P120-03-000
Issue: C
MATERIAL SAFETY DATA SHEET Rev Date: 01-02-05
Page: 1 of 6
PRODUCT NAME : GREASE - FOMBLIN (AR555)
1. Product and Company Identification
Product Name: Fomblin Y grease - Grade AR555
Synonyms: None
Item Numbers : H113-50-013, 000-007-696.
European Contact Details US Contact Details
BOC Edwards, Manor Royal, Crawley, BOC Edwards, 301 Ballardvale Street,
West Sussex, RH10 2LW, England Wilmington, MA 01887
General enquiries General enquiries
UK : +44 (0)1293 528844 +(1) 978-658-5410
France : +(33) 1 47 98 24 01 Toll Free: 1-800-848-9800
Germany : +(49) 89-991918-0
Italy : +(39) 0248-4471 24 h Emergency telephone number:
Chemtrec : 1-800-424-9300
2. Composition/Information on Ingredients
Ingredient % Weight CAS No Hazard class* Risk phrase*
Base Oil : Fomblin YR Not available 6991-67-9 Not applicable Not applicable
(Perfluorinated polyether)
Thickener : Algoflon Not available 9002-84-0 Not applicable Not applicable
(Polytetrafluoroethylene)
Anti rust additive : Fomblin Not available Not allocated Not applicable Not applicable
DA305
*Hazard class & Risk phrase. These columns are only completed for ingredients which are classified as hazardous
under EU Directive (67/548/EEC, as amended) and are present in sufficient concentration to make the overall
substance hazardous. In all other situations, the column will be completed as 鈥淣ot applicable鈥?.
OSHA Regulatory Status: This material is classified as hazardous under OSHA regulations.
3. Hazards Identification
EMERGENCY OVERVIEW
This material when properly handled according to good working and hygienic practices is not dangerous to human
health and the environment. Harmful effects are expected only when thermal decomposition produces irritating and
toxic vapours.
For short and long term exposure effects see Section 11 Toxicological data
705
DCC1 No :
BOC Edwards is part of BOC Limited
The stripe symbol is a trade mark of the BOC Group
Ref 2D01-010 form issue 1.2
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P120-03-000
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MATERIAL SAFETY DATA SHEET Rev Date: 01-02-05
Page: 2 of 6
PRODUCT NAME : GREASE - FOMBLIN (AR555)
Eye Effects: Repeated or prolonged contact with eyes may cause redness.
Skin Effects: Repeated or prolonged contact with skin may cause redness or dermatitis.
Ingestion/Oral Ingestion of the product in large amounts may cause abdominal pains, nausea and diarrhoea.
Effects:
Inhalation Effects: Low volatility makes inhalation an unlikely hazard. The thermal decomposition vapours of
fluorinated polymers may cause polymer fume fever with flu like symptoms in humans,
especially when smoking contaminated tobacco.
MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE: May aggravate pre-existing eye and skin disorders.
NFPA Hazard codes HMIS Hazard codes Rating System
Health 1 Health 1 0 = No Hazard
Flammability 1 Flammability 1 1 = Slight hazard
Stability 0 Physical Hazard 0 2 = Moderate Hazard
3 = Serious Hazard
4 = Severe hazard
4. First Aid Measures
Immediately flush the eyes with plenty of water for at least 15 minutes.
Eyes:
In case of contact wash thoroughly with soap and water.
Skin:
Give two to three glasses of water. Induce vomiting if victim is conscious. Contact a
Ingestion/Oral:
physician immediately.
Not applicable in normal use. If fumes produced at elevated temperatures are inhaled,
Inhalation:
remove to fresh air. If breathing problems occur, a qualified individual should administer
oxygen or artificial respiration as indicated. Seek immediate medical attention.
None.
Other Information:
5. Fire Fighting Measures
Extinguishing Media: Water, foam, powder or carbon dioxide.
Fire and Explosion Hazard: Possible risk due to irritation and toxic affects of thermal combustion products.
These can include hydrogen fluoride and carbonyl fluoride. Direct water stream
may cause violent frothing.
Special Protective Equipment Fire fighters should wear a self-contained breathing apparatus (SCBA) which
for Fire Fighters: meets appropriate standards operated in positive pressure mode. Skin protection
should be worn to protect from hydrogen fluoride vapour.
For Flammability Properties - see Section 9
705
DCC1 No :
BOC Edwards is part of BOC Limited
The stripe symbol is a trade mark of the BOC Group
Ref 2D01-010 form issue 1.2
.
P120-03-000
Issue: C
MATERIAL SAFETY DATA SHEET Rev Date: 01-02-05
Page: 3 of 6
PRODUCT NAME : GREASE - FOMBLIN (AR555)
6. Accidental Release Measures
In the event of spillage :
鈥? Isolate area of spill. Do not walk through or otherwise scatter spilled material. Recover released product and
collect in a suitable container for reuse or disposal. Thoroughly remove residue to prevent slipping.
