ROCOL COPPER ANTI-SEIZE (J166)
ChemWatch Material Safety Data Sheet CHEMWATCH 4908-60
Issue Date: Fri 14-Jan-2005 CD 2004/4 Page 1 of 9
Section 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME
ROCOL COPPER ANTI-SEIZE (J166)
SYNONYMS
anti- seize grease
PRODUCT USE
Prevention of seizure in threaded fittings.
SUPPLIER
Company: ITW Polymers And Fluids Pty Ltd
Address:
100 Hassall Street
Wetherill Park
NSW, 2164
AUSTRALIA
Telephone: (+61 2) 9757 8800
Fax: 02 9757 3855
HAZARD RATINGS
Flammability
Toxicity
Body Contact
Reactivity
Chronic
SCALE: Min/Nil=0 Low=1 Moderate=2 High=3 Extreme=4
Section 2 - HAZARDS IDENTIFICATION
STATEMENT OF HAZARDOUS NATURE
HAZARDOUS SUBSTANCE. NON-DANGEROUS GOODS.
According to the Criteria of NOHSC, and the ADG Code.
POISONS SCHEDULE
None
RISK
Danger of cumulative effects.
Harmful: danger of serious damage to health by prolonged exposure through
inhalation.
SAFETY
Keep container in a well ventilated place.
Take off immediately all contaminated clothing.
If you feel unwell contact Doctor or Poisons Information Centre. (Show the label
if possible).
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ROCOL COPPER ANTI-SEIZE (J166)
ChemWatch Material Safety Data Sheet CHEMWATCH 4908-60
Issue Date: Fri 14-Jan-2005 CD 2004/4 Page 2 of 9
Section 3 - COMPOSITION / INFORMATION ON INGREDIENTS
NAME CAS RN %
mineral oil Not avail. 30-60
organically modified clay 1-10
graphite 7782-42-5 1-10^
molybdenum disulfide 1317-33-5 1-10^
copper 7440-50-8 1-10
Section 4 - FIRST AID MEASURES
SWALLOWED
鈥? Immediately give a glass of water.
鈥? First aid is not generally required. If in doubt, contact a Poisons
Information Centre or a doctor.
EYE
If this product comes in contact with eyes:
鈥? Wash out immediately with water.
鈥? If irritation continues, seek medical attention.
鈥? Removal of contact lenses after an eye injury should only be undertaken by
skilled personnel.
SKIN
If skin or hair contact occurs:
鈥? Flush skin and hair with running water (and soap if available).
鈥? Seek medical attention in event of irritation.
INHALED
鈥? If fumes or combustion products are inhaled remove from contaminated area.
鈥? Other measures are usually unnecessary.
NOTES TO PHYSICIAN
Treat symptomatically.
鈥? Heavy and persistent skin contamination over many years may lead to dysplastic
changes. Pre-existing skin disorders may be aggravated by exposure to this
product.
鈥? In general, emesis induction is unnecessary with high viscosity, low
volatility products, i.e. most oils and greases.
鈥? High pressure accidental injection through the skin should be assessed for
possible incision, irrigation and/or debridement.
NOTE: Injuries may not seem serious at first, but within a few hours tissue may
become swollen, discoloured and extremely painful with extensive subcutaneous
necrosis. Product may be forced through considerable distances along tissue
planes.
Section 5 - FIRE FIGHTING MEASURES
EXTINGUISHING MEDIA
鈥? Foam.
鈥? Dry chemical powder.
鈥? BCF (where regulations permit).
鈥? Carbon dioxide.
鈥? Water spray or fog - Large fires only.
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ROCOL COPPER ANTI-SEIZE (J166)
ChemWatch Material Safety Data Sheet CHEMWATCH 4908-60
Issue Date: Fri 14-Jan-2005 CD 2004/4 Page 3 of 9
Section 5 - FIRE FIGHTING MEASURES
FIRE FIGHTING
鈥? Alert Fire Brigade and tell them location and nature of hazard.
