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MSDS Material Safety Data Sheet
CAS

8002-13-9

File Name: rocol_com_au---bio_rail_curve_grease_msds.asp
                              ROCOL BIO RAIL CURVE GREASE
Chemwatch Material Safety Data Sheet
Issue Date: 17-May-2007 CHEMWATCH 6608-45
NC317ECP Version No:2
CD 2007/2 Page 1 of 7



Section 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION


PRODUCT NAME
ROCOL BIO RAIL CURVE GREASE

SYNONYMS



PRODUCT USE
Lubrication for rail curves and train wheels.

SUPPLIER
Company: ITW Polymers & Fluids
Address:
100 Hassall Street
Wetherill Park
NSW, 2164
AUS
Telephone: +61 2 9757 8800
Emergency Tel: +61 2 9757 8800
Fax: 1800 803 596



Section 2 - HAZARDS IDENTIFICATION


STATEMENT OF HAZARDOUS NATURE
NON-HAZARDOUS SUBSTANCE. NON-DANGEROUS GOODS. According to the Criteria of
NOHSC, and the ADG Code.

POISONS SCHEDULE
None

RISK SAFETY
None under normal operating conditions. Wear eye/face protection.
In case of contact with eyes, rinse with plenty
of water and contact Doctor or Poisons
Information Centre.


Section 3 - COMPOSITION / INFORMATION ON INGREDIENTS

NAME CAS RN %
canola oil 8002-13-9 70-80
clay thickener 10-15
ingredients nonhazardous <25


Section 4 - FIRST AID MEASURES


SWALLOWED
- If swallowed do NOT induce vomiting.
- If vomiting occurs, lean patient forward or place on left side (head-down position, if

continued...
ROCOL BIO RAIL CURVE GREASE
Chemwatch Material Safety Data Sheet
Issue Date: 17-May-2007 CHEMWATCH 6608-45
NC317ECP Version No:2
CD 2007/2 Page 2 of 7
Section 4 - FIRST AID MEASURES

possible) to maintain open airway and prevent aspiration.
- Observe the patient carefully.
- Never give liquid to a person showing signs of being sleepy or with reduced awareness;
i.e. becoming unconscious.
- Give water to rinse out mouth, then provide liquid slowly and as much as casualty can
comfortably drink.
- Seek medical advice.

EYE
If this product comes in contact with eyes:
- Wash out immediately with water.
- If irritation continues, seek medical attention.
- Removal of contact lenses after an eye injury should only be undertaken by skilled
personnel.

SKIN
If skin contact occurs:
- Immediately remove all contaminated clothing, including footwear.
- Flush skin and hair with running water (and soap if available).
- Seek medical attention in event of irritation.
If failure/misuse of high pressure/hydraulic equipment results in injection of grease/oil
through the skin seek urgent medical attention. Treat as surgical emergency.

INHALED
- If fumes or combustion products are inhaled remove from contaminated area.
- Other measures are usually unnecessary.

NOTES TO PHYSICIAN
Treat symptomatically.


Section 5 - FIRE FIGHTING MEASURES


EXTINGUISHING MEDIA
- Foam.
- Dry chemical powder.
- BCF (where regulations permit).
- Carbon dioxide.
- Water spray or fog - Large fires only.

FIRE FIGHTING
- Alert Fire Brigade and tell them location and nature of hazard.
- Wear breathing apparatus plus protective gloves.
- Prevent, by any means available, spillage from entering drains or water course.
- Use water delivered as a fine spray to control fire and cool adjacent area.
- Avoid spraying water onto liquid pools.
- Do not approach containers suspected to be hot.
- Cool fire exposed containers with water spray from a protected location.
- If safe to do so, remove containers from path of fire.

FIRE/EXPLOSION HAZARD
- Combustible.
- Slight fire hazard when exposed to heat or flame.
- Heating may cause expansion or decomposition leading to violent rupture of containers.
- On combustion, may emit toxic fumes of carbon monoxide (CO).
- May emit acrid smoke.
- Mists containing combustible materials may be explosive.

continued...
ROCOL BIO RAIL CURVE GREASE
Chemwatch Material Safety Data Sheet
Issue Date: 17-May-2007 CHEMWATCH 6608-45
NC317ECP Version No:2
CD 2007/2 Page 3 of 7
Section 5 - FIRE FIGHTING MEASURES

Combustion products include: carbon dioxide (CO2), sulfur oxides (SOx), nitrogen oxides
(NOx), other pyrolysis products typical of burning organic material.
May emit poisonous fumes.

FIRE INCOMPATIBILITY
Avoid contamination with oxidising agents i.e. nitrates, oxidising acids, chlorine
bleaches, pool chlorine etc. as ignition may result.

