MOLYBOND 122L DRY FILM LUBRICANT
Chemwatch Material Safety Data Sheet
Issue Date: 16-Jun-2006 CHEMWATCH 40185
XCC317SCP Version No:3
CD 2007/3 Page 1 of 6
Section 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME
MOLYBOND 122L DRY FILM LUBRICANT
SYNONYMS
"molybdenum disulfide lubricant"
PROPER SHIPPING NAME
FLAMMABLE LIQUID, N.O.S.
(contains methylated spirits)
PRODUCT USE
Dry solid film lubricant applied by spraying, dipping or brushing.
SUPPLIER
Company:ITW Polymers& Fluids Company:ITW Polymers& Fluids New Zealand
Address: Address:
100 Hassall St Unit 2 / 38 Trugood Drive
Wetherill Park, NSW, 2164 East Tamaki, Auckland,2013
Australia New Zealand
Telephone:(02) 9757 8800 Telephone:(09) 272 1945
EmergencyTel: (02) 9757 8800 EmergencyTel: (09) 272 1945
Fax: (03) 9757 3855 Fax: (09) 273 6489
Section 2 - HAZARDS IDENTIFICATION
STATEMENT OF HAZARDOUS NATURE
HAZARDOUS SUBSTANCE. DANGEROUS GOODS. According to the Criteria of NOHSC, and the ADG Code.
POISONS SCHEDULE
None
RISK
Risk Codes Risk Phrases
R11 Highly flammable.
R36/38 Irritating to eyes and skin.
R52/53 Harmful to aquatic organisms may cause long- term adverse
effects in the aquatic environment.
R67 Vapours may cause drowsiness and dizziness.
SAFETY
Safety Codes Safety Phrases
S16 Keep away from sources of ignition. No smoking.
S23 Do not breathe gas/ fumes/ vapour/ spray.
S39 Wear eye/ face protection.
S51 Use only in well ventilated areas.
S09 Keep container in a well ventilated place.
S29 Do not empty into drains.
S401 To clean the floor and all objects contaminated by this
material use water and detergent.
S07 Keep container tightly closed.
S27 Take off immediately all contaminated clothing.
S26 In case of contact with eyes rinse with plenty of water and
contact Doctor or Poisons Information Centre.
S46 If swallowed IMMEDIATELY contact Doctor or Poisons
Information Centre (show this container or label).
S60 This material and its container must be disposed of as
hazardous waste.
continued...
MOLYBOND 122L DRY FILM LUBRICANT
Chemwatch Material Safety Data Sheet
Issue Date: 16-Jun-2006 CHEMWATCH 40185
XCC317SCP Version No:3
CD 2007/3 Page 2 of 6
Section 3 - COMPOSITION / INFORMATION ON INGREDIENTS
NAME CAS RN %
methylated spirits Not avail. 30-60
molybdenum disulfide 1317-33-5 10-30^
ketone solvent <30
hydrocarbon solvents <30
resins <30
phosphoric acid 7664-38-2 <10
NOTE: Manufacturer has supplied full ingredient
information to allow CHEMWATCH assessment.
Section 4 - FIRST AID MEASURES
SWALLOWED
路 For advice, contact a Poisons Information Centre or a doctor at once.
路 Urgent hospital treatment is likely to be needed.
EYE
If this product comes in contact with the eyes:
路 Wash out immediately with fresh running water.
路 Ensure complete irrigation of the eye by keeping eyelids apart and away from eye and moving the eyelids by occasionally lifting
the upper and lower lids.
SKIN
If skin contact occurs:
路 Immediately remove all contaminated clothing, including footwear.
路 Flush skin and hair with running water (and soap if available).
INHALED
路 If fumes or combustion products are inhaled remove from contaminated area.
路 Lay patient down. Keep warm and rested.
NOTES TO PHYSICIAN
For acute or short term repeated exposures to ethanol:
路 Acute ingestion in non-tolerant patients usually responds to supportive care with special attention to prevention of aspiration
, replacement of fluid and correction of nutritional deficiencies (magnesium, thiamine pyridoxine, Vitamins C and K).
路 Give 50% dextrose (50-100 ml) IV to obtunded patients following blood draw for glucose determination.
路 Comatose patients should be treated with initial attention to airway, breathing, circulation and drugs of immediate importance
(glucose, thiamine).
路 Decontamination is probably unnecessary more than 1 hour after a single observed ingestion. Cathartics and charcoal may be
given but are probably not effective in single ingestions.