鈥? Wear breathing apparatus plus protective gloves.
鈥? Prevent, by any means available, spillage from entering drains or water
courses.
鈥? Use water delivered as a fine spray to control fire and cool adjacent area.
鈥? DO NOT approach containers suspected to be hot.
鈥? Cool fire exposed containers with water spray from a protected location.
鈥? If safe to do so, remove containers from path of fire.
鈥? Equipment should be thoroughly decontaminated after use.
FIRE/EXPLOSION HAZARD
鈥? Hot organic vapours or mist are capable of sudden spontaneous combustion when
mixed with air even at temperatures below their published autoignition
temperatures.
鈥? The temperature of ignition decreases with increasing vapour volume and
vapour/air contact times and is influenced by pressure change.
鈥? Ignition may occur under elevated-temperature process conditions especially in
processes performed under vacuum subjected to sudden ingress of air or in
processes performed at elevated pressure, where sudden escape of vapours or
mists to the atmosphere occurs.
鈥? Combustible.
鈥? Slight fire hazard when exposed to heat or flame.
鈥? Heating may cause expansion or decomposition leading to violent rupture of
containers.
鈥? On combustion, may emit toxic fumes of carbon monoxide (CO).
鈥? May emit acrid smoke.
鈥? Mists containing combustible materials may be explosive.
Combustion products include , carbon dioxide (CO2) , other pyrolysis products
typical of burning organic material.
May emit poisonous fumes.
FIRE INCOMPATIBILITY
Avoid contamination with oxidising agents i.e. nitrates, oxidising acids,
chlorine bleaches, pool chlorine etc. as ignition may result
HAZCHEM
None
Section 6 - ACCIDENTAL RELEASE MEASURES
EMERGENCY PROCEDURES
MINOR SPILLS
Slippery when spilt.
鈥? Clean up all spills immediately.
鈥? Avoid contact with skin and eyes.
鈥? Wear impervious gloves and safety goggles.
鈥? Trowel up/scrape up.
鈥? Place spilled material in clean, dry, sealed container.
鈥? Flush spill area with water.
MAJOR SPILLS
Slippery when spilt.
Minor hazard.
鈥? Clear area of personnel.
鈥? Alert Fire Brigade and tell them location and nature of hazard.
鈥? Control personal contact by using protective equipment as required.
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ROCOL COPPER ANTI-SEIZE (J166)
ChemWatch Material Safety Data Sheet CHEMWATCH 4908-60
Issue Date: Fri 14-Jan-2005 CD 2004/4 Page 4 of 9
Section 6 - ACCIDENTAL RELEASE MEASURES
鈥? Prevent spillage from entering drains or water ways.
鈥? Contain spill with sand, earth or vermiculite.
鈥? Collect recoverable product into labelled containers for recycling.
鈥? Absorb remaining product with sand, earth or vermiculite and place in
appropriate containers for disposal.
鈥? Wash area and prevent runoff into drains or waterways.
鈥? If contamination of drains or waterways occurs, advise emergency services.
Personal Protective Equipment advice is contained in Section 8 of the MSDS.
Section 7 - HANDLING AND STORAGE
PROCEDURE FOR HANDLING
鈥? Avoid all personal contact, including inhalation.
鈥? Wear protective clothing when risk of exposure occurs.
鈥? Use in a well-ventilated area.
鈥? Prevent concentration in hollows and sumps.
鈥? DO NOT enter confined spaces until atmosphere has been checked.
鈥? DO NOT allow material to contact humans, exposed food or food utensils.
鈥? Avoid contact with incompatible materials.
鈥? When handling, DO NOT eat, drink or smoke.
鈥? Keep containers securely sealed when not in use.
鈥? Avoid physical damage to containers.
鈥? Always wash hands with soap and water after handling.
鈥? Work clothes should be laundered separately. Launder contaminated clothing
before re-use.
