MOLYBOND GH101
ChemWatch Material Safety Data Sheet CHEMWATCH 40257
Issue Date: Thu 10-Mar-2005 CD 2004/4 Page 1 of 10
Section 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME
MOLYBOND GH101
SYNONYMS
grease 26/B0777
PRODUCT USE
Lubricating grease.
SUPPLIER
Company: ITW Polymers And Fluids Pty Ltd Company: ITW Polymers And Fluids Pty Ltd
Address: Address:
100 Hassall Street Private Mail Bag 35
Wetherill Park Wetherill Park
NSW, 2164 NSW, 2164
AUSTRALIA AUSTRALIA
Telephone: (+61 2) 9757 8800
Fax: 1800 803 596
HAZARD RATINGS
Flammability
Toxicity
Body Contact
Reactivity
Chronic
SCALE: Min/Nil=0 Low=1 Moderate=2 High=3 Extreme=4
Section 2 - HAZARDS IDENTIFICATION
STATEMENT OF HAZARDOUS NATURE
NON-HAZARDOUS SUBSTANCE. NON-DANGEROUS GOODS.
According to the Criteria of NOHSC, and the ADG Code.
POISONS SCHEDULE
None
RISK
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MOLYBOND GH101
ChemWatch Material Safety Data Sheet CHEMWATCH 40257
Issue Date: Thu 10-Mar-2005 CD 2004/4 Page 2 of 10
Section 2 - HAZARDS IDENTIFICATION ...
SAFETY
Avoid contact with skin.
Section 3 - COMPOSITION / INFORMATION ON INGREDIENTS
NAME CAS RN %
mineral oil Not avail. >60
lithium soap
copolymer lubricant 10-30
molybdenum disulfide 1-10
graphite 7782-42-5 <5^
NOTE: Manufacturer has supplied full ingredient
information to allow CHEMWATCH assessment.
Section 4 - FIRST AID MEASURES
SWALLOWED
鈥? Immediately give a glass of water.
鈥? First aid is not generally required. If in doubt, contact a Poisons
Information Centre or a doctor.
EYE
If this product comes in contact with eyes:
鈥? Wash out immediately with water.
鈥? If irritation continues, seek medical attention.
鈥? Removal of contact lenses after an eye injury should only be undertaken by
skilled personnel.
SKIN
If skin or hair contact occurs:
鈥? Flush skin and hair with running water (and soap if available).
鈥? Seek medical attention in event of irritation.
INHALED
鈥? If fumes or combustion products are inhaled remove from contaminated area.
鈥? Other measures are usually unnecessary.
NOTES TO PHYSICIAN
Treat symptomatically.
鈥? Heavy and persistent skin contamination over many years may lead to dysplastic
changes. Pre-existing skin disorders may be aggravated by exposure to this
product.
鈥? In general, emesis induction is unnecessary with high viscosity, low
volatility products, i.e. most oils and greases.
鈥? High pressure accidental injection through the skin should be assessed for
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MOLYBOND GH101
ChemWatch Material Safety Data Sheet CHEMWATCH 40257
Issue Date: Thu 10-Mar-2005 CD 2004/4 Page 3 of 10
Section 4 - FIRST AID MEASURES ...
possible incision, irrigation and/or debridement.
NOTE: Injuries may not seem serious at first, but within a few hours tissue may
become swollen, discoloured and extremely painful with extensive subcutaneous
necrosis. Product may be forced through considerable distances along tissue
planes.
Section 5 - FIRE FIGHTING MEASURES
EXTINGUISHING MEDIA
鈥? Foam.
鈥? Dry chemical powder.
鈥? BCF (where regulations permit).
鈥? Carbon dioxide.
鈥? Water spray or fog - Large fires only.
FIRE FIGHTING
鈥? Alert Fire Brigade and tell them location and nature of hazard.
鈥? Wear breathing apparatus plus protective gloves.
鈥? Prevent, by any means available, spillage from entering drains or water
courses.
鈥? Use water delivered as a fine spray to control fire and cool adjacent area.
鈥? DO NOT approach containers suspected to be hot.
鈥? Cool fire exposed containers with water spray from a protected location.
鈥? If safe to do so, remove containers from path of fire.
鈥? Equipment should be thoroughly decontaminated after use.