路 Fructose administration is contra-indicated due to side effects.
Section 5 - FIRE FIGHTING MEASURES
EXTINGUISHING MEDIA
路 Foam.
路 Dry chemical powder.
路 BCF (where regulations permit).
路 Carbon dioxide.
路 Water spray or fog - Large fires only.
FIRE FIGHTING
路 Alert Fire Brigade and tell them location and nature of hazard.
路 May be violently or explosively reactive.
路 Wear breathing apparatus plus protective gloves.
路 Prevent, by any means available, spillage from entering drains or water course.
路 Consider evacuation (or protect in place).
路 Fight fire from a safe distance, with adequate cover.
路 If safe, switch off electrical equipment until vapour fire hazard removed.
路 Use water delivered as a fine spray to control the fire and cool adjacent area.
路 Avoid spraying water onto liquid pools.
路 Do not approach containers suspected to be hot.
路 Cool fire exposed containers with water spray from a protected location.
路 If safe to do so, remove containers from path of fire.
FIRE/EXPLOSION HAZARD
路 Liquid and vapour are highly flammable.
路 Severe fire hazard when exposed to heat, flame and/or oxidisers.
路 Vapour may travel a considerable distance to source of ignition.
continued...
MOLYBOND 122L DRY FILM LUBRICANT
Chemwatch Material Safety Data Sheet
Issue Date: 16-Jun-2006 CHEMWATCH 40185
XCC317SCP Version No:3
CD 2007/3 Page 3 of 6
Section 5 - FIRE FIGHTING MEASURES
路 Heating may cause expansion or decomposition leading to violent rupture of containers.
路 On combustion, may emit toxic fumes of carbon monoxide (CO).
Combustion products include:.
carbon dioxide (CO2).
other pyrolysis products typical of burning organic material.
FIRE INCOMPATIBILITY
Avoid contamination with oxidising agents i.e. nitrates, oxidising acids, chlorine bleaches, pool chlorine etc. as ignition may
result.
HAZCHEM: 3[Y]E
Section 6 - ACCIDENTAL RELEASE MEASURES
EMERGENCY PROCEDURES
MINOR SPILLS
路 Remove all ignition sources.
路 Clean up all spills immediately.
路 Avoid breathing vapours and contact with skin and eyes.
路 Control personal contact by using protective equipment.
路 Contain and absorb small quantities with vermiculite or other absorbent material.
路 Wipe up.
路 Collect residues in a flammable waste container.
MAJOR SPILLS
路 Clear area of personnel and move upwind.
路 Alert Fire Brigade and tell them location and nature of hazard.
路 May be violently or explosively reactive.
路 Wear breathing apparatus plus protective gloves.
路 Prevent, by any means available, spillage from entering drains or water course.
路 Consider evacuation (or protect in place).
路 No smoking, naked lights or ignition sources.
路 Increase ventilation.
路 Stop leak if safe to do so.
路 Water spray or fog may be used to disperse /absorb vapour.
路 Contain spill with sand, earth or vermiculite.
路 Use only spark-free shovels and explosion proof equipment.
路 Collect recoverable product into labelled containers for recycling.
路 Absorb remaining product with sand, earth or vermiculite.
路 Collect solid residues and seal in labelled drums for disposal.
路 Wash area and prevent runoff into drains.
路 If contamination of drains or waterways occurs, advise emergency services.
Personal Protective Equipment advice is contained in Section 8 of the MSDS.
Section 7 - HANDLING AND STORAGE
PROCEDURE FOR HANDLING
路 Avoid all personal contact, including inhalation.
路 Wear protective clothing when risk of exposure occurs.
路 Use in a well-ventilated area.
路 Prevent concentration in hollows and sumps.
路 DO NOT enter confined spaces until atmosphere has been checked.
路 Avoid smoking, naked lights, heat or ignition sources.
路 When handling, DO NOT eat, drink or smoke.
路 Vapour may ignite on pumping or pouring due to static electricity.
路 DO NOT use plastic buckets.
路 Earth and secure metal containers when dispensing or pouring product.
路 Use spark-free tools when handling.
路 Avoid contact with incompatible materials.
路 Keep containers securely sealed.
路 Avoid physical damage to containers.
路 Always wash hands with soap and water after handling.
路 Work clothes should be laundered separately.
路 Use good occupational work practice.
路 Observe manufacturer's storing and handling recommendations.
路 Atmosphere should be regularly checked against established exposure standards to ensure safe working conditions.
