronic, short or long term effect reported. Specific toxicological tests on
Grafix acetate films h ve not been conducted. However, practical experience and literature surveys for the key components reveal the following
information:
INHALATION: Not applicable. INGESTION /ORAL TOXICITY: (LD50): 8600 mg / kg (rat) for cellulose diacetate 9000 mg / kg (rat) for
DEP. SKIN SENSITIVITY: No adverse effects anticipated. EYE CONTACT: Normal discomfort resulting from foreign bodies in the eye.
Page 3 of 4
Part Number(s):
MATERIAL SAFETY DATA SHEET 17-222-11
Form WI04-11A Rev. 1
Product Name: TRACING PAPER TABLET Release Date: February 13, 2006
12. Ecological Information
Toxicity, Environmental Fate, Physical/Chemical Data, or Other Data Supporting Environmental Hazard Statements
Raw materials and the manufacturing process. Over 80 % of Grafix film is cellulose diacetate. This is derived from natural cellulose sources, cotton
linters and wood pulp, from managed forests predominately in North America. We use no hardwoods from endangered rain forests. MOBILITY
AND DEGRADADABILITY: Biodegradation studies indicate around 15 % ( by wt ) of grafix film is lost over 28 days. This is thought to be
largely due to DEP biodegradation. The two primary constituents of grafix film (cellulose diacetate and DEP) have long since been recognized as
biodegradable. RECYCLING: Grafix acetate is suitable for recycling in various forms.
13. Disposal Considerations
Regulations
Grafix acetate can be recycled, incinerated or land filled. There are no known dangers resulting from these methods of
disposal. Incineration produces no toxic by- products.
Properties (Physical/Chemical) Affecting Disposal
NA
14. Transport Information
Regulated for shipping? Proper Shipping Name Packing Group
Tracing paper tablet NA
Yes No
Hazard Class Identification Number
Do changes in quantity, packaging, or shipment method change product classification?
NA NA
Yes No
Other
The material is not regulated for transport and shipping purposes. Materials packed on pallets should not be broken
down during shipment.
15. Regulatory Information
Federal Regulations NA
International Regulations NA
Other
FOOD CONTACT 鈥? Grafix acetate films comply with US FDA Regulations as set out in CFR 21, parts 170 鈥? 199.
Grafix acetate films comply with EC directives 90 /128 / EEC, 92 / 39 / EEC, 93 /9 / EEC, 95 /3 / EEC, and 96 / 11 /
EEC and are classified as being suitable for food contact applications. HEAVY METALS: No heavy metals are used
in the manufacture of Grafix acetate. The resulting film complies with U.S - CONEG legislation, and European
standard EN 71-3, the packaging (Essential requirements) Regulations (1998).
16. Other Information
Supplier Number: 24 / 17 Supplier Release: May 2003
N/A = not applicable. NA = not available, N/E = not established. N/D = not determined.
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