ROCOL EASYLINE ULTIMATE ALL COLOURS
Chemwatch Material Safety Data Sheet
Issue Date: 13-Nov-2007 CHEMWATCH 61611
C9317EC Version No:4
CD 2007/3 Page 1 of 7
Section 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME
ROCOL EASYLINE ULTIMATE ALL COLOURS
SYNONYMS
"line-marking spray paint"
PROPER SHIPPING NAME
AEROSOLS
PRODUCT USE
Application is by spray atomisation from a hand held aerosol pack. Line marking paint.
SUPPLIER
Company: ITW POLYMERS & FLUID (NZ) Company: ITW POLYMERS & FLUIDS
Address: Address:
UNIT 2/ 38 TRUEGOOD DRIVE 100 Hassall Street
EAST TAMAKI Wetherill Park
AUCKLAND, 2013 NSW, 2164
NZL AUS
Telephone: +64 9 272 1945 Telephone: +61 2 9757 8800
Emergency Tel: +64 9 273 6489 Emergency Tel: +61 2 9757 8800
Fax: +64 9 272 1945 Fax: +61 2 9757 3855
Section 2 - HAZARDS IDENTIFICATION
STATEMENT OF HAZARDOUS NATURE
DANGEROUS GOODS. NON-HAZARDOUS SUBSTANCE. According to the Criteria of the ADG Code and NOHSC.
POISONS SCHEDULE
S5
RISK SAFETY
Extremely flammable. Keep away from sources of ignition. No
smoking.
Vapours may cause drowsiness and dizziness. Do not breathe gas/fumes/vapour/spray.
Use only in well ventilated areas.
Take off immediately all contaminated
clothing.
In case of contact with eyes rinse with
plenty of water and contact Doctor or
Poisons Information Centre.
This material and its container must be
disposed of in a safe way.
Section 3 - COMPOSITION / INFORMATION ON INGREDIENTS
NAME CAS RN %
acetone 67-64-1 10-30
xylene 1330-20-7 10-30
propylene glycol monomethyl ether 107-98-2 1-10
dimethyl ether 115-10-6 10-30
Section 4 - FIRST AID MEASURES
SWALLOWED
Not considered a normal route of entry.
For advice, contact a Poisons Information Centre or a doctor.
- If swallowed do NOT induce vomiting.
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ROCOL EASYLINE ULTIMATE ALL COLOURS
Chemwatch Material Safety Data Sheet
Issue Date: 13-Nov-2007 CHEMWATCH 61611
C9317EC Version No:4
CD 2007/3 Page 2 of 7
Section 4 - FIRST AID MEASURES
- If vomiting occurs, lean patient forward or place on left side (head-down position, if possible) to maintain open airway and
prevent aspiration.
EYE
If this product comes in contact with the eyes:
- Wash out immediately with fresh running water.
- Ensure complete irrigation of the eye by keeping eyelids apart and away from eye and moving the eyelids by occasionally lifting
the upper and lower lids.
SKIN
If skin contact occurs:
- Immediately remove all contaminated clothing, including footwear.
- Flush skin and hair with running water (and soap if available).
INHALED
- If fumes or combustion products are inhaled remove from contaminated area.
- Lay patient down. Keep warm and rested.
NOTES TO PHYSICIAN
Treat symptomatically.
Section 5 - FIRE FIGHTING MEASURES
EXTINGUISHING MEDIA
- Water spray or fog.
- Foam.
FIRE FIGHTING
- Alert Fire Brigade and tell them location and nature of hazard.
- May be violently or explosively reactive.
When any large container (including road and rail tankers) is involved in a fire,
consider evacuation by 100 metres in all directions.
FIRE/EXPLOSION HAZARD
- Liquid and vapour are highly flammable.
- Severe fire hazard when exposed to heat or flame.
Other combustion products include: carbon dioxide (CO2).
FIRE INCOMPATIBILITY
Avoid contamination with strong oxidising agents as ignition may result.
HAZCHEM:
Personal Protective Equipment
Gas tight chemical resistant suit.