HAZCHEM: None


Section 6 - ACCIDENTAL RELEASE MEASURES


EMERGENCY PROCEDURES

MINOR SPILLS
Slippery when spilt.
- Clean up all spills immediately.
- Avoid contact with skin and eyes.
- Wear impervious gloves and safety goggles.
- Trowel up/scrape up.
- Place spilled material in clean, dry, sealed container.
- Flush spill area with water.

MAJOR SPILLS
Slippery when spilt.
Remove all ignition sources.
Minor hazard.
- Clear area of personnel.
- Alert Fire Brigade and tell them location and nature of hazard.
- Control personal contact by using protective equipment as required.
- Prevent spillage from entering drains or water ways.
- Contain spill with sand, earth or vermiculite.
- Collect recoverable product into labelled containers for recycling.
- Absorb remaining product with sand, earth or vermiculite and place in appropriate
containers for disposal.
- Wash area and prevent runoff into drains or waterways.
- If contamination of drains or waterways occurs, advise emergency services.

Personal Protective Equipment advice is contained in Section 8 of the MSDS.


Section 7 - HANDLING AND STORAGE


PROCEDURE FOR HANDLING
Remove all ignition sources.
- Limit all unnecessary personal contact.
- Wear protective clothing when risk of exposure occurs.
- Use in a well-ventilated area.
- When handling DO NOT eat, drink or smoke.
- Always wash hands with soap and water after handling.
- Avoid physical damage to containers.
- Use good occupational work practice.
- Observe manufacturer's storing and handling recommendations.



continued...
ROCOL BIO RAIL CURVE GREASE
Chemwatch Material Safety Data Sheet
Issue Date: 17-May-2007 CHEMWATCH 6608-45
NC317ECP Version No:2
CD 2007/2 Page 4 of 7
Section 7 - HANDLING AND STORAGE

SUITABLE CONTAINER
- Metal can or drum
- Packaging as recommended by manufacturer.
- Check all containers are clearly labelled and free from leaks.

STORAGE INCOMPATIBILITY
Avoid reaction with oxidising agents.

STORAGE REQUIREMENTS
- Store in original containers.
- Keep containers securely sealed.
- No smoking, naked lights or ignition sources.
- Store in a cool, dry, well-ventilated area.
- Store away from incompatible materials and foodstuff containers.
- Protect containers against physical damage and check regularly for leaks.
- Observe manufacturer's storing and handling recommendations.


Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION


EXPOSURE CONTROLS
The following materials had no OELs on our records
鈥? canola oil: CAS:8002- 13- 9



MATERIAL DATA
Not available. Refer to individual constituents.

INGREDIENT DATA
CANOLA OIL:
vegetable oil mists (except castor, cashew nut and similar irritant oils)
TLV TWA: 10 mg/m3
ES TWA: 10 mg/m3
OSHA PEL TWA: 15 mg/m3, total particulate; 5 mg/m3, respirable particulate
The common vegetable oil mists are considered "nuisance" particulates which have little
adverse effect on the lung. They do not produce toxic effects or significant organic
disease when exposures are kept under reasonable control. Direct instillation of
vegetable oils into rabbit lungs produces acute bronchitis whilst high oral doses are
laxatives.

PERSONAL PROTECTION

EYE
- Safety glasses with side shields
- Chemical goggles.
- Contact lenses may pose a special hazard; soft contact lenses may absorb and
concentrate irritants. A written policy document, describing the wearing of lens or
restrictions on use, should be created for each workplace or task. This should include a
review of lens absorption and adsorption for the class of chemicals in use and an account
of injury experience. Medical and first-aid personnel should be trained in their removal
and suitable equipment should be readily available. In the event of chemical exposure,
begin eye irrigation immediately and remove contact lens as soon as practicable. Lens
should be removed at the first signs of eye redness or irritation - lens should be
removed in a clean environment only after workers have washed hands thoroughly. [CDC
NIOSH Current Intelligence Bulletin 59].


continued...
ROCOL BIO RAIL CURVE GREASE
Chemwatch Material Safety Data Sheet
Issue Date: 17-May-2007 CHEMWATCH 6608-45
NC317ECP Version No:2
CD 2007/2 Page 5 of 7
Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION

HANDS/FEET
Wear chemical protective gloves, eg. PVC.
Wear safety footwear or safety gumboots, eg. Rubber.

OTHER
- Overalls.
- P.V.C. apron.
- Barrier cream.
- Skin cleansing cream.
- Eye wash unit.

The local concentration of material, quantity and conditions of use determine the type of
personal protective equipment required.
For further information consult site specific
CHEMWATCH data (if available), or your
Occupational Health and Safety Advisor.

