P120-05-000
Issue: B
MATERIAL SAFETY DATA SHEET Rev Date: 01-02-05
Page: 1 of 7
PRODUCT NAME : GS BATTERY
1. Product and Company Identification
Product Name: GS Battery (sealed maintenance free batteries)
Synonyms: STP turbo pump batteries
Item Numbers : E21932003, E21932004, E21932005
European Contact Details US Contact Details
BOC Edwards, Manor Royal, Crawley, BOC Edwards, 301 Ballardvale Street,
West Sussex, RH10 2LW, England Wilmington, MA 01887
General enquiries General enquiries
UK : +44 (0)1293 528844 +(1) 978-658-5410
France : +(33) 1 47 98 24 01 Toll Free: 1-800-848-9800
Germany : +(49) 89-991918-0
Italy : +(39) 0248-4471 24 h Emergency telephone number:
Chemtrec : 1-800-424-9300
2. Composition/Information on Ingredients
Ingredient % Weight CAS No Hazard class* Risk phrase*
Lead (Pb) Not allocated Not applicable Not applicable
PbO2 70 total for lead & lead 1309-60-0 Not applicable Not applicable
compounds
PbSO4 7446-14-2 Not applicable Not applicable
Sulphuric Acid 20 7664-93-9 Not applicable Not applicable
*Hazard class & Risk phrase. These columns are only completed for ingredients which are classified as hazardous
under EU Directive (67/548/EEC, as amended) and are present in sufficient concentration to make the overall
substance hazardous. In all other situations, the column will be completed as 鈥淣ot applicable鈥?.
3. Hazards Identification
EMERGENCY OVERVIEW
Not hazardous in normal use. Can produce flammable gas (hydrogen) if the battery is overcharged. Exposure to
sulphuric acid can occur if the battery is damaged or its vents are tampered with. Shorting across the battery
terminals produces high currents.
For short and long term exposure effects see Section 11 Toxicological data
Eye Effects: None under normal conditions of use. See note below
Skin Effects: None under normal conditions of use. See note below
705
DCC1 No :
BOC Edwards is part of BOC Limited
The stripe symbol is a trade mark of the BOC Group
Ref 2D01-010 form issue 1.2
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MATERIAL SAFETY DATA SHEET Rev Date: 01-02-05
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PRODUCT NAME : GS BATTERY
Ingestion/Oral None under normal conditions of use. See note below
Effects:
Inhalation Effects: None under normal conditions of use. See note below
Note : The toxic effects of lead are cumulative and slow to appear. It affects the bone marrow, kidneys,
reproductive organs, central nervous system, and developing foetus. The symptoms of lead overexposure are:
anaemia, vomiting, head aches, stomach pains (lead colic), dizziness, loss of appetite, muscle and joint pain.
Exposure to lead from a battery most often occurs during lead reclamation operations through the breathing or
ingestion of lead dust and/or fumes. Exposure to lead compounds may increase the risks of developing cancer.
Sulphuric acid is highly corrosive. Contact can cause severe burns in the skin and eyes. Ingestion of sulphuric
acid will cause GI tract burns. Exposure to sulphuric acid may occur if the battery case has been damaged or the
vents have been tampered with. Inhalation of mists may damage the lungs and cause pulmonary edema.
Exposure to strong inorganic acid mists containing sulphuric acid can increase the risks of developing cancer.
This sheet must be passed to any reclamation agent or smelter when the battery is resold/disposed.
MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE: None known (for intact product).
NFPA Hazard codes HMIS Hazard codes Rating System
Health 0 Health 0 0 = No Hazard
Flammability 0 Flammability 0 1 = Slight hazard
Instability 0 Reactivity 0 2 = Moderate Hazard
3 = Serious Hazard
4 = Severe hazard
4. First Aid Measures
Sulphuric acid : flush with plenty of water until medical help arrives. Call a physician
Eyes:
immediately.
Sulphuric acid : wash with plenty of water. Seek medical advice if the contaminated area is
Skin:
large or if blisters occur.
Sulphuric acid: call a physician immediately. If patient is conscious, flush mouth with water,
Ingestion/Oral:
have the patient drink milk or sodium bicarbonate solution. DO NOT give anything to an
unconscious person.
If contents of battery are inhaled, remove to fresh air. If breathing problems occur, a
Inhalation:
qualified individual should administer oxygen or artificial respiration as indicated. Seek
immediate medical attention.
The first aid measures indicated above will only be pertinent in cases of leakage or damage
Other Information:
to the battery or during lead reclamation.
705
DCC1 No :
BOC Edwards is part of BOC Limited
The stripe symbol is a trade mark of the BOC Group
Ref 2D01-010 form issue 1.2
.
P120-05-000
Issue: B
MATERIAL SAFETY DATA SHEET Rev Date: 01-02-05
Page: 3 of 7
PRODUCT NAME : GS BATTERY
5. Fire Fighting Measures
Extinguishing Media: No information available.