Section 6 - ACCIDENTAL RELEASE MEASURES
EMERGENCY PROCEDURES
MINOR SPILLS
- Clean up all spills immediately.
- Avoid breathing vapours and contact with skin and eyes.
MAJOR SPILLS
- Clear area of personnel and move upwind.
- Alert Fire Brigade and tell them location and nature of hazard.
Personal Protective Equipment advice is contained in Section 8 of the MSDS.
Section 7 - HANDLING AND STORAGE
PROCEDURE FOR HANDLING
- Avoid all personal contact, including inhalation.
- Wear protective clothing when risk of exposure occurs.
SUITABLE CONTAINER
- Aerosol dispenser.
continued...
ROCOL EASYLINE ULTIMATE ALL COLOURS
Chemwatch Material Safety Data Sheet
Issue Date: 13-Nov-2007 CHEMWATCH 61611
C9317EC Version No:4
CD 2007/3 Page 3 of 7
Section 7 - HANDLING AND STORAGE
- Check that containers are clearly labelled.
STORAGE INCOMPATIBILITY
Avoid storage with oxidisers.
STORAGE REQUIREMENTS
- Store in original containers in approved flame-proof area.
- DO NOT store in pits, depressions, basements or areas where vapours may be trapped.
Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION
EXPOSURE CONTROLS
Source Material TWAppm TWAmg/m鲁 STELppm STELmg/m鲁
__________________ __________________ _______ _______ _______ _______
AustraliaExposureStandar acetone(Acetone) 500 1185 1000 2375
ds
AustraliaExposureStandar xylene(Xylene(o- , m- , 80 350 150 655
ds p- isomers))
AustraliaExposureStandar propylene glycol monomethy 100 369 150 553
ds lether (Propylene glycolmo
nomethylether)
AustraliaExposureStandar dimethyl ether(Dimethylet 400 760 500 950
ds her)
PERSONAL PROTECTION
RESPIRATOR
Type AX Filter of sufficient capacity
EYE
No special equipment for minor exposure i.e. when handling small quantities.
HANDS/FEET
No special equipment needed when handling small quantities.
OTHERWISE: Wear general protective gloves, eg.
OTHER
No special equipment needed when handling small quantities.
OTHERWISE:
- Overalls.
- Skin cleansing cream.
ENGINEERING CONTROLS
General exhaust is adequate under normal operating conditions. If risk of overexposure exists, wear SAA approved respirator.
Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
APPEARANCE
Supplied as an aerosol pack. Contents under PRESSURE.
Highly flammable coloured liquid with characteristic odour; mixes with water.
PHYSICAL PROPERTIES
Liquid.
Gas.
Mixes with water.
Molecular Weight: Not applicable. Boiling Range (掳 >40 solvent
C):
Melting Range (掳 <0
C): Specific Gravity (water=1): 1.0 approx
Solubility in water (g/L): Miscible pH (as supplied): Not applicable
pH (1% solution): Not applicable. Vapour Pressure (kPa): Not Available
Volatile Component (%vol): Not available Evaporation Rate: Fast
Relative Vapour Density (air=1): >1 Flash Point (掳 - 30
C):
Lower Explosive Limit (%): Not available. Upper Explosive Limit (%): Not available.
Autoignition Temp (掳 Not Available
C): Decomposition Temp (掳 Not Available
C):
State: Liquid Viscosity: Not Available
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ROCOL EASYLINE ULTIMATE ALL COLOURS
Chemwatch Material Safety Data Sheet
Issue Date: 13-Nov-2007 CHEMWATCH 61611
C9317EC Version No:4
CD 2007/3 Page 4 of 7
Section 10 - CHEMICAL STABILITY AND REACTIVITY INFORMATION
CONDITIONS CONTRIBUTING TO INSTABILITY
- Elevated temperatures.
- Presence of open flame.
Section 11 - TOXICOLOGICAL INFORMATION
POTENTIAL HEALTH EFFECTS
ACUTE HEALTH EFFECTS CHRONIC HEALTH EFFECTS
Vapours may cause dizziness or suffocation. Not applicable.
Vapours may cause drowsiness and dizziness.