FIRE/EXPLOSION HAZARD
鈥? Combustible.
鈥? Slight fire hazard when exposed to heat or flame.
鈥? Heating may cause expansion or decomposition leading to violent rupture of
containers.
鈥? On combustion, may emit toxic fumes of carbon monoxide (CO).
鈥? May emit acrid smoke.
鈥? Mists containing combustible materials may be explosive.
Combustion products include.
carbon dioxide (CO2).
other pyrolysis products typical of burning organic material.
May emit poisonous fumes.
FIRE INCOMPATIBILITY
Avoid contamination with oxidising agents i.e. nitrates, oxidising acids,
chlorine bleaches, pool chlorine etc. as ignition may result
HAZCHEM
None
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MOLYBOND GH101
ChemWatch Material Safety Data Sheet CHEMWATCH 40257
Issue Date: Thu 10-Mar-2005 CD 2004/4 Page 4 of 10
Section 5 - FIRE FIGHTING MEASURES ...
Personal Protective Equipment
PERSONAL PROTECTION EQUIPMENT
Breathing apparatus.
Chemical splash suit.
Section 6 - ACCIDENTAL RELEASE MEASURES
EMERGENCY PROCEDURES
MINOR SPILLS
Slippery when spilt.
鈥? Clean up all spills immediately.
鈥? Avoid contact with skin and eyes.
鈥? Wear impervious gloves and safety goggles.
鈥? Trowel up/scrape up.
鈥? Place spilled material in clean, dry, sealed container.
鈥? Flush spill area with water.
MAJOR SPILLS
Slippery when spilt.
Minor hazard.
鈥? Clear area of personnel.
鈥? Alert Fire Brigade and tell them location and nature of hazard.
鈥? Control personal contact by using protective equipment as required.
鈥? Prevent spillage from entering drains or water ways.
鈥? Contain spill with sand, earth or vermiculite.
鈥? Collect recoverable product into labelled containers for recycling.
鈥? Absorb remaining product with sand, earth or vermiculite and place in
appropriate containers for disposal.
鈥? Wash area and prevent runoff into drains or waterways.
鈥? If contamination of drains or waterways occurs, advise emergency services.
Personal Protective Equipment advice is contained in Section 8 of the MSDS.
Section 7 - HANDLING AND STORAGE
PROCEDURE FOR HANDLING
鈥? Avoid all personal contact, including inhalation.
鈥? Wear protective clothing when risk of exposure occurs.
鈥? Use in a well-ventilated area.
鈥? Prevent concentration in hollows and sumps.
鈥? DO NOT enter confined spaces until atmosphere has been checked.
鈥? DO NOT allow material to contact humans, exposed food or food utensils.
鈥? Avoid contact with incompatible materials.
鈥? When handling, DO NOT eat, drink or smoke.
鈥? Keep containers securely sealed when not in use.
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MOLYBOND GH101
ChemWatch Material Safety Data Sheet CHEMWATCH 40257
Issue Date: Thu 10-Mar-2005 CD 2004/4 Page 5 of 10
Section 7 - HANDLING AND STORAGE ...
鈥? Avoid physical damage to containers.
鈥? Always wash hands with soap and water after handling.
鈥? Work clothes should be laundered separately. Launder contaminated clothing
before re-use.
鈥? Use good occupational work practice.
鈥? Observe manufacturer's storing and handling recommendations.
鈥? Atmosphere should be regularly checked against established exposure standards
to ensure safe working conditions are maintained.
SUITABLE CONTAINER
鈥? Metal can or drum
鈥? Packaging as recommended by manufacturer.
鈥? Check all containers are clearly labelled and free from leaks.
STORAGE INCOMPATIBILITY
CARE: Water in contact with heated material may cause foaming or a steam
explosion with possible severe burns from wide scattering of hot material.
Resultant overflow of containers may result in fire.
Avoid reaction with oxidising agents
STORAGE REQUIREMENTS
鈥? Store in original containers.
鈥? Keep containers securely sealed.
鈥? Store in a cool, dry, well-ventilated area.
鈥? Store away from incompatible materials and foodstuff containers.
鈥? Protect containers against physical damage and check regularly for leaks.
鈥? Observe manufacturer's storing and handling recommendations.
Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION
EXPOSURE CONTROLS
No data available for mineral oil as (CAS: Not avail)
None assigned. Refer to individual constituents.
INGREDIENT DATA
MINERAL OIL:
TLV TWA: 5 mg/m鲁 () [ACGIH]
TLV STEL: 10 mg/m鲁 [ACGIH]
oil mist, mineral
TLV TWA: 5 mg/m鲁; STEL: 10 mg/m鲁.
NOTICE OF INTENDED CHANGE.
TLV TWA 0.2 mg/m鲁 inhalable fraction highly refined A4
NOTE: This substance has been classified by the ACGIH as A4
NOT classifiable as causing cancer in humans.
ES TWA: 5 mg/m鲁 (oil mist, refined mineral)
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MOLYBOND GH101
ChemWatch Material Safety Data Sheet CHEMWATCH 40257
Issue Date: Thu 10-Mar-2005 CD 2004/4 Page 6 of 10
Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION ...
Human exposure to oil mist alone has not been demonstrated to cause health
effects except at levels above 5 mg/m鲁 (this applies to particulates sampled by
a method that does not collect vapour). It is not advisable to apply this
standard to oils containing unknown concentrations and types of additive.
PERSONAL PROTECTION
EYE
鈥? Safety glasses with side shields
鈥? Chemical goggles.
鈥? Contact lenses pose a special hazard; soft lenses may absorb irritants and all
lenses concentrate them.
HANDS/FEET
Wear chemical protective gloves, eg. PVC.
Wear safety footwear or safety gumboots, eg. Rubber
OTHER
鈥? Overalls.
鈥? P.V.C. apron.
鈥? Barrier cream.
鈥? Skin cleansing cream.
鈥? Eye wash unit.
RESPIRATOR
Selection of the Class and Type of respirator will depend upon the level of
breathing zone contaminant and the chemical nature of the contaminant.
Protection Factors (defined as the ratio of contaminant outside and inside the
mask) may also be important.
Breathing Zone Maximum Protection Half-face Full-Face
Level ppm (volume) Factor Respirator Respirator
1000 10 -AUS P -
1000 50 - -AUS P
5000 50 Airline * -
5000 100 - -2 P
10000 100 - -3 P
100+ Airline**
* - Continuous Flow ** - Continuous-flow or positive pressure demand
The local concentration of material, quantity and conditions of use determine
the type of personal protective equipment required. For further information
consult site specific CHEMWATCH data (if available), or your Occupational
Health and Safety Advisor.
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MOLYBOND GH101
ChemWatch Material Safety Data Sheet CHEMWATCH 40257
Issue Date: Thu 10-Mar-2005 CD 2004/4 Page 7 of 10
Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION ...
ENGINEERING CONTROLS
General exhaust is adequate under normal operating conditions. If risk of
overexposure exists, wear SAA approved respirator. Correct fit is essential to
obtain adequate protection. Provide adequate ventilation in warehouse or closed
storage areas.
Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
APPEARANCE
Black grease; does not mix with water.
PHYSICAL PROPERTIES
Liquid.
Does not mix with water.
Molecular Weight: Not applicable. Boiling Range (掳C): Not available.
Melting Range (掳C): Not available. Specific Gravity (water=1): Not available.
Solubility in water (g/L): Immiscible pH (as supplied): Not applicable
pH (1% solution): Not applicable Vapour Pressure (kPa): Negligible
Volatile Component (%vol): Negligible Evaporation Rate: Not applicable
Relative Vapour Density (air=1): Not available. Flash Point (掳C): >200
Lower Explosive Limit (%): Not applicable Upper Explosive Limit (%): Not applicable
Autoignition Temp (掳C): Not available. Decomposition Temp (掳C): Not available.
State: Non slump paste
Section 10 - CHEMICAL STABILITY AND REACTIVITY INFORMATION
CONDITIONS CONTRIBUTING TO INSTABILITY
Product is considered stable and hazardous polymerisation will not occur.
