3M MATERIAL SAFETY DATA SHEET 3M(TM) Adhesive / Sealant Fast Cure 4200; PN 06560 11/19/2007
Material Safety Data Sheet
Copyright, 2007, 3M Company. All rights reserved. Copying and/or downloading of this information for the purpose of properly
utilizing 3M products is allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is
obtained from 3M, and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit
thereon.
SECTION 1: PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME: 3M(TM) Adhesive / Sealant Fast Cure 4200; PN 06560
MANUFACTURER: 3M
DIVISION: Marine & Specialty Vehicle
ADDRESS: 3M Center
St. Paul, MN 55144-1000
EMERGENCY PHONE: 1-800-364-3577 or (651) 737-6501 (24 hours)
Issue Date: 11/19/2007
Supercedes Date: 05/09/2007
Document Group: 18-1639-6
Product Use:
Specific Use: Adhesive sealant
Intended Use: Sealant
SECTION 2: INGREDIENTS
Ingredient C.A.S. No. % by Wt
URETHANE POLYMER 68130-40-5 20 - 40
PHENOL ALKYLSULFONATE (CAS 91082-17-6 in Europe) 70775-94-9 20 - 40
POLY(VINYL CHLORIDE) 9002-86-2 20 - 30
HYDROTREATED LIGHT PETROLEUM DISTILLATES 64742-47-8 5 - 10
TITANIUM DIOXIDE 13463-67-7 3- 7
P,P'-METHYLENEBIS(PHENYL ISOCYANATE) 101-68-8 < 0.3
BIS(1,2,2,6,6-PENTAMETHYL-4-PIPERIDINYL) SEBACATE 41556-26-7 < 0.2
SECTION 3: HAZARDS IDENTIFICATION
3.1 EMERGENCY OVERVIEW
Specific Physical Form: Paste
Odor, Color, Grade: White thixotropic paste, slight odor.
General Physical Form: Solid
Immediate health, physical, and environmental hazards: May cause allergic skin reaction. May cause allergic
respiratory reaction. May cause target organ effects.
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3M MATERIAL SAFETY DATA SHEET 3M(TM) Adhesive / Sealant Fast Cure 4200; PN 06560 11/19/2007
3.2 POTENTIAL HEALTH EFFECTS
Eye Contact:
Moderate Eye Irritation: Signs/symptoms may include redness, swelling, pain, tearing, and blurred or hazy vision.
Vapors released during curing may cause eye irritation. Signs/symptoms may include redness, swelling, pain, tearing, and blurred or
hazy vision.
Dust created by cutting, grinding, sanding, or machining may cause eye irritation. Signs/symptoms may include redness, swelling,
pain, tearing, and blurred or hazy vision.
Skin Contact:
Moderate Skin Irritation: Signs/symptoms may include localized redness, swelling, itching, and dryness.
Prolonged or repeated exposure may cause:
Allergic Skin Reaction (non-photo induced): Signs/symptoms may include redness, swelling, blistering, and itching.
Inhalation:
Vapors released during curing may cause irritation of the respiratory system. Signs/symptoms may include cough, sneezing, nasal
discharge, headache, hoarseness, and nose and throat pain.
Dust from cutting, grinding, sanding or machining may cause irritation of the respiratory system. Signs/symptoms may include cough,
sneezing, nasal discharge, headache, hoarseness, and nose and throat pain.
Prolonged or repeated exposure may cause:
Allergic Respiratory Reaction: Signs/symptoms may include difficulty breathing, wheezing, cough, and tightness of chest.
Respiratory Effects: Signs/symptoms may include cough, shortness of breath, chest tightness, wheezing, increased heart rate,
bluish colored skin (cyanosis), sputum production, changes in lung function tests, and/or respiratory failure.
Pneumoconiosis: Sign/symptoms may include persistent cough, breathlessness, chest pain, increased amounts of sputum, and
changes in lung function tests.
May be absorbed following inhalation and cause target organ effects.
Ingestion:
Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhea.
May be absorbed following ingestion and cause target organ effects.