DO NOT allow clothing wet with material to stay in contact with skin.
SUITABLE CONTAINER
路 Packing as supplied by manufacturer.
continued...
MOLYBOND 122L DRY FILM LUBRICANT
Chemwatch Material Safety Data Sheet
Issue Date: 16-Jun-2006 CHEMWATCH 40185
XCC317SCP Version No:3
CD 2007/3 Page 4 of 6
Section 7 - HANDLING AND STORAGE
路 Plastic containers may only be used if approved for flammable liquid.
路 Check that containers are clearly labelled and free from leaks.
路 For low viscosity materials (i) : Drums and jerry cans must be of the non-removable head type. (ii) : Where a can is to be used
as an inner package, the can must have a screwed enclosure.
路 For materials with a viscosity of at least 2680 cSt. (23 deg. C)
路 For manufactured product having a viscosity of at least 250 cSt. (23 deg. C)
路 Manufactured product that requires stirring before use and having a viscosity of at least 20 cSt (25 deg. C)
(i) : Removable head packaging;
(ii) : Cans with friction closures and
(iii) : low pressure tubes and cartridges may be used.
路 Where combination packages are used, and the inner packages are of glass, there must be sufficient inert cushioning material in
contact with inner and outer packages
路 In addition, where inner packagings are glass and contain liquids of packing group I there must be sufficient inert absorbent
to absorb any spillage, unless the outer packaging is a close fitting moulded plastic box and the substances are not incompatible
with the plastic.
STORAGE INCOMPATIBILITY
Avoid reaction with oxidising agents.
STORAGE REQUIREMENTS
路 Store in original containers in approved flame-proof area.
路 No smoking, naked lights, heat or ignition sources.
路 DO NOT store in pits, depressions, basements or areas where vapours may be trapped.
路 Keep containers securely sealed.
路 Store away from incompatible materials in a cool, dry well ventilated area.
路 Protect containers against physical damage and check regularly for leaks.
路 Observe manufacturer's storing and handling recommendations.
Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION
EXPOSURE CONTROLS
Source Material TWA mg/m鲁 STEL mg/m鲁
_________ _________ _____ _____
Australia Exposure phosphoric acid 1 3
Standards (Phosphoric acid)
PERSONAL PROTECTION
RESPIRATOR
Type AB-P Filter of sufficient capacity
EYE
路 Safety glasses with side shields.
路 Chemical goggles.
路 Contact lenses may pose a special hazard; soft contact lenses may absorb and concentrate irritants. A written policy document,
describing the wearing of lens or restrictions on use, should be created for each workplace or task. This should include a review
of lens absorption and adsorption for the class of chemicals in use and an account of injury experience. Medical and first-aid
personnel should be trained in their removal and suitable equipment should be readily available. In the event of chemical
exposure, begin eye irrigation immediately and remove contact lens as soon as practicable. Lens should be removed at the first
signs of eye redness or irritation - lens should be removed in a clean environment only after workers have washed hands
thoroughly. [CDC NIOSH Current Intelligence Bulletin 59].
HANDS/FEET
Wear chemical protective gloves, eg. PVC.
Wear safety footwear or safety gumboots, eg. Rubber.
OTHER
路 Overalls.
路 PVC Apron.
路 PVC protective suit may be required if exposure severe.
路 Eyewash unit.
路 Ensure there is ready access to a safety shower.
ENGINEERING CONTROLS
For flammable liquids and flammable gases, local exhaust ventilation or a process enclosure ventilation system may be required.
Ventilation equipment should be explosion-resistant.
continued...
MOLYBOND 122L DRY FILM LUBRICANT
Chemwatch Material Safety Data Sheet
Issue Date: 16-Jun-2006 CHEMWATCH 40185
XCC317SCP Version No:3
CD 2007/3 Page 5 of 6
Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
APPEARANCE
Black highly flammableliquid with solvent odour; partly mixes with water. Leaves black film on evaporationof solvents.
PHYSICAL PROPERTIES
Does not mix with water.
Molecular Weight: Not applicable. Boiling Range (掳C): Not available
Melting Range (掳C): Not available. Specific Gravity (water=1): Not available
Solubility in water (g/L): Partly miscible pH (as supplied): Not applicable
pH (1% solution): Not available. Vapour Pressure (kPa): Not available
Volatile Component (%vol): >60 Evaporation Rate: Fast
Relative Vapour Density (air=1): >1 Flash Point (掳C): <23
Lower Explosive Limit (%): Not available Upper Explosive Limit (%): Not available
Autoignition Temp (掳C): Not available. Decomposition Temp (掳C): Not available.
