MOLYBOND G3500
ChemWatch Material Safety Data Sheet CHEMWATCH 40232
Issue Date: Sun 28-Dec-2003 CD 2004/2 Page 1 of 9
Section 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME
MOLYBOND G3500
SYNONYMS
G-3500 lubricant
PRODUCT USE
Lubricant, particularly for use where heat stability and
wear resistance is required.
SUPPLIER
Company: ITW Polymers And Fluids Pty Ltd Company: ITW Polymers And Fluids Pty Ltd
Address: Address:
100 Hassall Street Private Mail Bag 35
Wetherill Park Wetherill Park
NSW, 2164 NSW, 2164
AUSTRALIA AUSTRALIA
Telephone: (+61 2) 9757 8800
Fax: 02 9757 3855
HAZARD RATINGS
Flammability:
Toxicity:
Body Contact:
Reactivity:
Chronic:
SCALE: Min/Nil=0 Low=1 Moderate=2 High=3 Extreme=4
Section 2 - HAZARDS IDENTIFICATION
STATEMENT OF HAZARDOUS NATURE
NON-HAZARDOUS SUBSTANCE. NON-DANGEROUS GOODS.
According to the Criteria of NOHSC, and the ADG Code.
POISONS SCHEDULE
None
RISK
Cumulative effects may result following exposure*.
* (limited evidence)
SAFETY
Do not breathe gas/fumes/vapour/spray.
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MOLYBOND G3500
ChemWatch Material Safety Data Sheet CHEMWATCH 40232
Issue Date: Sun 28-Dec-2003 CD 2004/2 Page 2 of 9
Section 2 - HAZARDS IDENTIFICATION ...
Avoid contact with skin.
Section 3 - COMPOSITION / INFORMATION ON INGREDIENTS
NAME CAS RN %
mineral oil Not avail. >60
Section 4 - FIRST AID MEASURES
SWALLOWED
路 If swallowed do NOT induce vomiting.
路 If vomiting occurs, lean patient forward or place on left side (head-down
position, if possible) to maintain open airway and prevent aspiration.
路 Observe the patient carefully.
路 Never give liquid to a person showing signs of being sleepy or with reduced
awareness; i.e. becoming unconscious.
路 Give water to rinse out mouth, then provide liquid slowly and as much as
casualty can comfortably drink.
路 Seek medical advice.
EYE
If this product comes in contact with the eyes:
路 Wash out immediately with fresh running water.
路 Ensure complete irrigation of the eye by keeping eyelids apart and away from
eye and moving the eyelids by occasionally lifting the upper and lower lids.
路 If pain persists or recurs seek medical attention.
路 Removal of contact lenses after an eye injury should only be undertaken by
skilled personnel.
SKIN
If skin contact occurs:
路 Immediately remove all contaminated clothing, including footwear
路 Flush skin and hair with running water (and soap if available).
路 Seek medical attention in event of irritation.
INHALED
路 If fumes or combustion products are inhaled remove from contaminated area.
路 Lay patient down. Keep warm and rested.
路 Prostheses such as false teeth, which may block airway, should be removed,
where possible, prior to initiating first aid procedures.
路 Apply artificial respiration if not breathing, preferably with a demand valve
resuscitator, bag-valve mask device, or pocket mask as trained. Perform CPR if
necessary.
路 Transport to hospital, or doctor.
NOTES TO PHYSICIAN
Treat symptomatically.
路 Heavy and persistent skin contamination over many years may lead to dysplastic
changes. Pre-existing skin disorders may be aggravated by exposure to this
product.
路 In general, emesis induction is unnecessary with high viscosity, low
volatility products, i.e. most oils and greases.
路 High pressure accidental injection through the skin should be assessed for
possible incision, irrigation and/or debridement.
NOTE: Injuries may not seem serious at first, but within a few hours tissue may
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MOLYBOND G3500
ChemWatch Material Safety Data Sheet CHEMWATCH 40232
Issue Date: Sun 28-Dec-2003 CD 2004/2 Page 3 of 9
Section 4 - FIRST AID MEASURES ...
become swollen, discoloured and extremely painful with extensive subcutaneous
necrosis. Product may be forced through considerable distances along tissue
planes.
Section 5 - FIRE FIGHTING MEASURES
EXTINGUISHING MEDIA
Foam.
Dry chemical powder.
BCF (where regulations permit).
Carbon dioxide.
Water spray or fog - Large fires only.