鈥? Avoid discharge into sewage systems, in surface or underground waters and in the soil.
7. Handling and Storage
Handling : Do not drink, eat or smoke during handling. Avoid heating above the decomposition temperature of
290oC/554oF. If heating is necessary, use adequate ventilation. Do not carry cigarettes or cigars or smoke in
areas where this product is being used or stored. Greasy hands may contaminate tobacco products. Smoking
contaminated products may cause polymer fume fever. Wash thoroughly after handling and before meals and
breaks.
Storage : keep away from heat sources, from flammable , combustible or explosive materials and incompatible
compounds. Store in metal, glass or plastic (polyethylene) containers.
8. Exposure Controls/Personal Protection
Exposure Limits
Ingredient* ACGIH - TLV - OSHA - PEL Occupational Exposure
Limits EH40 (UK)
None Not applicable Not applicable Not applicable
* This column shows only hazardous ingredients that have established OSHA or ACGIH exposure guidelines.
ACGIH recommends PTFE decomposition products be quantitatively determined in air as fluoride to provide an
index of exposure. Although no TLV is recommended, ACGIH states 鈥渁ir concentration should be controlled as low
as possible.鈥?
Threshold limits of decomposition products(ACGIH 2003) :
Hydrogen fluoride : ACGIH TLV 3 ppm (Ceiling); OSHA PEL 3 ppm
Carbonyl fluoride : ACGIH TLV 2 ppm (TWA), 5 ppm (Ceiling)
Personal Protection:
Engineering Measures: General ventilation. Use local exhaust and additional engineering controls in
areas if product is heated to high temperature.
Respiratory Protection: No specific measures required under normal conditions.
Hand/Skin Protection: Wear rubber gloves (hygiene measure only).
Eye/Face Protection: Not necessary for product. Safety glasses are generally required in the work area.
Hygiene Measures: Avoid contact with skin. DO NOT eat or smoke whilst using the product. Wash
hands after use and before eating or smoking.
Other/General Protection: None.
705
DCC1 No :
BOC Edwards is part of BOC Limited
The stripe symbol is a trade mark of the BOC Group
Ref 2D01-010 form issue 1.2
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P120-03-000
Issue: C
MATERIAL SAFETY DATA SHEET Rev Date: 01-02-05
Page: 4 of 6
PRODUCT NAME : GREASE - FOMBLIN (AR555)
9. Physical and Chemical Properties
0
C/ 0F
Appearance and Odour White, odourless grease Boiling Point No data available
0
C/ 0F
pH (as supplied) No data available Freezing Point No data available
0
C/ 0F
Solubility in Water Insoluble in water. Soluble in Auto Ignition Not flammable
fluorinated solvents
0
C/ 0F
Volatile Content by Volume No data available Flash Point Not explosive
Specific Gravity 1.9
<1.3x10-6 mbar @ 20oC <10-6 @ 68o F
Vapour Pressure (mbar) Vapour Pressure (Torr)
10. Stability and Reactivity
Stability: Stable in normal conditions of use.
Avoid exposing the product to temperatures above 290oC/554oF. Avoid contact
Material/Conditions to Avoid:
with strong alkaline compounds (alkaline hydroxides and ammonia) , Lewis acids
(like AlCl3, SbF5, CoF3) above 100oC/212oF.
Hazardous Decomposition: Thermal decomposition products: hydrogen fluoride, carbonyl fluoride.
11. Toxicological Information
For a comprehensive description for the various toxicological (health) effects which may arise if the user comes
into contact with the substance or preparation refer to Section 3 Hazards Identification.
Animal Data:
LD50 value: No data available.
LC50 value: No data available.
Carcinogenicity, etc :
The product has no known effects in relation to carcinogenesis, mutagenesis and reprotoxicity.
Toxicity information for PTFE decomposition products:
Inhalation: PTFE decomposition products vary widely in toxicity in experimental animals. Four hour LC50s
(inhalation) for decomposition products range from 0.76 ppm (perfluoroisobutane) to 40,000 ppm
(tetrafluoroethylene monomer). Workers exposed to PTFE fumes produced at 350-380 掳C (temperatures
associated with liberation of hexafluoroethane, perfluoroisobutylene and octafluorocyclobutene) exhibited
symptoms consistent with polymer fume fever at workplace air concentrations of 3.5 mg/m3 compounds containing
fluorine.
Chronic: Repeated episodes of polymer fume fever may damage the lungs.
705
DCC1 No :
BOC Edwards is part of BOC Limited
The stripe symbol is a trade mark of the BOC Group
Ref 2D01-010 form issue 1.2
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P120-03-000
Issue: C
MATERIAL SAFETY DATA SHEET Rev Date: 01-02-05
Page: 5 of 6
PRODUCT NAME : GREASE - FOMBLIN (AR555)
12. Ecological Information
No foreseeable hazards. Use the product according to good working practices, avoiding polluting the environment.
