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MSDS Material Safety Data Sheet
CAS

120-04-0
01-02-0
127-01-0
64-19-7

File Name: bocedwards_com---p120-04-010_silcoset_sealant.asp
                                                                                                        P120-04-010
Issue: B
MATERIAL SAFETY DATA SHEET Rev Date: 01-02-05
Page: 1 of 6

PRODUCT NAME : SILCOSET SEALANT

1. Product and Company Identification
Product Name: Silcoset 151
Synonyms: None
Item Numbers : H127-01-000
European Contact Details US Contact Details

BOC Edwards, Manor Royal, Crawley, BOC Edwards, 301 Ballardvale Street,
West Sussex, RH10 2LW, England Wilmington, MA 01887
General enquiries General enquiries
UK : +44 (0)1293 528844 +(1) 978-658-5410
France : +(33) 1 47 98 24 01 Toll Free: 1-800-848-9800
Germany : +(49) 89-991918-0
Italy : +(39) 0248-4471 24 h Emergency telephone number:
Chemtrec : 1-800-424-9300


2. Composition/Information on Ingredients
General description: A blend of polymethylsiloxanes, silica fillers, a mixture of acetoxysilanes and a small amount
of an organotin compound (plus bulking fillers/pigments as required)


Ingredient % Weight CAS No Hazard class* Risk phrase*
Acetoxysilanes <5 Not allocated Not applicable Not applicable
Acetic acid (this is produced <3.5 64-19-7 Not applicable Not applicable
from Acetoxysilanes in the
presence of moisture during
curing of the material)
*Hazard class & Risk phrase. These columns are only completed for ingredients which are classified as hazardous
under EU Directive (67/548/EEC, as amended) and are present in sufficient concentration to make the overall
substance hazardous. In all other situations, the column will be completed as 鈥淣ot applicable鈥?.


3. Hazards Identification
EMERGENCY OVERVIEW
Although this product is not classified as irritant, it has been known for many years that operators working in confined
areas can experience transient eye and respiratory irritation due to the small amount of acetic acid evolved during the
curing cycle. This can be avoided by employing good standards of industrial hygiene and operating in a well
ventilated area. An exposure risk to acetic acid and possibly silica dust exists from hydrolysis and combustion.
For short and long term exposure effects see Section 11 Toxicological data




705
DCC1 No :
BOC Edwards is part of BOC Limited
The stripe symbol is a trade mark of the BOC Group
Ref 2D01-010 form issue 1.2
.
P120-04-010
Issue: B
MATERIAL SAFETY DATA SHEET Rev Date: 01-02-05
Page: 2 of 6

PRODUCT NAME : SILCOSET SEALANT


Eye Effects: Irritant.
Skin Effects: Irritant.
Ingestion/Oral Low systemic toxicity.
Effects:
Inhalation Effects: Acetic acid in excess of OEL causes irritation of the nasal membranes.
MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE: Irritant properties may aggravate pre-existing eye, skin,
and respiratory disorders.


NFPA Hazard codes HMIS Hazard codes Rating System
Health 1 Health 1 0 = No Hazard
Flammability 1 Flammability 1 1 = Slight hazard
Instability 0 Reactivity 0 2 = Moderate Hazard
3 = Serious Hazard
4 = Severe hazard

4. First Aid Measures
Wash the affected eye(s) immediately with clean cold water or eyewash and irrigate for at
Eyes:
least 15 minutes. Seek medical attention immediately.
Remove soiled clothing immediately and wash the affected area with soap and water. Seek
Skin:
medical advice if irritation persists.
Treat symptomatically. Give water or milk to drink. DO NOT induce vomiting.
Ingestion/Oral:
Remove person to fresh air. Treat symptomatically. If breathing problems occur, a qualified
Inhalation:
individual should administer oxygen or artificial respiration as indicated. Seek immediate
medical attention.
None.
Other Information:


