MATERIAL SAFETY DATA SHEET
MSDS IDENTIFICATION NAME: TYFO餂? FC Component B DATE: Nov. 13,1997 PAGE: 1 OF 6
MSDS NUMBER: TYFO-FCB00-01 SUPERSEDES MSDS: 393-7373-TYFO-FCB0-04
SECTION I: MATERIAL AND MANUFACTURER IDENTIFICATION
MANUFACTURER: EMERGENCY TELEPHONE NUMBER:
FYFE CO., LLC 800-282-8200
6044 Cornerstone Court West Suite 鈥淐鈥? INFORMATION TELEPHONE NUMBER:
San Diego, CA 92121-4730 619-642-0694
PRODUCTION IDENTIFICATION NUMBER: TYFO餂欶C, Component B
CHEMICAL FAMILY: Hardener
SECTION II: HAZARDOUS INGREDIENTS
MATERIAL OR CAS % BY OSHA(PEL) ACGIH(TLV)
COMPONENT NUMBER WEIGHT
Proprietary Proprietary 89-95 Not determined Not determined
component #1
Proprietary Proprietary 5-7 Not determined Not determined
component #2
THE PERCENTAGES WILL VARY DEPENDING ON THE INDIVIDUAL MATERIAL
OR COMPONENT VARIATION.
SECTION III: HAZARD IDENTIFICATION
EMERGENCY OVERVIEW:
APPEARANCE AND ODOR:
Pale yellow to clear liquid with an ammonia-like odor.
STATEMENTS OF HAZARD:
DANGER ! CORROSIVE ! CAUSE SEVERE EYE AND SKIN BURNS.
MAY CAUSE BLINDNESS.
HARMFUL IF ABSORBED THROUGH SKIN.
HARMFUL OR FATAL IF SWALLOWED AND CAN CAUSE LUNG INJURY IF SWALLOWED AND ASPIRATED.
MAY CAUSE RESPIRATORY TRACT IRRITATION.
PRIMARY ROUTES OF EXPOSURE:
EYES--YES SKIN CONTACT--YES INHALATION--YES INGESTION--NO
HMIS RATING:
HEALTH--3 FLAMMABILITY--1 REACTIVITY--0 SPECIAL--NONE
MSDS NUMBER: TYFO-FCB00-01 DATE: Nov. 13,1997 PAGE 2 OF 6
SECTION III: HAZARD IDENTIFICATION (CONTINUED)
POTENTIAL HEALTH EFFECTS:
EYES: Cause irritation with pain and excess blinking and tear production with excess redness and swelling and chemical
burns of the eye. Severe eye damage may cause blindness. This product contains one or amines which may produce
temporary and reversible hazy or blurred vision.
SKIN: Causes severe irritation with pain; severe excess redness and swelling with chemical burns, blister formation and
possible tissue destruction. Repeated skin contact may cause persistent irritation or dermatitis and result in the
absorption of harmful amounts of material.
INHALATION: Inhalation of vapor or mist may cause irritation to the nose, throat or chest. Repeated or severe over
exposure may result in difficulty in breathing, headache, nausea, vomiting and drowsiness. Prolonged or repeated over-
exposure may result in lung damage.
INGESTION: Cause burning of mouth, throat and stomach with abdominal pain, nausea, vomiting, diarrhea, thirst,
weakness and collapse. Aspiration may occur during swallowing or vomiting resulting in lung damage.
MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE: Preexisting conditions such as asthma, allergies, eczema,
bronchitis, inflammatory or fibrotic respiratory disease and other lung and skin disorders may be aggravated by exposure
to the product.
OTHER: The components present in this material at concentrations equal to or greater than 0.1% are not listed or
regulated by IARC, NTP, OSHA OR ACGIH as a carcinogen. Dust from machining the cured product may cause
mechanical irritation of the eyes, skin, nose, throat and upper respiratory tract.