Target Organ Effects:
Central Nervous System (CNS) Depression: Signs/symptoms may include headache, dizziness, drowsiness, incoordination, nausea,
slowed reaction time, slurred speech, giddiness, and unconsciousness.
Persons previously sensitized to isocyanates may develop a cross-sensitization reaction to other isocyanates.
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3M MATERIAL SAFETY DATA SHEET 3M(TM) Adhesive / Sealant Fast Cure 4200; PN 06560 11/19/2007
SECTION 4: FIRST AID MEASURES
4.1 FIRST AID PROCEDURES
The following first aid recommendations are based on an assumption that appropriate personal and industrial hygiene practices are
followed.
Eye Contact: Flush eyes with large amounts of water. If signs/symptoms persist, get medical attention.
Skin Contact: Remove contaminated clothing and shoes. Immediately flush skin with large amounts of water. Get medical
attention. Wash contaminated clothing and clean shoes before reuse.
Inhalation: Remove person to fresh air. If signs/symptoms develop, get medical attention.
If Swallowed: Do not induce vomiting unless instructed to do so by medical personnel. Give victim two glasses of water. Never
give anything by mouth to an unconscious person. Get medical attention.
SECTION 5: FIRE FIGHTING MEASURES
5.1 FLAMMABLE PROPERTIES
>=750 潞F
Autoignition temperature
[Details: Not a flammable solid per testing.]
Flash Point
Not Applicable
Flammable Limits - LEL
Not Applicable
Flammable Limits - UEL
5.2 EXTINGUISHING MEDIA
Use fire extinguishers with class B extinguishing agents (e.g., dry chemical, carbon dioxide).
5.3 PROTECTION OF FIRE FIGHTERS
Special Fire Fighting Procedures: Wear full protective equipment (Bunker Gear) and a self-contained breathing apparatus
(SCBA).
Unusual Fire and Explosion Hazards: No unusual fire or explosion hazards are anticipated.
Note: See STABILITY AND REACTIVITY (SECTION 10) for hazardous combustion and thermal decomposition
information.
SECTION 6: ACCIDENTAL RELEASE MEASURES
Accidental Release Measures: Observe precautions from other sections. Call 3M- HELPS line (1-800-364-3577) for more
information on handling and managing the spill. Evacuate unprotected and untrained personnel from hazard area. The spill should be
cleaned up by qualified personnel. Ventilate the area with fresh air. Collect as much of the spilled material as possible. Clean up
residue with an appropriate solvent selected by a qualified and authorized person. Ventilate the area with fresh air. Read and follow
safety precautions on the solvent label and MSDS. Collect the resulting residue containing solution. Place in a closed container
approved for transportation by appropriate authorities. Dispose of collected material as soon as possible.
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3M MATERIAL SAFETY DATA SHEET 3M(TM) Adhesive / Sealant Fast Cure 4200; PN 06560 11/19/2007
In the event of a release of this material, the user should determine if the release qualifies as reportable according to
local, state, and federal regulations.
SECTION 7: HANDLING AND STORAGE
7.1 HANDLING
Avoid eye contact with vapors, mists, or spray. Avoid eye contact with dust or airborne particles. Avoid skin contact. Do not breathe
vapors. Avoid breathing of dust created by cutting, sanding, grinding or machining. Use general dilution ventilation and/or local
exhaust ventilation to control airborne exposures to below Occupational Exposure Limits. If ventilation is not adequate, use
respiratory protection equipment. Do not ingest. Do not eat, drink or smoke when using this product. Wash exposed areas thoroughly
with soap and water.
7.2 STORAGE
Store away from acids. Store away from heat. Store out of direct sunlight. Keep container in well-ventilated area.
SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION
8.1 ENGINEERING CONTROLS
Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below Occupational Exposure Limits
and/or control dust, fume, or airborne particles. If ventilation is not adequate, use respiratory protection equipment. Provide local
exhaust ventilation at transfer points. Provide appropriate local exhaust for cutting, grinding, sanding or machining.