State: LIQUID Viscosity: Not available
Section 10 - CHEMICAL STABILITY AND REACTIVITY INFORMATION
CONDITIONS CONTRIBUTING TO INSTABILITY
路 Presence of incompatible materials.
路 Product is considered stable.
路 Hazardous polymerisation will not occur.
Section 11 - TOXICOLOGICAL INFORMATION
POTENTIAL HEALTH EFFECTS
ACUTE HEALTH EFFECTS CHRONIC HEALTH EFFECTS
Irritating to eyes and skin. Not applicable.
Vapours may cause dizziness or suffocation.
Vapours may cause drowsiness and dizziness.
TOXICITY AND IRRITATION
Not available. Refer to individual constituents.
Section 12 - ECOLOGICAL INFORMATION
Marine Pollutant:Not Determined
Harmful to aquatic organisms,may cause long-term adverse effects in the aquatic environment.
This material and its container must be disposed of as hazardouswaste.
Section 13 - DISPOSAL CONSIDERATIONS
路 Containers may still present a chemical hazard/ danger when empty.
路 Return to supplier for reuse/ recycling if possible.
Otherwise:
路 If container can not be cleaned sufficiently well to ensure that residuals do not remain or if the container cannot be used to
store the same product, then puncture containers, to prevent re-use, and bury at an authorised landfill.
路 Where possible retain label warnings and MSDS and observe all notices pertaining to the product.
Section 14 - TRANSPORTATION INFORMATION
Labels Required: FLAMMABLE LIQUID
HAZCHEM: 3[Y]E
UNDG:
Dangerous Goods Class: 3 Subrisk: None
UN Number: 1993 Packing Group: II
Shipping Name:FLAMMABLE LIQUID, N.O.S.
(contains methylated spirits)
continued...
MOLYBOND 122L DRY FILM LUBRICANT
Chemwatch Material Safety Data Sheet
Issue Date: 16-Jun-2006 CHEMWATCH 40185
XCC317SCP Version No:3
CD 2007/3 Page 6 of 6
Section 14 - TRANSPORTATION INFORMATION
Air Transport IATA:
ICAO/IATA Class: 3 ICAO/IATA Subrisk: None
UN/ID Number: 1993 Packing Group: II
Special provisions: A3
Shipping Name: FLAMMABLE LIQUID N.O.S.
Maritime Transport IMDG:
IMDG Class: 3 IMDG Subrisk: None
UN Number: 1993 Packing Group: II
EMS Number: F- E, S- E Special provisions: 274 330 944
Marine Pollutant: Not Determined
Shipping Name: FLAMMABLE LIQUID, N.O.S.
Section 15 - REGULATORY INFORMATION
POISONS SCHEDULE: None
REGULATIONS
Molybond 122L Dry Film Lubricant (CAS: None):
No regulationsapplicable
phosphoricacid (CAS: 7664-38-2)is found on the following regulatorylists;
AustraliaExposure Standards
AustraliaHigh Volume Industrial Chemical List (HVICL)
AustraliaInventoryof Chemical Substances(AICS)
AustraliaNational Pollutant Inventory
AustraliaStandard for the Uniform Schedulingof Drugs and Poisons (SUSDP) - AppendixE (Part 2)
AustraliaStandard for the Uniform Schedulingof Drugs and Poisons (SUSDP) - AppendixF (Part 3)
AustraliaStandard for the Uniform Schedulingof Drugs and Poisons (SUSDP) - Schedule 5
AustraliaStandard for the Uniform Schedulingof Drugs and Poisons (SUSDP) - Schedule 6
IMO MARPOL73/78 (Annex II) - List of Noxious Liquid SubstancesCarried in Bulk
InternationalCouncil of Chemical Associations(ICCA) - High ProductionVolume List
OECD RepresentativeList of High ProductionVolume (HPV) Chemicals
No data available for methylatedspirits as CAS: Not avail.
Section 16 - OTHER INFORMATION
Classification of the preparation and its individual components has drawn on official and authoritative sources as well as
independent review by the Chemwatch Classification committee using available literature references.
This document is copyright. Apart from any fair dealing for the purposes of private study, research, review or criticism, as permitted under the Copyright Act,
no part may be reproduced by any process without written permission from CHEMWATCH. TEL (+61 3) 9572 4700.
Issue Date: 16-Jun-2006
Print Date: 27-Sep-2007
|