ROCOL COPPER ANTI-SEIZE SPRAY
Chemwatch Material Safety Data Sheet
Issue Date: 16-Jun-2006 CHEMWATCH 203625
CC317SCP CD 2006/3 Page 1 of 7
Section 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME
ROCOL COPPER ANTI-SEIZE SPRAY
SYNONYMS
"anti-seize lubricant", "anti-scuffing lubricant"
PROPER SHIPPING NAME
AEROSOLS
PRODUCT USE
Aerosol spray applied dry film lubricant for prevention of seizure.
SUPPLIER
Company: ITW Polymers & Fluids
Address:
100 Hassall Street
Wetherill Park
NSW, 2164
AUS
Telephone: +61 2 9757 8800
Emergency Tel: +61 2 9757 8800
Fax: 1800 803 596
HAZARD RATINGS
Flammability
Toxicity
Body Contact
Reactivity
Chronic
SCALE: Min/Nil=0 Low=1 Moderate=2 High=3 Extreme=4
Section 2 - HAZARDS IDENTIFICATION
STATEMENT OF HAZARDOUS NATURE
DANGEROUS GOODS. NON-HAZARDOUS SUBSTANCE. According to the Criteria of NOHSC, and the ADG Code.
POISONS SCHEDULE
None
RISK SAFETY
Extremely flammable. Do not breathe gas/ fumes/ vapour/ spray.
Risk of explosion if heated under confinement. Wear eye/ face protection.
Toxic to aquatic organisms, may cause long- term adverse effects in Use only in well ventilated areas.
the aquatic environment.
Inhalation, skin contact and/or ingestion may produce health damage*. Keep container in a well ventilated place.
Cumulative effects may result following exposure*. To clean the floor and all objects contaminated by this material, use
water and detergent.
May produce discomfort of the eyes and respiratory tract*. Keep container tightly closed.
Repeated exposure potentially causes skin dryness and cracking*. This material and its container must be disposed of in a safe way.
Vapours potentially cause drowsiness and dizziness*. Take off immediately all contaminated clothing.
* (limited evidence). In case of contact with eyes, rinse with plenty of water and contact
Doctor or Poisons Information Centre.
Use appropriate container to avoid environment contamination.
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ROCOL COPPER ANTI-SEIZE SPRAY
Chemwatch Material Safety Data Sheet
Issue Date: 16-Jun-2006 CHEMWATCH 203625
CC317SCP CD 2006/3 Page 2 of 7
Section 2 - HAZARDS IDENTIFICATION
Avoid release to the environment. Refer to special instructions/
safety data sheets.
This material and its container must be disposed of as hazardous
waste.
Section 3 - COMPOSITION / INFORMATION ON INGREDIENTS
NAME CAS RN %
naphtha petroleum, light, hydrotreated 64742-49-0. 30-40
mineral oil Not avail. 30-40
(solvent refined)
graphite 7782-42-5 <10^
copper 7440-50-8 <10
hydrocarbon propellant 68476-85-7. 30-40
NOTE: Manufacturer has supplied full ingredient
information to allow CHEMWATCH assessment.
Section 4 - FIRST AID MEASURES
SWALLOWED
For advice, contact a Poisons Information Centre or a doctor.
路 If swallowed do NOT induce vomiting.
路 If vomiting occurs, lean patient forward or place on left side (head-down position, if possible) to maintain open airway and
prevent aspiration.
EYE
If this product comes in contact with the eyes:
路 Immediately hold eyelids apart and flush the eye continuously with running water.
路 Ensure complete irrigation of the eye by keeping eyelids apart and away from eye and moving the eyelids by occasionally lifting
the upper and lower lids.
SKIN
If skin contact occurs:
路 Immediately remove all contaminated clothing, including footwear
路 Flush skin and hair with running water (and soap if available).
INHALED
路 If fumes or combustion products are inhaled remove from contaminated area.
路 Lay patient down. Keep warm and rested.