鈥? Use good occupational work practice.
鈥? Observe manufacturer's storing and handling recommendations.
鈥? Atmosphere should be regularly checked against established exposure standards
to ensure safe working conditions are maintained.
SUITABLE CONTAINER
鈥? Metal can or drum
鈥? Packaging as recommended by manufacturer.
鈥? Check all containers are clearly labelled and free from leaks.
STORAGE INCOMPATIBILITY
Avoid reaction with oxidising agents
Store between 1-40 deg C.
STORAGE REQUIREMENTS
鈥? Store in original containers.
鈥? Keep containers securely sealed.
鈥? Store in a cool, dry, well-ventilated area.
鈥? Store away from incompatible materials and foodstuff containers.
鈥? Protect containers against physical damage and check regularly for leaks.
鈥? Observe manufacturer's storing and handling recommendations.
Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION
EXPOSURE CONTROLS
No data available for mineral oil as (CAS: Not avail) / (CAS: 7440-50-8)
None assigned. Refer to individual constituents.
EXPOSURE STANDARDS FOR MIXTURE
"Worst Case" computer-aided prediction of spray/ mist or fume/ dust components
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ROCOL COPPER ANTI-SEIZE (J166)
ChemWatch Material Safety Data Sheet CHEMWATCH 4908-60
Issue Date: Fri 14-Jan-2005 CD 2004/4 Page 5 of 9
Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION
and concentration:
Composite Exposure Standard for Mixture (TWA) :3.1818 mg/m鲁.
Operations which produce a spray/mist or fume/dust, introduce particulates to
the breathing zone.
If the breathing zone concentration of ANY of the components listed below is
exceeded, "Worst Case" considerations deem the individual to be overexposed.
Component Breathing Zone ppm Breathing Zone mg/m鲁 Mixture Conc (%)
Component Breathing Zone Mixture Conc
(mg/m鲁) (%)
copper 0.4545 10.0
mineral oil 2.7273 60.0
INGREDIENT DATA
MINERAL OIL:
TLV TWA: 5 mg/m鲁 () [ACGIH]
TLV STEL: 10 mg/m鲁 [ACGIH]
oil mist, mineral
TLV TWA: 5 mg/m鲁; STEL: 10 mg/m鲁.
NOTICE OF INTENDED CHANGE.
TLV TWA 0.2 mg/m鲁 inhalable fraction highly refined A4
NOTE: This substance has been classified by the ACGIH as A4
NOT classifiable as causing cancer in humans.
ES TWA: 5 mg/m鲁 (oil mist, refined mineral)
Human exposure to oil mist alone has not been demonstrated to cause health
effects except at levels above 5 mg/m鲁 (this applies to particulates sampled by
a method that does not collect vapour). It is not advisable to apply this
standard to oils containing unknown concentrations and types of additive.
COPPER:
TLV TWA: 1 mg/m鲁 Dusts and mists as Cu [ACGIH]
TLV TWA: 0.2 mg/m鲁 Fume [ACGIH]
PEL TWA: 1 mg/m鲁 [OSHA Z1]
copper dusts and mists, as Cu (A.Wt: 63.54)
ES TWA: 1 mg/m鲁
TLV TWA: 1 mg/m鲁
OES TWA: 1 mg/m鲁; STEL: 2 mg/m鲁
copper fume, as Cu
ES-TWA: 0.2 mg/m鲁
TLV-TWA: 0.2 mg/m鲁
OES-TWA: 0.2 mg/m鲁
IDLH Level: 100 mg/m鲁 (fume)
PERSONAL PROTECTION
EYE
鈥? Safety glasses with side shields
鈥? Chemical goggles.
鈥? Contact lenses pose a special hazard; soft lenses may absorb irritants and all
lenses concentrate them.
HANDS/FEET
Wear chemical protective gloves, eg. PVC.
