MATERIAL SAFETY 3M
DATA SHEET 3M Center
St. Paul, Minnesota
55144-1000
1-800-364-3577 or (651) 737-6501 (24 hours)
Copyright, 2001, Minnesota Mining and Manufacturing Company.
All rights reserved. Copying and/or downloading of this
information for the purpose of properly utilizing 3M products
is allowed provided that:
1) the information is copied in full with no changes unless
prior agreement is obtained from 3M, and
2) neither the copy nor the original is resold or otherwise
distributed with the intention of earning a profit thereon.
DIVISION: ENGINEERED ADHESIVES
HOME CARE DIVISION
ENGINEERED ADHESIVES
TRADE NAME:
SAFETY-WALK(TM) Brand Primer
ID NUMBER/U.P.C.:
62-2141-6550-8 00-21200-20243-8 70-0705-4945-9 00-48011-19339-2
ISSUED: November 28, 2001
SUPERSEDES: May 24, 2001
DOCUMENT: 10-5126-7
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1. INGREDIENT C.A.S. NO. PERCENT
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TOLUENE................................. 108-88-3 30.0 - 40.0
PETROLEUM DISTILLATE.................... 64742-88-7 10 - 20
ACETONE................................. 67-64-1 10.0 - 20.0
MAGNESIUM RESINATE...................... 68611-24-5 10.0 - 20.0
POLYCHLOROPRENE......................... 9010-98-4 10 - 20
N-HEXANE................................ 110-54-3 3 - 7
PENTAERYTHRITOL ESTER OF ROSIN.......... 8050-26-8 1.0 - 5
The components of this product are in compliance with the chemical
notification requirements of TSCA.
This product contains the following toxic chemical or chemicals subject to
the reporting requirements of Section 313 of Title III of the Emergency
Planning and Community Right-To-Know Act of 1986 and 40 CFR Part 372:
TOLUENE
N-HEXANE
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2. PHYSICAL DATA
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BOILING POINT:................. 132 F
(acetone)
VAPOR PRESSURE:................ 180.0000 mmHg
@ 68F
VAPOR DENSITY:................. 3.00 Air=1
EVAPORATION RATE:.............. >2.50 ether = 1
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Abbreviations: N/D - Not Determined N/A - Not Applicable CA - Approximately
MSDS: SAFETY-WALK(TM) Brand Primer
November 28, 2001 PAGE 2
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2. PHYSICAL DATA (continued)
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SOLUBILITY IN WATER:........... Slight
SPECIFIC GRAVITY:.............. 0.860 Water=1
PERCENT VOLATILE:.............. 69.00 % by wt
pH:............................ N/D
VISCOSITY:..................... ca. 1725.0 centistoke
MELTING POINT:................. N/D
APPEARANCE AND ODOR:
Tan - medium syrup, solvent odor
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3. FIRE AND EXPLOSION HAZARD DATA
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FLASH POINT:................... -14 F.T.C.C.
FLAMMABLE LIMITS - LEL:........ 1.00 % by vol
FLAMMABLE LIMITS - UEL:........ 12.80 % by vol
AUTOIGNITION TEMPERATURE:...... N/D
EXTINGUISHING MEDIA:
Carbon dioxide, Dry chemical, Foam
SPECIAL FIRE FIGHTING PROCEDURES:
Wear full protective clothing, including helmet, self-contained,
positive pressure or pressure demand breathing apparatus, bunker coat
and pants, bands around arms, waist and legs, face mask, and
protective covering for exposed areas of the head.
UNUSUAL FIRE AND EXPLOSION HAZARDS:
Closed containers exposed to heat from fire may build pressure and
explode. Vapors may travel long distances along the ground or floor
to an ignition source and flash back.
NFPA HAZARD CODES: HEALTH: 2 FIRE: 3 REACTIVITY: 0
UNUSUAL REACTION HAZARD: none
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4. REACTIVITY DATA
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STABILITY: Stable
INCOMPATIBILITY - MATERIALS/CONDITIONS TO AVOID:
Strong Oxidizing Agents.