NOTES TO PHYSICIAN
For acute or short term repeated exposures to petroleum distillates or related hydrocarbons:
路 Primary threat to life, from pure petroleum distillate ingestion and/or inhalation, is respiratory failure.
路 Patients should be quickly evaluated for signs of respiratory distress (e.g. cyanosis, tachypnoea, intercostal retraction,
obtundation) and given oxygen. Patients with inadequate tidal volumes or poor arterial blood gases (pO2 50 mm Hg) should be
intubated.
路 Arrhythmias complicate some hydrocarbon ingestion and/or inhalation and electrocardiographic evidence of myocardial injury has
been reported; intravenous lines and cardiac monitors should be established in obviously symptomatic patients. The lungs excrete
inhaled solvents, so that hyperventilation improves clearance.
路 A chest x-ray should be taken immediately after stabilisation of breathing and circulation to document aspiration and detect
the presence of pneumothorax.
路 Epinephrine (adrenalin) is not recommended for treatment of bronchospasm because of potential myocardial sensitisation to
catecholamines. Inhaled cardioselective bronchodilators (e.g. Alupent, Salbutamol) are the preferred agents, with aminophylline a
second choice.
路 Lavage is indicated in patients who require decontamination; ensure use of cuffed endotracheal tube in adult patients.
[Ellenhorn and Barceloux: Medical Toxicology].
Section 5 - FIRE FIGHTING MEASURES
EXTINGUISHING MEDIA
路 Water spray or fog.
路 Foam.
路 Dry chemical powder.
路 BCF (where regulations permit).
路 Carbon dioxide.
FIRE FIGHTING
路 Alert Fire Brigade and tell them location and nature of hazard.
路 May be violently or explosively reactive.
路 Wear breathing apparatus plus protective gloves.
路 Prevent, by any means available, spillage from entering drains or water course.
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ROCOL COPPER ANTI-SEIZE SPRAY
Chemwatch Material Safety Data Sheet
Issue Date: 16-Jun-2006 CHEMWATCH 203625
CC317SCP CD 2006/3 Page 3 of 7
Section 5 - FIRE FIGHTING MEASURES
路 If safe, switch off electrical equipment until vapour fire hazard removed.
路 Use water delivered as a fine spray to control fire and cool adjacent area.
路 DO NOT approach containers suspected to be hot.
路 Cool fire exposed containers with water spray from a protected location.
路 If safe to do so, remove containers from path of fire.
路 Equipment should be thoroughly decontaminated after use.
FIRE/EXPLOSION HAZARD
路 Liquid and vapour are highly flammable.
路 Severe fire hazard when exposed to heat or flame.
路 Vapour forms an explosive mixture with air.
路 Severe explosion hazard, in the form of vapour, when exposed to flame or spark.
路 Vapour may travel a considerable distance to source of ignition.
路 Heating may cause expansion or decomposition with violent container rupture.
路 Aerosol cans may explode on exposure to naked flames.
路 Rupturing containers may rocket and scatter burning materials.
路 Hazards may not be restricted to pressure effects.
路 May emit acrid, poisonous or corrosive fumes.
路 On combustion, may emit toxic fumes of carbon monoxide (CO).
Other combustion products include: carbon dioxide (CO2).
FIRE INCOMPATIBILITY
Avoid contamination with strong oxidising agents as ignition may result.
HAZCHEM: 2Y
Personal Protective Equipment
Breathing apparatus.
Gas tight chemical resistant suit.
Limit exposure duration to 1 BA set30 mins.
Section 6 - ACCIDENTAL RELEASE MEASURES
EMERGENCY PROCEDURES
MINOR SPILLS
路 Clean up all spills immediately.
路 Avoid breathing vapours and contact with skin and eyes.
路 Wear protective clothing, impervious gloves and safety glasses.
路 Shut off all possible sources of ignition and increase ventilation.
路 Wipe up.
路 If safe, damaged cans should be placed in a container outdoors, away from all ignition sources, until pressure has dissipated.
路 Undamaged cans should be gathered and stowed safely.
MAJOR SPILLS
路 Clear area of personnel and move upwind.
