Part No.: 19-0133-04
MATERIAL SAFETY DATA SHEET
Prescription Treatment庐 brand Advance庐 375A Select Granular Ant Bait
EMERGENCY PHONE NUMBERS:
MEDICAL: 800-225-3320 (Prosar) TRANSPORTATION: 800-424-9300 (Chemtrec)
IN CASE OF FIRE
SECTION 1. PRODUCT AND COMPANY IDENTIFICATION Extinguisher Media: CO2, Dry Chemical, Foam
Product Name: Prescription Treatment brand Advance 375A
庐 庐
Special Fire Fighting Procedures: Respiratory protection is recommended for
Select Granular Ant Bait fire fighters. Excessive use of water may create excess run-off water which may lead
EPA Reg. No.: 499-370 to contamination of the environment. Follow environmental and personal safety pre-
Product Code: 02-0375 (12 x 8 oz) cautions noted for spill or leak.
02-0375-1 (4 x 2 lbs)
EPA Signal Word: CAUTION
SECTION 6. ACCIDENTAL RELEASE MEASURES
Distributed by: Whitmire Micro-Gen Research Laboratories, Inc.
3568 Tree Court Industrial Blvd. IN CASE 0F SPILL OR LEAK
St. Louis MO 63122-6682 Spilled material should be carefully collected and containerized in a manner that
produces the least amount of airborne dust. Residual surface material may be
removed with towels moistened with water. This product contains no Comprehen-
SECTION 2. COMPOSITION / INFORMATION ON INGREDIENTS sive Environmental Response, Compensation and Liability Act (CERCLA) listed
COMPOSITION INFORMATION chemicals. Spills/releases of this product are not reportable to the National
Response Center.
ACTIVE INGREDIENT (0.011%) % CAS NO.
Emergency Telephone Number of Chemtrec: 800-424-9300 (for transporta-
Abamectin B1 0.011 71751-41-2
tion spills)
OTHER INGREDIENTS* (99.989%) PROTECTIVE EQUIPMENT FOR CLEANUP PERSONNEL
Eyes: Use proper protection 鈥? safety glasses are recommended.
* All ingredients may not be listed. Ingredients not listed do not meet the reporting requirements of the
Skin: Wear chemical-resistant gloves. (Good practice requires that gross amounts
OSHA Hazard Communication Standard (HCS) as specified in 29 CFR 1910.1200.
of any chemical be removed from the skin as soon as practical, especially before
EXPOSURE INFORMATION eating or smoking.)
OSHA PEL ACGIH TLV Inhalation: Use of a respirator may be appropriate when working with spills in
MATERIAL STEL TWA STEL TWA enclosed or confined spaces. When using a respirator, wear a NIOSH approved res-
Abamectin B1* NE NE NE NE pirator with an organic vapor (OV) cartridge or canister with any R or P prefilter. See
*TWA recommended by ingredient supplier = 0.02 mg/m鲁 29 CFR 1910.134 for respiratory protection, training and testing requirements.
WASTE DISPOSAL METHOD
SECTION 3. HAZARDS IDENTIFICATION Do not contaminate water, food or feed by storage or disposal of wastes. Take full or
leaking containers to a local disposal company for biological treatment or incinera-
SIGNS/SYMPTOMS OF EXPOSURE
tion. Review all local, state and federal regulations concerning health and pollution
May cause some reversible eye irritation.
to determine approved disposal procedures. NEVER PLACE WASTES DOWN ANY
ROUTES OF ENTRY INDOOR OR OUTDOOR DRAIN OR SEWER.
Primary: Skin Secondary: Ingestion Tertiary: Inhalation
HAZARDOUS DECOMPOSITION PRODUCTS
SECTION 7. HANDLING AND STORAGE
If involved in fire, toxic gases including carbon monoxide and carbon dioxide, toxic
HAZARDS TO HUMANS AND DOMESTIC ANIMALS
dust and smoke may be generated.