OSHA(PEL) ACGIH(TLV)
3 3
15 mg/m (Total) 10 mg/m (Total)
EXPOSURE LIMITS FOR CURED
3 3
PRODUCT DUST: 5 mg/ m (Respirable) 3 mg/ m (Respirable)
SECTION IV: FIRST AID MEASURES
EYES: In case of eye contact, immediately flush eyes with large amounts of water for at least 15 minutes, keeping the
eyelids open. Get medical attention.
SKIN CONTACT: In case of contact, immediately wash skin with soap and plenty of water. Get medical attention if
irritation develops.
INHALATION: If excessive inhalation of vapor occurs, remove to fresh air. If not breathing, give artificial respiration,
preferably mouth-to-mouth. If breathing is difficult, qualified personnel may administer oxygen. Get medical attention.
INGESTION: If swallowed, get medical attention immediately. Do not induce vomiting.
SECTION V: FIRE FIGHTING MEASURES
FLASH POINT/METHOD OF DETERMINATION: 250掳F-325掳F/121掳C-163掳C, PMCC
MEANS OF EXTINCTION: Use water-spray, dry chemical, foam or C02 to extinguish fires, Use water to cool containers.
SPECIAL FIRE HAZARDS: Avoid exposure through use of a self-contained, positive-pressure breathing apparatus.
MSDS NUMBER: TYFO-FCB00-01 DATE: Nov. 13,1997 PAGE 3 OF 6
SECTION VI: ACCIDENTAL RELEASE MEASURES
PROCEDURES IN CASE OF ACCIDENTAL RELEASE OF LEAKAGE: Ventilate area. Avoid breathing vapor. Use self-
contained breathing apparatus or supplied air of large spills or confined areas. Avoid contact with skin, eyes or clothing
(See Section VIII). Contain spill if possible. Absorb or wipe up with suitable material, put into a container and dispose of
properly (See Section XIII). Prevent entry into sewers and waterways.
SECTION VII: HANDLING AND STORAGE
PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE: Minimum feasible handling temperatures should be
maintained. Avoid exposure to temperatures above 100掳F/38掳C. Avoid water contamination. Have an eye wash and
shower available for emergencies.
SECTION VIII: EXPOSURE CONTROLS / PERSONAL PROTECTION
EYE/FACE PROTECTION: Avoid eye and skin contact. Wear chemical type goggles and a faceshield.
SKIN PROTECTION: Protective clothing such as uniforms, coveralls or lab coats must be worn. Launder or dry-clean
when soiled. Gloves resistant to chemicals and petroleum distillates are required. When handling large quantities,
impervious suits, gloves and rubber boots must be worn.
RESPIRATORY PROTECTION: Airborne concentrations should be kept to the lowest levels possible. If vapor or mist is
generated, use a NIOSH approved organic vapor respirator. Supplied air respiratory protection should be used for
cleaning large spills or upon entry into tank, vessels or other confined spaces. If sufficient dust is generated during
machining of the cured product, use a NIOSH approved dust respirator.
VENTILATION: Local exhaust ventilation recommended sufficient to control the vapor, mist or dust being generated. If
exhaust ventilation is not available or is inadequate, use a NIOSH approved respirator, as appropriate.
GENERAL HYGIENE RECOMMENDATIONS: Before eating, drinking, smoking or using toilet facilities, wash face and
hands thoroughly with soap and water. Remove any contaminated clothing and launder before reuse. Properly dispose
of shoes and clothing that are extremely contaminated. Use vacuum equipment to remove cured product dust from
clothing and work areas. Compressed air is not recommended.
SECTION IX: PHYSICAL AHD CHEMICAL PROPERTIES
Pale yellow to clear-liquid with an ammonia-like odor
APPEARANCE AND ODOR
掳掳
BOILING POINT (掳F/掳C) 500掳F/260掳C
掳掳 Not determined
MELTING POINT (掳F/掳C)
0.640-0.975
SPECIFIC GRAVITY ( WATER=1)
11.5-12.5
pH OF UNDILUTED PRODUCT
Not determined
VAPOR PRESSURE (mm Hg.)