5. Fire Fighting Measures
Extinguishing Media: Carbon dioxide, foam, dry chemical powder or fine water spray.
Fire and Explosion Hazard: Acetic acid and possibly silica dust are produced from hydrolysis and combustion.
Hazardous decomposition products : carbon monoxide, carbon dioxide, silicon
dioxide
Special Protective Equipment Fire fighters should wear a self-contained breathing apparatus (SCBA) which
for Fire Fighters: meets appropriate standards operated in positive pressure mode and full turn out
gear.
For Flammability Properties - see section 9




705
DCC1 No :
BOC Edwards is part of BOC Limited
The stripe symbol is a trade mark of the BOC Group
Ref 2D01-010 form issue 1.2
.
P120-04-010
Issue: B
MATERIAL SAFETY DATA SHEET Rev Date: 01-02-05
Page: 3 of 6

PRODUCT NAME : SILCOSET SEALANT

6. Accidental Release Measures
This product is supplied in tightly sealed container for the purpose of excluding moisture. Should the container be
ruptured the product will not readily spill out. Damaged containers should be removed to a safe non-working area
and allowed to cure completely before disposal. See Section 13 鈥楧isposal Considerations鈥?.


7. Handling and Storage
This product should be kept in its original containers under normal dry storage conditions.


8. Exposure Controls/Personal Protection
Exposure Limits
Ingredient ACGIH - TLV - OSHA 鈥? PEL Occupational Exposure
Limits EH40 (UK)
Acetic acid 10 ppm - TWA 10 ppm - TWA 10 ppm - TWA
15 ppm - STEL 15 ppm - STEL

Personal Protection:
Engineering Measures: Ensure adequate ventilation in the work area.
Respiratory Protection: Ensure adequate ventilation.
Hand/Skin Protection: The wearing of gloves is recommended.
Eye/Face Protection: The wearing of goggles is recommended.
Hygiene Measures: Employ good personal hygiene. Do not eat, drink or smoke when handling the
product. Wash hands before eating.
Other/General Protection: None.


9. Physical and Chemical Properties
0
C/ 0F
Appearance and Odour White flowable self-levelling Boiling Point No data available
paste. Acetic acid odour
0
C/ 0F
pH (as supplied) No data available Freezing Point No data available
0
C/ 0F
Solubility in Water Not Soluble Auto Ignition No data available
0
C/ 0F
Volatile Content by Volume No data available Flash Point >300/572
Specific Gravity 1.04
Vapour Pressure (mbar) No data available Vapour Pressure (Torr) No data available




705
DCC1 No :
BOC Edwards is part of BOC Limited
The stripe symbol is a trade mark of the BOC Group
Ref 2D01-010 form issue 1.2
.
P120-04-010
Issue: B
MATERIAL SAFETY DATA SHEET Rev Date: 01-02-05
Page: 4 of 6

PRODUCT NAME : SILCOSET SEALANT

10. Stability and Reactivity
Stability: Stable
Material/Conditions to Avoid: Moisture (when in uncured state)
Hazardous Decomposition: Carbon monoxide, carbon dioxide, silicon dioxide


11. Toxicological Information
For a comprehensive description for the various toxicological (health) effects which may arise if the user comes
into contact with the substance or preparation refer to Section 3 Hazards Identification.
Animal Data:
LD50 value: Acute oral value : >3000 mg/kg
LC50 value: No data available
Carcinogenicity:
No information available.


12. Ecological Information
No information available.


13. Disposal Considerations
Disposal is notifiable in the UK under the Deposit of Poisonous Waste Act 1972. Disposal is normally by burial on
an approved site or by burning under controlled conditions. Users outside UK legislation should consult their own
local authority.