Fire and Explosion Hazard: Hazardous decomposition products of sulphuric acid: sulphur dioxide, sulphur
trioxide, hydrogen sulphide and hydrogen.
Special Protective Equipment No information available.
for Fire Fighters:
For Flammability Properties - see Section 9
6. Accidental Release Measures
If sulphuric acid is spilled from the battery, neutralise the acid with sodium bicarbonate (baking soda), sodium
carbonate (soda ash) or calcium oxide (lime). Flush the area with water. It is acceptable to discard the neutralised
acid into the sewage system.
7. Handling and Storage
Handling : due to the batteries low internal resistance and high power density, high levels of short circuit current
can develop across the battery terminals. Do not rest tools or cables on the battery. Use insulated tools only.
Follow all installation instructions and diagrams when installing or maintaining a battery system.
Storage: Store new batteries in a dry environment at room temperature. Store in their original protective
packaging.
8. Exposure Controls/Personal Protection
Exposure Limits
Ingredient ACGIH - TLV - OSHA - PEL Occupational Exposure
Limits EH40 (UK)
0.05 mg/m3 - 8 H TWA 0.15 mg/m3 (as Pb)
30 碌g/m3 (action level)
Lead/ lead compounds
(elemental, organic cpds.)
50 碌g/m3 - 8 H TWA
1 mg/m3 鈥? TWA 1 mg/m3 鈥? TWA 1 mg/m3 鈥? TWA
Sulphuric acid
3 mg/m3 鈥? STEL
Personal Protection:
Engineering Measures: None required under conditions of normal use.
Respiratory Protection: None required under conditions of normal use. A respirator should be worn during
lead reclamation operations if the TLV is exceeded.
Hand/Skin Protection: None required under conditions of normal use. Wear rubber gloves in cases of
leakage/damage.
Eye/Face Protection: None required under conditions of normal use. Wear goggles or face shield in
cases of leakage/damage.
Hygiene Measures: Observe normal standards of industrial hygiene. Do not eat, drink or smoke when
handling material. Wash hands before eating, drinking or smoking.
Other/General Protection: None
705
DCC1 No :
BOC Edwards is part of BOC Limited
The stripe symbol is a trade mark of the BOC Group
Ref 2D01-010 form issue 1.2
.
P120-05-000
Issue: B
MATERIAL SAFETY DATA SHEET Rev Date: 01-02-05
Page: 4 of 7
PRODUCT NAME : GS BATTERY
9. Physical and Chemical Properties
Lead
0
C/ 0F
Appearance and Odour Silver -grey metal. No odour Boiling Point No data available
0
C/ 0F
pH (as supplied) Not applicable Freezing Point 327/622?
0
C/ 0F
Solubility in Water Not soluble Auto Ignition Not applicable
0
C/ 0F
Volatile Content by Volume none Flash Point Not applicable
Specific Gravity 11.34
Vapour Pressure (mbar) No data available Vapour Pressure (Torr) No data available
Sulphuric acid
0
C/ 0F
Appearance and Odour Clear colourless liquid. Acidic Boiling Point 114/237
odour
0
C/ 0F
pH (as supplied) No data available Freezing Point No data available
0
C/ 0F
Solubility in Water 100% Soluble Auto Ignition Not applicable
0
C/ 0F
Volatile Content by Volume No data available Flash Point Not applicable
Specific Gravity About 1.3
Vapour Pressure (mbar) No data available Vapour Pressure (Torr) No data available
Lead sulphate
0
C/ 0F
Appearance and Odour White odourless powder Boiling Point 1070/1958
0
C/ 0F
pH (as supplied) No data available Freezing Point No data available
40mg/l @ 15oC 0
C/ 0F
Solubility in Water Auto Ignition Not applicable
0
C/ 0F
Volatile Content by Volume No data available Flash Point Not applicable
Specific Gravity 6.2
Vapour Pressure (mbar) No data available Vapour Pressure (Torr) No data available
Lead dioxide
0
C/ 0F
Appearance and Odour Brown odourless powder Boiling Point 290/554
0
C/ 0F
pH (as supplied) No data available Freezing Point No data available
0
C/ 0F
Solubility in Water Not soluble Auto Ignition Not applicable
0
C/ 0F
Volatile Content by Volume No data available Flash Point Not applicable
Specific Gravity 9.4
Vapour Pressure (mbar) No data available Vapour Pressure (Torr) No data available
705
DCC1 No :
BOC Edwards is part of BOC Limited
The stripe symbol is a trade mark of the BOC Group
Ref 2D01-010 form issue 1.2
.
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Issue: B
MATERIAL SAFETY DATA SHEET Rev Date: 01-02-05
Page: 5 of 7
PRODUCT NAME : GS BATTERY
10. Stability and Reactivity
Sulphuric acid
Stability: Stable.
Material/Conditions to Avoid: Reactive materials, strong bases, most organic compounds. Excessive heat.
Prohibit smoking, sparks, flames etc. from battery charging area.
Hazardous Decomposition of Sulphur dioxide, sulphur trioxide, hydrogen sulphide and hydrogen.