Wear safety footwear or safety gumboots, eg. Rubber
OTHER
鈥? Overalls.
鈥? P.V.C. apron.
鈥? Barrier cream.
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ROCOL COPPER ANTI-SEIZE (J166)
ChemWatch Material Safety Data Sheet CHEMWATCH 4908-60
Issue Date: Fri 14-Jan-2005 CD 2004/4 Page 6 of 9
Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION
鈥? Skin cleansing cream.
鈥? Eye wash unit.
RESPIRATOR
Protection Factor Half-Face Full-Face Powered Air
Respirator Respirator Respirator
10 x ES P1 Air-line* -- PAPR-P1 -
50 x ES Air-line** P2 PAPR-P2
100 x ES - P3 -
Air-line* -
100+ x ES - Air-line** PAPR-P3
* - Negative pressure demand ** - Continuous flow
The local concentration of material, quantity and conditions of use determine
the type of personal protective equipment required. For further information
consult site specific CHEMWATCH data (if available), or your Occupational
Health and Safety Advisor.
ENGINEERING CONTROLS
General exhaust is adequate under normal operating conditions. If risk of
overexposure exists, wear SAA approved respirator. Correct fit is essential to
obtain adequate protection. Provide adequate ventilation in warehouse or closed
storage areas.
Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
APPEARANCE
Orange to brown odourless paste; does not mix with water.
PHYSICAL PROPERTIES
Liquid.
Does not mix with water.
Sinks in water.
Molecular Weight: Not applicable Boiling Range (掳C): Not available
Melting Range (掳C): Not available Specific Gravity (water=1): 1.3 (approx.)
Solubility in water (g/L): Immiscible pH (as supplied): Not applicable
pH (1% solution): Not applicable Vapour Pressure (kPa): Not available
Volatile Component (%vol): Not available Evaporation Rate: Not available
Relative Vapour Density (air=1): Not available Flash Point (掳C): >200
Lower Explosive Limit (%): Not available Upper Explosive Limit (%): Not available
Autoignition Temp (掳C): >200 Decomposition Temp (掳C): Not available
State: Non slump paste
Section 10 - CHEMICAL STABILITY AND REACTIVITY INFORMATION
CONDITIONS CONTRIBUTING TO INSTABILITY
Product is considered stable and hazardous polymerisation will not occur.
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ROCOL COPPER ANTI-SEIZE (J166)
ChemWatch Material Safety Data Sheet CHEMWATCH 4908-60
Issue Date: Fri 14-Jan-2005 CD 2004/4 Page 7 of 9
Section 11 - TOXICOLOGICAL INFORMATION
POTENTIAL HEALTH EFFECTS
ACUTE HEALTH EFFECTS
SWALLOWED
The material has NOT been classified by EC Directives or other classification
systems as "harmful by ingestion". This is because of the lack of corroborating
animal or human evidence. The material may still be damaging to the health of
the individual, following ingestion, especially where pre-existing organ (e.g
liver, kidney) damage is evident. Present definitions of harmful or toxic
substances are generally based on doses producing mortality rather than those
producing morbidity (disease, ill-health). Gastrointestinal tract discomfort may
produce nausea and vomiting. In an occupational setting however, ingestion of
insignificant quantities is not thought to be cause for concern.
EYE
Although the material is not thought to be an irritant (as classified by EC
Directives), direct contact with the eye may produce transient discomfort
characterised by tearing or conjunctival redness (as with windburn).
SKIN
The material is not thought to produce adverse health effects or skin irritation
following contact (as classified by EC Directives using animal models).
Nevertheless, good hygiene practice requires that exposure be kept to a minimum
and that suitable gloves be used in an occupational setting.
Entry into the blood-stream, through, for example, cuts, abrasions or lesions,
may produce systemic injury with harmful effects. Examine the skin prior to the
use of the material and ensure that any external damage is suitably protected.
INHALED
The material is not thought to produce adverse health effects or irritation of
the respiratory tract (as classified by EC Directives using animal models).