TOXICITY AND IRRITATION
Not available. Refer to individual constituents.
ACETONE:
unless otherwise specified data extracted from RTECS - Register of Toxic Effects of Chemical Substances.
TOXICITY IRRITATION
Oral (man) TDLo: 2857 mg/kg Eye (human): 500 ppm - Irritant
Oral (rat) LD50: 5800 mg/kg Eye (rabbit): 3.95 mg - SEVERE
Inhalation (human) TCLo: 500 ppm Eye (rabbit): 20mg/24hr - Moderate
Inhalation (man) TCLo: 12000 ppm/4 hr Skin (rabbit):395mg (open) - Mild
Inhalation (man) TCLo: 10 mg/m鲁/6 hr Skin (rabbit): 500 mg/24hr - Mild
Inhalation (rat) LC50: 50100 mg/m鲁/8 hr
Dermal (rabbit) LD50: 20000 mg/kg
XYLENE:
unless otherwise specified data extracted from RTECS - Register of Toxic Effects of Chemical Substances.
TOXICITY IRRITATION
Oral (human) LDLo: 50 mg/kg Skin (rabbit):500 mg/24h Moderate
Oral (rat) LD50: 4300 mg/kg Eye (human): 200 ppm Irritant
Inhalation (human) TCLo: 200 ppm Eye (rabbit): 87 mg Mild
Inhalation (man) LCLo: 10000 ppm/6h Eye (rabbit): 5 mg/24h SEVERE
Inhalation (rat) LC50: 5000 ppm/4h
Oral (Human) LD: 50 mg/kg
Inhalation (Human) TCLo: 200 ppm/4h
Intraperitoneal (Rat) LD50: 2459 mg/kg
Subcutaneous (Rat) LD50: 1700 mg/kg
Oral (Mouse) LD50: 2119 mg/kg
Intraperitoneal (Mouse) LD50: 1548 mg/kg
Intravenous (Rabbit) LD: 129 mg/kg
Inhalation (Guinea) pig: LC 450 ppm/4h
The material may produce severe irritation to the eye causing pronounced inflammation. Repeated or prolonged exposure to
irritants may produce conjunctivitis.
The material may cause skin irritation after prolonged or repeated exposure and may produce a contact dermatitis (nonallergic).
This form of dermatitis is often characterised by skin redness (erythema) and swelling the epidermis.
The substance is classified by IARC as Group 3:
NOT classifiable as to its carcinogenicity to humans.
Evidence of carcinogenicity may be inadequate or limited in animal testing.
Reproductive effector in rats
PROPYLENE GLYCOL MONOMETHYL ETHER:
unless otherwise specified data extracted from RTECS - Register of Toxic Effects of Chemical Substances.
TOXICITY IRRITATION
Oral (rat) LD50: 3739 mg/kg Skin (rabbit) 500 mg Open - Mild
Inhalation (human) TCLo: 3000 ppm Eye (rabbit) 230 mg Mild
Inhalation (rat) LC50: 10000 ppm/5 h. Eye (rabbit) 500 mg/24 h. - Mild
Dermal (rabbit) LD50: 13000 mg/kg
The material may be irritating to the eye, with prolonged contact causing inflammation. Repeated or prolonged exposure to
irritants may produce conjunctivitis.
The material may cause skin irritation after prolonged or repeated exposure and may produce a contact dermatitis (nonallergic).
This form of dermatitis is often characterised by skin redness (erythema) and swelling epidermis.
NOTE: Exposure of pregnant rats and rabbits to the substance did not
give rise to teratogenic effects at concentrations up to 3000 ppm.
Fetotoxic effects were seen in rats but not in rabbits at this
concentration; maternal toxicity was noted in both species.
DIMETHYL ETHER:
unless otherwise specified data extracted from RTECS - Register of Toxic Effects of Chemical Substances.