Keep out of reach of children. CAUTION 鈥? Harmful if swallowed or absorbed through
UNUSUAL FIRE, EXPLOSION AND REACTIVITY HAZARDS
skin. Avoid breathing dust. Avoid contact with eyes, skin or clothing. Wash thor-
Material will burn if ignited.
oughly with soap and water after handling. Do not contaminate kitchen utensils with
this product. Pets may be attracted to this product.
SECTION 4. FIRST AID MEASURES NOTE: Certain breeds of herding dogs (such as Collies, Border Collies, Old Eng-
lish Sheepdogs, Shelties and Australian Shepherds) may be sensitive to Abamectin,
Have the product container or label with you when calling a poison control center or
particularly if pure bred. Exposure of these breeds to Abamectin bait should be min-
doctor or going for treatment. Describe any symptoms and follow the advice given.
imized by placing it beyond their reach or scattering it well.
Ingestion: Call a poison control center or doctor immediately for treatment advice.
Have person sip a glass of water if able to swallow. Do not induce vomiting unless STORAGE
told to do so by the poison control center or doctor. Do not give anything by mouth Do not contaminate water, food or feed by storage. Store in a cool, secure, dry area
to an unconscious person. inaccessible to children, pets, livestock or wildlife. Do not store near heat or flame.
Keep container tightly closed. Do not reuse empty container.
Skin Contact: Take off contaminated clothing. Rinse skin immediately with plenty
of water for 15 - 20 min. Call a poison control center or doctor for treatment advice.
Eye Contact: Hold eyes open and rinse slowly and gently with water for 15 - 20 SECTION 8. EXPOSURE CONTROL / PERSONAL PROTECTION
min. Remove contact lenses, if present, after the first 5 min, then continue rinsing
PERSONAL PROTECTIVE EQUIPMENT (PPE)
eyes. Call a poison control center or doctor for treatment advice. Respiratory Protection: None required when used according to label directions.
Note to Physician: None Protective Gloves: Chemical-resistant gloves are recommended if prolonged
or repeated skin contact is likely. (Good practice requires that gross amounts of
Medical Conditions Generally Aggravated by Exposure: None known
any chemical be removed from the skin as soon as practical, especially before eat-
Emergency Telephone Number of Prosar: 800-225-3320 (for medical emergencies)
ing or smoking.)
Eye Protection: Use proper protection - safety glasses are recommended.
SECTION 5. FIRE FIGHTING MEASURES Other Protective Equipment: None required
VENTILATION
FIRE AND EXPLOSION
Local Exhaust: None required
Flash Point (TCC): NE Mechanical: None required
Explodibility Limits in Air (% by volume): Special: None required
Lower (LEL) = NE Upper (UEL) = NE Other: None required
NFPA 30B Flammability: NA
UNUSUAL FIRE, EXPLOSION AND REACTIVITY HAZARDS
Material will burn if ignited.
Page 1 of 2
MATERIAL SAFETY DATA SHEET
Prescription Treatment庐 brand Advance庐 375A Select Granular Ant Bait
SECTION 13. DISPOSAL CONSIDERATION
SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES
Do not contaminate water, food or feed by disposal of container or waste. Dispose of
Appearance: Yellow, granular bait Odor: NE
container and waste in accordance with all federal, state and local regulations.
Solubility in Water: Insoluble Vapor Pressure: NA
Container Disposal: Empty container by using the product according to the label
Viscosity: NA Vapor Density: NA
directions. Do not reuse container! Offer empty container for recycling, if available,
Boiling Point: NA Freezing/Melting Point: NE
or place in trash if allowed by state and local regulations. If container is partly full,
pH: NA Density: NE
contact your local solid waste agency for disposal instructions.
Waste Disposal: Wastes resulting from the use of this product may be disposed
SECTION 10. STABILITY AND REACTIVITY of on site or at an approved waste disposal facility. NEVER PLACE UNUSED PROD-
UCT OR WASTE DOWN ANY INDOOR OR OUTDOOR DRAIN OR SEWER!
