GP-04-Adh盲siv_Liquid ALGINAT-03-05_engl.
EC Safety Data Sheet 91/155/EWG
1. Commercial product name and supplier
Commercial product name: Adhesive Liquid ALGINATE 9002480
Producer: Henry Schein Inc, Melville, 11747 NY USA
Henry Schein UK Holdings Ltd
Gillingham ME8 0SB
Tel.: ++44(0)1634/ 878750
TOX emergency number: Landesberatungsstelle f眉r Vergiftungserscheinungen und Embryonal-
Toxikologie Pulsstra脽e 3-7, D-14059 Berlin
Chemtrec +1 703 527 3887 Tel. ++49 (0)30 19240;
Telefax: ++49 (0)30 32680721
2. Composition/information on ingredients
Hazardous components:
CAS-No. EINECS-No. EG-Ind.-No. Label R-Phrases %
F
Ethanole 64-17-5 200-578-6 603-005-00-5 F 11 40-70
Leichtentz眉ndlich
3. Hazard identification
F
R 11 Highly flammable.
Leichtentz眉ndlich
Specific hazards:
4. First aid measures
General information:
Remove affected person from the danger area and lay down. Change out of contaminated, saturated
clothing.
On contact with eyes:
On contact with the eyes, rinse immediately with plenty of water. Seek ophthalmological advice.
On contact with skin:
On contact with the skin, wash off immediately with soap and water. If skin irritation persists, seek
medical advice.
If swallowed:
After Ingestion drink plenty of water and call a physician immediately (show packaging or label).
On Inhalation:
Provide with fresh air. In case of inhalation, affected person should be moved into fresh air and kept still
5. Fire-fighting measures
Suitable extinguishing media:
Foam, powder, carbon dioxide, water fog
extinguishing media to avoid:
Do not use direct water stream
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EC Safety Data Sheet 91/155/EWG
6. Accidental release measures
Personal precautions:
Avoid skin contact with liquid.
Environmental precautions:
Keep away from sources of ignition. No smoking - Explosion hazards! Do not allow to enter
drains/surface waters/groundwater.
Methods for cleaning up / taking up:
Suitable material for picking up: Universal binder, Sand, Kieselguhr. Treat recovered material as
prescribed in: Disposal considerations.
Additional information:
Take precautionary measures against static discharges.
7. Handling and storage
Hints for safe handling:
Avoid the following: Skin and eye contact and inhalation of substance. Keep container closed.
Hints for protection against fire and explosion
Protect from sunlight and do not expose to temperatures exceeding 50掳C.
Storage:
Product is highly flammable. Store in cool, dry well ventilated area away from sources of ignition and
heat. Do not smoke. Take precautionary measures against static discharges.
Storage class:
3A
8. Exposure limitation and personal protective equipment
Constituents with occupational exposure limits rsp. biological occupational exposure limits requiring
monitoring:
Ethanole CAS-No. : 64-17-5
Exposure limit type:
MAK (TRGS 900): 1000ml/m3 1900mg/m3 (Ethanole)
Personal protection equipment
Respiratory protection:
Respiratory protection necessary at exposure limit excess. Filtering device (full mask or mouthpiece)
with filter A2.
Hand protection:
Hand protection is necessary. Suitable materials is Butyl (butyl rubber) 0,5mm. Breakthrough time
(maximal wear duration at permanent contact:): 480min.
Eye protection:
Eye glasses with side protection.
Protective clothing:
Labor smock.
General health and safety measures:
Usual hygienic measures are necessary. When using, do not drink, eat or smoke. Remove contaminated,
saturated clothing.
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EC Safety Data Sheet 91/155/EWG
9. Physical and chemical properties
Appearance: viscous liquid
Colour: red
Odour: alcoholic
Boiling point: 78掳C
Ignition temperature: 425掳C (Ethanole)
Flashpoint: 12掳C (Ethanole)
Explosion limits: Lower: 3,5 Vol.% Upper: 15,0 Vol.% (Ethanole)
Vapourpressure: 60 mbar at 20掳C (Ethanole)
Solubility in water: soluble
pH-Value: not applicable
10. Stability and reactivity
Conditions to avoid:
When heated:
Do not expose to temperatures exceeding 50掳C,Formation of explosive mixtures with air.
Materials to avoid:
Strong acids and bases.
Hazardous decomposition products:
No hazardous decomposition products if stored and handled as prescribed.
Further information:
Highly flammable product. Avoid ignition sources such as flames or spark producing equipment.
11. Toxicological information
Acute toxicity:
LD50 oral 7060 mg/kg (rat, Ethanole)
After eye contact:
Not irritant.
After skin contact:
Not irritant. May cause frostbite.
After inhalation:
Not irritant.
Sensitization:
Not sensitizing.
12. Ecological information
Information about elimination (persistence and degradation)
Abbiotic degradation in air.
Aquatic toxicity:
LC50 (Leuc. Idus) 8150 mg/l (Ethanole)
EC0 (Pseudomonas putida) 6500 mg/l (Ethanole)
Further ecological information:
Will not pollute the effluent provided it is processed correctly. Do not allow to enter drains/surface
waters/groundwater.
German 鈥濿assergef盲hrdungsklasse鈥? WGK 0.
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13. Disposal considerations
Disposal / Waste (product):
080409 waste adhesives and sealants containing organic solvents or other dangerous substances.
Packages:
Dispose of in compliance with official regulations.
14. Transport information
Transport at land (GGVS/GGVE)
GGVS/E Class: 3
Kemler-No: 33
UN-No: 1133
Name of substance: Adhesives, containing a flammable liquid
Packing group: II
Transport at sea (IMDG/GGVSee):
IMDG/GGVSee-Class: 3.2
IMDG-Code page: 3174
UN-No: 1133
EMS-Nummer: 3-05
MFAG: 305
Air transport (ICAO-TI and IATA-DGR):
ICAO/IATA-Class: 3
UN/ID-No: 1133
Packing group: II
Name of substance: Adhesives, containing a flammable liquid
15. Regulatory information
This product requires classification according to the criteria of the EC and the 鈥濭efahrstoffverordnung鈥?
Labelling
F
F Highly flammable
Leichtentz眉ndlich
Risk phrases:
R 11 Highly flammable
Safety phrases:
S 9 Keep container in a well-ventilated place.
S 16 Keep away from sources of ignition 鈥? No smoking.
S 33 Take precautionary measures against static discharges.
16. Other information
The above mentioned date correspond to our present state of knowledge and experience. The safety data
sheet serves as description of the products in regard to necessary safety measures. The indications have
not the meaning of guarantees on properties.
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