Part Number(s):
MATERIAL SAFETY DATA SHEET 17-123-45
Form WI04-11A Rev. 1
Product Name: Ortho Ice 10 0z (Chill Spray) Release Date: April 10, 2007
1. Product and Company Identification
Trade Name & Synonyms MSDS Code Number
Essix freeze spray Refer to part number
Chemical Name Manufacture / Distributor
NA GAC International Inc.
C.A.S. Number Address
811-97-2 355 Knickerbocker Ave.
Bohemia, NY USA 11716
Grades or Minor Variant Identities Information Telephone Number
NA 1-631-419-1700
Product Use (for Canada) Emergency Telephone Number
NA 1-631-419-1700
2. Composition of Ingredients
Hazardous Components C.A.S. Number Exposure Limits %
1,1, 1,2- Tetrafluoroethane 811-97-2 NA 100
OSHA Hazardous components (29 CFR 1910.1200) NA 8 hours TWA NA
(PPM)
OSHA: NA NA NA
PELACGIH:
TLV Supplier:
NIF: 1000
3. Hazard Identification
Emergency Overview
NA
Single,
Repeated, or
Routes of Signs and Symptoms Lifetime Severity (Mild, Acute and Chronic Target
Exposure
Exposure Moderate, Severe) Health Effect(s) Organ(s)
Liquid can cause slight, temporary NA NA NA NA
Eye
irritation with slight temporary corneal
injury. Vapors can irritate eyes.
Prolonged or repeated contact with NA NA NA NA
Skin
liquid can cause freezing of skin
tissues, defatting, and dermatitis.
Major potential route of exposure. NA NA NA NA
Inhalation
Minimal effects observed below 1,000
ppm. Dizziness, drowsiness, and throat
irritation possible at levels above 1,000
ppm. Unconsciousness and death at
levels above 10,000 ppm. Blood
pressure, depression, cardiac
sensitization, and ventricular
arrhythmia can result from exposure to
near-anesthetic levels.
Single dose toxicity is low to moderate. NA NA NA NA
Ingestion
If vomiting occurs the liquid can be
aspirate into lungs, which can cause
chemical pneumonia and systemic
effects. Human psychotropic,
gastrointestinal and central nervous
system effects possible.
NA NA NA NA NA
Other
Medical Conditions Aggravated by Exposure
NA
Carcinogenicity (IARC, NTP)
NA
Potential Environmental Effects
NA
Page 1 of 5
Part Number(s):
MATERIAL SAFETY DATA SHEET 17-123-45
Form WI04-11A Rev. 1
Product Name: Ortho Ice 10 0z (Chill Spray) Release Date: April 10, 2007
4. First Aid Measures
Routes of Exposure First Aid Instructions Immediate Medical Attention Delayed Effects
Flush eyes with large amounts of If irritation persists, get medical NA
Eye
water for 15 minutes or until attention.
irritation subside.
Remove contaminated clothing If irritation persists, seek NA
Skin
(including shoes) and wash before medical attention.
reuse. Flush with large amounts of
water. Use soap if available.
Move to fresh air in case of Call for prompt medical NA
Inhalation
accidental inhalation of vapors. If attention.
victim has stopped breathing, give
artificial respiration.
Do not induce vomiting unless Seek medical attention NA
Ingestion
directed by physician. If conscious immediately.
and alert, give two glasses of
water.
NA NA NA
Other
Note to Physicians (Treatment, Testing, and Monitoring)
NA
5. Fire and Explosion Data
Flashpoint & Method: Flammable (Explosive) Limits in Air Autoignition Temperature Other
掳C / 掳F None TCC method LEL: N/A UEL: N/A NA
NA
Properties Contributing to Flammability Classification
Flame Propagation or Burning
Fire Intensity Health-1 , Flammability-1 , Reactivity-
Hazardous combustion
NA 1
products: Smoke, fumes and
oxides of carbon.