Nevertheless, good hygiene practice requires that exposure be kept to a minimum
and that suitable control measures be used in an occupational setting.
Not normally a hazard due to non-volatile nature of product
CHRONIC HEALTH EFFECTS
Substance accumulation, in the human body, may occur and may cause some concern following
repeated or long-term occupational exposure. Principal route of exposure is by skin
contact; lesser exposures include inhalation of fumes from hot oils, oil mists or
droplets. Prolonged contact with mineral oils carries with it the risk of skin conditions
such as oil folliculitis, eczematous dermatitis, pigmentation of the face (melanosis) and
warts on the sole of the foot (plantar warts). With highly refined mineral oils no
appreciable systemic effects appear to result through skin absorption. Exposure to oil
mists frequently elicits respiratory conditions, such as asthma; the provoking agent is
probably an additive. High oil mist concentrations may produce lipoid pneumonia although
clinical evidence is equivocal. In animals exposed to concentrations of 100 mg/m3 oil
mist, for periods of 12 to 26 months, the activity of lung and serum alkaline phosphatase
enzyme was raised; 5 mg/m3 oil mist did not produce this response. These enzyme changes
are sensitive early indicators of lung damage. Workers exposed to vapours of mineral oil
and kerosene for 5 to 35 years showed an increased prevalence of slight basal lung
fibrosis. Many studies have linked cancers of the skin and scrotum with mineral oil
exposure. Contaminants in the form of additives and the polycyclic aromatic hydrocarbons
(PAHs - as in the crude base stock) are probably responsible. PAH levels are higher in
aromatic process oils/used/reclaimed motor oils. Subchronic 90-day feeding studies
conducted on male and female rats on highly refined white mineral oils and waxes found
that higher molecular-weight hydrocarbons (microcrystalline waxes and the higher viscosity
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ROCOL COPPER ANTI-SEIZE (J166)
ChemWatch Material Safety Data Sheet CHEMWATCH 4908-60
Issue Date: Fri 14-Jan-2005 CD 2004/4 Page 8 of 9
Section 11 - TOXICOLOGICAL INFORMATION
oils) were without biological effects. Paraffin waxes and low- to mid viscosity oils
produced biological effects that were inversely proportional to molecular weight,
viscosity and melting point: oil-type and processing did not appear to be determinants.
Biological effects were more pronounced in females than in males. Effects occurred mainly
in the liver and mesenteric lymph nodes and included increased organ weights, microscopic
inflammatory changes, and evidence for the presence of saturated mineral hydrocarbons in
affected tissues. Inflammation of the cardiac mitral valve was also observed at high doses
in rats treated with paraffin waxes. Smith J.H., et al: Toxicologic Pathology: 24, 2,
214-230, 1996. Cattle, rabbits, and chicks on high dietary levels of molybdenum exhibited
deformities of joints of the extremities. Chronic exposure of workers in Russian
molybdenum-copper plant resulted in a fall in the albumin/globulin ratio owing to a rise
in globulins (particularly alpha-globulins) which is interpreted as evidence of liver
dysfunction with hyperbilirubinaemia. Hepatotoxic effects are also found in animals given
molybdenum salts with a rise in alpha-globulin levels, hypoalbuminaemia and increased
serum bilirubin reported. Other reported biochemical effects include an early depletive
effect on tissue nicotinamide nucleotides, hyperaminoaciduria, reduction in red blood cell
life-span and hyper-thyroidism. Industrial exposure to some insoluble molybdenum compounds
is thought to have resulted in an increased incidence of weakness, fatigue, anorexia,
headache and joint and muscular pain. Animals exposed to certain insoluble molybdenum
compounds show anorexia, diarrhoea, weight loss, listlessness, and liver and kidney
damage. Molybdenum disturbs bone metabolism, giving rise to lameness, bone joint
abnormalities, osteoporosis and high serum phosphatase levels. Low molybdenum intake has
been attributed to the high incidence of oesophageal cancer in South Africa among the
Bantu of Transkei, in China and in Russia. Under the conditions of a 2-year inhalation
study* there was equivocal evidence of carcinogenic activity of molybdenum trioxide in
male rats, male mice and female mice based on a marginally significant positive trend of
alveolar/bronchiolar adenoma or carcinoma. There was no evidence of carcinogenic activity
in female rats exposed to 10, 30 and 100 mg/m3. Exposure of male and female rats to
molybdenum trioxide by inhalation resulted in increased incidences of chronic alveolar
inflammation, hyaline degeneration of the olfactory epithelium (females), hyaline
degeneration of the respiratory epithelium and squamous metaplasia of the epiglottis.