路 Alert Fire Brigade and tell them location and nature of hazard.
路 May be violently or explosively reactive.
路 Wear breathing apparatus plus protective gloves.
路 Prevent, by any means available, spillage from entering drains or water courses
路 No smoking, naked lights or ignition sources.
路 Increase ventilation.
路 Stop leak if safe to do so.
路 Water spray or fog may be used to disperse / absorb vapour.
路 Absorb or cover spill with sand, earth, inert materials or vermiculite.
路 If safe, damaged cans should be placed in a container outdoors, away from ignition sources, until pressure has dissipated.
路 Undamaged cans should be gathered and stowed safely.
路 Collect residues and seal in labelled drums for disposal.
Personal Protective Equipment advice is contained in Section 8 of the MSDS.
Section 7 - HANDLING AND STORAGE
PROCEDURE FOR HANDLING
路 Avoid all personal contact, including inhalation.
路 Wear protective clothing when risk of exposure occurs.
路 Use in a well-ventilated area.
路 Prevent concentration in hollows and sumps.
路 DO NOT enter confined spaces until atmosphere has been checked.
路 Avoid smoking, naked lights or ignition sources.
路 Avoid contact with incompatible materials.
路 When handling, DO NOT eat, drink or smoke.
路 DO NOT incinerate or puncture aerosol cans.
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ROCOL COPPER ANTI-SEIZE SPRAY
Chemwatch Material Safety Data Sheet
Issue Date: 16-Jun-2006 CHEMWATCH 203625
CC317SCP CD 2006/3 Page 4 of 7
Section 7 - HANDLING AND STORAGE
路 DO NOT spray directly on humans, exposed food or food utensils.
路 Avoid physical damage to containers.
路 Always wash hands with soap and water after handling.
路 Work clothes should be laundered separately.
路 Use good occupational work practice.
路 Observe manufacturer's storing and handling recommendations.
路 Atmosphere should be regularly checked against established exposure standards to ensure safe working conditions are maintained.
SUITABLE CONTAINER
路 Aerosol dispenser.
路 Check that containers are clearly labelled.
STORAGE INCOMPATIBILITY
Avoid storage with oxidisers.
STORAGE REQUIREMENTS
路 Store in original containers in approved flame-proof area.
路 DO NOT store in pits, depressions, basements or areas where vapours may be trapped.
路 No smoking, naked lights, heat or ignition sources.
路 Keep containers securely sealed. Contents under pressure.
路 Store away from incompatible materials.
路 Store in a cool, dry, well ventilated area in an upright position.
路 Avoid storage at temperatures higher than 40 deg C.
路 Protect containers against physical damage and check regularly for leaks.
路 Observe manufacturer's storing and handling recommendations.
Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION
EXPOSURE CONTROLS
Source Material TWA TWA STEL STEL Peak Peak TWA
ppm mg/m鲁 ppm mg/m鲁 ppm mg/m鲁 F/CC
_________________ __________________ ______ ______ ______ ______ ______ ______ ______
Australia Exposure copper (Copper, 1
Standards dusts & mists (as
Cu))
Australia Exposure copper (Copper 0.2
Standards (fume))
Australia Exposure hydrocarbon 1, 000 1, 800
Standards propellant (LPG
(liquified
petroleum gas))
The following materials had no OELs on our record under the following CAS or Chemwatch
(CW) numbers
鈥? Rocol Copper Anti-Seize Spray: No data available for CW:203625
鈥? naphtha petroleum, light, hydrotreated: No data available for CAS:64742-49-0
CW:595264
鈥? mineral oil: No data available for CW:11349
鈥? copper: No data available for CAS:7440-50-8
鈥? hydrocarbon propellant: No data available for CAS:68476-86-8
鈥? 518: No data available for CW:562033 CW:621221 CW:84407
PERSONAL PROTECTION
RESPIRATOR
Type A-P Filter of sufficient capacity
EYE
No special equipment for minor exposure i.e. when handling small quantities.
路 OTHERWISE:
路 Safety glasses with side shields.