Extinguishing Media Extinguishing Media to Avoid
Fire fighting equipment: Water, foam, dry chemical, and carbon NA
dioxide.
Protection and Procedures for Firefighters
Fire fighters should wear self-contained, positive 鈥? pressure breathing apparatus and avoid skin contact.
Unusual Fire and Explosion Hazards
General hazard: Aerosol cans may erupt with force at temperatures about 120 degrees F.
6. Accidental Release Measures
Containment Techniques
NA
Spill/Leak Clean-Up Procedures and Equipment
Land spill: Evacuate area. Ventilate area well and avoid breathing vapors. Vapor concentration will be highest along floor and in low-lying areas.
Pick up liquid on suitable absorbent and store in sealed containers.
Evacuation Procedures
NA
Special Instructions
NA
Reporting Requirements
NA
Page 2 of 5
Part Number(s):
MATERIAL SAFETY DATA SHEET 17-123-45
Form WI04-11A Rev. 1
Product Name: Ortho Ice 10 0z (Chill Spray) Release Date: April 10, 2007
7. Handling and Storage
Handling Practices and Warnings
Keep container closed when not in use.
Storage Practices and Warnings
(掳C / 掳F). Storage temperature: Ambient. Storage pressure: Atmospheric. Store in cool, well-ventilated place out of direct sunlight and away from
incompatible materials. (See stability and reactivity data) Follow all MSDS and label warnings even after container is emptied.
8. Exposure Control/Personal Protection
Ventilation Other Engineering Controls
NA
Local exhaust ventilation acceptable.
Routes of Entry: Personal Protective Equipment (PPE) for Normal Use: PPE for Emergencies:
Eye/Face Safety glasses NA
Skin Gloves recommended- solvex, butyl, natural latex, neoprene, Buna, NA
cotton jersey.
Inhalation Respirator: If concentrations are over the exposure limit and are known, NA
air-purifying respirator with organic vapor cartridges may be acceptable.
Refer to cartridges for acceptable levels. If concentrations are over
exposure limit and are unknown, use a supplier air respirator.
General Hygiene Considerations and Work Practices
NA
Protective Measures During Repair and Maintenance of Contaminated Equipment
NA
Other Protective Measures and Equipment
NA
9. Physical and Chemical Characteristics
Appearance Odor
Clear water-white liquid Low odor
Boiling Point -16 掳C / -27 掳F
Normal Physical State:
Liquid Gas
Melting Point 掳C / 掳F NA
Solid (Other) Freezing Point 掳C / 掳F NIF
Specific Gravity or Density (H20=1) Solubility in Water pH
1.202 0 7-8
Vapor Pressure (mm Hg @ 20掳C) Vapor Density (AIR= 1) Evaporation Rate (Butyl Acetate = 1)
NA 3.0 >1
Other
% volatile: 100. % solids: 0. Viscosity: N/A. Molecular weight: N/A Non-exempt VOC (g/l): 0
10. Stability and Reactivity Data
Incompatibility (Materials to Avoid)
Contact with open flame, heat. Reactive alkali metals, strong acids and bases.
Hazardous Products Produced During Decomposition
Hydrogen fluoride, carbon dioxide, and carbon monoxide.
Hazardous Polymerization? Conditions to Avoid
掳C / 掳F NA
May Occur May Not Occur NA
Stability? Conditions to Avoid
Stable Unstable 掳C / 掳F NA
Page 3 of 5
Part Number(s):
MATERIAL SAFETY DATA SHEET 17-123-45
Form WI04-11A Rev. 1
Product Name: Ortho Ice 10 0z (Chill Spray) Release Date: April 10, 2007
11. Toxicological Information
Toxicity Data, Epidemiology Studies, Carcinogenicity, Neurological Effects, Genetic or Reproductive Effects, or Structure Activity Data
Result of component toxicity test performed: Information not available.
Human experience: Information not available.
This product does not contain any compounds listed by NTC or IARC or regulated by OSHA as a carcinogen.