TOXICITY IRRITATION
Inhalation (rat) LC50: 308000 mg/m鲁 Nil Reported
MATERIAL CARCINOGEN REPROTOXIN SENSITISER SKIN
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ROCOL EASYLINE ULTIMATE ALL COLOURS
Chemwatch Material Safety Data Sheet
Issue Date: 13-Nov-2007 CHEMWATCH 61611
C9317EC Version No:4
CD 2007/3 Page 5 of 7
Section 11 - TOXICOLOGICAL INFORMATION
_______________ ____________ __________ __________ __________
xylene ILOEl
REPROTOXIN
ILOEl: ILO Chemicals in the electronics industry that have toxic effects on reproduction: xylene
Section 12 - ECOLOGICAL INFORMATION
Marine Pollutant:Not Determined
No data for Rocol Easyline Ultimate all colours.
Refer to data for ingredients, which follows:
ACETONE:
log Kow: -0.24
Half-life (hr) air: 312-1896
Half-life (hr) H2O surface water: 20
Henry's atm m鲁 /mol: 3.67E-05
BOD 5 if unstated: 0.31-1.76,46-55%
COD: 1.12-2.07
ThOD: 2.2
BCF: 0.69
Toxicity Fish: LC50(96) 5540-13000mg/L
Toxicity invertebrate: cell mult. inhib. 28-7500mg/L
Bioaccumulation: not sig
Nitrif. inhib.: 75% decr. at 840mg/L
Anaerobic effects: sig degrad
Degradation Biological: sig
processes Abiotic: Rxn OH*,photodissoc
In air, acetone is lost by photolysis and reaction with photochemically
produced hydroxyl radicals; the estimated half-life of these combined
processes is about 22 days. The relatively long half-life allows acetone
to be transported long distances from its emission source.
Acetone is highly soluble and slightly persistent in water, with a
half-life of about 20 hours; it is minimally toxic to aquatic life.
Acetone released to soil volatilises although some may leach into the
ground where it rapidly biodegrades.
Acetone does not concentrate in the food chain.
Drinking Water Standard: none available.
Soil Guidelines: none available.
Air Quality Standards: none available.
DIMETHYL ETHER:
log Kow: 0.1-0.12
Koc: 14
Half-life (hr) air: 528
Half-life (hr) H2O surface water: 2.6-30
Henry's atm m鲁 /mol: 9.78E-04
BCF: 1.7
Bioaccumulation: not sig
processes Abiotic: RxnOH*
Section 13 - DISPOSAL CONSIDERATIONS
- Consult State Land Waste Management Authority for disposal.
- Discharge contents of damaged aerosol cans at an approved site.
Section 14 - TRANSPORTATION INFORMATION
Labels Required: FLAMMABLE GAS
continued...
ROCOL EASYLINE ULTIMATE ALL COLOURS
Chemwatch Material Safety Data Sheet
Issue Date: 13-Nov-2007 CHEMWATCH 61611
C9317EC Version No:4
CD 2007/3 Page 6 of 7
Section 14 - TRANSPORTATION INFORMATION
HAZCHEM:
UNDG:
Dangerous Goods 2.1 Subrisk: None
Class:
UN Number: 1950 Packing Group: None
Shipping Name:AEROSOLS
Air Transport IATA:
ICAO/IATA Class: 2.1 ICAO/IATA Subrisk: None
UN/ID Number: 1950 Packing Group: None
Special provisions: None
Shipping Name: AEROSOLS, FLAMMABLE
Maritime Transport IMDG:
IMDG Class: 2.1 IMDG Subrisk: SP63
UN Number: 1950 Packing Group: None
EMS Number: F- D, S- U Special provisions: 63 190 277 327 959
Marine Pollutant: Not Determined
Shipping Name: AEROSOLS
Section 15 - REGULATORY INFORMATION
POISONS SCHEDULE: S5
REGULATIONS
Rocol Easyline Ultimate all colours (CAS: None):
No regulations applicable
acetone (CAS: 67-64-1) is found on the following regulatory lists;
Australia Exposure Standards
Australia High Volume Industrial Chemical List (HVICL)
Australia Illicit Drug Reagents/Essential Chemicals - Category III
Australia Inventory of Chemical Substances (AICS)
Australia National Pollutant Inventory
Australia Standard for the Uniform Scheduling of Drugs and Poisons (SUSDP) - Appendix E (Part 2)
Australia Standard for the Uniform Scheduling of Drugs and Poisons (SUSDP) - Appendix F (Part 3)
Australia Standard for the Uniform Scheduling of Drugs and Poisons (SUSDP) - Schedule 5
IMO IBC Code Chapter 18: List of products to which the Code does not apply
IMO MARPOL 73/78 (Annex II) - List of Other Liquid Substances
