REAGENTS, INC-MSDS- CUPRIETHYLENEDIAMINE 0.5 MOLAR PAGE 1
CUPRIETHYLENEDIAMINE 0.5 MOLAR SOLUTION
1. Chemical Product And Company Identification
Company's Name: REAGENTS, INC.
Company's P. O. Box: 240746
Company's City: CHARLOTTE
Company's State: NC
Company's Country: US
Company's Zip Code: 28224
Company's Info Ph #: 704/554-7474, 800/732-8484
Emergencies, call CHEMTREC: 800-424-9300
Date MSDS Prepared: April 28, 2008
Synonyms: Copper(2++), bis(1,2-Ethanediamine-N,N')-, Dihydroxide Solution / Deionized Water
CAS No.: 14552-35-3
Molecular Formula: C2Cu2H8N2-n
Molecular Weight: 159.148
Product Codes: C-1008
2. Composition/Information on Ingredients
Ingredient (CAS No) Percent Hazardous
--------------------------------------- ------------ ---------------
Copper (II)-Ethylenediamine (14552-35-3) 7.96% Yes
Water (7732-18-5) Remainder No
3. Hazards Identification
Emergency Overview
--------------------------
DANGER! CAUSES BURNS. VAPOR HARMFUL. AVOID CONTACT WITH EYES, SKIN OR
CLOTHING. DO NOT BREATHE VAPOR. USE ONLY WITH ADEQUATE VENTILATION.
KEEP TIGHTLY CLOSED. WASH THOROUGHLY AFTER HANDLING.
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Health Rating: 2 - Moderate
Flammability Rating: 0 - None
Reactivity Rating: 0 - Slight
Contact Rating: 2 - Moderate
Lab Protective Equip: GOGGLES; LAB COAT
Storage Color Code: White (Corrosive Storage)
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Potential Health Effects
----------------------------------
REAGENTS, INC-MSDS- CUPRIETHYLENEDIAMINE 0.5 MOLAR PAGE 2
Eye: Contact with eyes may cause severe irritation, and possible eye burns.
Skin: Causes skin burns.
Ingestion: May cause severe and permanent damage to the digestive tract. Causes gastrointestinal tract
burns.
Inhalation: May cause severe irritation of the respiratory tract with sore throat, coughing, shortness of
breath and delayed lung edema. Causes chemical burns to the respiratory tract.
Chronic: None
4. First Aid Measures
Inhalation: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give
oxygen. Get medical attention for any breathing difficulty.
Ingestion: Give large amounts of water to drink. Never give anything by mouth to an unconscious
person. Get medical attention for any gastrointestinal irritation.
Skin Contact: Immediately flush skin with plenty of water for at least 15 minutes while removing
contaminated clothing and shoes. Wash clothing before reuse. Thoroughly clean shoes before reuse. Get
medical attention if symptoms occur.
Eye Contact: Immediately flush eyes with plenty of water for at least 15 minutes, lifting upper and lower
eyelids occasionally. Get medical attention for any irritation.
5. Fire Fighting Measures
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: No information found.
Explosion Limits, upper: No information found.
Fire: Not considered to be a fire hazard.
Explosion: Not considered to be an explosion hazard.
Extinguishing Media: In case of fire, use water, dry chemical, chemical foam, or alcohol-resistant
foam.
Special Information: In the event of a fire, wear full protective clothing and NIOSH-approved selfcontained
breathing apparatus with full-facepiece operated in the pressure demand or other positive
pressure mode.
6. Accidental Release Measures
General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks: Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable
container. Clean up spills immediately, observing precautions in the Protective Equipment section.
Provide ventilation.
7. Handling and Storage
Handling: Keep container tightly closed. Do not get on skin or in eyes. Do not ingest or inhale. Use
with adequate ventilation. Discard contaminated shoes.
Storage: Keep container closed when not in use. Store in a cool, dry, well-ventilated area away from
incompatible substances. Corrosives area.
REAGENTS, INC-MSDS- CUPRIETHYLENEDIAMINE 0.5 MOLAR PAGE 3
8. Exposure Controls/Personal Protection
Airborne Exposure Limits: None established.
COPPER(II)-ETHYLENEDIAMINE: No OSHA Vacated PELs are listed for this chemical.
Ventilation System: A system of local and/or general exhaust is recommended to keep employee
exposures as low as possible. Local exhaust ventilation is generally preferred because it can control the
emissions of the contaminant at its source, preventing dispersion of it into the general work area. Please
refer to the ACGIH document, Industrial Ventilation, A Manual of Recommended Practices, most recent
edition, for details.
Personal Respirators (NIOSH-Approved): For conditions of use where exposure to the dust or mist is
apparent, a half-face dust/mist respirator may be worn. For emergencies or instances where the
exposure levels are not known, use a full-face positive-pressure, air-supplied respirator. WARNING:
Air-purifying respirators do not protect workers in oxygen-deficient atmospheres.
Skin Protection: Wear protective gloves.
Eye Protection: Use chemical safety goggles. Maintain eye wash fountain and quick-drench facilities in
work area.
9. Physical and Chemical Properties
Appearance: Dark, blue liquid
Odor: Slight amine odor.
Solubility: Miscible in water.
Specific Gravity: No information found.
pH: No information found.