8.2 PERSONAL PROTECTIVE EQUIPMENT (PPE)
8.2.1 Eye/Face Protection
Avoid eye contact with vapors, mists, or spray.
The following eye protection(s) are recommended: Safety Glasses with side shields.
8.2.2 Skin Protection
Avoid skin contact. Gloves are not required.
Select and use gloves and/or protective clothing to prevent skin contact based on the results of an exposure assessment. Consult with
your glove and/or protective clothing manufacturer for selection of appropriate compatible materials.
Gloves made from the following material(s) are recommended: Nitrile Rubber.
8.2.3 Respiratory Protection
Avoid breathing of vapors, mists or spray. Avoid breathing of dust created by cutting, sanding, grinding or machining.
Select one of the following NIOSH approved respirators based on airborne concentration of contaminants and in accordance with
OSHA regulations: Half facepiece or fullface air-purifying respirator with organic vapor cartridges and P95 particulate prefilters,
Half facepiece or fullface air-purifying respirator with organic vapor cartridges and N95 particulate prefilters, Half facepiece or
fullface air-purifying respirator with organic vapor cartridges and P100 particulate prefilters, Half facepiece or fullface pressure
demand self-contained breathing apparatus. Consult the current 3M Respiratory Selection Guide for additional information or call 1-
800-243-4630 for 3M technical assistance.
8.2.4 Prevention of Swallowing
Do not eat, drink or smoke when using this product. Wash exposed areas thoroughly with soap and water.
8.3 EXPOSURE GUIDELINES
Ingredient Authority Type Limit Additional Information
BIS(1,2,2,6,6-PENTAMETHYL-4- CMRG TWA 1 mg/m3
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3M MATERIAL SAFETY DATA SHEET 3M(TM) Adhesive / Sealant Fast Cure 4200; PN 06560 11/19/2007
PIPERIDINYL) SEBACATE
FREE ISOCYANATES 3M TWA 0.005 ppm
FREE ISOCYANATES 3M STEL 0.02 ppm
HYDROTREATED LIGHT PETROLEUM CMRG TWA 300 ppm
DISTILLATES
P,P'-METHYLENEBIS(PHENYL ACGIH TWA 0.005 ppm
ISOCYANATE)
P,P'-METHYLENEBIS(PHENYL OSHA CEIL 0.02 ppm Table Z-1
ISOCYANATE)
TITANIUM DIOXIDE ACGIH TWA 10 mg/m3 Table A4
TITANIUM DIOXIDE CMRG TWA, as respirable 5 mg/m3
dust
TITANIUM DIOXIDE OSHA TWA, Vacated, as 10 mg/m3
dust
TITANIUM DIOXIDE OSHA TWA, as total dust 15 mg/m3 Table Z-1
VAC Vacated PEL:Vacated Permissible Exposure Limits [PEL] are enforced as the OSHA PEL in some states. Check with your local
regulatory agency.
SOURCE OF EXPOSURE LIMIT DATA:
ACGIH: American Conference of Governmental Industrial Hygienists
CMRG: Chemical Manufacturer Recommended Guideline
OSHA: Occupational Safety and Health Administration
AIHA: American Industrial Hygiene Association Workplace Environmental Exposure Level (WEEL)
SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES
Paste
Specific Physical Form:
White thixotropic paste, slight odor.
Odor, Color, Grade:
Solid
General Physical Form:
>=750 潞F
Autoignition temperature
[Details: Not a flammable solid per testing.]
Flash Point
Not Applicable
Flammable Limits - LEL
Not Applicable
Flammable Limits - UEL
Not Applicable
Boiling point
1.18 g/cm3
Density
No Data Available
Vapor Density
No Data Available
Vapor Pressure
1.18 [Details: Water = 1]
Specific Gravity
Not Applicable
pH
No Data Available
Melting point
Nil
Solubility in Water
32 [Test Method: tested per EPA method 24]
Volatile Organic Compounds
2.67 % weight
Percent volatile
32 [Test Method: tested per EPA method 24]
VOC Less H2O & Exempt Solvents
SECTION 10: STABILITY AND REACTIVITY
Stability: Stable.