Section 11 - TOXICOLOGICAL INFORMATION
POTENTIAL HEALTH EFFECTS
ACUTE HEALTH EFFECTS
SWALLOWED
The material has NOT been classified by EC Directives or other classification
systems as "harmful by ingestion". This is because of the lack of corroborating
animal or human evidence. The material may still be damaging to the health of
the individual, following ingestion, especially where pre-existing organ (e.g
liver, kidney) damage is evident. Present definitions of harmful or toxic
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MOLYBOND GH101
ChemWatch Material Safety Data Sheet CHEMWATCH 40257
Issue Date: Thu 10-Mar-2005 CD 2004/4 Page 8 of 10
Section 11 - TOXICOLOGICAL INFORMATION ...
substances are generally based on doses producing mortality rather than those
producing morbidity (disease, ill-health). Gastrointestinal tract discomfort may
produce nausea and vomiting. In an occupational setting however, ingestion of
insignificant quantities is not thought to be cause for concern.
EYE
Although the material is not thought to be an irritant (as classified by EC
Directives), direct contact with the eye may produce transient discomfort
characterised by tearing or conjunctival redness (as with windburn).
SKIN
The material is not thought to produce adverse health effects or skin irritation
following contact (as classified by EC Directives using animal models).
Nevertheless, good hygiene practice requires that exposure be kept to a minimum
and that suitable gloves be used in an occupational setting.
Entry into the blood-stream, through, for example, cuts, abrasions or lesions,
may produce systemic injury with harmful effects. Examine the skin prior to the
use of the material and ensure that any external damage is suitably protected.
INHALED
The material is not thought to produce adverse health effects or irritation of
the respiratory tract (as classified by EC Directives using animal models).
Nevertheless, good hygiene practice requires that exposure be kept to a minimum
and that suitable control measures be used in an occupational setting.
Not normally a hazard due to non-volatile nature of product
CHRONIC HEALTH EFFECTS
Substance accumulation, in the human body, may occur and may cause some concern
following repeated or long-term occupational exposure. Principal route of
exposure is by skin contact; lesser exposures include inhalation of fumes from
hot oils, oil mists or droplets. Prolonged contact with mineral oils carries
with it the risk of skin conditions such as oil folliculitis, eczematous
dermatitis, pigmentation of the face (melanosis) and warts on the sole of the
foot (plantar warts). With highly refined mineral oils no appreciable systemic
effects appear to result through skin absorption. Exposure to oil mists
frequently elicits respiratory conditions, such as asthma; the provoking agent
is probably an additive. High oil mist concentrations may produce lipoid
pneumonia although clinical evidence is equivocal. In animals exposed to
concentrations of 100 mg/m3 oil mist, for periods of 12 to 26 months, the
activity of lung and serum alkaline phosphatase enzyme was raised; 5 mg/m3 oil
mist did not produce this response. These enzyme changes are sensitive early
indicators of lung damage. Workers exposed to vapours of mineral oil and
kerosene for 5 to 35 years showed an increased prevalence of slight basal lung
fibrosis. Many studies have linked cancers of the skin and scrotum with mineral
oil exposure. Contaminants in the form of additives and the polycyclic aromatic
hydrocarbons (PAHs - as in the crude base stock) are probably responsible. PAH
levels are higher in aromatic process oils/used/reclaimed motor oils. Subchronic
90-day feeding studies conducted on male and female rats on highly refined white
mineral oils and waxes found that higher molecular-weight hydrocarbons
(microcrystalline waxes and the higher viscosity oils) were without biological
effects. Paraffin waxes and low- to mid viscosity oils produced biological
effects that were inversely proportional to molecular weight, viscosity and
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MOLYBOND GH101
ChemWatch Material Safety Data Sheet CHEMWATCH 40257
Issue Date: Thu 10-Mar-2005 CD 2004/4 Page 9 of 10
Section 11 - TOXICOLOGICAL INFORMATION ...
melting point: oil-type and processing did not appear to be determinants.
Biological effects were more pronounced in females than in males. Effects
occurred mainly in the liver and mesenteric lymph nodes and included increased
organ weights, microscopic inflammatory changes, and evidence for the presence
of saturated mineral hydrocarbons in affected tissues. Inflammation of the
cardiac mitral valve was also observed at high doses in rats treated with
paraffin waxes. Smith J.H., et al: Toxicologic Pathology: 24, 2, 214-230, 1996.