HAZARDOUS POLYMERIZATION: Hazardous polymerization will not occur.
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Abbreviations: N/D - Not Determined N/A - Not Applicable CA - Approximately
MSDS: SAFETY-WALK(TM) Brand Primer
November 28, 2001 PAGE 3
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4. REACTIVITY DATA (continued)
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HAZARDOUS DECOMPOSITION PRODUCTS:
Carbon Monoxide and Carbon Dioxide, Hydrogen Chloride, Aldehydes,
Ketones, Hydrocarbons.
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5. ENVIRONMENTAL INFORMATION
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SPILL RESPONSE:
Refer to other sections of this MSDS for information regarding
physical and health hazards, respiratory protection, ventilation, and
personal protective equipment. Ventilate area. Extinguish all
ignition sources. Cover with absorbent material. Collect using non-
sparking tools. Place in a U.S. DOT-approved container.
RECOMMENDED DISPOSAL:
Incinerate in a permitted hazardous waste incinerator in the presence
of a combustible material. Dispose of waste product in a facility
permitted to accept chemical waste.
ENVIRONMENTAL DATA:
Not determined.
REGULATORY INFORMATION:
Volatile Organic Compounds: 596 gms/liter South Coast Air Quality Mgmt
Dist Method Rule 443.1, calculated.
VOC Less H2O & Exempt Solvents: 596 gms/liter South Coast Air Quality Mgmt
Dist Method Rule 443.1, calculated.
Since regulations vary, consult applicable regulations or authorities
before disposal. U.S. EPA Hazardous Waste Number = D001 (Ignitable)
EPCRA HAZARD CLASS:
FIRE HAZARD: Yes PRESSURE: No REACTIVITY: No ACUTE: Yes CHRONIC: Yes
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6. SUGGESTED FIRST AID
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EYE CONTACT:
Immediately flush eyes with large amounts of water. Get immediate
medical attention.
SKIN CONTACT:
Flush skin with large amounts of water. If irritation persists, get
medical attention.
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Abbreviations: N/D - Not Determined N/A - Not Applicable CA - Approximately
MSDS: SAFETY-WALK(TM) Brand Primer
November 28, 2001 PAGE 4
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6. SUGGESTED FIRST AID (continued)
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INHALATION:
Remove person to fresh air. If not breathing, give artificial
respiration. If breathing is difficult, get immediate medical
attention.
IF SWALLOWED:
If swallowed, call a physician immediately. Only induce vomiting at
the instruction of a physician. Never give anything by mouth to an
unconscious person.
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7. PRECAUTIONARY INFORMATION
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EYE PROTECTION:
Avoid eye contact. Wear unvented goggles during operations in which
exposure is likely.
SKIN PROTECTION:
Avoid skin contact. Wear appropriate gloves when handling this
material. A pair of gloves made from the following material(s) are
recommended: polyethylene/ethylene vinyl alcohol, polyvinyl alcohol,
fluoroelastomer (Viton). Use one or more of the following personal
protection items as necessary to prevent skin contact: apron.
Protective garments (other than gloves) should be made of either of
the following materials: polyethylene/ethylene vinyl alcohol,
fluoroelastomer (Viton).
RECOMMENDED VENTILATION:
Use in a well-ventilated area. Provide sufficient ventilation to
maintain emissions below recommended exposure limits. If exhaust
ventilation is not adequate, use appropriate respiratory protection.
RESPIRATORY PROTECTION:
Avoid prolonged breathing of vapors. Select one of the following
NIOSH approved respirators based on airborne concentration of
contaminants and in accordance with OSHA regulations: half-mask
organic vapor respirator, full-face organic vapor respirator.
PREVENTION OF ACCIDENTAL INGESTION:
Do not ingest.
RECOMMENDED STORAGE:
Store in a cool place. Store away from heat. Store out of direct
sunlight. Keep container closed when not in use. Keep container in
well-ventilated area. Keep out of the reach of children.