FIRE FIGHTING
路 Alert Fire Brigade and tell them location and nature of hazard.
路 Wear breathing apparatus plus protective gloves.
路 Prevent, by any means available, spillage from entering drains or water
course.
路 Use water delivered as a fine spray to control fire and cool adjacent area.
路 Avoid spraying water onto liquid pools.
路 Do not approach containers suspected to be hot.
路 Cool fire exposed containers with water spray from a protected location.
路 If safe to do so, remove containers from path of fire.
FIRE/EXPLOSION HAZARD
路 Combustible.
路 Slight fire hazard when exposed to heat or flame.
路 Heating may cause expansion or decomposition leading to violent rupture of
containers.
路 On combustion, may emit toxic fumes of carbon monoxide (CO).
路 May emit acrid smoke.
路 Mists containing combustible materials may be explosive.
Other combustion products include carbon dioxide (CO2) , nitrogen oxides (NOx)
and sulfur oxides (SOx)
FIRE INCOMPATIBILITY
Avoid contamination with strong oxidising agents as ignition may result
HAZCHEM
None
Personal Protective Equipment
Glasses:
Not normally required.
Gloves:
When handling larger quantities:
PVC chemical resistant type.
Respirator:
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MOLYBOND G3500
ChemWatch Material Safety Data Sheet CHEMWATCH 40232
Issue Date: Sun 28-Dec-2003 CD 2004/2 Page 4 of 9
Section 6 - ACCIDENTAL RELEASE MEASURES
EMERGENCY PROCEDURES
MINOR SPILLS
Slippery when spilt.
路 Remove all ignition sources.
路 Clean up all spills immediately.
路 Avoid breathing vapours and contact with skin and eyes.
路 Control personal contact by using protective equipment.
路 Contain and absorb spill with sand, earth, inert material or vermiculite.
路 Wipe up.
路 Place in a suitable labelled container for waste disposal.
MAJOR SPILLS
Slippery when spilt.
Remove all ignition sources.
Minor hazard.
路 Clear area of personnel.
路 Alert Fire Brigade and tell them location and nature of hazard.
路 Control personal contact by using protective equipment as required.
路 Prevent spillage from entering drains or water ways.
路 Contain spill with sand, earth or vermiculite.
路 Collect recoverable product into labelled containers for recycling.
路 Absorb remaining product with sand, earth or vermiculite and place in
appropriate containers for disposal.
路 Wash area and prevent runoff into drains or waterways.
路 If contamination of drains or waterways occurs, advise emergency services.
Personal Protective Equipment advice is contained in Section 8 of the MSDS.
Section 7 - HANDLING AND STORAGE
PROCEDURE FOR HANDLING
Avoid smoking, naked lights or ignition sources.
路 Limit all unnecessary personal contact.
路 Wear protective clothing when risk of exposure occurs.
路 Use in a well-ventilated area.
路 Avoid contact with incompatible materials.
路 When handling, DO NOT eat, drink or smoke.
路 Keep containers securely sealed when not in use.
路 Avoid physical damage to containers.
路 Always wash hands with soap and water after handling.
路 Work clothes should be laundered separately.
路 Use good occupational work practice.
路 Observe manufacturer's storing and handling recommendations.
路 Atmosphere should be regularly checked against established exposure standards
to ensure safe working conditions are maintained.
SUITABLE CONTAINER
路 Metal can or drum
路 Packaging as recommended by manufacturer.
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MOLYBOND G3500
ChemWatch Material Safety Data Sheet CHEMWATCH 40232
Issue Date: Sun 28-Dec-2003 CD 2004/2 Page 5 of 9
Section 7 - HANDLING AND STORAGE ...
路 Check all containers are clearly labelled and free from leaks.
STORAGE INCOMPATIBILITY
Store away from oxidising materials.
STORAGE REQUIREMENTS
路 Store in original containers.
路 Keep containers securely sealed.
路 No smoking, naked lights or ignition sources.
路 Store in a cool, dry, well-ventilated area.
路 Store away from incompatible materials and foodstuff containers.
路 Protect containers against physical damage and check regularly for leaks.
路 Observe manufacturer's storing and handling recommendations.
Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION
EXPOSURE CONTROLS
No data for Molybond G3500.
EXPOSURE STANDARDS FOR MIXTURE
"Worst Case" computer-aided prediction of spray/ mist or fume/ dust components
and concentration:
Composite Exposure Standard for Mixture (TWA) :5 mg/m鲁.