12. Ecological Information
Toxicity, Environmental Fate, Physical/Chemical Data, or Other Data Supporting Environmental Hazard Statements
Further information: Information not available.
13. Disposal Considerations
Regulations
RCRA 40 CFR 261 Classification: Federal, state and local laws governing disposal of materials can differ. Ensure
proper disposal compliance with proper authorities before disposal.
Properties (Physical/Chemical) Affecting Disposal
NA
14. Transport Information
Regulated for shipping? Proper Shipping Name Packing Group
NA N/A
Yes No NA
Hazard Class Identification Number
Do changes in quantity, packaging, or shipment method change product classification?
N/A UN Number: N/A
Yes No NA
Other
U.S DOT Information: Proper shipping name: Consumer commodity ORM- D
Hazard class: N/A
Packaging group: N/A
UN number: N/A
Limitations: Must place consumer commodity ORM-D on box.
IATA: Proper shipping name: Consumer commodity ID8000.
Hazard class: N/A
UN number: ID8000
Limitations: A Copy of the DOT-E 10232 must be attached to the shipment. CARGO AIRCRAFT ONLY.
Domestic shipments only. When shipping international, contact tech spray shipping department.
IMO: Proper shipping name: Aerosols class: 2.2
UN number: UN1950
Packaging group: N/A
EMS: 2-13
MFAG: 350
Marine pollutant: N/A
Canadian TDG: N/A
IMDG Page: 2102
Limitations: Must have Non-flammable label
Page 4 of 5
Part Number(s):
MATERIAL SAFETY DATA SHEET 17-123-45
Form WI04-11A Rev. 1
Product Name: Ortho Ice 10 0z (Chill Spray) Release Date: April 10, 2007
15. Regulatory Information
Federal Regulations
United states federal regulations: MSDS complies with OSHA hazard communication rule, 29CFR 1910.1200.
CERCLA / SUPERFUND, 40 CFR 119,302: None of the chemicals are superfund hazards.
SARA Superfund and reauthorization act of 1986 title II sections 302, 311, 312 and 313: Section 302- Extremely hazardous
substances (40CFR): None of the chemicals are section 302 hazards.
Section 311/312: MSDS Requirements (40 CFR 370): By our evaluation this product is hazardous. It should be reported under the
following EPA HAZARD: Immediate (acute health hazard).
Section 313- List of toxic chemicals (40 CFR 372): This product contains the following chemicals (at levels of 1% or greater)
which are found on the 313 list of toxic chemicals: None of the chemicals are 313 toxic chemicals.
Toxic substance control act (TSCA): All substances are TSCA listed.
Resource conservation and recovery act (RCRA 40 CFR 261): Subpart C & D: Refer to section 11 for RCRA classification.
Federal water pollution control act, clean water act, 40 CFR 401.15 (Formerly Section 307), 40 CFR 116 (Formerly section
311): This product contains the following chemicals which are listed.
State regulations: Clean air act: No information.
California proposition 65: This product contains the following ingredients which appear on the California proposition 65 list:
None of the chemicals are on the proposition 65 list.
International Regulations
Canada WHMIS: NIF
Europe EINECS numbers: Tetrafluoroethane; 811-97-2
Other
Label information: European risk and safety phrases: s2, s23, s24/25, s51.
European symbols needed: None.
Canadian WHMIS Symbols: NIF
NFPA Hazard rating: 1- Fire; 1-Health; 1- Reactivity.
Revision dates, sections, revised by: 27-Jul-94, converted to ANSI standard, An. Riffel; 01-Aug 96, Updated shipping
information, L. Humphrey; 07-Oct-96, updated section 11, B. Riffel; 14-Jan 97, Updated shipping information, R.
Prichard.
16. Other Information
Supplier Number: 40/17 Supplier Release: NA
N/A = not applicable. NA = not available, N/E = not established. N/D = not determined.
Page 5 of 5
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