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Abbreviations: N/D - Not Determined N/A - Not Applicable CA - Approximately
MSDS: SAFETY-WALK(TM) Brand Primer
November 28, 2001 PAGE 5
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7. PRECAUTIONARY INFORMATION (continued)
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FIRE AND EXPLOSION AVOIDANCE:
Keep container tightly closed. Flammable liquid and vapor. Keep
away from heat, sparks, open flame, and other sources of ignition.
Ground containers securely when transferring contents. Wear low
static or properly grounded shoes. No smoking while handling this
material. Vapors may ignite explosively. Explosive when mixed with
oxidizing substance.
EXPOSURE LIMITS
INGREDIENT VALUE UNIT TYPE AUTH SKIN*
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TOLUENE.............................. 50 PPM TWA ACGIH Y
TOLUENE.............................. 100 PPM TWA OSHAV
OSHA VACATED PEL
TOLUENE.............................. 150 PPM STEL OSHAV
OSHA VACATED PEL
TOLUENE.............................. 200 PPM TWA OSHA
TOLUENE.............................. 300 PPM CEIL OSHA
TOLUENE.............................. 75 PPM STEL CMRG Y
PETROLEUM DISTILLATE................. 100 PPM TWA CMRG
ACETONE.............................. 500 PPM TWA ACGIH
ACETONE.............................. 750 PPM STEL ACGIH
ACETONE.............................. 750 PPM TWA OSHAV
OSHA VACATED PEL
ACETONE.............................. 1000 PPM STEL OSHAV
OSHA VACATED PEL
ACETONE.............................. 1000 PPM TWA OSHA
MAGNESIUM RESINATE................... NONE NONE NONE NONE
POLYCHLOROPRENE...................... NONE NONE NONE NONE
N-HEXANE............................. 50 PPM TWA ACGIH Y
N-HEXANE............................. 50 PPM TWA OSHAV
OSHA VACATED PEL
N-HEXANE............................. 500 PPM TWA OSHA
PENTAERYTHRITOL ESTER OF ROSIN....... NONE NONE NONE NONE
* SKIN NOTATION: Listed substances indicated with 'Y' under SKIN refer to
the potential contribution to the overall exposure by the cutaneous route
including mucous membrane and eye, either by airborne or, more particularly,
by direct contact with the substance. Vehicles can alter skin absorption.
SOURCE OF EXPOSURE LIMIT DATA:
- ACGIH: American Conference of Governmental Industrial Hygienists
- CMRG: Chemical Manufacturer Recommended Exposure Guidelines
- OSHA: Occupational Safety and Health Administration
- OSHAV: Occupational Safety and Health Administration Vacated PEL.
Vacated Permissible Exposure Limits (PEL) are enforced as
the OSHA PEL in some states. Check with your local
regulatory authority.
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Abbreviations: N/D - Not Determined N/A - Not Applicable CA - Approximately
MSDS: SAFETY-WALK(TM) Brand Primer
November 28, 2001 PAGE 6
EXPOSURE LIMITS (continued)
INGREDIENT VALUE UNIT TYPE AUTH SKIN*
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- NONE: None Established
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8. HEALTH HAZARD DATA
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EYE CONTACT:
Moderate Eye Irritation: signs/symptoms can include redness, swelling,
pain, tearing, and hazy vision.
SKIN CONTACT:
Moderate Skin Irritation: signs/symptoms can include redness,
swelling, itching, and dryness.
INHALATION:
Cardiac Sensitization: sudden heart stoppage due to a reflex effect
on the nerves which control the heart. This effect usually occurs
only after inhalation of concentrated vapors such as in intentional
abusive sniffing of certain solvents and propellants.
Nervous System Effects: signs/symptoms can include emotional changes,
lack of coordination, tremors and sensory loss.
Central Nervous System Depression: signs/symptoms can include
headache, dizziness, drowsiness, incoordination, slowed reaction time,
slurred speech, giddiness and unconsciousness.
Irritation (upper respiratory): signs/symptoms can include soreness
of the nose and throat, coughing and sneezing.