路 Contact lenses may pose a special hazard; soft contact lenses may absorb and concentrate irritants. A written policy document,
describing the wearing of lens or restrictions on use, should be created for each workplace or task. This should include a review
of lens absorption and adsorption for the class of chemicals in use and an account of injury experience. Medical and first-aid
personnel should be trained in their removal and suitable equipment should be readily available. In the event of chemical
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ROCOL COPPER ANTI-SEIZE SPRAY
Chemwatch Material Safety Data Sheet
Issue Date: 16-Jun-2006 CHEMWATCH 203625
CC317SCP CD 2006/3 Page 5 of 7
Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION
exposure, begin eye irrigation immediately and remove contact lens as soon as practicable. Lens should be removed at the first
signs of eye redness or irritation - lens should be removed in a clean environment only after workers have washed hands
thoroughly. [CDC NIOSH Current Intelligence Bulletin 59].
HANDS/FEET
No special equipment needed when handling small quantities.
OTHERWISE: Wear general protective gloves, eg. light weight rubber gloves. Or as required: Wear chemical protective gloves, eg.
PVC. Wear safety footwear.
OTHER
No special equipment needed when handling small quantities.
OTHERWISE:
路 Overalls.
路 Skin cleansing cream.
路 Eyewash unit.
路 Do not spray on hot surfaces.
ENGINEERING CONTROLS
Use in a well-ventilated area.
General exhaust is adequate under normal operating conditions. If risk of overexposure exists, wear SAA approved respirator.
Correct fit is essential to obtain adequate protection. Provide adequate ventilation in warehouse or closed storage areas.
Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
APPEARANCE
Dark flammable liquid with hydrocarbon solvent odour; does not mix with water. Supplied as an aerosol pack. Contents under
PRESSURE. Contains highly flammable hydrocarbon propellant.
PHYSICAL PROPERTIES
Liquid.
Gas.
Does not mix with water.
Molecular Weight: Not applicable. Boiling Range (掳 Not a vailable
C):
Melting Range (掳 Not available.
C): Specific Gravity (water =1): Not available
Solubility in water (g/L): Immiscible pH (as supplied): Not applicable
pH (1% solution): Not applicable Vapour Pressure (kPa): Not available.
Volatile Component (%vol): Not available Evaporation Rate: >1 BuAc=1
Relative Vapour Density (air=1): >1 Flash Point (掳 -81 pr opellant
C):
Lower Explosive Limit (%): Not available Upper Explosive Limit (%): Not available
Autoignition Temp (掳 Not available.
C): Decomposition Temp (掳 Not available
C):
State: Liquid
Section 10 - CHEMICAL STABILITY AND REACTIVITY INFORMATION
CONDITIONS CONTRIBUTING TO INSTABILITY
路 Elevated temperatures.
路 Presence of open flame.
路 Product is considered stable.
路 Hazardous polymerisation will not occur.
Section 11 - TOXICOLOGICAL INFORMATION
POTENTIAL HEALTH EFFECTS
ACUTE HEALTH EFFECTS CHRONIC HEALTH EFFECTS
Can be absorbed through skin. Cumulative effects may result following exposure*.
Vapours may cause dizziness or suffocation. Repeated exposure potentially causes skin dryness
and cracking*.
Inhalation, skin contact and/or * (limited evidence).
ingestion may produce health damage*.
May produce discomfort of the eyes and
respiratory tract*.
Vapours potentially cause drowsiness and
dizziness*.
* (limited evidence).
TOXICITY AND IRRITATION
Not available. Refer to individual constituents.
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ROCOL COPPER ANTI-SEIZE SPRAY
Chemwatch Material Safety Data Sheet
Issue Date: 16-Jun-2006 CHEMWATCH 203625
CC317SCP CD 2006/3 Page 6 of 7
Section 12 - ECOLOGICAL INFORMATION
Marine Pollutant:Not Determined
Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
This material and its container must be disposed of as hazardous waste.
Avoid release to the environment.
Refer to special instructions/ safety data sheets.