Not determined
VAPOR DENSITY (AIR-1)
Not determined
VISCOSITY
Not determined
PERCENT (%) VOC
>10%
SOLUBILITY IN WATER
MSDS NUMBER: TYFO-FCB00-01 DATE: Nov. 13,1997 PAGE 4 OF 6
SECTION X: STABILITY AND REACTIVITY
STABILITY: Stable under normal handling and storage conditions.
INCOMPATIBLE MATERIALS: Reacts violently with acids.
PRODUCTS EVOLVED FROM HEAT OF COMBUSTION OR DECOMPOSITION:
The products of combustion and decomposition depend on other materials present in the fire and the actual conditions of
the fire. Burning will produce ammonia, combustion products of nitrogen, carbon monoxide, carbon dioxide, irritating
aldehydes, ketones and other unidentified gases and vapors which may to toxic. Avoid inhalation.
HAZARDOUS POLYMERIZATIONS: Will not occur under normal conditions of use. When mixed with the resin,
Component A of a resin system and / or rapid heating of the product in bulk may produce an uncontrolled exothermic
reaction which may char and decompose the resin system, generating unidentified gases and vapors which may be toxic.
Avoid inhalation.
SECTION XI: TOXICOLOGICAL INFORMATION
MATERIAL OR COMPONENT TOXICITY DATA:
MEDIAN LETHAL DOSE (SPECIES):
ORAL (LD50) Proprietary component #1 2,880 mg/kg (Rat)
Proprietary component #2 1,100 mg/kg (Rat)
DERMAL (LD50) Proprietary component #1 2,980 mg/kg (Rabbit)
Proprietary component #2 980 mg/kg (Rabbit)
IRRITATION INDEX, ESTIMATION OF IRRITATION (SPECIES):
SKIN Proprietary component #1 (Draize) Believed to be >6.50-8.00/8.0
(Rabbit); corrosive.
Proprietary component #2 (Draize)4.6/8.0 (Rabbit), corrosive
EYES Proprietary component #1 (Draize) Believed to be 80.00-
110.00/110 (Rabbit), extreme irritation
Proprietary component #2 (Draize)94.00/110 (Rabbit),
extreme irritation
SENSITIZATION Proprietary component #1 Negative-skin (Guinea Pig)
Proprietary component #2 Negative-skin (Guinea Pig)
OTHER: None
SECTION XII: ECOLOGICAL INFORMATION
No ecological date has been determined.
SECTION XII: DISPOSAL CONSIDERATIONS
WASTE DISPOSAL METHODS: Material for disposal should be placed in appropriate sealed containers to avoid
potential human and environmental exposure. It is the responsibility of the generator to comply with all federal, state,
provincial and local laws and regulations. We recommend that you contact an appropriate waste disposal contractor and
environmental agency for relevant laws and regulation. Under the US, Resource Conservation and Recovery Act
(RCRA), it is the responsibility of the user of the product to determine at the time of disposal, whether the product meets
relevant waste classification and to assure proper disposal.
MSDS NUMBER: TYFO-FCB00-01 DATE: Nov. 13,1997 PAGE 5 OF 6
SECTION XIV: TRANSPORTATION INFORMATION
DOT AND IATA:
PROPER SHIPPING NAME Amines, liquid, corrosive, n.o.s.
(Polypropylenediamine),(Polyoxyproplyenediamine)
HAZARD CLASS Class 8
IDENTIFICATION NUMBER UN 2735
PACKING GROUP III
LABEL REQUIRED Corrosive
SECTION XV: REGULATORY INFORMATION
SARA TITLE III:
SECTION 302/304 EXTREMELY HAZARDOUS SUBSTANCE:
None
SECTION 311 HAZARDOUS CATEGORIZATION:
Proprietary mixture, Class 1 (Acute)
SECTION 313 TOXIC CHEMICALS:
None
CERCLA SECTION 102(a) HAZARDOUS SUBSTANCE:
This product is not listed as a Hazardous Substance in 40 CFR, Part 302.4.