Operations which produce a spray/mist or fume/dust, introduce particulates to
the breathing zone.
If the breathing zone concentration of ANY of the components listed below is
exceeded, "Worst Case" considerations deem the individual to be overexposed.
Component Breathing Zone ppm Breathing Zone mg/m鲁 Mixture Conc (%)
Component Breathing Zone Mixture Conc
(mg/m鲁) (%)
mineral oil 5.0000 100.0
INGREDIENT DATA
MINERAL OIL:
TLV TWA: 5 mg/m鲁 () [ACGIH]
TLV STEL: 10 mg/m鲁 [ACGIH]
PEL TWA: 5 mg/m鲁 [OSHA Z1]
oil mist, mineral
TLV TWA: 5 mg/m鲁; STEL: 10 mg/m鲁.
NOTICE OF INTENDED CHANGE.
TLV TWA 0.2 mg/m鲁 inhalable fraction highly refined A4
NOTE: This substance has been classified by the ACGIH as A4
NOT classifiable as causing cancer in humans.
ES TWA: 5 mg/m鲁 (oil mist, refined mineral)
Human exposure to oil mist alone has not been demonstrated to cause health
effects except at levels above 5 mg/m鲁 (this applies to particulates sampled by
a method that does not collect vapour). It is not advisable to apply this
standard to oils containing unknown concentrations and types of additive.
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MOLYBOND G3500
ChemWatch Material Safety Data Sheet CHEMWATCH 40232
Issue Date: Sun 28-Dec-2003 CD 2004/2 Page 6 of 9
Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION ...
PERSONAL PROTECTION
EYE
No special equipment for minor exposure i.e. when handling small quantities.
路 OTHERWISE:
路 Safety glasses with side shields.
路 Contact lenses pose a special hazard; soft lenses may absorb irritants and all
lenses concentrate them.
HANDS/FEET
No special equipment needed when handling small quantities.
OTHERWISE: Wear chemical protective gloves, eg. PVC.
Safety footwear may be required.
ENGINEERING CONTROLS
General exhaust is adequate under normal operating conditions. Local exhaust
ventilation may be required in specific circumstances. If risk of overexposure
exists, wear approved respirator. Correct fit is essential to obtain adequate
protection. Provide adequate ventilation in warehouse or closed storage areas.
Air contaminants generated in the workplace possess varying "escape" velocities
which, in turn, determine the "capture velocities" of fresh circulating air
required to effectively remove the contaminant.
Type of Contaminant: Air Speed:
solvent, vapours, degreasing etc., 0.25-0.5 m/s (50-100 f/min)
evaporating from tank (in still air).
aerosols, fumes from pouring 0.5-1 m/s (100-200 f/min.)
operations, intermittent container
filling, low speed conveyer transfers,
welding, spray drift, plating acid
fumes, pickling (released at low
velocity into zone of active
generation)
direct spray, spray painting in shallow 1-2.5 m/s (200-500 f/min.)
booths, drum filling, conveyer loading,
crusher dusts, gas discharge (active
generation into zone of rapid air
motion)
grinding, abrasive blasting, tumbling, 2.5-10 m/s (500-2000 f/min.)
high speed wheel generated dusts
(released at high initial velocity into
zone of very high rapid air motion).
Within each range the appropriate value depends on:
Lower end of the range Upper end of the range
1: Room air currents minimal or 1: Disturbing room air currents
favourable to capture
2: Contaminants of low toxicity or of 2: Contaminants of high toxicity
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MOLYBOND G3500
ChemWatch Material Safety Data Sheet CHEMWATCH 40232
Issue Date: Sun 28-Dec-2003 CD 2004/2 Page 7 of 9
Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION ...
nuisance value only.
3: Intermittent, low production. 3: High production, heavy use
4: Large hood or large air mass in 4: Small hood-local control only
motion
Simple theory shows that air velocity falls rapidly with distance away from the
opening of a simple extraction pipe. Velocity generally decreases with the
square of distance from the extraction point (in simple cases). Therefore the
air speed at the extraction point should be adjusted, accordingly, after
reference to distance from the contaminating source. The air velocity at the
extraction fan, for example, should be a minimum of 1-2 m/s (200-400 f/min) for
extraction of solvents generated in a tank 2 meters distant from the extraction
point. Other mechanical considerations, producing performance deficits within
the extraction apparatus, make it essential that theoretical air velocities are
multiplied by factors of 10 or more when extraction systems are installed or
used.
Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
APPEARANCE
Green/black liquid; does not mix with water.
PHYSICAL PROPERTIES
Liquid.
Does not mix with water.
Floats on water.
Molecular Weight: Not applicable. Boiling Range (掳C): > 200
Melting Range (掳C): Not available. Specific Gravity (water=1): 0.95
Solubility in water (g/L): Immiscible pH (as supplied): Not applicable
pH (1% solution): Not applicable. Vapour Pressure (kPa): Negligible.
Volatile Component (%vol): Negligible Evaporation Rate: Very low.
Relative Vapour Density (air=1): Not available. Flash Point (掳C): > 200
Lower Explosive Limit (%): Not available. Upper Explosive Limit (%): Not available.
Autoignition Temp (掳C): Not available. Decomposition Temp (掳C): Not available.
State: Liquid
Section 10 - CHEMICAL STABILITY AND REACTIVITY INFORMATION
CONDITIONS CONTRIBUTING TO INSTABILITY
路 Presence of incompatible materials.
路 Product is considered stable.
路 Hazardous polymerisation will not occur.
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MOLYBOND G3500
ChemWatch Material Safety Data Sheet CHEMWATCH 40232
Issue Date: Sun 28-Dec-2003 CD 2004/2 Page 8 of 9
Section 11 - TOXICOLOGICAL INFORMATION
POTENTIAL HEALTH EFFECTS
ACUTE HEALTH EFFECTS
SWALLOWED
The material is slightly discomforting to the gastro-intestinal tract
Considered an unlikely route of entry in commercial/industrial environments
EYE
The material is slightly discomforting to the eyes
SKIN
The material is slightly discomforting to the skin and is capable of causing
skin reactions from repeated exposures over long periods which may lead to
dermatitis
INHALED
Not normally a hazard due to non-volatile nature of product
The vapour/mist is moderately discomforting to the upper respiratory tract
Inhalation hazard is increased at higher temperatures.
CHRONIC HEALTH EFFECTS
Oil may contact the skin or be inhaled. Extended exposure can lead to eczema,
inflammation of hair follicles, pigmentation of the face and warts on the soles
of the feet. There are few systemic effects, but prolonged exposure may lead to
a higher incidence of lung scarring.
Molybond G3500
Not available. Refer to individual constituents.
unless otherwise specified data extracted from RTECS - Register of Toxic Effects
of Chemical Substances
MINERAL OIL:
Toxicity and Irritation data is related to chemical components and
varies as does the composition and source of the original crude.
A small but definite risk of occupational skin cancer occurs in workers
exposed to persistent skin contamination by oils over a period of years.
This risk has been attributed to the presence of certain polycyclic
aromatic hydrocarbons (PAH) (typified by benz[a]pyrene).
Petroleum oils which are solvent refined/extracted or severely hydrotreated,
contain very low concentrations of both.
Section 12 - ECOLOGICAL INFORMATION
No data for Molybond G3500.
Refer to data for ingredients, which follows:
MINERAL OIL:
No data for mineral oil.
Section 13 - DISPOSAL CONSIDERATIONS
路 Recycle wherever possible or consult manufacturer for recycling options.
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MOLYBOND G3500
ChemWatch Material Safety Data Sheet CHEMWATCH 40232
Issue Date: Sun 28-Dec-2003 CD 2004/2 Page 9 of 9
Section 13 - DISPOSAL CONSIDERATIONS ...
路 Consult State Land Waste Authority for disposal.
路 Bury or incinerate residue at an approved site.
路 Recycle containers if possible, or dispose of in an authorised landfill.
Section 14 - TRANSPORTATION INFORMATION
Shipping Name:
None.
Dangerous Goods Class: None
UN/NA Number: None
ADR Number:
Packing Group: None
Labels Required:
Additional Shipping Information:
International Transport Regulations:
IMO: None
HAZCHEM
None
Section 15 - REGULATORY INFORMATION
POISONS SCHEDULE
None
Section 16 - OTHER INFORMATION
This document is copyright. Apart from any fair dealing for the purposes of
private study, research, review or criticism, as permitted under the Copyright
Act, no part may be reproduced by any process without written permission from
CHEMWATCH. TEL (+61 3) 9572 4700.
Issue Date: Sun 28-Dec-2003
Print Date: Mon 7-Jun-2004
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