Section 13 - DISPOSAL CONSIDERATIONS
路 Consult State Land Waste Management Authority for disposal.
路 Discharge contents of damaged aerosol cans at an approved site.
路 Allow small quantities to evaporate.
路 DO NOT incinerate or puncture aerosol cans.
路 Bury residues and emptied aerosol cans at an approved site.
Section 14 - TRANSPORTATION INFORMATION
Labels Required: FLAMMABLE GAS
HAZCHEM: 2Y
UNDG:
Dangerous Goods Class: 2.1 Subrisk: None
UN Number: 1950 Packing Group: None
Shipping Name:AEROSOLS
Section 15 - REGULATORY INFORMATION
POISONS SCHEDULE: None
REGULATIONS
naphtha petroleum, light, hydrotreated (CAS: 64742-49-0) is found on the following regulatory lists;
Australia High Volume Industrial Chemical List (HVICL)
Australia Inventory of Chemical Substances (AICS)
Australia Poisons Schedule
International Council of Chemical Associations (ICCA) - High Production Volume List
OECD Representative List of High Production Volume (HPV) Chemicals
mineral oil (CAS No:Not avail):
No regulations applicable
copper (CAS: 7440-50-8) is found on the following regulatory lists;
Australia - Australia New Zealand Food Standards Code - Processing Aids - Permitted catalysts
Australia - Australian Capital Territory Environment Protection Regulation Agricultural Uses (IRRIG) - Physical and chemica
quality
Australia - Australian Capital Territory Environment Protection Regulation Agricultural uses (STOCK) - Physical and chemic
quality
Australia - Australian Capital Territory Environment Protection Regulation Domestic water quality standards - Inorganic
chemicals
Australia - Australian Capital Territory Environment Protection Regulation Ecosystem maintenance - Inorganic chemicals
Australia - Australian Capital Territory Environment Protection Regulation Pollutants entering waterways - Agricultural uses
(Irrig)
Australia - Australian Capital Territory Environment Protection Regulation Pollutants entering waterways - Agricultural uses
(Stock)
Australia - Australian Capital Territory Environment Protection Regulation Pollutants entering waterways - Domestic water
quality
Australia - Australian Capital Territory Environment Protection Regulation Pollutants entering waterways - Ecosystem
maintenance
Australia Dangerous Goods Code Draft 7th Edition - List of Common Pesticides with Corresponding UN Numbers
Australia Exposure Standards
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ROCOL COPPER ANTI-SEIZE SPRAY
Chemwatch Material Safety Data Sheet
Issue Date: 16-Jun-2006 CHEMWATCH 203625
CC317SCP CD 2006/3 Page 7 of 7
Section 15 - REGULATORY INFORMATION
Australia High Volume Industrial Chemical List (HVICL)
Australia Inventory of Chemical Substances (AICS)
Australia National Pollutant Inventory
OECD Representative List of High Production Volume (HPV) Chemicals
WHO Guidelines for Drinking-water Quality - Guideline values for chemicals that are of health significance in drinking-water
hydrocarbon propellant (CAS: 68476-85-7) is found on the following regulatory lists;
Australia Exposure Standards
Australia High Volume Industrial Chemical List (HVICL)
Australia Inventory of Chemical Substances (AICS)
OECD Representative List of High Production Volume (HPV) Chemicals
hydrocarbon propellant (CAS: 68476-86-8) is found on the following regulatory lists;
Australia Inventory of Chemical Substances (AICS)
OECD Representative List of High Production Volume (HPV) Chemicals
No data available for mineral oil as CAS: Not avail.
Section 16 - OTHER INFORMATION
INGREDIENTS WITH MULTIPLE CAS NUMBERS
Ingredient Name CAS
hydrocarbon 68476- 85- 7, 68476- 86- 8
propellant
This document is copyright. Apart from any fair dealing for the purposes of private study, research, review or criticism, as permitted under the Copyright Act,
no part may be reproduced by any process without written permission from CHEMWATCH. TEL (+61 3) 9572 4700.
Issue Date: 16-Jun-2006
Print Date: 15-Jan-2007
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