Sulphuric Acid:
11. Toxicological Information
For a comprehensive description for the various toxicological (health) effects which may arise if the user comes
into contact with the substance or preparation refer to Section 3 Hazards Identification.
Animal Data:
LD50 oral value: 500mg/kg for lead/lead compounds
2140 mg/kg for sulphuric acid
LC50 value: No information available.
Carcinogenicity:
No information available.
12. Ecological Information
No information available.
13. Disposal Considerations
Neutralised acid may be discarded in the sewage system. Spent batteries must be treated as hazardous waste and
disposed of in accordance with local, state and federal regulations.
14. Transport Information
This product is not regulated as dangerous under transport regulations.
PARAMETER EUROPEAN CANADIAN TDG UNITED STATES DOT
Proper Shipping Name Batteries, wet, non- Batteries, wet, non- Batteries, wet, non-
spillable, electric storage spillable, electric storage spillable, electric storage
Hazard Class 8 8 8
Identification Number 2800 2800 2800
Shipping Label CORROSIVE CORROSIVE CORROSIVE
705
DCC1 No :
BOC Edwards is part of BOC Limited
The stripe symbol is a trade mark of the BOC Group
Ref 2D01-010 form issue 1.2
.
P120-05-000
Issue: B
MATERIAL SAFETY DATA SHEET Rev Date: 01-02-05
Page: 6 of 7
PRODUCT NAME : GS BATTERY
15. Regulatory Information
European Regulatory Information
This product has been classified in accordance with the Dangerous Substances Directive (67/548/EEC, as
amended) and the Preparations Directive (88/379/EEC, as amended), implemented in the UK as the Chemical
(Hazard Information and Packing) Regulations 1994 (CHIP, as amended).
Classified as dangerous to supply : No
Risk Phrases : Not applicable
Safety Phrases : Not applicable
Symbols : None
United States Regulatory Information
Product is a manufactured article not subject to TSCA listing.
SARA TITLE III - SECTION 313 SUPPLIER NOTIFICATION:
This product constitutes an 鈥渁rticle鈥? and, as such is exempt from SARA 313 reporting requirements (40 CFR Part
372.38, Paragraph B).
California Proposition 65: This product contains chemicals (lead and sulphuric acid) known to the State of California
to cause cancer or reproductive toxicity.
Canadian Regulatory Information
WHMIS Classification: Product is a manufactured article not subject to WHMIS regulations.
Product is a manufactured item not subject to DSL listing.
16. Other Information
This MSDS is compiled in accordance with ANSI Z400.1 and the EU Safety Data Sheet Directive 91/155/EEC.
Sources of information for this data sheet:
GS Battery (USA) Material Safety Data Sheet for Sealed Maintenance Free Batteries. Date : November 1993
705
DCC1 No :
BOC Edwards is part of BOC Limited
The stripe symbol is a trade mark of the BOC Group
Ref 2D01-010 form issue 1.2
.
P120-05-000
Issue: B
MATERIAL SAFETY DATA SHEET Rev Date: 01-02-05
Page: 7 of 7
PRODUCT NAME : GS BATTERY
Glossary : CAS, Chemical Abstracts Service; NFPA, National Fire Protection Association; HMIS, Hazardous
Material Information Service; LD, Lethal Dose; LC, Lethal Concentration; ACGIH, American Conference of
Governmental Industrial Hygienists; TLV, threshold limit value; OSHA, Occupational Safety and Health
Administration, US department of Labour; PEL, Permissible exposure limit; EH40 (UK), HSE Guidance Note EH40
Occupational exposure limits; PPM, parts per million; TWA, Time-Weighted Average; STEL, Short Term Exposure
Limit; Canadian TDG, Canadian Transportation of Dangerous Goods; US DOT,US Department of Transportation.
HSDB, Hazardous Substances Data Bank; RTECS, Registry of Toxic Effects of Chemical Substances; CHEMID,
Chemical Identification; DSL, Domestic Substances List ; TSCA, Toxic Substances Control Act Public Law 94-469:
CERCLA, Comprehensive Environmental Response, Compensation and Liability Act; EPCRA. Emergency Planning
and Community Right-to-Know Act; CAA, Clean Air Act; US, SARA (Title III), Superfund Amendments and
Reauthorization Act.; SARA 313, Superfund Amendments and Reauthorization Act, Section 313; EHS, Extremely
Hazardous Substance; WHMIS, Workplace Hazardous Materials Information System.
Revisions
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_
Although the information and recommendations in this data sheet are to the best of our knowledge correct, it is recommended that
you make your own determination of the material鈥檚 suitability for your purpose before you use it. The information contained in this
data sheet has been reproduced from the manufacturers data, the accuracy of this information is the responsibility of the
manufacturer. BOC Edwards accept no responsibility for damage of any nature resulting from the use of, or the reliance upon this
data sheet.
705
DCC1 No :
BOC Edwards is part of BOC Limited
The stripe symbol is a trade mark of the BOC Group
Ref 2D01-010 form issue 1.2
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