Ecotoxicity : No data available.
13. Disposal Considerations
Incinerate in high temperature incinerators designed to burn fluorine compounds in accordance with local and
national regulations.
14. Transport Information
This product is not regulated as dangerous under transport regulations.
PARAMETER EUROPEAN CANADIAN TDG UNITED STATES DOT
Proper Shipping Name Not applicable Not applicable Not applicable
Hazard Class Not applicable Not applicable Not applicable
Identification Number Not applicable Not applicable Not applicable
Shipping Label Not applicable Not applicable Not applicable
15. Regulatory Information
European Regulatory Information
This product has been classified in accordance with the Dangerous Substances Directive (67/548/EEC, as
amended) and the Preparations Directive (88/379/EEC, as amended), implemented in the UK as the Chemical
(Hazard Information and Packing) Regulations 1994 (CHIP, as amended).
Classified as dangerous to supply : No
Risk Phrases : Not applicable
Safety Phrases : Not applicable
Symbols : None
United States Regulatory Information
SARA TITLE III SECTION 313 SUPPLIER INFORMATION:
Base oil and thickeners are not toxic chemicals subject to the reporting requirements of section 313 of the
Emergency Planning and Community Right-to-Know Act (EPCRA) of 1986 and 40 CFR Part 372.
California Proposition 65: Base oil and thickener are not listed as chemicals known to the State of California to
cause cancer, birth defects or other reproductive harm.
705
DCC1 No :
BOC Edwards is part of BOC Limited
The stripe symbol is a trade mark of the BOC Group
Ref 2D01-010 form issue 1.2
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P120-03-000
Issue: C
MATERIAL SAFETY DATA SHEET Rev Date: 01-02-05
Page: 6 of 6
PRODUCT NAME : GREASE - FOMBLIN (AR555)
Canadian Regulatory Information
WHMIS Classification: D2B
16. Other Information
This MSDS is compiled in accordance with ANSI Z400.1 and the EU Safety Data Sheet Directive 91/155/EEC.
Source of information for this data sheet:
鈥? Ausimont Safety Data Sheet for Fomblin Grease AR 555. Reference : sym/ss 346. Date : 28 June, 1995
鈥? National Library of Medicine (NLM) electronic databases (HSDB, RTECS, CHEMID, Toxline)
Glossary : CAS, Chemical Abstracts Service; NFPA, National Fire Protection Association; HMIS, Hazardous
Material Information Service; LD, Lethal Dose; LC, Lethal Concentration; ACGIH, American Conference of
Governmental Industrial Hygienists; TLV, threshold limit value; OSHA, Occupational Safety and Health
Administration, US department of Labour; PEL, Permissible exposure limit; EH40 (UK), HSE Guidance Note EH40
Occupational exposure limits; PPM, parts per million; TWA, Time-Weighted Average; STEL, Short Term Exposure
Limit; Canadian TDG, Canadian Transportation of Dangerous Goods; US DOT,US Department of Transportation.
HSDB, Hazardous Substances Data Bank; RTECS, Registry of Toxic Effects of Chemical Substances; CHEMID,
Chemical Identification; DSL, Domestic Substances List ; TSCA, Toxic Substances Control Act Public Law 94-469:
CERCLA, Comprehensive Environmental Response, Compensation and Liability Act; EPCRA. Emergency Planning
and Community Right-to-Know Act; CAA, Clean Air Act; US, SARA (Title III), Superfund Amendments and
Reauthorization Act.; SARA 313, Superfund Amendments and Reauthorization Act, Section 313; EHS, Extremely
Hazardous Substance; WHMIS, Workplace Hazardous Materials Information System.
Revisions
___________________________________________________________________________________________
_
Although the information and recommendations in this data sheet are to the best of our knowledge correct, it is recommended that
you make your own determination of the material鈥檚 suitability for your purpose before you use it. The information contained in this
data sheet has been reproduced from the manufacturers data, the accuracy of this information is the responsibility of the
manufacturer. BOC Edwards accept no responsibility for damage of any nature resulting from the use of, or the reliance upon this
data sheet.
705
DCC1 No :
BOC Edwards is part of BOC Limited
The stripe symbol is a trade mark of the BOC Group
Ref 2D01-010 form issue 1.2
.
P120-03-000
Issue: C
MATERIAL SAFETY DATA SHEET Rev Date: 01-02-05
Page: 7 of 6
PRODUCT NAME : GREASE - FOMBLIN (AR555)
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705
DCC1 No :
BOC Edwards is part of BOC Limited
The stripe symbol is a trade mark of the BOC Group
Ref 2D01-010 form issue 1.2
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