RCRA INFORMATION:
Currently, this product is not listed in federal hazardous waste regulation 40 CFR, Part 261.33, paragraphs (e) or (f), i.e.
chemical products that are considered hazardous if they become wastes. become wastes. It does not exhibit any of the
hazardous characteristics listed in 40 CFR, Part 261, Subpart C. State or local hazardous waster regulations may apply if
they are different from the federal regulation. It is the responsibility of the user of the product to determine at the time of
disposal, whether the product meets relevant waste classification and to assure proper disposal.
WHMIS (CANADA):
CLASSIFICATION:
Class D, Division 1, Subdivision B: Toxic
Class E: Corrosive
INGREDIENT DISCLOSURE LIST: None
CALIFORNIA SAFE DRINKING WATER AND TOXIC ENFORCEMENT ACT OF 1986 (PROPOSITION 65):
WARNING ! THE STATE OF CALIFORNIA HAS DETERMINED THAT THE FOLLOWING LISTED MATERIAL OR
COMPONENT CHEMICALS IN THIS PRODUCT MAY CAUSE CANCER, BIRTH DEFECT OR OTHER
REPRODUCTIVE HARM:
None
ALL MATERIALS OF COMPONENTS OF THIS PRODUCT ARE EITHER LISTED OR ARE NOT REQUIRED TO BE
LISTED IN THE EPA TSCA INVENTORY.
THIS PRODUCT DOES NOT CONTAIN OR IS NOT MANUFACTURED WITH OZONE DEPLETING SUBSTANCES AS
IDENTIFIED IN THE TITLE VI, CLEAN AIR ACT 鈥淪TRATOSPHERIC OZONE PROTECTION鈥? AND THE
REGULATIONS SET FORTH IN 40 CFR, PART 82.
MSDS NUMBER: TYFO-FCB00-01 DATE: Nov. 13,1997 PAGE 6 OF 6
SECTION XVI: OTHER INFORMATION
SPECIAL PRECAUTIONS: Empty containers will retain some of the product residue. When handing or disposing of
them, follow all label warnings, other instructions and waste disposal procedures.
EXPLANATION AND DISCLAIMER: Wherever such words or phrases as 鈥渉azardous,鈥? 鈥渢oxic,鈥? 鈥渃arcinogen,鈥? etc. appear
herein, they are used as defined or described under state employee right-to-know laws, Federal OSHA laws or the direct
sources for these laws such as the International Agency for Research on Cancer (IARC), the National Toxicology
Program (NTP), etc. The use of such words or phrases should not be taken to mean that we deem or imply any
substance or exposure to be toxic, hazardous or otherwise harmful. ANY EXPOSURE CAN ONLY BE UNDERSTOOD
WITHIN THE ENTIRE CONTEXT OF ITS OCCURRENCE, WHICH INCLUDES SUCH FACTORS AS THE
SUBSTANCE鈥? CHARACTERISTICS AS DEFINED IN THE MSDS, AMOUNT AND DURATION OF EXPOSURES,
OTHER CHEMICALS PRESENT AND PREEXISTING INDIVIDUAL DIFFERENCES IN RESPONSE TO THE
EXPOSURE.
The data provided is based on the information received from our raw material suppliers and other sources believed to be
reliable. THIS DATA DOES NOT CONSTITUTE A GUARANTEE (EXPRESSED OR IMPLIED), WARRANTY
(INCLUDING WARRANTY WITHOUT LIMITATION, MERCHANT ABILITY OR FITNESS FOR A PARTICULAR
PURPOSE) OR REPRESENTATION (INCLUDING FREEDOM FROM PATENT LIABILITY) BY US WITH RESPECT TO
THE DATA, THE PRODUCT DESCRIBED OR ITS USE FOR ANY SPECIFIC PURPOSE, EVEN IF THAT PURPOSE IS
KNOW TO US. WE DISCLAIM LIABILITY FOR DAMAGE OR INJURY INCURRING DIRECTLY OR INDIRECTLY
FROM THE USE OF THIS PRODUCT.
Edward R. Fyfe
APPROVED AND AUTHORIZED BY:
|