14. Transport Information
This product is not regulated as dangerous under transport regulations.


PARAMETER EUROPEAN CANADIAN TDG UNITED STATES DOT
Proper Shipping Name Not applicable Not applicable Not applicable
Hazard Class Not applicable Not applicable Not applicable
Identification Number Not applicable Not applicable Not applicable
Shipping Label Not applicable Not applicable Not applicable




705
DCC1 No :
BOC Edwards is part of BOC Limited
The stripe symbol is a trade mark of the BOC Group
Ref 2D01-010 form issue 1.2
.
P120-04-010
Issue: B
MATERIAL SAFETY DATA SHEET Rev Date: 01-02-05
Page: 5 of 6

PRODUCT NAME : SILCOSET SEALANT

15. Regulatory Information
European Regulatory Information
This product has been classified in accordance with the Dangerous Substances Directive (67/548/EEC, as
amended) and the Preparations Directive (88/379/EEC, as amended), implemented in the UK as the Chemical
(Hazard Information and Packing) Regulations 1994 (CHIP, as amended).
Classified as dangerous to supply : No
Risk Phrases : Not applicable
Safety Phrases : Not applicable
Symbols : None
United States Regulatory Information
All materials contained in this product are listed on the U.S. Toxic Substances Control Act (TSCA).
SARA TITLE III 鈥? SECTION 313 SUPPLIER NOTIFICATION:
This product does not contain toxic chemicals subject to the reporting requirements of section 313 of the Emergency
Planning and Community Right-to-Know Act (EPCRA of 1986 and 40 CFR Part 372.
California Proposition 65: This product contains chemicals known to the State of California to cause cancer
(crystalline silica).
Canadian Regulatory Information
All ingredients contained in this product are listed on the Canadian DSL.
WHMIS Classification: D2A, D2B


16. Other Information
This MSDS is compiled in accordance with ANSI Z400.1 and the EU Safety Data Sheet Directive 91/155/EEC.
Source of information for this data sheet :
鈥? Ambersil Silicones Material Data Safety Sheet Ref 22-37649G / 22-37646H


Glossary : CAS, Chemical Abstracts Service; NFPA, National Fire Protection Association; HMIS, Hazardous
Material Information Service; LD, Lethal Dose; LC, Lethal Concentration; ACGIH, American Conference of
Governmental Industrial Hygienists; TLV, threshold limit value; OSHA, Occupational Safety and Health
Administration, US department of Labour; PEL, Permissible exposure limit; EH40 (UK), HSE Guidance Note EH40
Occupational exposure limits; PPM, parts per million; TWA, Time-Weighted Average; STEL, Short Term Exposure
Limit; Canadian TDG, Canadian Transportation of Dangerous Goods; US DOT,US Department of Transportation.
HSDB, Hazardous Substances Data Bank; RTECS, Registry of Toxic Effects of Chemical Substances; CHEMID,
Chemical Identification; DSL, Domestic Substances List ; TSCA, Toxic Substances Control Act Public Law 94-469:
CERCLA, Comprehensive Environmental Response, Compensation and Liability Act; EPCRA. Emergency Planning
and Community Right-to-Know Act; CAA, Clean Air Act; US, SARA (Title III), Superfund Amendments and
Reauthorization Act.; SARA 313, Superfund Amendments and Reauthorization Act, Section 313; EHS, Extremely
Hazardous Substance; WHMIS, Workplace Hazardous Materials Information System.




705
DCC1 No :
BOC Edwards is part of BOC Limited
The stripe symbol is a trade mark of the BOC Group
Ref 2D01-010 form issue 1.2
.
P120-04-010
Issue: B
MATERIAL SAFETY DATA SHEET Rev Date: 01-02-05
Page: 6 of 6

PRODUCT NAME : SILCOSET SEALANT


Revisions


___________________________________________________________________________________________
_
Although the information and recommendations in this data sheet are to the best of our knowledge correct, it is recommended that
you make your own determination of the material鈥檚 suitability for your purpose before you use it. The information contained in this
data sheet has been reproduced from the manufacturers data, the accuracy of this information is the responsibility of the
manufacturer. BOC Edwards accept no responsibility for damage of any nature resulting from the use of, or the reliance upon this
data sheet.




705
DCC1 No :
BOC Edwards is part of BOC Limited
The stripe symbol is a trade mark of the BOC Group
Ref 2D01-010 form issue 1.2
.

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