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MSDS Material Safety Data Sheet
CAS

7553-56-2
7681-11-0
7732-18-5

File Name: reagents_com---7-21780.asp
                      MATERIAL SAFETY DATA SHEET




REAGENTS, INC. CHEM-TREC EMERGENCY NUMBER
704/554-7474 1/800/424-9300
P.O. BOX 240746 DATE PREPARED
CHARLOTTE, NC 28224 September 18, 2000

______________________________________________________________
___
______________________________________________________________
___

SECTION I - GENERAL INFORMATION

Chemical Name: Iodine Solution, Lugol's
Catalog Number: 7-21780
Formula: I2/KI/H2O
DOT Shipping Information: Not regulated.


SECTION II - HAZARDOUS INGREDIENTS
Hazardous Component/C.A.S. No. OSHA PEL ACGIH TLV
%
Iodine(CAS 7553-56-2) 0.1ppm TWA 0.1ppm TWA
1%

(w/v)
Potassium Iodide(CAS 7681-11-0) None Established
2%

(w/v)
Water, Deionized(CAS 7732-18-5) None Established


SECTION III - PHYSICAL DATA
Boiling Point(at 760 mm Hg): Approx. 100
Melting Point(oC): No information found
Specific Gravity: No information found
Vapor Pressure(mm Hg): No information found
Vapor density(Air=1): No information found
Evaporation Rate(n-BuAc=1): 0.4(Water)
Solubility in Water: Complete
Appearance and Odor: Dark red-brown liquid with
characteristic iodine odor.




1
SECTION IV - FIRE AND EXPLOSION HAZARD DATA
Flash Point: N/A
Flammable Limits: N/A LEL %--- UEL%---
Extinguishing Media: Use any suitable for extinguishing
surrounding fire.
Fire Fighting Procedures: Wear full protective clothing and
NIOSH approved self-contained breathing apparatus operated
in the pressure demand or other positive pressure mode.
Fire and Explosion Hazards: Not combustible. However,
oxidizers in contact with reducing agents or combustible
material may cause ignition.



SECTION V - REACTIVITY DATA
Stability: Unstable: Stable: X
Conditions to Avoid: Solution may discolor on exposure to
light.
Incompatibility(Materials to avoid): Acetaldehyde,
acetylene, ammonium hydroxide, ammonia, strong acids,
powdered metals, alkali metals and strong reducing agents.
Hazardous Decomposition or Byproducts: May emit toxic fumes
of iodine.
Hazardous Polymerization: May Occur Will Not Occur X
Conditions to Avoid: N/A




2
SECTION VI - HEALTH HAZARD DATA(ACUTE AND CHRONIC
Routes of Entry: Inhalation-Yes Skin-Yes Ingestion-Yes
Health Hazards(Acute and Chronic):
Inhalation-Symptoms from exposure to iodine solutions are
not expected to be as severe as exposure to concentrated
iodine vapors, where symptoms may include severe irritation
to the mucous membranes and respiratory tract, excessive
tearing, sore throat, headache, and delayed pulmonary edema.
Ingestion-Large oral doses may cause systematic iodine
poisoning which may include abdominal pain, diarrhea, fever,
vomiting, stupor and shock.
Skin Contact-Symptoms are not expected to be as severe as
exposure to concentrated solutions, where symptoms may
include severe skin irritation resembling thermal burns.
Eye Contact-Splashes may cause irritation with redness and
pain.
Carcinogenicity: NTP-No IARC Monographs-No OSHA-No
Signs and Symptoms of Exposure: See Health Hazards above.
Medical Conditions Generally Aggravated by Exposure:
Allergic sensitization may occur from prolonged or repeated
exposure to iodine. Chronic iodine overdoses have produced
iodism. Headache, fever, sneezing, salivation and skin
rashes may occur.
Emergency and First Aid Procedures:
Inhalation-Remove to fresh air. Get medical attention for an
breathing difficulty.
Ingestion-If swallowed, induce vomiting immediately by
giving two glasses of water and sticking finger down throat.
Call a
physician immediately. Never give anything by mouth to an
unconscious person.
Skin Exposure-Wash exposed area with soap and water. get
medical attention if irritation develops.
Eye Exposure-Wash eyes with plenty of water for at least 15
minutes. Call a physician.




3
SECTION VII - PRECAUTIONS FOR SAFE HANDLING AND USE
Steps to Be Taken in Case Material is Released or Spilled:
Clean-up personnel require protective clothing and
respiratory protection from vapors. Dike and cover spill
with soda ash or lime. Cover large spills with earth, sand
or inert solid. Collect or flush to sump for disposal.
Waste Disposal Method: Neutralized waste may be
containerized and disposed in a RCRA approved facility.
Ensure compliance with local, state and federal regulations.
Precautions to Be Taken in Handling and Storing: Keep in
tightly closed containers, stored in a cool, dry, ventilated
area. Protect against physical damage. Store separately from
reactive or combustible materials and out of direct
sunlight.
Other Precautions: To be used by qualified personnel only.


SECTION VIII - SPECIAL PROTECTION INFORMATION
Respiratory Protection(Specify Type): NIOSH approved self-
contained breathing apparatus in areas where TLV is
exceeded.
Ventilation: Local Exhaust- X Special---
Mechanical(General)- X Other---
Protective Gloves: Rubber
Eye Protection: Chemical splash goggles
Other Protective Clothing or Equipment: Apron
Work/Hygienic Practices: Clean up spills immediately. Do not
eat, smoke or drink in area of solution use.


DISCLAIMER OF LIABILITY
The information in this MSDS was obtained from sources which
we believe are reliable. HOWEVER, THE INFORMATION IS
PROVIDED WITHOUT REPRESENTATION OF WARRANTY, EXPRESS OR
IMPLIED, REGARDING ITS ACCURACY OR CORRECTNESS.

The conditions or methods of handling, storage use and
disposal of this product are beyond our control and may be
beyond our knowledge. FOR THIS AND OTHER REASONS, WE DO NOT
ASSUME RESPONSIBILITY, DIRECTLY OR INDIRECTLY, AND EXPRESSLY
DISCLAIM LIABILITY OR LOSS, DAMAGE OR EXPENSE ARISING OUT OF
OR IN ANY WAY CONNECTED WITH THE HANDLING, STORAGE, USE OR
DISPOSAL OF THE PRODUCT OR THE INFORMATION FURNISHED
THEREWITH.




4

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