OECD Representative List of High Production Volume (HPV) Chemicals
United Nations Convention Against Illicit Traffic in Narcotic Drugs and Psychotropic Substances - Table II
United Nations List of Precursors and Chemicals Frequently used in the Illicit Manufacture of Narcotic Drugs and Psychotropic Substances Under International Control -
xylene (CAS: 1330-20-7) is found on the following regulatory lists;
Australia - Australian Capital Territory - Environment Protection Regulation: Ambient environmental standards (Domestic water supply - organic compounds)
Australia - Australian Capital Territory Environment Protection Regulation Pollutants entering waterways - Domestic water quality
Australia Dangerous Goods Code (ADG Code) - Goods Too Dangerous To Be Transported
Australia Dangerous Goods Code Draft 7th Edition - Goods too Dangerous to be Transported
Australia Exposure Standards
Australia Standard for the Uniform Scheduling of Drugs and Poisons (SUSDP) - Appendix E (Part 2)
Australia Standard for the Uniform Scheduling of Drugs and Poisons (SUSDP) - Schedule 6
IMO MARPOL 73/78 (Annex II) - List of Noxious Liquid Substances Carried in Bulk
WHO Guidelines for Drinking-water Quality - Guideline values for chemicals that are of health significance in drinking-water
propylene glycol monomethyl ether (CAS: 107-98-2) is found on the following regulatory lists;
Australia Dangerous Goods Code (ADG Code) - Goods Too Dangerous To Be Transported
Australia Exposure Standards
Australia Inventory of Chemical Substances (AICS)
IMO MARPOL 73/78 (Annex II) - List of Noxious Liquid Substances Carried in Bulk
International Council of Chemical Associations (ICCA) - High Production Volume List
OECD Representative List of High Production Volume (HPV) Chemicals
propylene glycol monomethyl ether (CAS: 1320-67-8) is found on the following regulatory lists;
Australia Dangerous Goods Code (ADG Code) - Goods Too Dangerous To Be Transported
propylene glycol monomethyl ether (CAS: 28677-93-2) is found on the following regulatory lists;
Australia Inventory of Chemical Substances (AICS)
dimethyl ether (CAS: 115-10-6) is found on the following regulatory lists;
Australia Dangerous Goods Code (ADG Code) - Goods Too Dangerous To Be Transported
Australia Exposure Standards
Australia Inventory of Chemical Substances (AICS)
International Council of Chemical Associations (ICCA) - High Production Volume List
OECD Representative List of High Production Volume (HPV) Chemicals
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ROCOL EASYLINE ULTIMATE ALL COLOURS
Chemwatch Material Safety Data Sheet
Issue Date: 13-Nov-2007 CHEMWATCH 61611
C9317EC Version No:4
CD 2007/3 Page 7 of 7
Section 16 - OTHER INFORMATION
INGREDIENTS WITH MULTIPLE CAS NUMBERS
Ingredient Name CAS
propylene glycol monomethyl ether 107- 98- 2, 1320- 67- 8, 28677- 93- 2
Classification of the preparation and its individual components has drawn on official and authoritative sources as well as
independent review by the Chemwatch Classification committee using available literature references.
The (M)SDS is a Hazard Communication tool and should be used to assist in the Risk Assessment. Many factors determine whether the
reported Hazards are Risks in the workplace or other settings. Risks may be determined by reference to Exposures Scenarios. Scale
of use, frequency of use and current or available engineering controls must be considered.
This document is copyright. Apart from any fair dealing for the purposes of private study, research, review or criticism, as permitted under the Copyright Act,
no part may be reproduced by any process without written permission from CHEMWATCH. TEL (+61 3) 9572 4700.
Issue Date: 13-Nov-2007
Print Date: 13-Nov-2007
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