REACTIVITY
Stability: Stable under normal conditions.
Conditions to Avoid: None known SECTION 14. TRANSPORT INFORMATION
Incompatibility (Material to Avoid): Abamectin can be hydrolyzed by strong,
This product is not regulated for transportation via any mode of transport.
caustic solutions.
Hazardous Polymerization: Will not occur
SECTION 15. REGULATORY INFORMATION
HAZARDOUS DECOMPOSITION PRODUCTS
If involved in a fire, toxic gases including carbon monoxide and carbon dioxide, CERCLA
toxic dust and smoke may be generated. This product contains no CERCLA listed chemicals.
SARA TITLE III SECTION 311/312 HAZARD CLASS
SECTION 11. TOXICOLOGICAL INFORMATION This product has been reviewed according to the EPA 鈥淗azard Categories鈥? promul-
gated under Section 311 and 312 of the Superfund Amendment and Reauthorization
ROUTES OF ENTRY
Act of 1986 (SARA Title III) and is considered, under applicable definitions, to meet
Primary: Skin Secondary: Ingestion Tertiary: Inhalation
the following categories:
ACUTE
Immediate Health Hazard
Eyes: Product produced slight conjunctival eye irritation in albino rabbit eyes
SARA TITLE III SECTION 313 CHEMICALS
reversible within 7 days. Caused a dull cornea in albino rabbit eyes, reversible in 3
This product contains no substances subject to the reporting requirements of Sec-
days. No iritis was observed.
tion 313 of the Superfund Amendments and Reauthorization Act of 1986 (SARA Title
Skin: Non-irritating to skin. Acute dermal LD50 = 2,000 mg/kg (rabbits). Primary skin
III) or 40 CFR Part 372 in concentrations above the de minimis concentration level.
irritation index = 0.00 (rats). Product is not a sensitizer when tested on guinea pigs.
Ingestion: Acute oral toxicity LD50 > 5,000 mg/kg (rats). TSCA
Inhalation: Bait particles are not respirable. The product does not represent an All components of this product are listed or excluded from listing on the US Toxic
inhalation hazard. Substance Control Act (TSCA) Chemical Substance Inventory.
CHRONIC / CARCINOGENICITY
Neither this product nor any of its ingredients are classified as carcinogens by the
SECTION 16. OTHER INFORMATION
National Toxicity Program (NTP), the International Agency for Research on Cancer
(IARC) or the Occupational Safety and Health Administration (OSHA). NFPA HEALTH RATING INFORMATION KEY: 4 = Severe
HEALTH - 1 FLAMMABILITY - 1 REACTIVITY - 0 3 = Serious
2 = Moderate
SECTION 12. ECOLOGICAL INFORMATION HMIS HAZARD RATING INFORMATION 1 = Slight
This pesticide is toxic to fish and wildlife. Do not apply directly to water, to areas where HEALTH - 1 FLAMMABILITY - 1 REACTIVITY - 0 0 = Minimal
surface water is present, or to intertidal areas below the mean high water mark. Do not
contaminate water when disposing of equipment washwaters.
The information and recommendations contained herein are based upon data believed to be correct. However, no guarantee or warranty of any kind, expressed or implied, is made
with respect to the information contained herein. For automatic MSDS updates, register at www.wmmg.com.
Questions concerning the safe handling of the product should be referred to the Whitmire Micro-Gen Customer Service Department at 800-777-8570.
NA - Not Applicable Effective Date: 11/07/06
NE - Not Established Review Date: 11/07/06
WHITMIRE MICRO-GEN
PEL - Permissible Exposure Limit Supersedes: 02/17/04
TLV - Threshold Limit Value Code #: 209-035
RESEARCH LABORATORIES, INC.
STEL - Short Term Exposure Limit (15 min) Text ID: 070511-6
TWA - Time Weighted Average (8 hr) Part No.: 19-0133-04
Page 2 of 2
|