Materials and Conditions to Avoid: Not Applicable Additional Information: Material is a moisture cure adhesive/sealant.
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3M MATERIAL SAFETY DATA SHEET 3M(TM) Adhesive / Sealant Fast Cure 4200; PN 06560 11/19/2007
Hazardous Polymerization: Hazardous polymerization will not occur.
Hazardous Decomposition or By-Products
Substance Condition
Carbon monoxide During Combustion
Carbon dioxide During Combustion
Hydrogen Cyanide During Combustion
Oxides of Nitrogen During Combustion
Oxides of Sulfur During Combustion
SECTION 11: TOXICOLOGICAL INFORMATION
Please contact the address listed on the first page of the MSDS for Toxicological Information on this material and/or its
components.
SECTION 12: ECOLOGICAL INFORMATION
ECOTOXICOLOGICAL INFORMATION
Not determined.
CHEMICAL FATE INFORMATION
Not determined.
SECTION 13: DISPOSAL CONSIDERATIONS
Waste Disposal Method: Cure (harden, set, or react) the product according to product instructions.
Dispose of completely cured (or polymerized) wastes in a sanitary landfill.
As a disposal alternative, incinerate uncured product in an industrial or commercial incinerator in the presence of a combustible
material.
EPA Hazardous Waste Number (RCRA): Not regulated
Since regulations vary, consult applicable regulations or authorities before disposal.
SECTION 14:TRANSPORT INFORMATION
ID Number(s):
60-9801-0569-0
Please contact the emergency numbers listed on the first page of the MSDS for Transportation Information for this
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3M MATERIAL SAFETY DATA SHEET 3M(TM) Adhesive / Sealant Fast Cure 4200; PN 06560 11/19/2007
material.
SECTION 15: REGULATORY INFORMATION
US FEDERAL REGULATIONS
Contact 3M for more information.
311/312 Hazard Categories:
Fire Hazard - No Pressure Hazard - No Reactivity Hazard - No Immediate Hazard - Yes Delayed Hazard - Yes
STATE REGULATIONS
Contact 3M for more information.
CHEMICAL INVENTORIES
The components of this product are in compliance with the chemical notification requirements of TSCA.
Contact 3M for more information.
INTERNATIONAL REGULATIONS
Contact 3M for more information.
WHMIS: Hazardous
This MSDS has been prepared to meet the U.S. OSHA Hazard Communication Standard, 29 CFR 1910.1200.
SECTION 16: OTHER INFORMATION
NFPA Hazard Classification
Health: 2 Flammability: 2 Reactivity: 0 Special Hazards: None
National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address the hazards that are
presented by short-term, acute exposure to a material under conditions of fire, spill, or similar emergencies. Hazard ratings are primarily based on the
inherent physical and toxic properties of the material but also include the toxic properties of combustion or decomposition products that are known to
be generated in significant quantities.
Reason for Reissue: Update MSDS
Revision Changes:
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3M MATERIAL SAFETY DATA SHEET 3M(TM) Adhesive / Sealant Fast Cure 4200; PN 06560 11/19/2007
Section 8: Respiratory protection - recommended respirators information was modified.
Section 14: ID Number Heading Template 1 was added.
Section 14: ID Number(s) Template 1 was added.
Section 2: Ingredient table was added.
Section 8: Exposure guidelines ingredient information was added.
Section 8: Exposure guidelines legend was added.
Section 8: Exposure guidelines data source legend was added.
DISCLAIMER: The information in this Material Safety Data Sheet (MSDS) is believed to be correct as of the date issued. 3M
MAKES NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY
OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF
TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable for user's method of
use or application. Given the variety of factors that can affect the use and application of a 3M product, some of which are uniquely
within the user's knowledge and control, it is essential that the user evaluate the 3M product to determine whether it is fit for a
particular purpose and suitable for user's method of use or application.
3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer may
have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness or accuracy.
In addition, information obtained from a database may not be as current as the information in the MSDS available directly from 3M.
3M MSDSs are available at www.3M.com
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