% Volatiles by volume @ 21oC (70oF): No information found.
Boiling Point: No information found.
Melting Point: No information found.
Vapor Density (Air=1): No information found.
Vapor Pressure (mm Hg): No information found.
Evaporation Rate (BuAc=1): No information found.
10. Stability and Reactivity
Chemical Stability: Stable under normal temperatures and pressures.
Conditions to Avoid: Excess heat, oxidizers.
Incompatibilities with Other Materials: Strong oxidizing agents.
Hazardous Decomposition Products: Nitrogen oxides, carbon monoxide, carbon dioxide, nitrogen.
Hazardous Polymerization: Has not been reported.
11. Toxicological Information
LD50, oral rat: 4747mg/Kg
--------\Cancer Lists\------------------------------------------------------
---NTP Carcinogen---
Ingredient Known Anticipated IARC Category
--------------------------------- --- ----- ----------- ---- ---------
Copper (II)-Ethylenediamine (14552-35-3) No No None
Water (7732-18-5) No No None
REAGENTS, INC-MSDS- CUPRIETHYLENEDIAMINE 0.5 MOLAR PAGE 4
12. Ecological Information
Environmental Fate: No information found.
Environmental Toxicity: No information found.
13. Disposal Considerations
Whatever cannot be saved for recovery or recycling should be managed in an appropriate and approved
waste disposal facility. Processing, use or contamination of this product may change the waste
management options. State and local disposal regulations may differ from federal disposal regulations.
Dispose of container and unused contents in accordance with federal, state and local requirements.
14. Transport Information
US DOT
Shipping Name: CUPRIETHYLENEDIAMINE SOLUTION
Hazard Class: 8, 6.1
UN Number: UN1761
Packing Group: III
15. Regulatory Information
--------\Chemical Inventory Status - Part 1\---------------------------------
Ingredient TSCA EC Japan Australia
----------------------------------------------- ---- --- ----- ---------
Copper (II)-Ethylenediamine (14552-35-3) Yes Yes Yes Yes
Water (7732-18-5) Yes Yes Yes Yes
--------\Chemical Inventory Status - Part 2\---------------------------------
--Canada--
Ingredient Korea DSL NDSL Phil.
----------------------------------------------- ----- --- ---- -----
Copper (II)-Ethylenediamine (14552-35-3) Yes Yes No Yes
Water (7732-18-5) Yes Yes No Yes
--------\Federal, State & International Regulations - Part 1\----------------
-SARA 302- ------SARA 313------
Ingredient RQ TPQ List Chemical Catg.
----------------------------------------- --- ----- ---- --------------
Copper (II)-Ethylenediamine (14552-35-3) No No No No
Water (7732-18-5) No No No No
--------\Federal, State & International Regulations - Part 2\----------------
-RCRA- -TSCA-
Ingredient CERCLA 261.33 8(d)
----------------------------------------- ------ ------ ------
Copper (II)-Ethylenediamine (14552-35-3) No No No
Water (7732-18-5) No No No
Chemical Weapons Convention: No TSCA 12(b): No CDTA: No
SARA 311/312: Acute: Yes Chronic: Yes Fire: No Pressure: No
REAGENTS, INC-MSDS- CUPRIETHYLENEDIAMINE 0.5 MOLAR PAGE 5
Reactivity: No (Mixture / Liquid)
CAS# 14552-35-3 is not listed on Canada's Ingredient Disclosure List.
16. Other Information
NFPA Ratings: Health: 2 Flammability: 0 Reactivity: 0
Label Hazard Warning: DANGER! CAUSES BURNS. VAPOR HARMFUL. AVOID CONTACT
WITH EYES, SKIN OR CLOTHING. DO NOT BREATHE VAPOR. USE ONLY WITH
ADEQUATE VENTILATION. KEEP TIGHTLY CLOSED. WASH THOROUGHLY AFTER
HANDLING.
Label Precautions:
Avoid contact with eyes, skin and clothing.
Keep container closed.
Use with adequate ventilation.
Wash thoroughly after handling.
Label First Aid: In case of contact, immediately flush eyes or skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes. Wash clothing before reuse. If inhaled,
remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. If
swallowed, give large amounts of water to drink. Never give anything by mouth to an unconscious
person. In all cases, get medical attention.
Product Use: Laboratory Reagent.
Disclaimer:
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Reagents, Inc. provides the information contained herein in good faith but makes no representation
as to its comprehensiveness or accuracy. This document is intended only as a guide to the appropriate
precautionary handling of the material by a properly trained person using this product. Individuals
receiving the information must exercise their independent judgment in determining its
appropriateness for a particular purpose. REAGENTS, INC. MAKES NO REPRESENTATIONS OR
WARRANTIES, EITHER EXPRESS OR IMPLIED, INCLUDING WITHOUT LIMITATION ANY
WARRANTIES OF MERCHANTABILITY, FITNESS FOR A PARTICULAR PURPOSE WITH
RESPECT TO THE INFORMATION SET FORTH HEREIN OR THE PRODUCT TO WHICH
THE INFORMATION REFERS. ACCORDINGLY, REAGENTS, INC. WILL NOT BE
RESPONSIBLE FOR DAMAGES RESULTING FROM USE OF OR RELIANCE UPON THIS
INFORMATION.
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