Exposure of female and male mice to molybdenum trioxide resulted in an increased incidence
of metaplasia of the alveolar epithelium, histiocyte cellular inflammation (males),
hyaline degeneration of the respiratory epithelium, hyaline degeneration of the olfactory
epithelium (females), squamous metaplasia of the epiglottis, and hyperplasia of the
larynx. Molybdenum trioxide was not mutagenic in any of five strains of Salmonella
typhimurium and did not induce sister chromatid exchanges or chromosomal aberrations in
cultured Chinese hamster ovary cells in vitro. All tests were conducted with or without S9
metabolic activation enzymes. National Toxicology Program: Technical Report Series 462,
April 1997
Rocol Copper Anti-Seize (J166)
Not available. Refer to individual constituents.
unless otherwise specified data extracted from RTECS - Register of Toxic Effects
of Chemical Substances
MINERAL OIL:
Toxicity and Irritation data is related to chemical components and
varies as does the composition and source of the original crude.
A small but definite risk of occupational skin cancer occurs in workers
exposed to persistent skin contamination by oils over a period of years.
This risk has been attributed to the presence of certain polycyclic
aromatic hydrocarbons (PAH) (typified by benz[a]pyrene).
Petroleum oils which are solvent refined/extracted or severely hydrotreated,
contain very low concentrations of both.
COPPER:
TOXICITY IRRITATION
Oral (human) TDLo : 0.12 mg/kg Nil Reported
WARNING: Inhalation of high concentrations of copper fume
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ROCOL COPPER ANTI-SEIZE (J166)
ChemWatch Material Safety Data Sheet CHEMWATCH 4908-60
Issue Date: Fri 14-Jan-2005 CD 2004/4 Page 9 of 9
Section 11 - TOXICOLOGICAL INFORMATION
may cause "metal
fume fever", an acute industrial disease of short duration. Symptoms are
tiredness, influenza like respiratory tract irritation with fever.
Section 12 - ECOLOGICAL INFORMATION
DO NOT discharge into sewer or waterways.
Mobility: The product is insoluble in water. The product is poorly
absorbed onto soils or sediments.
Persistence / Degradability: Product is expected to be resistant to
biodegradation.
Bioaccumulation: Product is not expected to bioaccumulate. [Rocol]
Section 13 - DISPOSAL CONSIDERATIONS
Puncture containers to prevent re-use and bury at an authorised landfill.
Section 14 - TRANSPORTATION INFORMATION
Shipping Name:
NONE
Dangerous Goods Class: None
UN/NA Number: None
ADR Number: None
Packing Group: None
Labels Required:
Additional Shipping Information:
International Transport Regulations:
IMO: None
HAZCHEM
None
Section 15 - REGULATORY INFORMATION
POISONS SCHEDULE
None
Section 16 - OTHER INFORMATION
This document is copyright. Apart from any fair dealing for the purposes of
private study, research, review or criticism, as permitted under the Copyright
Act, no part may be reproduced by any process without written permission from
CHEMWATCH. TEL (+61 3) 9572 4700.
Issue Date: Fri 14-Jan-2005
Print Date: Fri 25-Feb-2005
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