ENGINEERING CONTROLS
General exhaust is adequate under normal operating conditions. If risk of overexposure
exists, wear SAA approved respirator. Correct fit is essential to obtain adequate
protection. Provide adequate ventilation in warehouse or closed storage areas.


Section 9 - PHYSICAL AND CHEMICAL PROPERTIES


APPEARANCE
Dark semi- solid grease; does not mix with water.

PHYSICAL PROPERTIES
Does not mix with water.

Molecular Weight: Not Applicable Boiling Range (掳 Not Av ailable
C):
Melting Range (掳 Not Available
C): Specific Gravity (water= 1): Not Available
Solubility in water (g/L): Immiscible pH (as supplied): Not Applicable
pH (1% solution): Not Applicable Vapour Pressure (kPa): Negligible
Volatile Component (%vol): Not Applicable Evaporation Rate: Not Applicable
Relative Vapour Density (air=1): Not Available Flash Point (掳 >200
C):
Lower Explosive Limit (%): Not Available Upper Explosive Limit (%): Not Available
Autoignition Temp (掳 Not Available
C): Decomposition Temp ( 掳 Not Available
C):
State: Non Slump Paste Viscosity: Not Available


Section 10 - CHEMICAL STABILITY AND REACTIVITY INFORMATION


CONDITIONS CONTRIBUTING TO INSTABILITY
- Presence of incompatible materials.
- Product is considered stable.
- Hazardous polymerisation will not occur.


Section 11 - TOXICOLOGICAL INFORMATION


POTENTIAL HEALTH EFFECTS



continued...
ROCOL BIO RAIL CURVE GREASE
Chemwatch Material Safety Data Sheet
Issue Date: 17-May-2007 CHEMWATCH 6608-45
NC317ECP Version No:2
CD 2007/2 Page 6 of 7
Section 11 - TOXICOLOGICAL INFORMATION

ACUTE HEALTH EFFECTS

SWALLOWED
The material has NOT been classified by EC Directives or other classification systems as
"harmful by ingestion". This is because of the lack of corroborating animal or human
evidence. The material may still be damaging to the health of the individual, following
ingestion, especially where pre-existing organ (eg. liver, kidney) damage is evident.
Present definitions of harmful or toxic substances are generally based on doses producing
mortality rather than those producing morbidity (disease, ill-health). Gastrointestinal
tract discomfort may produce nausea and vomiting. In an occupational setting however,
ingestion of insignificant quantities is not thought to be cause for concern.

EYE
Although the material is not thought to be an irritant (as classified by EC Directives),
direct contact with the eye may produce transient discomfort characterised by tearing or
conjunctival redness (as with windburn).

SKIN
The material is not thought to produce adverse health effects or skin irritation
following contact (as classified by EC Directives using animal models). Nevertheless,
good hygiene practice requires that exposure be kept to a minimum and that suitable
gloves be used in an occupational setting.

INHALED
Not normally a hazard due to non-volatile nature of product.

CHRONIC HEALTH EFFECTS
Long-term exposure to the product is not thought to produce chronic effects adverse to
the health (as classified by EC Directives using animal models); nevertheless exposure by
all routes should be minimised as a matter of course.

TOXICITY AND IRRITATION
Not available. Refer to individual constituents.

CANOLA OIL:
No significant acute toxicological data identified in literature search.



Section 12 - ECOLOGICAL INFORMATION

Contains biodegradable vegetable oil.


Section 13 - DISPOSAL CONSIDERATIONS

- Recycle wherever possible or consult manufacturer for recycling options.
- Consult State Land Waste Authority for disposal.
- Bury or incinerate residue at an approved site.
- Recycle containers if possible, or dispose of in an authorised landfill.


Section 14 - TRANSPORTATION INFORMATION

HAZCHEM: None


NOT REGULATED FOR TRANSPORT OF DANGEROUS GOODS:UN, IATA,
IMDG
continued...
ROCOL BIO RAIL CURVE GREASE
Chemwatch Material Safety Data Sheet
Issue Date: 17-May-2007 CHEMWATCH 6608-45
NC317ECP Version No:2
CD 2007/2 Page 7 of 7
Section 14 - TRANSPORTATION INFORMATION



Section 15 - REGULATORY INFORMATION


POISONS SCHEDULE: None

REGULATIONS
canola oil (CAS: 8002-13-9) is found on the following regulatory lists;
Australia Inventory of Chemical Substances (AICS)
Australia Therapeutic Goods Administration (TGA) Substances that may be used as active
ingredients in Listed medicines


Section 16 - OTHER INFORMATION


This document is copyright. Apart from any fair dealing for the purposes of private study, research, review or
criticism, as permitted under the Copyright Act, no part may be reproduced by any process without written permission
from CHEMWATCH. TEL (+61 3) 9572 4700.

Issue Date: 17-May-2007
Print Date: 17-May-2007

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