Pulmonary Edema: signs/symptoms can include coughing, congestion,
difficulty breathing, which can result in respiratory failure and
death.
WHILE THE FOLLOWING EFFECTS ARE ASSOCIATED WITH ONE OR MORE OF THE
INDIVIDUAL INGREDIENTS IN THIS PRODUCT AND ARE REQUIRED TO BE
INCLUDED ON THE MSDS BY THE U.S. OSHA HAZARD COMMUNICATION STANDARD,
THEY ARE NOT EXPECTED EFFECTS DURING FORESEEABLE USE OF THIS PRODUCT.
Blood disorders: signs/symptoms can include prolonged weakness and
fatigue.
Arrhythmia: signs/symptoms can include palpitations, pounding, or
irregular pulse.
Kidney Effects: signs/symptoms can include reduced urine volume,
blood in urine and back pain.
Liver Effects: signs/symptoms can include yellow skin(jaundice) and
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Abbreviations: N/D - Not Determined N/A - Not Applicable CA - Approximately
MSDS: SAFETY-WALK(TM) Brand Primer
November 28, 2001 PAGE 7
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8. HEALTH HAZARD DATA (continued)
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tenderness of upper abdomen.
Peripheral Neuropathy: signs/symptoms can include tingling of
extremities, incoordination, numbness, weakness and tremors.
IF SWALLOWED:
Irritation of Gastrointestinal Tissues: signs/symptoms can include
pain, vomiting, abdominal tenderness, nausea, blood in vomitus, and
blood in feces.
Central Nervous System Depression: signs/symptoms can include
headache, dizziness, drowsiness, muscular weakness, incoordination,
slowed reaction time, fatigue, blurred vision, slurred speech,
giddiness, tremors and convulsions.
Aspiration Pneumonitis: signs/symptoms can include coughing,
difficulty breathing, wheezing, coughing up blood and pneumonia,
which can be fatal.
WHILE THE FOLLOWING EFFECTS ARE ASSOCIATED WITH ONE OR MORE OF THE
INDIVIDUAL INGREDIENTS IN THIS PRODUCT AND ARE REQUIRED TO BE
INCLUDED ON THE MSDS BY THE U.S. OSHA HAZARD COMMUNICATION STANDARD,
THEY ARE NOT EXPECTED EFFECTS DURING FORESEEABLE USE OF THIS PRODUCT.
Kidney Effects: signs/symptoms can include reduced urine volume,
blood in urine and back pain.
Liver Effects: signs/symptoms can include yellow skin(jaundice) and
tenderness of upper abdomen.
Peripheral Neuropathy: signs/symptoms can include tingling of
extremities, incoordination, numbness, weakness and tremors.
REPRODUCTIVE/DEVELOPMENTAL TOXINS:
WARNING: Contains a chemical which can cause birth defects. (108-88-
3)
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SECTION CHANGE DATES
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PRECAUTIONARY INFO. SECTION CHANGED SINCE May 24, 2001 ISSUE
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Abbreviations: N/D - Not Determined N/A - Not Applicable CA - Approximately
MSDS: SAFETY-WALK(TM) Brand Primer
November 28, 2001 PAGE 8
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The information in this Material Safety Data Sheet (MSDS) is believed to
be correct as of the date issued. 3M MAKES NO WARRANTIES, EXPRESSED OR
IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF
MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF
PERFORMANCE OR USAGE OF TRADE. User is responsible for determining
whether the 3M product is fit for a particular purpose and suitable for
user's method of use or application. Given the variety of factors that
can affect the use and application of a 3M product, some of which are
uniquely within the user's knowledge and control, it is essential that
the user evaluate the 3M product to determine whether it is fit for a
particular purpose and suitable for user's method of use or application.
3M provides information in electronic form as a service to its customers.
Due to the remote possibility that electronic transfer may have resulted
in errors, omissions or alterations in this information, 3M makes no
representations as to its completeness or accuracy. In addition,
information obtained from a database may not be as current as the
information in the MSDS available directly from 3M.
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