Cattle, rabbits, and chicks on high dietary levels of molybdenum exhibited
deformities of joints of the extremities. Chronic exposure of workers in Russian
molybdenum-copper plant resulted in a fall in the albumin/globulin ratio owing
to a rise in globulins (particularly alpha-globulins) which is interpreted as
evidence of liver dysfunction with hyperbilirubinaemia. Hepatotoxic effects are
also found in animals given molybdenum salts with a rise in alpha-globulin
levels, hypoalbuminaemia and increased serum bilirubin reported. Other reported
biochemical effects include an early depletive effect on tissue nicotinamide
nucleotides, hyperaminoaciduria, reduction in red blood cell life-span and
hyper-thyroidism. Industrial exposure to some insoluble molybdenum compounds is
thought to have resulted in an increased incidence of weakness, fatigue,
anorexia, headache and joint and muscular pain. Animals exposed to certain
insoluble molybdenum compounds show anorexia, diarrhoea, weight loss,
listlessness, and liver and kidney damage. Molybdenum disturbs bone metabolism,
giving rise to lameness, bone joint abnormalities, osteoporosis and high serum
phosphatase levels. Low molybdenum intake has been attributed to the high
incidence of oesophageal cancer in South Africa among the Bantu of Transkei, in
China and in Russia. Under the conditions of a 2-year inhalation study* there
was equivocal evidence of carcinogenic activity of molybdenum trioxide in male
rats, male mice and female mice based on a marginally significant positive trend
of alveolar/bronchiolar adenoma or carcinoma. There was no evidence of
carcinogenic activity in female rats exposed to 10, 30 and 100 mg/m3. Exposure
of male and female rats to molybdenum trioxide by inhalation resulted in
increased incidences of chronic alveolar inflammation, hyaline degeneration of
the olfactory epithelium (females), hyaline degeneration of the respiratory
epithelium and squamous metaplasia of the epiglottis. Exposure of female and
male mice to molybdenum trioxide resulted in an increased incidence of
metaplasia of the alveolar epithelium, histiocyte cellular inflammation (males),
hyaline degeneration of the respiratory epithelium, hyaline degeneration of the
olfactory epithelium (females), squamous metaplasia of the epiglottis, and
hyperplasia of the larynx. Molybdenum trioxide was not mutagenic in any of five
strains of Salmonella typhimurium and did not induce sister chromatid exchanges
or chromosomal aberrations in cultured Chinese hamster ovary cells in vitro. All
tests were conducted with or without S9 metabolic activation enzymes. National
Toxicology Program: Technical Report Series 462, April 1997
Molybond GH101
TOXICITY IRRITATION
None (None) None: None None
MINERAL OIL:
contain very low concentrations of both.
Toxicity and Irritation data is related to chemical components and
varies as does the composition and source of the original crude.
A small but definite risk of occupational skin cancer occurs in workers
exposed to persistent skin contamination by oils over a period of years.
This risk has been attributed to the presence of certain polycyclic
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MOLYBOND GH101
ChemWatch Material Safety Data Sheet CHEMWATCH 40257
Issue Date: Thu 10-Mar-2005 CD 2004/4 Page 10 of 10
Section 11 - TOXICOLOGICAL INFORMATION ...
aromatic hydrocarbons (PAH) (typified by benz[a]pyrene).
Petroleum oils which are solvent refined/extracted or severely hydrotreated,
Section 12 - ECOLOGICAL INFORMATION
DO NOT discharge into sewer or waterways.
Section 13 - DISPOSAL CONSIDERATIONS
Puncture containers to prevent re-use and bury at an authorised landfill.
Section 14 - TRANSPORTATION INFORMATION
Shipping Name:
None
Dangerous Goods Class: None
UN/NA Number: None
ADR Number: None
Packing Group: None
Additional Shipping Information:
International Transport Regulations:
IMO: None
HAZCHEM
None
Section 15 - REGULATORY INFORMATION
POISONS SCHEDULE
None
Section 16 - OTHER INFORMATION
This document is copyright. Apart from any fair dealing for the purposes of
private study, research, review or criticism, as permitted under the Copyright
Act, no part may be reproduced by any process without written permission from
CHEMWATCH. TEL (+61 3) 9572 4700.
Issue Date: Thu 10-Mar-2005
Print Date: Thu 10-Mar-2005
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